ABCDEFGHIJKLMNOPQRSTUVWXYZAAABACADAEAFAGAHAIAJAKALAMANAOAPAQARASATAUAVAWAXAYAZBABBBCBDBEBFBGBHBIBJBKBLBMBNBOBPBQBRBSBTBUBVBWBXBYBZCACBCCCDCECFCGCHCICJCKCLCMCNCOCPCQCRCSCTCUCVCWCXCYCZDADBDCDDDEDF
1
ID
Added date
AID
Added by
DOI_short
Topic
photochem
electrochem
ONHDOI
Link
Citation
Citation_list
Year
Reaction SchemeConditionExperiment sectionMechanism
note on photocatalyst
Ligand ImagePC (Photocatalyst) ImageAdditional FigureNoteR1R2RoleLVG1LVG1 Figure
(Auto)
RG1LVG2LVG2 Figure
(Auto)
RG2Wave length (for Photochemistry)Second Metal (for Photochemistry)Potential different (For Electrochemistry)Ligand 1Ligand 1 figure (auto)Ligand 2Ligand 2 figure (auto)Ligand 3Ligand 3 figure (auto)TempBase 1Base 2AcidSalt
Solvent 1
Solvent 2
Solvent 3Main Sol
Reductant
AdditiveOtherProposed MechanismLigand 1 Sub ClassLigand Sub Class 2Ligand 1 ClassCoupling TypeLV Group 1 bond strengthLV Group 1 ClassLV Group 1 Sub ClassLV Group 2 ClassRG1 HBDRG2 HBDRCT1RCT2RCT1_dRCT1_d2RCT2_dRCT2_d2Sol ClassSol dielectric constantBase ClassBase_type_1Base Sub Class 2
LVG1C_level
LVG1_sub_ClassJournalRLM_Ee_hammette_p
base_B1
base_B5
base_Bbase_L
base_pka
nu_pkanu_p
nu_TPSA
nu_B1nu_B5nu_Bnu_Le_spnu_sp
nu_CNMR
image_url
LVG1_smiLVG2_smiRG1_smiRG2_smiRG1_smi_revRG2_smi_revLigand_smiBase_smiSolvent_smi
2
110/31/2021292
Long
jacs.7b06191
C-N Activation
x10.1021/jacs.7b061912017
With a practical catalyst system identified for the model
reaction of 1a with PhBpin, we next evaluated carboacylation reactions of 1a with a broad range of arylboronic acid
pinacol esters (ArBpin) (Scheme 2). The carboacylation of 1a
with a range of para-substituted, electron-rich ArBpin reagents generated ketones 2b-e in good-to-excellent yields
(78-99%). The reaction of 1a with para-substituted electrondeficient ArBpin reagents formed indanones 2f-2j in moderate-to-high yields (54-85%). The carboacylation of 1a with
ArBpin compounds containing electron-donating groups at
the meta-position formed ketones 2k-2l in 85-99% yield,
while meta-halogenated ArBpin compunds reacted with 1a
to form 2m-2n in 54-67% yield. Reactions of ArBpin reagents containing electron-donating groups at the ortho-position with 1a were also possible and generated the carboacylation products 2o and 2p in 50% and 90% yield. However,
reactions of 1a with ortho-halogenated ArBpin reagents did
not occur under our reaction conditions. The scope of alkene
carboacylation is not limited to substituted ArBpin compounds but also includes boronic acid pinacol esters of polycyclic arenes and heteroarenes. The carboacylation reactions of 1a with heteroarylboronic acid pinacol esters formed
ketone products 2r-2s in 63-88% yields. Reactions of 1a
with arylboronic acids and alkylboronic acid pinacol esters
did not occur under our standard reaction conditions.
13E-NuN(Bn)Boc
CarbonylBpin
ArylSIPr
#N/A#N/A60K3PO4THFTHFNHCCarbeneCarbeneCsp2-Csp2_arNN(Bn)BocBCsp2Csp2_arCsp2-NCsp2_ar-BCarbonyl-N[Carbonyl]-N(Bn)BocAryl-Bpin[Aryl]-BpinPolar7.58Ionic-PO4K+#N/A#N/A
J AM CHEM SOC
_2.244780372.9696246982.6072025343.5700586912.37#REF!24.0118.463.1465845953.9827799333.5646822646.55194167#REF!#REF!131.5N(C(=O)OC(C)(C)(C))C(C1=CC=CC=C1)[B](OC1(C)(C))OC1(C)(C)CC(=O)CC1=CC=CC=C1C(=O)CCC1=CC=CC=C1CC(C)c1cccc(C(C)C)c1N2[C]N(CC2)c3c(cccc3C(C)C)C(C)C[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1CCOC1
3
210/31/2021292
Long
jacs.7b06191
C-N Activation
x10.1021/jacs.7b061912017
13E-NuN(Bn)Boc
CarbonylBPin
ArylSIPr
#N/A#N/A60K3PO4THFTHFNHCCarbeneCarbeneCsp2-Csp2_arNN(Bn)BocBCsp2Csp2_arCsp2-NCsp2_ar-BCarbonyl-N[Carbonyl]-N(Bn)BocAryl-BPin[Aryl]-BPinPolar7.58Ionic-PO4K+#N/A#N/A
J AM CHEM SOC
_2.244780372.9696246982.6072025343.5700586912.37#REF!24.0118.463.1465845953.9827799333.5646822646.55194167#REF!#REF!131.5N(C(=O)OC(C)(C)(C))C(C1=CC=CC=C1)[B](OC1(C)(C))OC1(C)(C)CC(=O)CC1=CC=CC=C1C(=O)CCC1=CC=CC=C1CC(C)c1cccc(C(C)C)c1N2[C]N(CC2)c3c(cccc3C(C)C)C(C)C[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1CCOC1
4
310/31/202143
Long
acscatal.0c00246
C-N Activation
x10.1021/acscatal.0c002462020
12E-EIm
CarbonylBr
Arylbpy
#N/A#N/A60DMFDMFZnZnBrUniqueN-NbpyNitrogenCsp2-Csp2_arE-HNImXCsp2Csp2_arCsp2-NCsp2_ar-XCarbonyl-N[Carbonyl]-ImAryl-Br[Aryl]-BrPolar36.7No baseNo BaseNo base#N/A#N/A
ACS CATAL
_#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XN1C=CN=C1BrCC(=O)CC1=CC=CC=C1C(=O)CCC1=CC=CC=C1C1(C2=NC=CC=C2)=CC=CC=N1#N/ACN(C)C=O
5
410/31/202143
Long
acscatal.0c00246
C-N Activation
x10.1021/acscatal.0c002462020
Im is Imidazole12E-EIm
CarbonylBr
Arylbpy
#N/A#N/A60DMFDMFZnUniqueN-NbpyNitrogenCsp2-Csp2_arE-HNImXCsp2Csp2_arCsp2-NCsp2_ar-XCarbonyl-N[Carbonyl]-ImAryl-Br[Aryl]-BrPolar36.7No baseNo BaseNo base#N/A#N/A
ACS CATAL
_#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XN1C=CN=C1BrCC(=O)CC1=CC=CC=C1C(=O)CCC1=CC=CC=C1C1(C2=NC=CC=C2)=CC=CC=N1#N/ACN(C)C=O
6
510/31/202143
Long
acscatal.0c00246
C-N Activation
x10.1021/acscatal.0c002462020
Im is Imidazole13E-EIm
CarbonylBr
Aryl4,4'-Dimethoxy-2,2'-bipyridine
#N/A#N/ArtMgCl2THFDMFDMFZnUniqueN-NbpyNitrogenCsp2-Csp2_arE-HNImXCsp2Csp2_arCsp2-NCsp2_ar-XCarbonyl-N[Carbonyl]-ImAryl-Br[Aryl]-BrPolar36.7#N/ANo Base#N/A#N/A#N/A
ACS CATAL
_#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XN1C=CN=C1BrCC(=O)CC1=CC=CC=C1C(=O)CCC1=CC=CC=C1COC1=CC=NC(C2=NC=CC(OC)=C2)=C1#N/AC1CCOC1
7
810/31/2021125
Shihong
acscatal.7b01058
C-O Activation
x10.1021/acscatal.7b010582017
11.5E-NuOMe
ArylAl(iBu)2
ArylICy.HCl
#N/A#N/A90NaOtButoluenetolueneunder argonNHCCarbeneCarbene
Csp2_ar-Csp2_ar
StrongOO-Csp3AlCsp2_arCsp2_arCsp2_ar-OCsp2_ar-AlAryl-O[Aryl]-O-Csp3Aryl-Al(iBu)2[Aryl]-Al(iBu)2Non-Polar2.38Ionic-OtBuNa+HardO-EDG
ACS CATALYSIS
_-0.2812.862.8589353663.2821934583.0705644124.0077900319#REF!27.6402.4811865675.826321844.1537542046.96337555#REF!#REF!128OC[Al](CC(C)C)CC(C)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1[n+]1(C2CCCCC2)cn(C3CCCCC3)cc1.[Cl-][Na]OC(C)(C)CCc1ccccc1
8
910/31/2021125
Shihong
acscatal.7b01058
C-O Activation
x10.1021/acscatal.7b010582017
11.2E-NuOMs
ArylAl(iBu)2
ArylPCy3
#N/A#N/Arttoluenetolueneunder argonPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'AlCsp2_arCsp2_arCsp2_ar-OCsp2_ar-AlAryl-O[Aryl]-O-SO2-R'Aryl-Al(iBu)2[Aryl]-Al(iBu)2Non-Polar2.38No baseNo BaseNo baseEasyOSO2-EDG
ACS CATALYSIS
_0.36#N/A#N/A#N/A#N/A#N/A#REF!27.6402.4811865675.826321844.1537542046.96337555#REF!#REF!128OS(=O)(=O)C[Al](CC(C)C)CC(C)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/ACc1ccccc1
9
1010/31/2021125
Shihong
acscatal.7b01058
C-O Activation
x10.1021/acscatal.7b010582017
11.2E-NuOTf
ArylAl(iBu)2
ArylPCy3
#N/A#N/Arttoluenetolueneunder argonPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'AlCsp2_arCsp2_arCsp2_ar-OCsp2_ar-AlAryl-O[Aryl]-O-SO2-R'Aryl-Al(iBu)2[Aryl]-Al(iBu)2Non-Polar2.38No baseNo BaseNo baseEasyOSO2-EWG
ACS CATALYSIS
_0.53#N/A#N/A#N/A#N/A#N/A#REF!27.6402.4811865675.826321844.1537542046.96337555#REF!#REF!128OS(=O)(=O)C(F)(F)F[Al](CC(C)C)CC(C)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/ACc1ccccc1
10
1110/31/2021125
Shihong
acscatal.7b01058
C-O Activation
x10.1021/acscatal.7b010582017
11.2E-NuOTs
ArylAl(iBu)2
ArylPCy3
#N/A#N/Arttoluenetolueneunder argonPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'AlCsp2_arCsp2_arCsp2_ar-OCsp2_ar-AlAryl-O[Aryl]-O-SO2-R'Aryl-Al(iBu)2[Aryl]-Al(iBu)2Non-Polar2.38No baseNo BaseNo baseEasyOSO2-EDG
ACS CATALYSIS
_0.36#N/A#N/A#N/A#N/A#N/A#REF!27.6402.4811865675.826321844.1537542046.96337555#REF!#REF!128OS(=O)(=O)(C1=CC=C(C)C=C1)[Al](CC(C)C)CC(C)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/ACc1ccccc1
11
1210/31/2021125
Shihong
acscatal.7b01058
C-O Activation
x10.1021/acscatal.7b010582017
10.75E-NuOPiv
ArylAl(iBu)2
ArylPCy3
#N/A#N/A90toluenetolueneunder argonPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
MediumOO-CO-R'AlCsp2_arCsp2_arCsp2_ar-OCsp2_ar-AlAryl-O[Aryl]-O-CO-R'Aryl-Al(iBu)2[Aryl]-Al(iBu)2Non-Polar2.38No baseNo BaseNo baseMediumOCO-EDG
ACS CATALYSIS
_0.3320.28#N/A#N/A#N/A#N/A#N/A#REF!27.6402.4811865675.826321844.1537542046.96337555#REF!#REF!128OC(=O)C(C)(C)C[Al](CC(C)C)CC(C)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/ACc1ccccc1
12
1310/31/2021125
Shihong
acscatal.7b01058
C-O Activation
x10.1021/acscatal.7b010582017
11.5E-NuOCONEt2
ArylAl(iBu)2
ArylPCy3
#N/A#N/Arttoluenetolueneunder argonPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
MediumOO-CO-R'AlCsp2_arCsp2_arCsp2_ar-OCsp2_ar-AlAryl-O[Aryl]-O-CO-R'Aryl-Al(iBu)2[Aryl]-Al(iBu)2Non-Polar2.38No baseNo BaseNo baseMediumOCO-EDG
ACS CATALYSIS
_0.3121.41#N/A#N/A#N/A#N/A#N/A#REF!27.6402.4811865675.826321844.1537542046.96337555#REF!#REF!128OC(N(CC)CC)=O[Al](CC(C)C)CC(C)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/ACc1ccccc1
13
1410/31/2021125
Shihong
acscatal.7b01058
C-O Activation
x10.1021/acscatal.7b010582017
11.5E-NuOCONEt2
ArylAl(iBu)2
VinylPCy3
#N/A#N/A90toluenetolueneunder argonPPhosphine (Monodentate)PhosphineCsp2_ar-Csp2MediumOO-CO-R'AlCsp2_arCsp2Csp2_ar-OCsp2-AlAryl-O[Aryl]-O-CO-R'Vinyl-Al(iBu)2[Vinyl]-Al(iBu)2Non-Polar2.38No baseNo BaseNo baseMediumOCO-EDG
ACS CATALYSIS
_0.3121.41#N/A#N/A#N/A#N/A#N/A#REF!XX2.4811865675.826321844.1537542046.96337555#REF!#REF!116OC(N(CC)CC)=O[Al](CC(C)C)CC(C)CC1=CC=CC=C1C=CC1=CC=CC=C1C=CC1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/ACc1ccccc1
14
1510/31/2021125
Shihong
acscatal.7b01058
C-N Activation
x10.1021/acscatal.7b010582017
11.5E-NuNMe3+OTf-
ArylAl(iBu)2
ArylPCy3
#N/A#N/A50THFTHFunder argonPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
E-HNN(+)Me3AlCsp2_arCsp2_arCsp2_ar-NCsp2_ar-AlAryl-N[Aryl]-N(+)Me3Aryl-Al(iBu)2[Aryl]-Al(iBu)2Polar7.58No baseNo BaseNo base#N/A#N/A
ACS CATALYSIS
_#N/A#N/A#N/A#N/A#N/A#REF!27.6402.4811865675.826321844.1537542046.96337555#REF!#REF!128[N+]C(C)(C).[O-]S(=O)(=O)C(F)(F)F[Al](CC(C)C)CC(C)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/AC1CCOC1
15
1611/1/202146
Gerry
acscatal.0c00393
C-H Activation
10.1021/acscatal.0c003932020
12E-NuSMe
MorpholineH
Aryldcype
#N/A#N/A100LiHMDStoluenetolueneP-PPhosphine (Bidentate)PhosphineNsp3-Csp2_arSHNsp3Csp2_arNsp3-SCsp2_ar-HMorpholine-S[Morpholine]-Aryl-H[Aryl]-HNon-Polar2.38IonicNitrogen(neutral)Li+
ACS CATAL
_#N/A1.7105540393.2426955962.4766248184.9733801926#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5SCHN1CCCCC1C1=CC=CC=C1C1CCCCC1NC1=CC=CC=C1P(C1CCCCC1)(C2CCCCC2)CCP(C3CCCCC3)C4CCCCC4[Li]N([Si](C)(C)C)[Si](C)(C)CCc1ccccc1
16
1711/1/202146
Gerry
acscatal.0c00393
C-H Activation
10.1021/acscatal.0c003932020
12E-NuSMe
N(H)ArylH
Aryldcype
#N/A#N/A100LiHMDStoluenetolueneP-PPhosphine (Bidentate)PhosphineNsp3-Csp2_arSHNsp3Csp2_arNsp3-SCsp2_ar-HN(H)Aryl-S[N(H)Aryl]-Aryl-H[Aryl]-HNon-Polar2.38IonicNitrogen(neutral)Li+
ACS CATAL
_#N/A1.7105540393.2426955962.4766248184.9733801926#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5SCHNC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1NC1=CC=CC=C1P(C1CCCCC1)(C2CCCCC2)CCP(C3CCCCC3)C4CCCCC4[Li]N([Si](C)(C)C)[Si](C)(C)CCc1ccccc1
17
1811/1/2021202
Kelly
acscatal.7b01044
C-H Activation
x10.1021/acscatal.7b010442017
130Nu-NuH
HetH
Het2-(Diethylamino)-N-(8-quinolinyl)acetamide
#N/A#N/A150LiOtBuLiHMDS2-iodobutane
2-iodobutane
N-N-NPy-N-NNitrogen
Csp2_ar-Csp2_ar
Nu-HHHCsp2_arCsp2_arCsp2_ar-HCsp2_ar-HHet-H[Het]-Het-H[Het]-HNon-Polar6.35Ionic-OtBuLi+
ACS CATAL
_2.8589353663.2821934583.0705644124.0077900319#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8HHC1=NC=CC=C1C1=NC=CC=C1C1=CC=NC=C1C1=CC=NC=C1CCN(CC)CC(NC1=C(N=CC=C2)C2=CC=C1)=OCC(C)(C)[O-].[Li+]CCC(C)I
18
1911/1/2021202
Kelly
acscatal.7b01044
C-H Activation
x10.1021/acscatal.7b010442017
With the optimized reaction conditions in hand,
the benzylation of various indoles was examined either in neat
condition (using 30 equiv of toluene derivatives) or employing
10 equiv of chlorobenzene in addition to toluene derivatives,
130Nu-NuH
HetH
Het2-(Diethylamino)-N-(8-quinolinyl)acetamide
#N/A#N/A150LiOtBuLiHMDS2-iodobutane
2-iodobutane
N-N-NPy-N-NNitrogen
Csp2_ar-Csp2_ar
Nu-HHHCsp2_arCsp2_arCsp2_ar-HCsp2_ar-HHet-H[Het]-Het-H[Het]-HNon-Polar6.35Ionic-OtBuLi+
ACS CATAL
_2.8589353663.2821934583.0705644124.0077900319#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8HHC1=NC=CC=C1C1=NC=CC=C1C1=CC=NC=C1C1=CC=NC=C1CCN(CC)CC(NC1=C(N=CC=C2)C2=CC=C1)=OCC(C)(C)[O-].[Li+]CCC(C)I
19
2011/1/202154
Long
anie.201712693
C-H Activation
x10.1002/anie.2017126932018
12Nu-NuH
VinylH
Vinyl1,3-bis(2,4-dimethylphenyl)-2H-imidazole
#N/A#N/ArttoluenetolueneNHCCarbeneCarbeneCsp2-Csp2Nu-HHHCsp2Csp2Csp2-HCsp2-HVinyl-H[Vinyl]-Vinyl-H[Vinyl]-HNon-Polar2.38No baseNo BaseNo base
ANGEW CHEM INT EDIT
_#N/A#N/A#N/A#N/A#N/A#REF!6.0701.706749553.2392069642.4729782574.96639928#REF!#REF!115.6HHC=CC=CC=CC=CCC1=CC(C)=CC=C1N2CN(C3=C(C)C=C(C)C=C3)C=C2#N/ACc1ccccc1
20
2111/1/2021193
Long
acscatal.6b02003
C-H Activation
x10.1021/acscatal.6b020032016
unClear about X12E-NuX
AlkylH
Het2-(diethylamino)-N-(quinolin-8-yl)acetamide
#N/A#N/A150LiOtButoluenetolueneN-N-NPy-N-NNitrogenCsp3-Csp2_arXHCsp3Csp2_arCsp3-XCsp2_ar-HAlkyl-X[Alkyl]-Het-H[Het]-HNon-Polar2.38Ionic-OtBuLi+
ACS CATAL
_2.8589353663.2821934583.0705644124.0077900319#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8ClHCCC1=NC=CC=C1CCC1=CC=NC=C1O=C(NC1=C(N=CC=C2)C2=CC=C1)CN(CC)CCCC(C)(C)[O-].[Li+]Cc1ccccc1
21
2211/1/2021193
Long
acscatal.6b02003
C-H Activation
x10.1021/acscatal.6b020032016
NaNaE-NuBr
AlkylH
Het2-(diethylamino)-N-(quinolin-8-yl)acetamide
#N/A#N/A150LiOtButoluenetolueneN-N-NPy-N-NNitrogenCsp3-Csp2_arXHCsp3Csp2_arCsp3-XCsp2_ar-HAlkyl-X[Alkyl]-Het-H[Het]-HNon-Polar2.38Ionic-OtBuLi+
ACS CATAL
_2.8589353663.2821934583.0705644124.0077900319#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8BrHCCC1=NC=CC=C1CCC1=CC=NC=C1O=C(NC1=C(N=CC=C2)C2=CC=C1)CN(CC)CCCC(C)(C)[O-].[Li+]Cc1ccccc1
22
2311/1/2021193
Long
acscatal.6b02003
C-H Activation
x10.1021/acscatal.6b020032016
NaNaE-NuBr
HetH
Het2-(diethylamino)-N-(quinolin-8-yl)acetamide
#N/A#N/A150LiOtButoluenetolueneN-N-NPy-N-NNitrogen
Csp2_ar-Csp2_ar
XHCsp2_arCsp2_arCsp2_ar-XCsp2_ar-HHet-X[Het]-Het-H[Het]-HNon-Polar2.38Ionic-OtBuLi+
ACS CATAL
_2.8589353663.2821934583.0705644124.0077900319#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8BrHC1=NC=CC=C1C1=NC=CC=C1C1=CC=NC=C1C1=CC=NC=C1O=C(NC1=C(N=CC=C2)C2=CC=C1)CN(CC)CCCC(C)(C)[O-].[Li+]Cc1ccccc1
23
2411/1/202130
Long
acscatal.1c01626
C-H Activation
x10.1021/acscatal.1c016262021
dual cat11.13Nu-NuH
VinylH
AlkylC[C@H](C12=C(C3C4=C25P(C6=CC=CC=C6)C7=CC=CC=C7)[Fe]189%10%11345C%12C8=C9C%10=C%12%11)P(C(C)(C)C)C(C)(C)C
#N/A#N/A60DIPEATHFTHFP-PPhosphine (Bidentate)PhosphineCsp2-Csp3Nu-HHHCsp2Csp3Csp2-HCsp3-HVinyl-H[Vinyl]-Alkyl-H[Alkyl]-HPolar7.58NitrogenNitrogen(neutral)Nitrogen(neutral)
ACS CATAL
_1.7105540393.2426955962.4766248184.9733801910.75#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5HHC=CCCC=CCCC[C@H](C12=C(C3C4=C25P(C6=CC=CC=C6)C7=CC=CC=C7)[Fe]189%10%11345C%12C8=C9C%10=C%12%11)P(C(C)(C)C)C(C)(C)CCCN(C(C)C)C(C)CC1CCOC1
24
2511/1/202130
Long
acscatal.1c01626
C-H Activation
x10.1021/acscatal.1c016262021
dual cat11.13Nu-NuH
VinylH
AlkylC[C@H](C12=C(C3C4=C25P(C6=CC=CC=C6)C7=CC=CC=C7)[Fe]189%10%11345C%12C8=C9C%10=C%12%11)P(C(C)(C)C)C(C)(C)C
#N/A#N/A60DIPEATHFTHFP-PPhosphine (Bidentate)PhosphineCsp2-Csp3Nu-HHHCsp2Csp3Csp2-HCsp3-HVinyl-H[Vinyl]-Alkyl-H[Alkyl]-HPolar7.58NitrogenNitrogen(neutral)Nitrogen(neutral)
ACS CATAL
_1.7105540393.2426955962.4766248184.9733801910.75#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5HHC=CCCC=CCCC[C@H](C12=C(C3C4=C25P(C6=CC=CC=C6)C7=CC=CC=C7)[Fe]189%10%11345C%12C8=C9C%10=C%12%11)P(C(C)(C)C)C(C)(C)CCCN(C(C)C)C(C)CC1CCOC1
25
2611/1/202130
Long
acscatal.1c01626
C-H Activation
x10.1021/acscatal.1c016262021
dual cat11.13Nu-NuH
VinylH
AlkylC[C@H](C12=C(C3C4=C25P(C6=CC=CC=C6)C7=CC=CC=C7)[Fe]189%10%11345C%12C8=C9C%10=C%12%11)P(C(C)(C)C)C(C)(C)C
#N/A#N/A60DIPEATHFTHFP-PPhosphine (Bidentate)PhosphineCsp2-Csp3Nu-HHHCsp2Csp3Csp2-HCsp3-HVinyl-H[Vinyl]-Alkyl-H[Alkyl]-HPolar7.58NitrogenNitrogen(neutral)Nitrogen(neutral)
ACS CATAL
_1.7105540393.2426955962.4766248184.9733801910.75#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5HHC=CCCC=CCCC[C@H](C12=C(C3C4=C25P(C6=CC=CC=C6)C7=CC=CC=C7)[Fe]189%10%11345C%12C8=C9C%10=C%12%11)P(C(C)(C)C)C(C)(C)CCCN(C(C)C)C(C)CC1CCOC1
26
2711/1/2021228
Gerry
ja505823s
C-N Activation
x10.1021/ja505823s2014
ring opening13E-NuN(Ring-Opening)
AlkylZnX
AlkylMe4phen
#N/A#N/A26DCETHFTHFNi(0)/Ni(II)N-NbpyNitrogenCsp3-Csp3N
N(Ring-Opening)
ZnCsp3Csp3Csp3-NCsp3-ZnAlkyl-N[Alkyl]-N(Ring-Opening)Alkyl-ZnX[Alkyl]-ZnXPolar7.58No baseNo BaseNo base#N/A#N/A
J AM CHEM SOC
_#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XNC[Zn]ClCCCCCCCCCC1=C(C)C=NC2=C1C=CC3=C2N=CC(C)=C3C#N/AClCCCl
27
2811/1/2021228
Gerry
ja505823s
C-N Activation
x10.1021/ja505823s2014
ring opening13E-NuN(Ring-Opening)
AlkylZnX
AlkylMe4phen
#N/A#N/A26DCETHFTHFNi(0)/Ni(II)N-NbpyNitrogenCsp3-Csp3N
N(Ring-Opening)
ZnCsp3Csp3Csp3-NCsp3-ZnAlkyl-N[Alkyl]-N(Ring-Opening)Alkyl-ZnX[Alkyl]-ZnXPolar7.58No baseNo BaseNo base#N/A#N/A
J AM CHEM SOC
_#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XNC[Zn]ClCCCCCCCCCC1=C(C)C=NC2=C1C=CC3=C2N=CC(C)=C3C#N/AClCCCl
28
2911/1/2021228
Gerry
ja505823s
C-N Activation
x10.1021/ja505823s2014
ring opening13E-NuN(Ring-Opening)
AlkylZnX
Alkylphen
#N/A#N/A35LiClDCEDMADCENi(0)/Ni(II)N-NbpyNitrogenCsp3-Csp3N
N(Ring-Opening)
ZnCsp3Csp3Csp3-NCsp3-ZnAlkyl-N[Alkyl]-N(Ring-Opening)Alkyl-ZnX[Alkyl]-ZnXPolar10.36No baseNo BaseNo base#N/A#N/A
J AM CHEM SOC
_#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XNC[Zn]ClCCCCCCCCC1(C(N=CC=C2)=C2C=C3)=C3C=CC=N1#N/AClCCCl
29
3011/1/202144
Gerry
acscatal.0c01356
C-N Activation
xx10.1021/acscatal.0c013562020
temp1.21E-NuN(Me)Ph
AlkylH
Alkyl(S)-tol-MeO-BIPHEP
#N/A#N/A40-80Et2OEt2ONi(0)/Ni(II)P-PPhosphine (Bidentate)PhosphineCsp3-Csp3NN(Ph)AlkylHCsp3Csp3Csp3-NCsp3-HAlkyl-N[Alkyl]-N(Ph)AlkylAlkyl-H[Alkyl]-HNon-Polar4.33No baseNo BaseNo base#N/A#N/A
ACS CATAL
_#N/A#N/A#N/A#N/A#N/A#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5N(C1=CC=CC=C1)HCCCCCCCCCOC1=CC=CC(P(C2=CC=CC=C2)C3=CC=CC=C3)=[C@]1[C@]4=C(C=CC=C4P(C5=CC=CC=C5)C6=CC=CC=C6)OC#N/ACCOCC
30
3111/1/202144
Gerry
acscatal.0c01356
C-N Activation
xx10.1021/acscatal.0c013562020
?1.21E-NuN(Me)Ph
AlkylH
Alkyl(S)-tol-MeO-BIPHEP
#N/A#N/A0Et2OEt2ONi(0)/Ni(II)P-PPhosphine (Bidentate)PhosphineCsp3-Csp3NN(Ph)AlkylHCsp3Csp3Csp3-NCsp3-HAlkyl-N[Alkyl]-N(Ph)AlkylAlkyl-H[Alkyl]-HNon-Polar4.33No baseNo BaseNo base#N/A#N/A
ACS CATAL
_#N/A#N/A#N/A#N/A#N/A#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5N(C1=CC=CC=C1)HCCCCCCCCCOC1=CC=CC(P(C2=CC=CC=C2)C3=CC=CC=C3)=[C@]1[C@]4=C(C=CC=C4P(C5=CC=CC=C5)C6=CC=CC=C6)OC#N/ACCOCC
31
3211/1/2021398
Kelly
nature14615
C-N Activation
x10.1038/nature146152015
R=Bn11.2E-NuN(Bn)Boc
CarbonylH
ORSIPr
#N/A#N/A80toluenetolueneNi(0)/Ni(II)NHCCarbeneCarbeneCsp2-Osp2NN(Bn)BocHCsp2Osp2Csp2-NOsp2-HCarbonyl-N[Carbonyl]-N(Bn)BocOR-H[OR]-HNon-Polar2.38No baseNo BaseNo base#N/A#N/ANATURE_#N/A#N/A#N/A#N/A#N/A#REF!3.2120.231.706749553.2392069642.4729782574.96639928#REF!#REF!N(C(=O)OC(C)(C)(C))C(C1=CC=CC=C1)HCC(=O)COC(=O)CCOCC(C)c1cccc(C(C)C)c1N2[C]N(CC2)c3c(cccc3C(C)C)C(C)C#N/ACc1ccccc1
32
3311/1/2021398
Kelly
nature14615
C-N Activation
x10.1038/nature146152015
R=Me11.2E-NuN(Bn)Boc
CarbonylH
ORSIPr
#N/A#N/A80toluenetolueneNi(0)/Ni(II)NHCCarbeneCarbeneCsp2-Osp2NN(Bn)BocHCsp2Osp2Csp2-NOsp2-HCarbonyl-N[Carbonyl]-N(Bn)BocOR-H[OR]-HNon-Polar2.38No baseNo BaseNo base#N/A#N/ANATURE_#N/A#N/A#N/A#N/A#N/A#REF!3.2120.231.706749553.2392069642.4729782574.96639928#REF!#REF!N(C(=O)OC(C)(C)(C))C(C1=CC=CC=C1)HCC(=O)COC(=O)CCOCC(C)c1cccc(C(C)C)c1N2[C]N(CC2)c3c(cccc3C(C)C)C(C)C#N/ACc1ccccc1
33
3411/1/2021398
Kelly
nature14615
C-N Activation
x10.1038/nature146152015
11.2E-NuN(Bn)Boc
CarbonylH
ORSIPr
#N/A#N/A80toluenetolueneNi(0)/Ni(II)NHCCarbeneCarbeneCsp2-Osp2NN(Bn)BocHCsp2Osp2Csp2-NOsp2-HCarbonyl-N[Carbonyl]-N(Bn)BocOR-H[OR]-HNon-Polar2.38No baseNo BaseNo base#N/A#N/ANATURE_#N/A#N/A#N/A#N/A#N/A#REF!3.2120.231.706749553.2392069642.4729782574.96639928#REF!#REF!N(C(=O)OC(C)(C)(C))C(C1=CC=CC=C1)HCC(=O)COC(=O)CCOCC(C)c1cccc(C(C)C)c1N2[C]N(CC2)c3c(cccc3C(C)C)C(C)C#N/ACc1ccccc1
34
3511/1/2021398
Kelly
nature14615
C-N Activation
x10.1038/nature146152015
11.5E-NuN(Me)Ph
CarbonylH
ORSIPr
#N/A#N/A80toluenetolueneNi(0)/Ni(II)NHCCarbeneCarbeneCsp2-Osp2NN(Ph)AlkylHCsp2Osp2Csp2-NOsp2-HCarbonyl-N[Carbonyl]-N(Ph)AlkylOR-H[OR]-HNon-Polar2.38No baseNo BaseNo base#N/A#N/ANATURE_#N/A#N/A#N/A#N/A#N/A#REF!3.2120.231.706749553.2392069642.4729782574.96639928#REF!#REF!N(C1=CC=CC=C1)HCC(=O)COC(=O)CCOCC(C)c1cccc(C(C)C)c1N2[C]N(CC2)c3c(cccc3C(C)C)C(C)C#N/ACc1ccccc1
35
3611/1/2021321
Kelly
anie.201607856
C-N Activation
x10.1002/anie.2016078562016
11.25E-NuN(Bn)Boc
CarbonylH
ORterpyridine
#N/A#N/A100toluenetolueneN-N-NterpyNitrogenCsp2-Osp2NN(Bn)BocHCsp2Osp2Csp2-NOsp2-HCarbonyl-N[Carbonyl]-N(Bn)BocOR-H[OR]-HNon-Polar2.38No baseNo BaseNo base#N/A#N/A
ANGEW CHEM INT EDIT
_#N/A#N/A#N/A#N/A#N/A#REF!3.2120.231.706749553.2392069642.4729782574.96639928#REF!#REF!N(C(=O)OC(C)(C)(C))C(C1=CC=CC=C1)HCC(=O)COC(=O)CCOc1ccnc(c1)c2cccc(n2)c3ccccn3#N/ACc1ccccc1
36
3711/1/2021321
Kelly
anie.201607856
C-N Activation
x10.1002/anie.2016078562016
11.25E-NuN(Bn)Boc
CarbonylH
ORterpyridine
#N/A#N/A100toluenetolueneN-N-NterpyNitrogenCsp2-Osp2NN(Bn)BocHCsp2Osp2Csp2-NOsp2-HCarbonyl-N[Carbonyl]-N(Bn)BocOR-H[OR]-HNon-Polar2.38No baseNo BaseNo base#N/A#N/A
ANGEW CHEM INT EDIT
_#N/A#N/A#N/A#N/A#N/A#REF!3.2120.231.706749553.2392069642.4729782574.96639928#REF!#REF!N(C(=O)OC(C)(C)(C))C(C1=CC=CC=C1)HCC(=O)COC(=O)CCOc1ccnc(c1)c2cccc(n2)c3ccccn3#N/ACc1ccccc1
37
3811/1/2021321
Kelly
anie.201607856
C-N Activation
x10.1002/anie.2016078562016
11.25E-NuN(Bn)Boc
CarbonylH
Alkylterpyridine
#N/A#N/A100toluenetolueneN-N-NterpyNitrogenCsp2-Csp3NN(Bn)BocHCsp2Csp3Csp2-NCsp3-HCarbonyl-N[Carbonyl]-N(Bn)BocAlkyl-H[Alkyl]-HNon-Polar2.38No baseNo BaseNo base#N/A#N/A
ANGEW CHEM INT EDIT
_#N/A#N/A#N/A#N/A#N/A#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5N(C(=O)OC(C)(C)(C))C(C1=CC=CC=C1)HCC(=O)CCCC(=O)CCCCc1ccnc(c1)c2cccc(n2)c3ccccn3#N/ACc1ccccc1
38
3911/1/2021252
Long
ncomms12937
C-N Activation
x10.1038/ncomms129372016
NA11.1E-NuNMe3+OTf-
ArylSnMe3
ArylIcy
#N/A#N/A80dioxanedioxaneNi(0)/Ni(II)NHCCarbeneCarbene
Csp2_ar-Csp2_ar
E-HNN(+)Me3SnCsp2_arCsp2_arCsp2_ar-NCsp2_ar-SnAryl-N[Aryl]-N(+)Me3Aryl-SnMe3[Aryl]-SnMe3Polar2.25No baseNo BaseNo base#N/A#N/A
NAT COMMUN
_#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!X[N+]C(C)(C).[O-]S(=O)(=O)C(F)(F)F[Sn]C(C)(C)C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1N1(C2CCCCC2)C=CN(C3CCCCC3)[C]1#N/AC1COCCO1
39
4011/1/2021148
Long
jacs.9b05224
C-N Activation
xx10.1021/jacs.9b052242019
12E-ENMe3+OTf-
VinylOAc
BenzylBPhen
#N/A#N/A80NaOAcDMFDMFMnN-NbpyNitrogen
Csp2-Csp3-ring(s)
E-HNN(+)Me3OCsp2Csp3-ring(s)Csp2-NCsp3-ring(s)-OVinyl-N[Vinyl]-N(+)Me3Benzyl-OAc[Benzyl]-OAcPolar36.7Ionic-ORNa+#N/A#N/A
J AM CHEM SOC
_04.76#REF!0#REF!#REF!X[N+]C(C)(C).[O-]S(=O)(=O)C(F)(F)FOC(C)=OC=CCC1=CC=CC=C1C=CCC1=CC=CC=C1C1(C2=CC=CC=C2)=CC=NC3=C1C=CC4=C3N=CC=C4C5=CC=CC=C5[O-]C(C)=O.[Na]CN(C)C=O
40
4111/1/2021148
Long
jacs.9b05224
C-N Activation
x x10.1021/jacs.9b052242019
12E-ENMe3+OTf-
VinylOAc
BenzylBPhen
#N/A#N/A80NaOAcDMFDMFMnN-NbpyNitrogen
Csp2-Csp3-ring(s)
E-HNN(+)Me3OCsp2Csp3-ring(s)Csp2-NCsp3-ring(s)-OVinyl-N[Vinyl]-N(+)Me3Benzyl-OAc[Benzyl]-OAcPolar36.7Ionic-ORNa+#N/A#N/A
J AM CHEM SOC
_04.76#REF!0#REF!#REF!X[N+]C(C)(C).[O-]S(=O)(=O)C(F)(F)FOC(C)=OC=CCC1=CC=CC=C1C=CCC1=CC=CC=C1C1(C2=CC=CC=C2)=CC=NC3=C1C=CC4=C3N=CC=C4C5=CC=CC=C5[O-]C(C)=O.[Na]CN(C)C=O
41
4211/1/2021148
Long
jacs.9b05224
C-N Activation
xx10.1021/jacs.9b052242019
see table 112E-ENMe3+OTf-
ArylOTf
BenzylBPhen
#N/A#N/A80NaOAcDMFDMFMnN-NbpyNitrogen
Csp2_ar-Csp3-ring(s)
E-HNN(+)Me3OCsp2_arCsp3-ring(s)Csp2_ar-NCsp3-ring(s)-OAryl-N[Aryl]-N(+)Me3Benzyl-OTf[Benzyl]-OTfPolar36.7Ionic-ORNa+#N/A#N/A
J AM CHEM SOC
_04.76#REF!0#REF!#REF!X[N+]C(C)(C).[O-]S(=O)(=O)C(F)(F)FOS(=O)(=O)C(F)(F)FC1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1C1(C2=CC=CC=C2)=CC=NC3=C1C=CC4=C3N=CC=C4C5=CC=CC=C5[O-]C(C)=O.[Na]CN(C)C=O
42
4311/1/2021359
Long
jacs.7b02389
C-N Activation
x10.1021/jacs.7b023892017
BPhen
Not Clear13E-NuTriphenylpyridinium+BF4-
AlkylB(OH)2
Arylbphen
#N/A#N/A60KOtBuEtOHdioxanedioxaneNi(I)/Ni(III)N-NbpyNitrogenCsp3-Csp2_arNPyridiniumBCsp3Csp2_arCsp3-NCsp2_ar-BAlkyl-N[Alkyl]-PyridiniumAryl-B(OH)2[Aryl]-B(OH)2Polar2.25Ionic-OtBuK+#N/A#N/A
J AM CHEM SOC
_2.8589353663.2821934583.0705644124.0077900319#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6[N+]1=C(C=C(C=C1C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.F[B-](F)(F)FB(O)OCCC1=CC=CC=C1CCC1=CC=CC=C1C1(C2=CC=CC=C2)=CC=NC3=C1C=CC4=C3N=CC=C4C5=CC=CC=C5CC(C)(C)[O-].[K+]OCC
43
4411/1/2021359
Long
jacs.7b02389
C-N Activation
x10.1021/jacs.7b023892017
Scheme 3BPhen13E-NuTriphenylpyridinium+BF4-
AlkylB(OH)2
Arylbphen
#N/A#N/A60KOtBuEtOHdioxanedioxaneNi(I)/Ni(III)N-NbpyNitrogenCsp3-Csp2_arNPyridiniumBCsp3Csp2_arCsp3-NCsp2_ar-BAlkyl-N[Alkyl]-PyridiniumAryl-B(OH)2[Aryl]-B(OH)2Polar2.25Ionic-OtBuK+#N/A#N/A
J AM CHEM SOC
_2.8589353663.2821934583.0705644124.0077900319#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6[N+]1=C(C=C(C=C1C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.F[B-](F)(F)FB(O)OCCC1=CC=CC=C1CCC1=CC=CC=C1C1(C2=CC=CC=C2)=CC=NC3=C1C=CC4=C3N=CC=C4C5=CC=CC=C5CC(C)(C)[O-].[K+]OCC
44
4511/1/2021359
Long
jacs.7b02389
C-N Activation
x10.1021/jacs.7b023892017
Scheme 313E-NuTriphenylpyridinium+BF4-
AlkylB(OH)2
Arylbphen
#N/A#N/A60KOtBuEtOHdioxanedioxaneNi(I)/Ni(III)N-NbpyNitrogenCsp3-Csp2_arNPyridiniumBCsp3Csp2_arCsp3-NCsp2_ar-BAlkyl-N[Alkyl]-PyridiniumAryl-B(OH)2[Aryl]-B(OH)2Polar2.25Ionic-OtBuK+#N/A#N/A
J AM CHEM SOC
_2.8589353663.2821934583.0705644124.0077900319#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6[N+]1=C(C=C(C=C1C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.F[B-](F)(F)FB(O)OCCC1=CC=CC=C1CCC1=CC=CC=C1C1(C2=CC=CC=C2)=CC=NC3=C1C=CC4=C3N=CC=C4C5=CC=CC=C5CC(C)(C)[O-].[K+]OCC
45
4611/1/2021372
Long
ja3089422
C-N Activation
x10.1021/ja30894222013
CsF as base11.2E-NuNMe3+OTf-
HetB(OH)2
ArylPPh2Cy
#N/A#N/A40CsFdioxanedioxaneNi(0)/Ni(II)PPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
E-HNN(+)Me3BCsp2_arCsp2_arCsp2_ar-NCsp2_ar-BHet-N[Het]-N(+)Me3Aryl-B(OH)2[Aryl]-B(OH)2Polar2.25Ionic-FCs+#N/A#N/A
J AM CHEM SOC
_03.14#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6[N+]C(C)(C).[O-]S(=O)(=O)C(F)(F)FB(O)OC1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1C1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3CCCCC3[Cs]FC1COCCO1
46
4711/1/2021372
Long
ja3089422
C-N Activation
x10.1021/ja30894222013
K3PO4 as base11.2E-NuNMe3+OTf-
HetB(OH)2
HetPPh2Cy
#N/A#N/A40K3PO4dioxanedioxaneNi(0)/Ni(II)PPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
E-HNN(+)Me3BCsp2_arCsp2_arCsp2_ar-NCsp2_ar-BHet-N[Het]-N(+)Me3Het-B(OH)2[Het]-B(OH)2Polar2.25Ionic-PO4K+#N/A#N/A
J AM CHEM SOC
_2.244780372.9696246982.6072025343.5700586912.37#REF!12.6451.351.923.2525052362.5862526186.55955503#REF!#REF!150[N+]C(C)(C).[O-]S(=O)(=O)C(F)(F)FB(O)OC1=NC=CC=C1C1=NC=CC=C1C1=CC=NC=C1C1=CC=NC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1COCCO1
47
4811/1/2021372
Long
ja3089422
C-N Activation
x10.1021/ja30894222013
CsF as base11.2E-NuNMe3+OTf-
ArylB(OH)2
ArylPPh2Cy
#N/A#N/A40CsFdioxanedioxaneNi(0)/Ni(II)PPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
E-HNN(+)Me3BCsp2_arCsp2_arCsp2_ar-NCsp2_ar-BAryl-N[Aryl]-N(+)Me3Aryl-B(OH)2[Aryl]-B(OH)2Polar2.25Ionic-FCs+#N/A#N/A
J AM CHEM SOC
_03.14#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6[N+]C(C)(C).[O-]S(=O)(=O)C(F)(F)FB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3CCCCC3[Cs]FC1COCCO1
48
4911/1/2021372
Long
ja3089422
C-N Activation
x10.1021/ja30894222013
K3PO4 as base11.2E-NuNMe3+OTf-
ArylB(OH)2
HetPPh2Cy
#N/A#N/A40K3PO4dioxanedioxaneNi(0)/Ni(II)PPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
E-HNN(+)Me3BCsp2_arCsp2_arCsp2_ar-NCsp2_ar-BAryl-N[Aryl]-N(+)Me3Het-B(OH)2[Het]-B(OH)2Polar2.25Ionic-PO4K+#N/A#N/A
J AM CHEM SOC
_2.244780372.9696246982.6072025343.5700586912.37#REF!12.6451.351.923.2525052362.5862526186.55955503#REF!#REF!150[N+]C(C)(C).[O-]S(=O)(=O)C(F)(F)FB(O)OC1=CC=CC=C1C1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1COCCO1
49
5011/1/2021372
Long
ja3089422
C-N Activation
x10.1021/ja30894222013
11.2E-NuNMe3+OTf-
ArylB(OH)2
ArylP(o-tol)3
#N/A#N/A70K3PO4dioxanedioxaneNi(0)/Ni(II)PPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
E-HNN(+)Me3BCsp2_arCsp2_arCsp2_ar-NCsp2_ar-BAryl-N[Aryl]-N(+)Me3Aryl-B(OH)2[Aryl]-B(OH)2Polar2.25Ionic-PO4K+#N/A#N/A
J AM CHEM SOC
_2.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6[N+]C(C)(C).[O-]S(=O)(=O)C(F)(F)FB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1CC(C=CC=C1)=C1P(C2=C(C)C=CC=C2)C3=C(C)C=CC=C3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1COCCO1
50
5111/1/2021372
Long
ja3089422
C-N Activation
x10.1021/ja30894222013
11.2E-NuNMe3+OTf-
ArylB(OH)2
HetP(o-tol)3
#N/A#N/A70K3PO4dioxanedioxaneNi(0)/Ni(II)PPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
E-HNN(+)Me3BCsp2_arCsp2_arCsp2_ar-NCsp2_ar-BAryl-N[Aryl]-N(+)Me3Het-B(OH)2[Het]-B(OH)2Polar2.25Ionic-PO4K+#N/A#N/A
J AM CHEM SOC
_2.244780372.9696246982.6072025343.5700586912.37#REF!12.6451.351.923.2525052362.5862526186.55955503#REF!#REF!150[N+]C(C)(C).[O-]S(=O)(=O)C(F)(F)FB(O)OC1=CC=CC=C1C1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1CC(C=CC=C1)=C1P(C2=C(C)C=CC=C2)C3=C(C)C=CC=C3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1COCCO1
51
5211/1/2021372
Long
ja3089422
C-N Activation
x10.1021/ja30894222013
11.2E-NuNMe3+OTf-
ArylB(OH)2
VinylP(o-tol)3
#N/A#N/A70K3PO4dioxanedioxaneNi(0)/Ni(II)PPhosphine (Monodentate)PhosphineCsp2_ar-Csp2E-HNN(+)Me3BCsp2_arCsp2Csp2_ar-NCsp2-BAryl-N[Aryl]-N(+)Me3Vinyl-B(OH)2[Vinyl]-B(OH)2Polar2.25Ionic-PO4K+#N/A#N/A
J AM CHEM SOC
_2.244780372.9696246982.6072025343.5700586912.37#REF!9.2440.461.923.2525052362.5862526186.55955503#REF!#REF!120.7[N+]C(C)(C).[O-]S(=O)(=O)C(F)(F)FB(O)OC1=CC=CC=C1C=CC1=CC=CC=C1C=CCC(C=CC=C1)=C1P(C2=C(C)C=CC=C2)C3=C(C)C=CC=C3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1COCCO1
52
5311/1/2021372
Long
ja3089422
C-N Activation
x10.1021/ja30894222013
11.2E-NuNMe3+OTf-
ArylB(OH)2
Arylt-Bu-Xantphos
#N/A#N/A70K3PO4dioxanedioxaneNi(0)/Ni(II)P-O-PP-O-PMixed
Csp2_ar-Csp2_ar
E-HNN(+)Me3BCsp2_arCsp2_arCsp2_ar-NCsp2_ar-BAryl-N[Aryl]-N(+)Me3Aryl-B(OH)2[Aryl]-B(OH)2Polar2.25Ionic-PO4K+#N/A#N/A
J AM CHEM SOC
_2.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6[N+]C(C)(C).[O-]S(=O)(=O)C(F)(F)FB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1CC1(C2=CC=CC(P(C(C)(C)C)C(C)(C)C)=C2OC3=C1C=CC=C3P(C(C)(C)C)C(C)(C)C)C[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1COCCO1
53
5411/1/2021290
Long
c7sc01980g
C-N Activation
x10.1039/c7sc01980g2017
11.5E-NuN(Bn)Boc
CarbonylH
N(H)AlkylBenz-ICy.HCl
#N/A#N/A60NaOtButoluenetolueneNHCBImN-R2CarbeneCsp2-Nsp3NN(Bn)BocHCsp2Nsp3Csp2-NNsp3-HCarbonyl-N[Carbonyl]-N(Bn)BocN(H)Alkyl-H[N(H)Alkyl]-HNon-Polar2.38Ionic-OtBuNa+#N/A#N/ACHEM SCI_2.8589353663.2821934583.0705644124.0077900319#REF!5.6643.091.706749553.2392069642.4729782574.96639928#REF!#REF!N(C(=O)OC(C)(C)(C))C(C1=CC=CC=C1)HCC(=O)CNCC(=O)CCCNC12=CC=CC=C1N(C=[N+]2C3CCCCC3)C4CCCCC4.[Cl-][Na]OC(C)(C)CCc1ccccc1
54
5511/1/2021290#N/A
c7sc01980g
C-N Activation
x10.1039/c7sc01980g2017
11.5E-NuN(Bn)Boc
CarbonylH
N(Alkyl)CarbonylBenz-ICy.HCl
#N/A#N/A60NaOtButoluenetoluene#N/ANHCBImN-R2CarbeneCsp2-Nsp3NN(Bn)BocHCsp2Nsp3Csp2-NNsp3-HCarbonyl-N[Carbonyl]-N(Bn)BocN(Alkyl)Carbonyl-H[N(Alkyl)Carbonyl]-HNon-Polar2.38Ionic-OtBuNa+#N/A#N/ACHEM SCI_2.8589353663.2821934583.0705644124.0077900319#REF!9.3129.11.706749553.2392069642.4729782574.96639928#REF!#REF!N(C(=O)OC(C)(C)(C))C(C1=CC=CC=C1)HCC(=O)CN(C)(C(=O)C)C(=O)CCCC(=O)N(C)C12=CC=CC=C1N(C=[N+]2C3CCCCC3)C4CCCCC4.[Cl-][Na]OC(C)(C)CCc1ccccc1
55
5611/1/2021290
Long
c7sc01980g
C-N Activation
x10.1039/c7sc01980g2017
11.5E-NuN(Bn)Boc
CarbonylH
N(H)AlkylBenz-ICy.HCl
#N/A#N/A60NaOtButoluenetolueneNHCBImN-R2CarbeneCsp2-Nsp3NN(Bn)BocHCsp2Nsp3Csp2-NNsp3-HCarbonyl-N[Carbonyl]-N(Bn)BocN(H)Alkyl-H[N(H)Alkyl]-HNon-Polar2.38Ionic-OtBuNa+#N/A#N/ACHEM SCI_2.8589353663.2821934583.0705644124.0077900319#REF!5.6643.091.706749553.2392069642.4729782574.96639928#REF!#REF!N(C(=O)OC(C)(C)(C))C(C1=CC=CC=C1)HCC(=O)CNCC(=O)CCCNC12=CC=CC=C1N(C=[N+]2C3CCCCC3)C4CCCCC4.[Cl-][Na]OC(C)(C)CCc1ccccc1
56
5711/1/2021290
Long
c7sc01980g
C-N Activation
x10.1039/c7sc01980g2017
11.5E-NuN(Bn)Boc
CarbonylH
N(H)AlkylBenz-ICy.HCl
#N/A#N/A60NaOtButoluenetolueneNHCBImN-R2CarbeneCsp2-Nsp3NN(Bn)BocHCsp2Nsp3Csp2-NNsp3-HCarbonyl-N[Carbonyl]-N(Bn)BocN(H)Alkyl-H[N(H)Alkyl]-HNon-Polar2.38Ionic-OtBuNa+#N/A#N/ACHEM SCI_2.8589353663.2821934583.0705644124.0077900319#REF!5.6643.091.706749553.2392069642.4729782574.96639928#REF!#REF!N(C(=O)OC(C)(C)(C))C(C1=CC=CC=C1)HCC(=O)CNCC(=O)CCCNC12=CC=CC=C1N(C=[N+]2C3CCCCC3)C4CCCCC4.[Cl-][Na]OC(C)(C)CCc1ccccc1
57
5811/1/2021316
Long
acscatal.6b00793
C-N Activation
x10.1021/acscatal.6b007932016
11.5E-NuN(Me)Tos
CarbonylZnX
BenzylSIPr
#N/A#N/A23THFTHFNHCCarbeneCarbene
Csp2-Csp3-ring(s)
NN(SO2)(Me)ZnCsp2Csp3-ring(s)Csp2-NCsp3-ring(s)-ZnCarbonyl-N[Carbonyl]-N(SO2)(Me)Benzyl-ZnX[Benzyl]-ZnXPolar7.58No baseNo BaseNo base#N/A#N/A
ACS CATAL
_#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XN(C)S(=O)(=O)CC1=CC=C(C)C=C1[Zn]ClCC(=O)CCC1=CC=CC=C1C(=O)CCCC1=CC=CC=C1CC(C)c1cccc(C(C)C)c1N2[C]N(CC2)c3c(cccc3C(C)C)C(C)C#N/AC1CCOC1
58
5911/1/2021316
Long
acscatal.6b00793
C-N Activation
x10.1021/acscatal.6b007932016
11.5E-NuN(Me)Tos
CarbonylZnX
AlkylSIPr
#N/A#N/A23THFTHFNHCCarbeneCarbeneCsp2-Csp3NN(SO2)(Me)ZnCsp2Csp3Csp2-NCsp3-ZnCarbonyl-N[Carbonyl]-N(SO2)(Me)Alkyl-ZnX[Alkyl]-ZnXPolar7.58No baseNo BaseNo base#N/A#N/A
ACS CATAL
_#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XN(C)S(=O)(=O)CC1=CC=C(C)C=C1[Zn]ClCC(=O)CCCC(=O)CCCCCC(C)c1cccc(C(C)C)c1N2[C]N(CC2)c3c(cccc3C(C)C)C(C)C#N/AC1CCOC1
59
6011/1/2021136
Kelly
acscatal.6b00801
C-O Activation
x10.1021/acscatal.6b008012016
OCONEt2 as leaving group11.54E-NuOCONEt2
Aryl9-BBN
AlkylIPr.HCl
#N/A#N/A110Cs2CO3iPr2OiPr2ONHCCarbeneCarbeneCsp2_ar-Csp3MediumOO-CO-R'BCsp2_arCsp3Csp2_ar-OCsp3-BAryl-O[Aryl]-O-CO-R'Alkyl-9-BBN[Alkyl]-9-BBNPolar4.04Ionic-CO3Cs+MediumOCO-EDG
ACS CATALYSIS
_0.3121.411.72.530430542.115215273.4538974810.33#REF!19.7503.3213987613.7885441773.5549714696.18653403#REF!#REF!28.2OC(N(CC)CC)=OB1C2CCCC1CCC2C1=CC=CC=C1CCC1=CC=CC=C1CCCC(C)c1cccc(C(C)C)c1N2C=[N+](C=C2)c3c(C(C)C)cccc3C(C)C.[Cl-]C(=O)([O-])[O-].[Cs+].[Cs+]O(C(C)C)C(C)C
60
6111/1/2021136
Kelly
acscatal.6b00801
C-O Activation
xx10.1021/acscatal.6b008012016
OSO2NEt2 as Leaving group11.54E-NuOSO2NEt2
Aryl9-BBN
AlkylIPr.HCl
#N/A#N/A110Cs2CO3iPr2OiPr2ONHCCarbeneCarbeneCsp2_ar-Csp3WeakOO-SO2-R'BCsp2_arCsp3Csp2_ar-OCsp3-BAryl-O[Aryl]-O-SO2-R'Alkyl-9-BBN[Alkyl]-9-BBNPolar4.04Ionic-CO3Cs+MediumOCO-EDG
ACS CATALYSIS
_0.331.72.530430542.115215273.4538974810.33#REF!19.7503.3213987613.7885441773.5549714696.18653403#REF!#REF!28.2OS(=O)(N(CC)CC)=OB1C2CCCC1CCC2C1=CC=CC=C1CCC1=CC=CC=C1CCCC(C)c1cccc(C(C)C)c1N2C=[N+](C=C2)c3c(C(C)C)cccc3C(C)C.[Cl-]C(=O)([O-])[O-].[Cs+].[Cs+]O(C(C)C)C(C)C
61
6211/1/2021136
Kelly
acscatal.6b00801
C-O Activation
x10.1021/acscatal.6b008012016
OBoc as Leaving group11.54E-NuOBoc
Aryl9-BBN
AlkylIPr.HCl
#N/A#N/A110Cs2CO3iPr2OiPr2ONHCCarbeneCarbeneCsp2_ar-Csp3MediumOO-CO-R'BCsp2_arCsp3Csp2_ar-OCsp3-BAryl-O[Aryl]-O-CO-R'Alkyl-9-BBN[Alkyl]-9-BBNPolar4.04Ionic-CO3Cs+MediumOCO2-EDG
ACS CATALYSIS
_0.3120.971.72.530430542.115215273.4538974810.33#REF!19.7503.3213987613.7885441773.5549714696.18653403#REF!#REF!28.2OC(=O)OC(C)(C)CB1C2CCCC1CCC2C1=CC=CC=C1CCC1=CC=CC=C1CCCC(C)c1cccc(C(C)C)c1N2C=[N+](C=C2)c3c(C(C)C)cccc3C(C)C.[Cl-]C(=O)([O-])[O-].[Cs+].[Cs+]O(C(C)C)C(C)C
62
6311/1/2021136
Kelly
acscatal.6b00801
C-O Activation
xx10.1021/acscatal.6b008012016
OPiv as leaving group11.54E-NuOPiv
Aryl9-BBN
AlkylIPr.HCl
#N/A#N/A110Cs2CO3iPr2OiPr2ONHCCarbeneCarbeneCsp2_ar-Csp3MediumOO-CO-R'BCsp2_arCsp3Csp2_ar-OCsp3-BAryl-O[Aryl]-O-CO-R'Alkyl-9-BBN[Alkyl]-9-BBNPolar4.04Ionic-CO3Cs+MediumOCO-EDG
ACS CATALYSIS
_0.3320.281.72.530430542.115215273.4538974810.33#REF!19.7503.3213987613.7885441773.5549714696.18653403#REF!#REF!28.2OC(=O)C(C)(C)CB1C2CCCC1CCC2C1=CC=CC=C1CCC1=CC=CC=C1CCCC(C)c1cccc(C(C)C)c1N2C=[N+](C=C2)c3c(C(C)C)cccc3C(C)C.[Cl-]C(=O)([O-])[O-].[Cs+].[Cs+]O(C(C)C)C(C)C
63
6411/1/2021136
Kelly
acscatal.6b00801
C-O Activation
x10.1021/acscatal.6b008012016
OMe as Leaving group11.54E-NuOMe
Aryl9-BBN
AlkylIPr.HCl
#N/A#N/A110Cs2CO3iPr2OiPr2ONHCCarbeneCarbeneCsp2_ar-Csp3StrongOO-Csp3BCsp2_arCsp3Csp2_ar-OCsp3-BAryl-O[Aryl]-O-Csp3Alkyl-9-BBN[Alkyl]-9-BBNPolar4.04Ionic-CO3Cs+HardO-EDG
ACS CATALYSIS
_-0.2812.861.72.530430542.115215273.4538974810.33#REF!19.7503.3213987613.7885441773.5549714696.18653403#REF!#REF!28.2OCB1C2CCCC1CCC2C1=CC=CC=C1CCC1=CC=CC=C1CCCC(C)c1cccc(C(C)C)c1N2C=[N+](C=C2)c3c(C(C)C)cccc3C(C)C.[Cl-]C(=O)([O-])[O-].[Cs+].[Cs+]O(C(C)C)C(C)C
64
6511/1/2021136
Kelly
acscatal.6b00801
C-O Activation
xx10.1021/acscatal.6b008012016
11.54E-NuOPiv
Aryl9-BBN
AlkylIPr.HCl
#N/A#N/A110Cs2CO3iPr2OiPr2ONHCCarbeneCarbeneCsp2_ar-Csp3MediumOO-CO-R'BCsp2_arCsp3Csp2_ar-OCsp3-BAryl-O[Aryl]-O-CO-R'Alkyl-9-BBN[Alkyl]-9-BBNPolar4.04Ionic-CO3Cs+MediumOCO-EDG
ACS CATALYSIS
_0.3320.281.72.530430542.115215273.4538974810.33#REF!19.7503.3213987613.7885441773.5549714696.18653403#REF!#REF!28.2OC(=O)C(C)(C)CB1C2CCCC1CCC2C1=CC=CC=C1CCC1=CC=CC=C1CCCC(C)c1cccc(C(C)C)c1N2C=[N+](C=C2)c3c(C(C)C)cccc3C(C)C.[Cl-]C(=O)([O-])[O-].[Cs+].[Cs+]O(C(C)C)C(C)C
65
6611/1/2021136
Kelly
acscatal.6b00801
C-O Activation
xx10.1021/acscatal.6b008012016
R2=Alkyl11.54E-NuOPiv
Aryl9-BBN
AlkylIPr.HCl
#N/A#N/A110Cs2CO3iPr2OiPr2ONHCCarbeneCarbeneCsp2_ar-Csp3MediumOO-CO-R'BCsp2_arCsp3Csp2_ar-OCsp3-BAryl-O[Aryl]-O-CO-R'Alkyl-9-BBN[Alkyl]-9-BBNPolar4.04Ionic-CO3Cs+MediumOCO-EDG
ACS CATALYSIS
_0.3320.281.72.530430542.115215273.4538974810.33#REF!19.7503.3213987613.7885441773.5549714696.18653403#REF!#REF!28.2OC(=O)C(C)(C)CB1C2CCCC1CCC2C1=CC=CC=C1CCC1=CC=CC=C1CCCC(C)c1cccc(C(C)C)c1N2C=[N+](C=C2)c3c(C(C)C)cccc3C(C)C.[Cl-]C(=O)([O-])[O-].[Cs+].[Cs+]O(C(C)C)C(C)C
66
6711/1/202142
Kelly
jacs.0c00286
C-O Activation
x10.1021/jacs.0c002862020
11.2E-NuOTf
HetH
N(H)Arylbis[3,5-bis(trifluoromethyl)phenyl]-cyClopenta-2,4-dien-1-ylphosphane;bis[3,5-bis(trifluoromethyl)phenyl]-cyClopentylphosphane;iron
#N/A#N/A100Et3N2-Me-THF2-Me-THFN2P-PPhosphine (Bidentate)PhosphineCsp2_ar-Nsp3WeakOO-SO2-R'HCsp2_arNsp3Csp2_ar-ONsp3-HHet-O[Het]-O-SO2-R'N(H)Aryl-H[N(H)Aryl]-HPolar7.53NitrogenNitrogen(neutral)Nitrogen(neutral)EasyOSO2-EWG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.531.7105540393.2426955962.4766248184.9733801910.8#REF!11.526.021.706749553.2392069642.4729782574.96639928#REF!#REF!OS(=O)(=O)C(F)(F)FHC1=NC=CC=C1NC1=CC=CC=C1C1=CC=NC=C1C1=CC=CC=C1NFC(c1cc(C(F)(F)F)cc(P(c2cc(C(F)(F)F)cc(C(F)(F)F)c2)C34C5C6C7C3[Fe]675489%10%11C%12C8C9(C%10C%12%11)P(c%13cc(C(F)(F)F)cc(C(F)(F)F)c%13)c%14cc(C(F)(F)F)cc(C(F)(F)F)c%14)c1)(F)FCCN(CC)CCO1C(C)CCC1
67
6811/2/202162
Kelly
acscatal.6b00365
C-H Activation
x10.1021/acscatal.6b003652016
12E-NuBr
AlkylH
Aryl(R)-DIFLUORPHOS
#N/A#N/A85NaOtButoluenetolueneP-PPhosphine (Bidentate)PhosphineCsp3-Csp2_arXHCsp3Csp2_arCsp3-XCsp2_ar-HAlkyl-X[Alkyl]-Aryl-H[Aryl]-HNon-Polar2.38Ionic-OtBuNa+#REF!
ACS CATAL
_2.8589353663.2821934583.0705644124.0077900319#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5BrHCCC1=CC=CC=C1CCC1=CC=CC=C1FC1(F)OC2=C(C(C3=C(OC(F)(F)O4)C4=CC=C3P(C5=CC=CC=C5)C6=CC=CC=C6)=C(P(C7=CC=CC=C7)C8=CC=CC=C8)C=C2)O1[Na]OC(C)(C)CCc1ccccc1
68
6911/2/202162
Kelly
acscatal.6b00365
C-H Activation
x10.1021/acscatal.6b003652016
R=Me/Bn12E-NuBr
AlkylH
Aryl(R)-BINAP
#N/A#N/A25NaOtButoluenetolueneP-PPhosphine (Bidentate)PhosphineCsp3-Csp2_arXHCsp3Csp2_arCsp3-XCsp2_ar-HAlkyl-X[Alkyl]-Aryl-H[Aryl]-HNon-Polar2.38Ionic-OtBuNa+#REF!
ACS CATAL
_2.8589353663.2821934583.0705644124.0077900319#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5BrHCCC1=CC=CC=C1CCC1=CC=CC=C1c1ccc(cc1)P(c2ccccc2)c3ccc4ccccc4c3-c5c(ccc6ccccc56)P(c7ccccc7)c8ccccc8[Na]OC(C)(C)CCc1ccccc1
69
7011/2/202162
Kelly
acscatal.6b00365
C-H Activation
x10.1021/acscatal.6b003652016
12E-NuBr
AlkylH
Aryl(R)-DIFLUORPHOS
#N/A#N/A25NaOtBubenzonitriletoluenetolueneP-PPhosphine (Bidentate)PhosphineCsp3-Csp2_arXHCsp3Csp2_arCsp3-XCsp2_ar-HAlkyl-X[Alkyl]-Aryl-H[Aryl]-HNon-Polar2.38Ionic-OtBuNa+#REF!
ACS CATAL
_2.8589353663.2821934583.0705644124.0077900319#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5BrHCCC1=CC=CC=C1CCC1=CC=CC=C1FC1(F)OC2=C(C(C3=C(OC(F)(F)O4)C4=CC=C3P(C5=CC=CC=C5)C6=CC=CC=C6)=C(P(C7=CC=CC=C7)C8=CC=CC=C8)C=C2)O1[Na]OC(C)(C)CN#Cc1ccccc1
70
7111/2/2021389
Gerry
nchem.2388
C-N Activation
x10.1038/nchem.23882016
R is Bn11.2-2.5E-NuN(Bn)Boc
CarbonylBpin
HetSIPr
#N/A#N/A50K3PO4toluenetolueneNHCCarbeneCarbeneCsp2-Csp2_arNN(Bn)BocBCsp2Csp2_arCsp2-NCsp2_ar-BCarbonyl-N[Carbonyl]-N(Bn)BocHet-Bpin[Het]-BpinNon-Polar2.38Ionic-PO4K+
NAT CHEM
_2.244780372.9696246982.6072025343.5700586912.37#REF!23.1131.353.1465845953.9827799333.5646822646.55194167#REF!#REF!150N(C(=O)OC(C)(C)(C))C(C1=CC=CC=C1)[B](OC1(C)(C))OC1(C)(C)CC(=O)CC1=NC=CC=C1C(=O)CCC1=CC=NC=C1CC(C)c1cccc(C(C)C)c1N2[C]N(CC2)c3c(cccc3C(C)C)C(C)C[O-]P(=O)([O-])[O-].[K+].[K+].[K+]Cc1ccccc1
71
7211/2/2021389
Gerry
nchem.2388
C-N Activation
x10.1038/nchem.23882016
R is Me11.2-2.5E-NuN(Me)Boc
CarbonylBpin
HetSIPr
#N/A#N/A50K3PO4toluenetolueneNHCCarbeneCarbeneCsp2-Csp2_arNN(Boc)AlkylBCsp2Csp2_arCsp2-NCsp2_ar-BCarbonyl-N[Carbonyl]-N(Boc)AlkylHet-Bpin[Het]-BpinNon-Polar2.38Ionic-PO4K+
NAT CHEM
_2.244780372.9696246982.6072025343.5700586912.37#REF!23.1131.353.1465845953.9827799333.5646822646.55194167#REF!#REF!150N(C(OC(C)(C)C)=O)C[B](OC1(C)(C))OC1(C)(C)CC(=O)CC1=NC=CC=C1C(=O)CCC1=CC=NC=C1CC(C)c1cccc(C(C)C)c1N2[C]N(CC2)c3c(cccc3C(C)C)C(C)C[O-]P(=O)([O-])[O-].[K+].[K+].[K+]Cc1ccccc1
72
7311/2/2021220
Gerry
acscatal.7b03688
C-N Activation
x10.1021/acscatal.7b036882018
12.5E-NuN(Bn)Boc
CarbonylBPin
HetBenz-ICy.HCl
#N/A#N/A120K3PO4toluenetolueneNHCBImN-R2CarbeneCsp2-Csp2_arNN(Bn)BocBCsp2Csp2_arCsp2-NCsp2_ar-BCarbonyl-N[Carbonyl]-N(Bn)BocHet-BPin[Het]-BPinNon-Polar2.38Ionic-PO4K+#N/A#N/A
ACS CATAL
_2.244780372.9696246982.6072025343.5700586912.37#REF!23.1131.353.1465845953.9827799333.5646822646.55194167#REF!#REF!150N(C(=O)OC(C)(C)(C))C(C1=CC=CC=C1)[B](OC1(C)(C))OC1(C)(C)CC(=O)CC1=NC=CC=C1C(=O)CCC1=CC=NC=C1C12=CC=CC=C1N(C=[N+]2C3CCCCC3)C4CCCCC4.[Cl-][O-]P(=O)([O-])[O-].[K+].[K+].[K+]Cc1ccccc1
73
7411/2/2021220
Gerry
acscatal.7b03688
C-N Activation
x10.1021/acscatal.7b036882018
12.5E-NuN(Bn)Boc
CarbonylBPin
HetBenz-ICy.HCl
#N/A#N/A120K3PO4toluenetolueneNHCBImN-R2CarbeneCsp2-Csp2_arNN(Bn)BocBCsp2Csp2_arCsp2-NCsp2_ar-BCarbonyl-N[Carbonyl]-N(Bn)BocHet-BPin[Het]-BPinNon-Polar2.38Ionic-PO4K+#N/A#N/A
ACS CATAL
_2.244780372.9696246982.6072025343.5700586912.37#REF!23.1131.353.1465845953.9827799333.5646822646.55194167#REF!#REF!150N(C(=O)OC(C)(C)(C))C(C1=CC=CC=C1)[B](OC1(C)(C))OC1(C)(C)CC(=O)CC1=NC=CC=C1C(=O)CCC1=CC=NC=C1C12=CC=CC=C1N(C=[N+]2C3CCCCC3)C4CCCCC4.[Cl-][O-]P(=O)([O-])[O-].[K+].[K+].[K+]Cc1ccccc1
74
7511/2/2021129
Gerry
acscatal.7b01444
C-N Activation
x10.1021/acscatal.7b014442017
11.2E-NuN(Me)Ph
CarbonylH
ORSIPr
#N/A#N/A60toluenetolueneNHCCarbeneCarbeneCsp2-Osp2NN(Ph)AlkylHCsp2Osp2Csp2-NOsp2-HCarbonyl-N[Carbonyl]-N(Ph)AlkylOR-H[OR]-HNon-Polar2.38No baseNo BaseNo base
ACS CATAL
_#N/A#N/A#N/A#N/A#N/A#REF!3.2120.231.706749553.2392069642.4729782574.96639928#REF!#REF!N(C1=CC=CC=C1)HCC(=O)COC(=O)CCOCC(C)c1cccc(C(C)C)c1N2[C]N(CC2)c3c(cccc3C(C)C)C(C)C#N/ACc1ccccc1
75
7611/2/2021266
Kelly
jacs.5b02503
C-N Activation
x10.1021/jacs.5b025032015
R=Me/Alkyl, ring opening13E-NuN(Ring-Opening)
AlkylZnX
BenzylFro-DO
#N/A#N/A23DMADMAN-NN-NNitrogen
Csp3-Csp3-ring(s)
N
N(Ring-Opening)
ZnCsp3Csp3-ring(s)Csp3-NCsp3-ring(s)-ZnAlkyl-N[Alkyl]-N(Ring-Opening)Benzyl-ZnX[Benzyl]-ZnXPolar37.8No baseNo BaseNo base
J AM CHEM SOC
_#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XNC[Zn]ClCCCC1=CC=CC=C1CCCC1=CC=CC=C1O=S1(C[C@H]([C@@H]2N1C(/C=C/C(N([C@H](C(C=CC=C3)=C3C4)[C@H]4C5)S5(=O)=O)=O)=O)CC6=C2C=CC=C6)=O#N/ACN(C)C(C)=O
76
7711/2/2021266
Kelly
jacs.5b02503
C-N Activation
x10.1021/jacs.5b025032015
R=Alkyl, ring opening13E-NuN(Ring-Opening)
AlkylZnX
BenzylFro-DO
#N/A#N/A23DMADMAN-NN-NNitrogen
Csp3-Csp3-ring(s)
N
N(Ring-Opening)
ZnCsp3Csp3-ring(s)Csp3-NCsp3-ring(s)-ZnAlkyl-N[Alkyl]-N(Ring-Opening)Benzyl-ZnX[Benzyl]-ZnXPolar37.8No baseNo BaseNo base
J AM CHEM SOC
_#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XNC[Zn]ClCCCC1=CC=CC=C1CCCC1=CC=CC=C1O=S1(C[C@H]([C@@H]2N1C(/C=C/C(N([C@H](C(C=CC=C3)=C3C4)[C@H]4C5)S5(=O)=O)=O)=O)CC6=C2C=CC=C6)=O#N/ACN(C)C(C)=O
77
7811/2/2021266
Kelly
jacs.5b02503
C-N Activation
x10.1021/jacs.5b025032015
R=Aryl, ring opening13E-NuN(Ring-Opening)
AlkylZnX
BenzylFro-DO
#N/A#N/A23DMADMAZnBr2N-NN-NNitrogen
Csp3-Csp3-ring(s)
N
N(Ring-Opening)
ZnCsp3Csp3-ring(s)Csp3-NCsp3-ring(s)-ZnAlkyl-N[Alkyl]-N(Ring-Opening)Benzyl-ZnX[Benzyl]-ZnXPolar37.8No baseNo BaseNo base
J AM CHEM SOC
_#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XNC[Zn]ClCCCC1=CC=CC=C1CCCC1=CC=CC=C1O=S1(C[C@H]([C@@H]2N1C(/C=C/C(N([C@H](C(C=CC=C3)=C3C4)[C@H]4C5)S5(=O)=O)=O)=O)CC6=C2C=CC=C6)=O#N/ACN(C)C(C)=O
78
7911/2/2021393
Kelly
ja034908b
C-N Activation
x10.1021/ja034908b2003
12E-NuNMe3+OTf-
ArylB(OH)2
ArylIMes.HCl
#N/A#N/A80CsFdioxanedioxane
(a reaction is used K3PO4 as base instead of CsF)
NHCCarbeneCarbene
Csp2_ar-Csp2_ar
E-HNN(+)Me3BCsp2_arCsp2_arCsp2_ar-NCsp2_ar-BAryl-N[Aryl]-N(+)Me3Aryl-B(OH)2[Aryl]-B(OH)2Polar2.25Ionic-FCs+#N/A#N/A
J AM CHEM SOC
_03.14#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6[N+]C(C)(C).[O-]S(=O)(=O)C(F)(F)FB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1CC1=CC(=C(C(=C1)C)N2C=C[N+](=C2)C3=C(C=C(C=C3C)C)C)C.[Cl-][Cs]FC1COCCO1
79
8011/2/2021393
Kelly
ja034908b
C-N Activation
x10.1021/ja034908b2003
12E-NuNMe3+OTf-
ArylB(OH)2
ArylIMes.HCl
#N/A#N/A80CsFdioxanedioxaneNHCCarbeneCarbene
Csp2_ar-Csp2_ar
E-HNN(+)Me3BCsp2_arCsp2_arCsp2_ar-NCsp2_ar-BAryl-N[Aryl]-N(+)Me3Aryl-B(OH)2[Aryl]-B(OH)2Polar2.25Ionic-FCs+#N/A#N/A
J AM CHEM SOC
_03.14#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6[N+]C(C)(C).[O-]S(=O)(=O)C(F)(F)FB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1CC1=CC(=C(C(=C1)C)N2C=C[N+](=C2)C3=C(C=C(C=C3C)C)C)C.[Cl-][Cs]FC1COCCO1
80
8111/2/2021393
Kelly
ja034908b
C-N Activation
x10.1021/ja034908b2003
12E-NuNMe3+OTf-
ArylB(OH)2
ArylIMes.HCl
#N/A#N/A80CsFdioxanedioxaneNHCCarbeneCarbene
Csp2_ar-Csp2_ar
E-HNN(+)Me3BCsp2_arCsp2_arCsp2_ar-NCsp2_ar-BAryl-N[Aryl]-N(+)Me3Aryl-B(OH)2[Aryl]-B(OH)2Polar2.25Ionic-FCs+#N/A#N/A
J AM CHEM SOC
_03.14#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6[N+]C(C)(C).[O-]S(=O)(=O)C(F)(F)FB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1CC1=CC(=C(C(=C1)C)N2C=C[N+](=C2)C3=C(C=C(C=C3C)C)C)C.[Cl-][Cs]FC1COCCO1
81
8211/2/2021393
Kelly
ja034908b
C-N Activation
x10.1021/ja034908b2003
12E-NuNMe3+OTf-
ArylB(OH)2
ArylIMes.HCl
#N/A#N/A80CsFdioxanedioxaneNHCCarbeneCarbene
Csp2_ar-Csp2_ar
E-HNN(+)Me3BCsp2_arCsp2_arCsp2_ar-NCsp2_ar-BAryl-N[Aryl]-N(+)Me3Aryl-B(OH)2[Aryl]-B(OH)2Polar2.25Ionic-FCs+#N/A#N/A
J AM CHEM SOC
_03.14#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6[N+]C(C)(C).[O-]S(=O)(=O)C(F)(F)FB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1CC1=CC(=C(C(=C1)C)N2C=C[N+](=C2)C3=C(C=C(C=C3C)C)C)C.[Cl-][Cs]FC1COCCO1
82
8311/2/2021324
Kelly
c39880000975
C-N Activation
x10.1039/c398800009751988
X mentioned in Cond. Details13E-NuNMe3+I-
ArylMgX
Aryldppp
#N/A#N/AheatEt3NbenzenebenzeneP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
E-HNN(+)Me3MgCsp2_arCsp2_arCsp2_ar-NCsp2_ar-MgAryl-N[Aryl]-N(+)Me3Aryl-MgX[Aryl]-MgXNon-Polar2.27NitrogenNitrogen(neutral)Nitrogen(neutral)#N/A#N/A
J CHEM SOC CHEM COMM
_1.7105540393.2426955962.4766248184.9733801910.8#REF!0#REF!#REF!93.2[N+](C)(C)C.[I-][Mg]ClC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(c1ccccc1)(c2ccccc2)CCCP(c3ccccc3)c4ccccc4CCN(CC)CCc1ccccc1
83
8411/2/2021324
Kelly
c39880000975
C-N Activation
x10.1039/c398800009751988
X mentioned in Cond. Details13E-NuNMe3+I-
ArylMgX
Benzyldppp
#N/A#N/AheatEt3NbenzenebenzeneP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp3-ring(s)
E-HNN(+)Me3MgCsp2_arCsp3-ring(s)Csp2_ar-NCsp3-ring(s)-MgAryl-N[Aryl]-N(+)Me3Benzyl-MgX[Benzyl]-MgXNon-Polar2.27NitrogenNitrogen(neutral)Nitrogen(neutral)#N/A#N/A
J CHEM SOC CHEM COMM
_1.7105540393.2426955962.4766248184.9733801910.8#REF!0#REF!#REF!29[N+](C)(C)C.[I-][Mg]ClC1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1P(c1ccccc1)(c2ccccc2)CCCP(c3ccccc3)c4ccccc4CCN(CC)CCc1ccccc1
84
8511/2/2021324
Kelly
c39880000975
C-N Activation
x10.1039/c398800009751988
X mentioned in Cond. Details13E-NuNMe3+I-
ArylMgX
Alkyldppp
#N/A#N/AheatEt3NbenzenebenzeneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp3E-HNN(+)Me3MgCsp2_arCsp3Csp2_ar-NCsp3-MgAryl-N[Aryl]-N(+)Me3Alkyl-MgX[Alkyl]-MgXNon-Polar2.27NitrogenNitrogen(neutral)Nitrogen(neutral)#N/A#N/A
J CHEM SOC CHEM COMM
_1.7105540393.2426955962.4766248184.9733801910.8#REF!0#REF!#REF!12.2[N+](C)(C)C.[I-][Mg]ClC1=CC=CC=C1CCC1=CC=CC=C1CCP(c1ccccc1)(c2ccccc2)CCCP(c3ccccc3)c4ccccc4CCN(CC)CCc1ccccc1
85
8611/2/2021343
Kelly
anie.201100683
C-N Activation
x10.1002/anie.2011006832011
11.5E-NuNMe3+I-
ArylZnX
ArylPCy3
#N/A#N/A90THFNMPTHFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
E-HNN(+)Me3ZnCsp2_arCsp2_arCsp2_ar-NCsp2_ar-ZnAryl-N[Aryl]-N(+)Me3Aryl-ZnX[Aryl]-ZnXPolar7.58No baseNo BaseNo base
ANGEW CHEM INT EDIT
_#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!X[N+](C)(C)C.[I-][Zn]ClC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/AC1CCOC1
86
8711/2/2021343
Kelly
anie.201100683
C-N Activation
x10.1002/anie.2011006832011
R=Alkyl11.5E-NuNMe3+I-
ArylZnX
ArylPCy3
#N/A#N/A90THFNMPTHFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
E-HNN(+)Me3ZnCsp2_arCsp2_arCsp2_ar-NCsp2_ar-ZnAryl-N[Aryl]-N(+)Me3Aryl-ZnX[Aryl]-ZnXPolar7.58No baseNo BaseNo base
ANGEW CHEM INT EDIT
_#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!X[N+](C)(C)C.[I-][Zn]ClC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/AC1CCOC1
87
8811/2/2021343
Kelly
anie.201100683
C-N Activation
x10.1002/anie.2011006832011
R=Benzyl11.5E-NuNMe3+I-
ArylZnX
BenzylPCy3
#N/A#N/A90THFNMPTHFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp3-ring(s)
E-HNN(+)Me3ZnCsp2_arCsp3-ring(s)Csp2_ar-NCsp3-ring(s)-ZnAryl-N[Aryl]-N(+)Me3Benzyl-ZnX[Benzyl]-ZnXPolar7.58No baseNo BaseNo base
ANGEW CHEM INT EDIT
_#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!X[N+](C)(C)C.[I-][Zn]ClC1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/AC1CCOC1
88
8911/2/2021222
Long
c9sc00783k
C-N Activation
x10.1039/c9sc00783k2019
X=I1.51E-EN(Me)Ph
CarbonylI
Arylbpy
#N/A#N/A60DMADMAMnReductiveN-NbpyNitrogenCsp2-Csp2_arNN(Ph)AlkylXCsp2Csp2_arCsp2-NCsp2_ar-XCarbonyl-N[Carbonyl]-N(Ph)AlkylAryl-I[Aryl]-IPolar37.8No baseNo BaseNo baseCHEM SCI_#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XN(C1=CC=CC=C1)ICC(=O)CC1=CC=CC=C1C(=O)CCC1=CC=CC=C1C1(C2=NC=CC=C2)=CC=CC=N1#N/ACN(C)C(C)=O
89
9011/2/2021222
Long
c9sc00783k
C-N Activation
x10.1039/c9sc00783k2019
X=Br1.51E-EN(Me)Ph
CarbonylBr
ArylCC(C)(C)C1=CC(C2=CC(C(C)(C)C)=CC(C3=CC(C(C)(C)C)=CC=N3)=N2)=NC=C1#N/A#N/A#N/A60DMADMAMnReductive#N/A#N/A#N/ACsp2-Csp2_arNN(Ph)AlkylXCsp2Csp2_arCsp2-NCsp2_ar-XCarbonyl-N[Carbonyl]-N(Ph)AlkylAryl-Br[Aryl]-BrPolar37.8No baseNo BaseNo baseCHEM SCI_#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XN(C1=CC=CC=C1)BrCC(=O)CC1=CC=CC=C1C(=O)CCC1=CC=CC=C1#N/A#N/ACN(C)C(C)=O
90
9111/3/202162
Kelly
acscatal.6b00365
C-H Activation
x10.1021/acscatal.6b003652016
12E-NuCl
AlkylH
Aryl(R)-BINAP
#N/A#N/A65-70Et3NtoluenetolueneP-PPhosphine (Bidentate)PhosphineCsp3-Csp2_arXHCsp3Csp2_arCsp3-XCsp2_ar-HAlkyl-X[Alkyl]-Aryl-H[Aryl]-HNon-Polar2.38NitrogenNitrogen(neutral)Nitrogen(neutral)#REF!
ACS CATAL
_1.7105540393.2426955962.4766248184.9733801910.8#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5ClHCCC1=CC=CC=C1CCC1=CC=CC=C1c1ccc(cc1)P(c2ccccc2)c3ccc4ccccc4c3-c5c(ccc6ccccc56)P(c7ccccc7)c8ccccc8CCN(CC)CCCc1ccccc1
91
9211/3/2021301
Yizhou
ol048490d
C-N Activation
x10.1021/ol048490d2004
LVG1 is imidazole12E-NuIm
HetB(OH)2
ArylSIPr.HCl
#N/A#N/A60K3PO4THFTHFNHCCarbeneCarbene
Csp2_ar-Csp2_ar
E-HNImBCsp2_arCsp2_arCsp2_ar-NCsp2_ar-BHet-N[Het]-ImAryl-B(OH)2[Aryl]-B(OH)2Polar7.58Ionic-PO4K+ORG LETT_2.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6N1C=CN=C1B(O)OC1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1C1=CC=CC=C1CC(c1c(N2C=[N+](c3c(C(C)C)cccc3C(C)C)CC2)c(C(C)C)ccc1)C.[Cl-][O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1CCOC1
92
9311/3/2021167
Yizhou
jacs.8b08779
C-N Activation
x10.1021/jacs.8b087792018
12.5E-NuNMe2
ArylB(nep)
ArylIMes(Me)
#N/A#N/A135THFTHFMgNHCCarbeneCarbene
Csp2_ar-Csp2_ar
NNMe2BCsp2_arCsp2_arCsp2_ar-NCsp2_ar-BAryl-N[Aryl]-NMe2Aryl-B(nep)[Aryl]-B(nep)Polar7.58No baseNo BaseNo base#N/A#N/A
J AM CHEM SOC
_#N/A#N/A#N/A#N/A#N/A#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5N(C)CB1OCC(C)(CO1)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1CC1=C(C)N(C2=C(C)C=C(C)C=C2C)[C]N1C3=C(C)C=C(C)C=C3C#N/AC1CCOC1
93
9411/4/2021369
Long
ncomms11554
C-N Activation
x10.1038/ncomms115542016
R=Me11.5-2.5E-NuN(Me)Boc
CarbonylH
MorpholineSIPr
#N/A#N/A35-60t-AmylOHt-AmylOHNHCCarbeneCarbeneCsp2-Nsp3NN(Boc)AlkylHCsp2Nsp3Csp2-NNsp3-HCarbonyl-N[Carbonyl]-N(Boc)AlkylMorpholine-H[Morpholine]-HPolar5.82No baseNo BaseNo base
NAT COMMUN
_#N/A#N/A#N/A#N/A#N/A#REF!9.5921.261.706749553.2392069642.4729782574.96639928#REF!#REF!N(C(OC(C)(C)C)=O)CHCC(=O)CN1CCCCC1C(=O)CCC1CCCCC1NCC(C)c1cccc(C(C)C)c1N2[C]N(CC2)c3c(cccc3C(C)C)C(C)C#N/ACCC(C)(C)O
94
9511/4/2021369
Long
ncomms11554
C-N Activation
x10.1038/ncomms115542016
R=Bn11.5-2.5E-NuN(Bn)Boc
CarbonylH
N(H)ArylSIPr
#N/A#N/A35-60t-AmylOHt-AmylOHNHCCarbeneCarbeneCsp2-Nsp3NN(Bn)BocHCsp2Nsp3Csp2-NNsp3-HCarbonyl-N[Carbonyl]-N(Bn)BocN(H)Aryl-H[N(H)Aryl]-HPolar5.82No baseNo BaseNo base
NAT COMMUN
_#N/A#N/A#N/A#N/A#N/A#REF!11.526.021.706749553.2392069642.4729782574.96639928#REF!#REF!N(C(=O)OC(C)(C)(C))C(C1=CC=CC=C1)HCC(=O)CNC1=CC=CC=C1C(=O)CCC1=CC=CC=C1NCC(C)c1cccc(C(C)C)c1N2[C]N(CC2)c3c(cccc3C(C)C)C(C)C#N/ACCC(C)(C)O
95
9611/4/2021369
Long
ncomms11554
C-N Activation
x10.1038/ncomms115542016
R=Me11.5-2.5E-NuN(Me)Boc
CarbonylH
MorpholineSIPr
#N/A#N/A35-60t-AmylOHt-AmylOHNHCCarbeneCarbeneCsp2-Nsp3NN(Boc)AlkylHCsp2Nsp3Csp2-NNsp3-HCarbonyl-N[Carbonyl]-N(Boc)AlkylMorpholine-H[Morpholine]-HPolar5.82No baseNo BaseNo base
NAT COMMUN
_#N/A#N/A#N/A#N/A#N/A#REF!9.5921.261.706749553.2392069642.4729782574.96639928#REF!#REF!N(C(OC(C)(C)C)=O)CHCC(=O)CN1CCCCC1C(=O)CCC1CCCCC1NCC(C)c1cccc(C(C)C)c1N2[C]N(CC2)c3c(cccc3C(C)C)C(C)C#N/ACCC(C)(C)O
96
9711/4/2021369
Long
ncomms11554
C-N Activation
x10.1038/ncomms115542016
R=Bn11.5-2.5E-NuN(Bn)Boc
CarbonylH
N(H)ArylSIPr
#N/A#N/A35-60t-AmylOHt-AmylOHNHCCarbeneCarbeneCsp2-Nsp3NN(Bn)BocHCsp2Nsp3Csp2-NNsp3-HCarbonyl-N[Carbonyl]-N(Bn)BocN(H)Aryl-H[N(H)Aryl]-HPolar5.82No baseNo BaseNo base
NAT COMMUN
_#N/A#N/A#N/A#N/A#N/A#REF!11.526.021.706749553.2392069642.4729782574.96639928#REF!#REF!N(C(=O)OC(C)(C)(C))C(C1=CC=CC=C1)HCC(=O)CNC1=CC=CC=C1C(=O)CCC1=CC=CC=C1NCC(C)c1cccc(C(C)C)c1N2[C]N(CC2)c3c(cccc3C(C)C)C(C)C#N/ACCC(C)(C)O
97
9811/4/2021269
Long
acs.orglett.6b02952
C-N Activation
x10.1021/acs.orglett.6b029522016
Scheme 2 is the same11.5E-NuN(Boc)(Boc)
CarbonylZnX
ArylPPh3
#N/A#N/A23Et2OEt2OPPhosphine (Monodentate)PhosphineCsp2-Csp2_arNN(Boc)(Boc)ZnCsp2Csp2_arCsp2-NCsp2_ar-ZnCarbonyl-N[Carbonyl]-N(Boc)(Boc)Aryl-ZnX[Aryl]-ZnXNon-Polar4.33No baseNo BaseNo baseORG LETT_#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XN(C(OC(C)(C)C)=O)C(OC(C)(C)C)=O[Zn]ClCC(=O)CC1=CC=CC=C1C(=O)CCC1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3#N/ACCOCC
98
9911/4/2021248
Gerry
ja806244b
C-O Activation
x10.1021/ja806244b2008
14E-NuOPiv
ArylB(OH)2
ArylPCy3
#N/A#N/A80K3PO4toluenetoluenePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
MediumOO-CO-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-CO-R'Aryl-B(OH)2[Aryl]-B(OH)2Non-Polar2.38Ionic-PO4K+
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.3320.282.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OC(=O)C(C)(C)CB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]Cc1ccccc1
99
10011/4/2021244
Gerry
ja200398c
C-O Activation
x10.1021/ja200398c2011
Leavin group is OC(O)NEt214E-NuOCONEt2
ArylB(OH)2
ArylPCy3
#N/A#N/A130K3PO4toluenetoluenePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
MediumOO-CO-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-CO-R'Aryl-B(OH)2[Aryl]-B(OH)2Non-Polar2.38Ionic-PO4K+
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.3121.412.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OC(N(CC)CC)=OB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]Cc1ccccc1
100
10111/4/2021233
Gerry
ja074453g
C-O Activation
xx10.1021/ja074453g2008
13E-NuOTf
ArylH
Alkyldifluorphos
#N/A#N/A80-100NaOtButoluenetolueneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp3WeakOO-SO2-R'HCsp2_arCsp3Csp2_ar-OCsp3-HAryl-O[Aryl]-O-SO2-R'Alkyl-H[Alkyl]-HNon-Polar2.38Ionic-OtBuNa+
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.532.8589353663.2821934583.0705644124.0077900319#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5OS(=O)(=O)C(F)(F)FHC1=CC=CC=C1CCC1=CC=CC=C1CCC1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=C(C=C3)OC(O4)(F)F)C5=C(C=CC6=C5OC(O6)(F)F)P(C7=CC=CC=C7)C8=CC=CC=C8[Na]OC(C)(C)CCc1ccccc1
101
10211/4/2021239
Gerry
ja038752r
C-O Activation
x10.1021/ja038752r2004
leaving group is OTs11.5E-NuOTf
ArylB(OH)2
ArylPCy3
#N/A#N/ArtK3PO4THFTHFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar7.58Ionic-PO4K+
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.532.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(=O)C(F)(F)FB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1CCOC1
102
10311/4/2021239
Gerry
ja038752r
C-O Activation
x10.1021/ja038752r2004
leaving group sis OSO2Ph11.5E-NuOSO2Ph
ArylB(OH)2
ArylPCy3
#N/A#N/ArtK3PO4THFTHFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar7.58Ionic-PO4K+
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.72.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(=O)(C1=CC=CC=C1)B(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1CCOC1
103
10411/4/2021119
Gerry
acscatal.5b01021
C-O Activation
x10.1021/acscatal.5b010212015
12E-NuOFs
ArylB(OH)2
ArylPCy3
#N/A#N/A80K3PO4dioxanedioxanePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar2.25Ionic-PO4K+
ACS CATALYSIS
TM0.532.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(F)=OB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1COCCO1
104
10511/4/202169
Gerry
acscatal.7b04030
C-O Activation
xx10.1021/acscatal.7b040302018
11.05E-NuOP(O)(OEt)2
CarbonylMgX
Vinyldppe
#N/A#N/A23THFTHFP-PPhosphine (Bidentate)PhosphineCsp2-Csp2StrongOO-PO(OR')2MgCsp2Csp2Csp2-OCsp2-MgCarbonyl-O[Carbonyl]-O-PO(OR')2Vinyl-MgX[Vinyl]-MgXPolar7.58No baseNo BaseNo base
ACS CATALYSIS
_0.0417#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!150OP(OCC)(OCC)=O[Mg]ClCC(=O)CC=CC(=O)CCC=Cc1ccc(cc1)P(CCP(c2ccccc2)c3ccccc3)c4ccccc4#N/AC1CCOC1
105
10611/4/202169
Gerry
acscatal.7b04030
C-O Activation
xx10.1021/acscatal.7b040302018
11.05E-NuOP(O)(OEt)2
CarbonylMgX
Vinyldmpe
#N/A#N/A23THFTHFP-PPhosphine (Bidentate)PhosphineCsp2-Csp2StrongOO-PO(OR')2MgCsp2Csp2Csp2-OCsp2-MgCarbonyl-O[Carbonyl]-O-PO(OR')2Vinyl-MgX[Vinyl]-MgXPolar7.58No baseNo BaseNo base
ACS CATALYSIS
_0.0417#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!150OP(OCC)(OCC)=O[Mg]ClCC(=O)CC=CC(=O)CCC=CCP(C)CCP(C)C#N/AC1CCOC1
106
10911/4/2021234
Kelly
ja311783k
C-O Activation
x10.1021/ja311783k2013
12E-NuOPiv
BenzylB(nep)
ArylSIMes
#N/A#N/ArtKOtBun-BuOHTHFtoluene
THF/toluene
NHCCarbeneCarbene
Csp3-ring(s)-Csp2_ar
MediumOO-CO-R'BCsp3-ring(s)Csp2_arCsp3-ring(s)-OCsp2_ar-BBenzyl-O[Benzyl]-O-CO-R'Aryl-B(nep)[Aryl]-B(nep)Both1.19Ionic-OtBuK+#N/A#N/A
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.33#N/A2.8589353663.2821934583.0705644124.0077900319#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OC(=O)C(C)(C)CB1OCC(C)(CO1)CCC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1F[B-](F)(F)F.CC(C)c1cccc(C(C)C)c1N2CC[N+](=C2)c3c(cccc3C(C)C)C(C)CCC(C)(C)[O-].[K+]C1CCOC1
107
23311/9/2021141
Long
jacs.7b04973
C-O Activation
x10.1021/jacs.7b049732017
NAt-BuOH use to dissolve tBuOK
(Imanuel)
NANAE-NuOPiv
ArylB(nep)
ArylSIMes
#N/A#N/ArtKOtBuNaOtBuTHFTHFNHCCarbeneCarbene
Csp2_ar-Csp2_ar
MediumOO-CO-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-CO-R'Aryl-B(nep)[Aryl]-B(nep)Polar7.58Ionic-OtBuK+#N/A#N/A
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.3320.282.8589353663.2821934583.0705644124.0077900319#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OC(=O)C(C)(C)CB1OCC(C)(CO1)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1F[B-](F)(F)F.CC(C)c1cccc(C(C)C)c1N2CC[N+](=C2)c3c(cccc3C(C)C)C(C)CCC(C)(C)[O-].[K+]C1CCOC1
108
23411/9/2021141
Long
jacs.7b04973
C-O Activation
x10.1021/jacs.7b049732017
NAt-BuOH use to dissolve tBuOK
(Imanuel)
NANAE-NuOPiv
ArylB(nep)
ArylPCy3
#N/A#N/ArtKOtBun-BuOHTHFTHFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
MediumOO-CO-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-CO-R'Aryl-B(nep)[Aryl]-B(nep)Polar7.58Ionic-OtBuK+#N/A#N/A
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.3320.282.8589353663.2821934583.0705644124.0077900319#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OC(=O)C(C)(C)CB1OCC(C)(CO1)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3CC(C)(C)[O-].[K+]C1CCOC1
109
11011/4/202129
Kelly
anie.201806790
C-O Activation
x10.1002/anie.2018067902018
NaOtBu not base11.5E-NuOSi(tBu)Me2
ArylH
MorpholineIPrMe.HCl
#N/A#N/A120toluenetolueneNHCCarbeneCarbeneCsp2_ar-Nsp3StrongOO-SiR'3HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-SiR'3Morpholine-H[Morpholine]-HNon-Polar2.38No baseNo BaseNo base
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.2725.01#N/A#N/A#N/A#N/A#N/A#REF!9.5921.261.706749553.2392069642.4729782574.96639928#REF!#REF!O[Si](C)(C)C(C)(C)CHC1=CC=CC=C1N1CCCCC1C1=CC=CC=C1C1CCCCC1NCC(C)c1cccc(C(C)C)c1N2C=[N+](C(C)=C2C)c3c(C(C)C)cccc3C(C)C.[Cl-]#N/ACc1ccccc1
110
11111/4/202129
Kelly
anie.201806790
C-O Activation
x10.1002/anie.2018067902018
NaOtBu not base11.5E-NuOSi(tBu)Me2
ArylH
N(Alkyl)AlkylIPrMe.HCl
#N/A#N/A120toluenetolueneNHCCarbeneCarbeneCsp2_ar-Nsp3StrongOO-SiR'3HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-SiR'3N(Alkyl)Alkyl-H[N(Alkyl)Alkyl]-HNon-Polar2.38No baseNo BaseNo base
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.2725.01#N/A#N/A#N/A#N/A#N/A#REF!9.6512.031.706749553.2392069642.4729782574.96639928#REF!#REF!O[Si](C)(C)C(C)(C)CHC1=CC=CC=C1N(C)CC1=CC=CC=C1C(C)NCC(C)c1cccc(C(C)C)c1N2C=[N+](C(C)=C2C)c3c(C(C)C)cccc3C(C)C.[Cl-]#N/ACc1ccccc1
111
11611/4/2021151
Kelly
anie.201412051
C-O Activation
xx10.1002/anie.2014120512015
10.625E-NuOPiv
ArylH
Alkyl[1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane
#N/A#N/A80NaOtButoluenetolueneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp3MediumOO-CO-R'HCsp2_arCsp3Csp2_ar-OCsp3-HAryl-O[Aryl]-O-CO-R'Alkyl-H[Alkyl]-HNon-Polar2.38Ionic-OtBuNa+
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.3320.282.8589353663.2821934583.0705644124.0077900319#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5OC(=O)C(C)(C)CHC1=CC=CC=C1CCC1=CC=CC=C1CCCC1=CC=C(C=C1)P(C2=CC=C(C)C=C2)C3=[C@]([C@]4=C(C=CC=C5)C5=CC=C4P(C6=CC=C(C)C=C6)C7=CC=C(C)C=C7)C8=CC=CC=C8C=C3[Na]OC(C)(C)CCc1ccccc1
112
11711/4/2021151
Kelly
anie.201412051
C-O Activation
xx10.1002/anie.2014120512015
10.625E-NuOPiv
ArylH
Alkyl[1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane
#N/A#N/A110NaOtButoluenetolueneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp3MediumOO-CO-R'HCsp2_arCsp3Csp2_ar-OCsp3-HAryl-O[Aryl]-O-CO-R'Alkyl-H[Alkyl]-HNon-Polar2.38Ionic-OtBuNa+
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.3320.282.8589353663.2821934583.0705644124.0077900319#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5OC(=O)C(C)(C)CHC1=CC=CC=C1CCC1=CC=CC=C1CCCC1=CC=C(C=C1)P(C2=CC=C(C)C=C2)C3=[C@]([C@]4=C(C=CC=C5)C5=CC=C4P(C6=CC=C(C)C=C6)C7=CC=C(C)C=C7)C8=CC=CC=C8C=C3[Na]OC(C)(C)CCc1ccccc1
113
11811/4/2021151
Kelly
anie.201412051
C-O Activation
xx10.1002/anie.2014120512015
10.625E-NuOPiv
ArylH
Alkyl[1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane
#N/A#N/A80NaOtButoluenetolueneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp3MediumOO-CO-R'HCsp2_arCsp3Csp2_ar-OCsp3-HAryl-O[Aryl]-O-CO-R'Alkyl-H[Alkyl]-HNon-Polar2.38Ionic-OtBuNa+
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.3320.282.8589353663.2821934583.0705644124.0077900319#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5OC(=O)C(C)(C)CHC1=CC=CC=C1CCC1=CC=CC=C1CCCC1=CC=C(C=C1)P(C2=CC=C(C)C=C2)C3=[C@]([C@]4=C(C=CC=C5)C5=CC=C4P(C6=CC=C(C)C=C6)C7=CC=C(C)C=C7)C8=CC=CC=C8C=C3[Na]OC(C)(C)CCc1ccccc1
114
11911/4/2021225
Shihong
anie.200803814
C-O Activation
x10.1002/anie.2008038142008
13E-NuOPiv
ArylZnX
ArylPCy3
#N/A#N/A70THFDMADMAPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
MediumOO-CO-R'ZnCsp2_arCsp2_arCsp2_ar-OCsp2_ar-ZnAryl-O[Aryl]-O-CO-R'Aryl-ZnX[Aryl]-ZnXPolar37.8No baseNo BaseNo base
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.3320.28#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XOC(=O)C(C)(C)C[Zn]ClC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/AC1CCOC1
115
12011/4/2021225
Shihong
anie.200803814
C-O Activation
x10.1002/anie.2008038142008
13E-NuOPiv
ArylZnX
ArylPCy3
#N/A#N/A50THFDMADMAPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
MediumOO-CO-R'ZnCsp2_arCsp2_arCsp2_ar-OCsp2_ar-ZnAryl-O[Aryl]-O-CO-R'Aryl-ZnX[Aryl]-ZnXPolar37.8No baseNo BaseNo base
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.3320.28#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XOC(=O)C(C)(C)C[Zn]ClC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/AC1CCOC1
116
12211/4/2021270
Long
c5sc02942b
C-O Activation
xx10.1039/c5sc02942b2015
11.5E-NuOCONMe2
ArylH
Hetdcype
#N/A#N/A110K3PO4t-AmylOHt-AmylOHP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
MediumOO-CO-R'HCsp2_arCsp2_arCsp2_ar-OCsp2_ar-HAryl-O[Aryl]-O-CO-R'Het-H[Het]-HPolar5.82Ionic-PO4K+
CHEMICAL SCIENCE
_0.3117.732.244780372.9696246982.6072025343.5700586912.37#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8OC(=O)N(C)CHC1=CC=CC=C1C1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1P(C1CCCCC1)(C2CCCCC2)CCP(C3CCCCC3)C4CCCCC4[O-]P(=O)([O-])[O-].[K+].[K+].[K+]CCC(C)(C)O
117
12311/5/2021179
Kelly
ja4034999
C-O Activation
x10.1021/ja40349992013
R=Alkyl13E-Nu(Methylthio)acetic
BenzylZn(Me)2
AlkylDPEphos
#N/A#N/ArttoluenetolueneP-O-PP-O-PMixed
Csp3-ring(s)-Csp3
MediumOO-CO-R'ZnCsp3-ring(s)Csp3Csp3-ring(s)-OCsp3-ZnBenzyl-O[Benzyl]-O-CO-R'Alkyl-Zn(Me)2[Alkyl]-Zn(Me)2Non-Polar2.38No baseNo BaseNo base#N/A#N/A
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.31#N/A#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XOC(CSC)=O[Zn](C)CCC1=CC=CC=C1CCCC1=CC=CC=C1CCO(c1ccccc1P(c2ccccc2)c3ccccc3)c4ccccc4P(c5ccccc5)c6ccccc6#N/ACc1ccccc1
118
12411/5/2021179
Kelly
ja4034999
C-O Activation
x10.1021/ja40349992013
13E-Nu(Methylthio)acetic
BenzylZn(Me)2
AlkylXantphos
#N/A#N/A0toluenetolueneP-O-PP-O-PMixed
Csp3-ring(s)-Csp3
MediumOO-CO-R'ZnCsp3-ring(s)Csp3Csp3-ring(s)-OCsp3-ZnBenzyl-O[Benzyl]-O-CO-R'Alkyl-Zn(Me)2[Alkyl]-Zn(Me)2Non-Polar2.38No baseNo BaseNo base#N/A#N/A
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.31#N/A#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XOC(CSC)=O[Zn](C)CCC1=CC=CC=C1CCCC1=CC=CC=C1CCO6c1c(cccc1P(c2ccccc2)c3ccccc3)C(c7cccc(P(c4ccccc4)c5ccccc5)c67)(C)C#N/ACc1ccccc1
119
12511/5/2021201
Shihong
ja101186p
C-O Activation
x10.1021/ja101186p2010
NANAE-NuOMe
AllylAl(iBu)2
VinylP(o-anisyl)3
#N/A#N/ArtEt3NtoluenetoluenePPhosphine (Monodentate)PhosphineCsp3-Csp2StrongOO-Csp3AlCsp3Csp2Csp3-OCsp2-AlAllyl-O[Allyl]-O-Csp3Vinyl-Al(iBu)2[Vinyl]-Al(iBu)2Non-Polar2.38NitrogenNitrogen(neutral)Nitrogen(neutral)#N/A#N/A
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_-0.285.111.7105540393.2426955962.4766248184.9733801910.8#REF!XX2.4811865675.826321844.1537542046.96337555#REF!#REF!116OC[Al](CC(C)C)CC(C)CCC=CC=CC=CCC=CCOc1ccccc1P(c2ccccc2OC)c3ccccc3OCCCN(CC)CCCc1ccccc1
120
12611/5/2021201
Shihong
ja101186p
C-O Activation
x10.1021/ja101186p2010
NANAE-NuOMe
AllylAl(iBu)2
VinylP(o-anisyl)3
#N/A#N/ArtEt3NtoluenetolueneTESOTfPPhosphine (Monodentate)PhosphineCsp3-Csp2StrongOO-Csp3AlCsp3Csp2Csp3-OCsp2-AlAllyl-O[Allyl]-O-Csp3Vinyl-Al(iBu)2[Vinyl]-Al(iBu)2Non-Polar2.38NitrogenNitrogen(neutral)Nitrogen(neutral)#N/A#N/A
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_-0.285.111.7105540393.2426955962.4766248184.9733801910.8#REF!XX2.4811865675.826321844.1537542046.96337555#REF!#REF!116OC[Al](CC(C)C)CC(C)CCC=CC=CC=CCC=CCOc1ccccc1P(c2ccccc2OC)c3ccccc3OCCCN(CC)CCCc1ccccc1
121
12711/5/2021201
Shihong
ja101186p
C-O Activation
x10.1021/ja101186p2010
15E-NuOMe
AllylAl(iBu)2
VinylP(OPh)3
#N/A#N/ArtEt3NtoluenetolueneTESOTfPPhosphine (Monodentate)PhosphineCsp3-Csp2StrongOO-Csp3AlCsp3Csp2Csp3-OCsp2-AlAllyl-O[Allyl]-O-Csp3Vinyl-Al(iBu)2[Vinyl]-Al(iBu)2Non-Polar2.38NitrogenNitrogen(neutral)Nitrogen(neutral)#N/A#N/A
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_-0.285.111.7105540393.2426955962.4766248184.9733801910.8#REF!XX2.4811865675.826321844.1537542046.96337555#REF!#REF!116OC[Al](CC(C)C)CC(C)CCC=CC=CC=CCC=CP(Oc1ccccc1)(Oc2ccccc2)Oc3ccccc3CCN(CC)CCCc1ccccc1
122
12811/5/2021190
Shihong
anie.201510497
C-O Activation
xx10.1002/anie.2015104972016
12E-NuOMe
ArylAlMe2
Alkyldcype
#N/A#N/A100iPr2Otoluene
iPr2O/toluene
P-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp3StrongOO-Csp3AlCsp2_arCsp3Csp2_ar-OCsp3-AlAryl-O[Aryl]-O-Csp3Alkyl-AlMe2[Alkyl]-AlMe2Both22.665No baseNo BaseNo base#N/A#N/A
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!XX1.7950157593.6203448952.7076803276.94866248#REF!#REF!6.1OC[Al](C)CC1=CC=CC=C1CCC1=CC=CC=C1CCP(C1CCCCC1)(C2CCCCC2)CCP(C3CCCCC3)C4CCCCC4#N/AO(C(C)C)C(C)C
123
12911/5/2021193
Shihong
jacs.7b12865
C-O Activation
x10.1021/jacs.7b128652018
12E-NuOCOPh
Carbonyl9-BBN
AlkylPCy3
#N/A#N/A80Cs2CO3toluenetoluenePPhosphine (Monodentate)PhosphineCsp2-Csp3StrongOO-CO-R'BCsp2Csp3Csp2-OCsp3-BCarbonyl-O[Carbonyl]-O-CO-R'Alkyl-9-BBN[Alkyl]-9-BBNNon-Polar2.38Ionic-CO3Cs+
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.1316.341.72.530430542.115215273.4538974810.33#REF!19.7503.3213987613.7885441773.5549714696.18653403#REF!#REF!28.2OC(=O)C1=CC=CC=C1B1C2CCCC1CCC2CC(=O)CCCC(=O)CCCCC1CCC(CC1)P(C2CCCCC2)C3CCCCC3C(=O)([O-])[O-].[Cs+].[Cs+]Cc1ccccc1
124
13011/5/2021193
Shihong
jacs.7b12865
C-O Activation
x10.1021/jacs.7b128652018
12E-NuOCOPh
Carbonyl9-BBN
AlkylPCy3
#N/A#N/A80Cs2CO3toluenetoluenePPhosphine (Monodentate)PhosphineCsp2-Csp3StrongOO-CO-R'BCsp2Csp3Csp2-OCsp3-BCarbonyl-O[Carbonyl]-O-CO-R'Alkyl-9-BBN[Alkyl]-9-BBNNon-Polar2.38Ionic-CO3Cs+
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.1316.341.72.530430542.115215273.4538974810.33#REF!19.7503.3213987613.7885441773.5549714696.18653403#REF!#REF!28.2OC(=O)C1=CC=CC=C1B1C2CCCC1CCC2CC(=O)CCCC(=O)CCCCC1CCC(CC1)P(C2CCCCC2)C3CCCCC3C(=O)([O-])[O-].[Cs+].[Cs+]Cc1ccccc1
125
13111/5/2021193
Shihong
jacs.7b12865
C-O Activation
x10.1021/jacs.7b128652018
12E-NuOCOPh
Carbonyl9-BBN
AlkylPCy3
#N/A#N/A60Cs2CO3toluenetoluenePPhosphine (Monodentate)PhosphineCsp2-Csp3StrongOO-CO-R'BCsp2Csp3Csp2-OCsp3-BCarbonyl-O[Carbonyl]-O-CO-R'Alkyl-9-BBN[Alkyl]-9-BBNNon-Polar2.38Ionic-CO3Cs+
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.1316.341.72.530430542.115215273.4538974810.33#REF!19.7503.3213987613.7885441773.5549714696.18653403#REF!#REF!28.2OC(=O)C1=CC=CC=C1B1C2CCCC1CCC2CC(=O)CCCC(=O)CCCCC1CCC(CC1)P(C2CCCCC2)C3CCCCC3C(=O)([O-])[O-].[Cs+].[Cs+]Cc1ccccc1
126
6701/6/202252
Shihong
c1cc11193k
C-O Activation
x10.1039/c1cc11193k2011
14E-NuOPiv
CarbonylB(OH)2
ArylPCy3
#N/A#N/A100NaOtBuPhMeDMFPhMePPhosphine (Monodentate)PhosphineCsp2-Csp2_arMediumOO-CO-R'BCsp2Csp2_arCsp2-OCsp2_ar-BCarbonyl-O[Carbonyl]-O-CO-R'Aryl-B(OH)2[Aryl]-B(OH)2#N/A#N/AIonic-OtBuNa+MediumOCO-EDG
CHEMICAL COMMUNICATIONS
_0.3314.152.8589353663.2821934583.0705644124.0077900319#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OC(=O)C(C)(C)CB(O)OCC(=O)CC1=CC=CC=C1C(=O)CCC1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[Na]OC(C)(C)C#N/A
127
13311/5/2021177
Shihong
jacs.6b11412
C-O Activation
x10.1021/jacs.6b114122017
12.5E-NuOSO2NMe2
ArylB(OH)2
Aryldppf
#N/A#N/ArtK3PO4toluenetolueneP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2Non-Polar2.38Ionic-PO4K+
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(N(C)C)=OB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1c1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1[O-]P(=O)([O-])[O-].[K+].[K+].[K+]Cc1ccccc1
128
13411/5/2021177
Shihong
jacs.6b11412
C-O Activation
x10.1021/jacs.6b114122017
12.5E-NuOSO2NMe2
ArylB(OH)2
Aryldppf
#N/A#N/A80K3PO4toluenetolueneP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2Non-Polar2.38Ionic-PO4K+
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(N(C)C)=OB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1c1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1[O-]P(=O)([O-])[O-].[K+].[K+].[K+]Cc1ccccc1
129
13511/5/2021158
Shihong
jacs.6b08075
C-O Activation
x10.1021/jacs.6b080752016
15E-NuOAc
AlkylB(nep)
ArylCyJohnPhos
#N/A#N/A40NaOMe2-Me-THF2-Me-THFPPhosphine (Monodentate)PhosphineCsp3-Csp2_arMediumOO-CO-R'BCsp3Csp2_arCsp3-OCsp2_ar-BAlkyl-O[Alkyl]-O-CO-R'Aryl-B(nep)[Aryl]-B(nep)Polar7.53Ionic-ORNa+#N/A#N/A
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.317.81015.1#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OC(C)=OB1OCC(C)(CO1)CCCC1=CC=CC=C1CCC1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)c3ccccc3-c4ccccc4[Na]OCO1C(C)CCC1
130
13611/5/2021158
Shihong
jacs.6b08075
C-O Activation
x10.1021/jacs.6b080752016
15E-NuOAc
BenzylB(nep)
ArylCyJohnPhos
#N/A#N/A40NaOMe2-Me-THF2-Me-THFPPhosphine (Monodentate)Phosphine
Csp3-ring(s)-Csp2_ar
MediumOO-CO-R'BCsp3-ring(s)Csp2_arCsp3-ring(s)-OCsp2_ar-BBenzyl-O[Benzyl]-O-CO-R'Aryl-B(nep)[Aryl]-B(nep)Polar7.53Ionic-ORNa+#N/A#N/A
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.31#N/A015.1#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OC(C)=OB1OCC(C)(CO1)CCC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)c3ccccc3-c4ccccc4[Na]OCO1C(C)CCC1
131
13711/5/2021249
Shihong
ja8056503
C-O Activation
x10.1021/ja80565032008
11.2E-NuOPiv
ArylB(OH)2
ArylPCy3
#N/A#N/A110K3PO4dioxanedioxanePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
MediumOO-CO-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-CO-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar2.25Ionic-PO4K+
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
TM0.3320.282.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OC(=O)C(C)(C)CB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1COCCO1
132
13811/5/2021249
Shihong
ja8056503
C-O Activation
x10.1021/ja80565032008
11.32E-NuOPiv
ArylB(OH)2
ArylPCy3
#N/A#N/A110K3PO4dioxanedioxanePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
MediumOO-CO-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-CO-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar2.25Ionic-PO4K+
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
TM0.3320.282.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OC(=O)C(C)(C)CB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1COCCO1
133
13911/5/202113
Shihong
anie.202103327
C-O Activation
xx10.1002/anie.2021033272021
12E-NuOMe
Carbonyl9-BBN
AlkylIPrCypâ‹…HCl
#N/A#N/A100K3PO4KOtButoluenetolueneNHCCarbeneCarbeneCsp2-Csp3StrongOO-Csp3BCsp2Csp3Csp2-OCsp3-BCarbonyl-O[Carbonyl]-O-Csp3Alkyl-9-BBN[Alkyl]-9-BBNNon-Polar2.38Ionic-PO4K+
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.286.712.244780372.9696246982.6072025343.5700586912.37#REF!19.7503.3213987613.7885441773.5549714696.18653403#REF!#REF!28.2OCB1C2CCCC1CCC2CC(=O)CCCC(=O)CCCCC1(c2cc(C3CCCC3)cc(C4CCCC4)c2N5C=[N+](C=C5)c6c(C7CCCC7)cc(C8CCCC8)cc6C9CCCC9)CCCC1.[Cl-][O-]P(=O)([O-])[O-].[K+].[K+].[K+]Cc1ccccc1
134
14011/5/202113
Shihong
anie.202103327
C-O Activation
xx10.1002/anie.2021033272021
12E-NuOMe
Carbonyl9-BBN
AlkylIPrCypâ‹…HCl
#N/A#N/A100K3PO4KOtButoluenetolueneNHCCarbeneCarbeneCsp2-Csp3StrongOO-Csp3BCsp2Csp3Csp2-OCsp3-BCarbonyl-O[Carbonyl]-O-Csp3Alkyl-9-BBN[Alkyl]-9-BBNNon-Polar2.38Ionic-PO4K+
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.286.712.244780372.9696246982.6072025343.5700586912.37#REF!19.7503.3213987613.7885441773.5549714696.18653403#REF!#REF!28.2OCB1C2CCCC1CCC2CC(=O)CCCC(=O)CCCCC1(c2cc(C3CCCC3)cc(C4CCCC4)c2N5C=[N+](C=C5)c6c(C7CCCC7)cc(C8CCCC8)cc6C9CCCC9)CCCC1.[Cl-][O-]P(=O)([O-])[O-].[K+].[K+].[K+]Cc1ccccc1
135
14111/5/2021134
Kelly
anie.201607646
C-O Activation
xx10.1002/anie.2016076462016
11.6E-NuOMe
Aryl9-BBN
AlkylPCy3
#N/A#N/A110CsFiPr2OiPr2OPPhosphine (Monodentate)PhosphineCsp2_ar-Csp3StrongOO-Csp3BCsp2_arCsp3Csp2_ar-OCsp3-BAryl-O[Aryl]-O-Csp3Alkyl-9-BBN[Alkyl]-9-BBNPolar4.04Ionic-FCs+
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.2812.8603.14#REF!19.7503.3213987613.7885441773.5549714696.18653403#REF!#REF!28.2OCB1C2CCCC1CCC2C1=CC=CC=C1CCC1=CC=CC=C1CCC1CCC(CC1)P(C2CCCCC2)C3CCCCC3[Cs]FO(C(C)C)C(C)C
136
14211/5/2021134
Kelly
anie.201607646
C-O Activation
xx10.1002/anie.2016076462016
11.6E-NuOMe
Aryl9-BBN
AlkylPCy3
#N/A#N/A110CsFiPr2OiPr2OPPhosphine (Monodentate)PhosphineCsp2_ar-Csp3StrongOO-Csp3BCsp2_arCsp3Csp2_ar-OCsp3-BAryl-O[Aryl]-O-Csp3Alkyl-9-BBN[Alkyl]-9-BBNPolar4.04Ionic-FCs+
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.2812.8603.14#REF!19.7503.3213987613.7885441773.5549714696.18653403#REF!#REF!28.2OCB1C2CCCC1CCC2C1=CC=CC=C1CCC1=CC=CC=C1CCC1CCC(CC1)P(C2CCCCC2)C3CCCCC3[Cs]FO(C(C)C)C(C)C
137
14311/5/2021134
Kelly
anie.201607646
C-O Activation
x10.1002/anie.2016076462016
12E-NuOMe
Vinyl9-BBN
AlkylPCy3
#N/A#N/A100Cs2CO3iPr2OiPr2OPPhosphine (Monodentate)PhosphineCsp2-Csp3StrongOO-Csp3BCsp2Csp3Csp2-OCsp3-BVinyl-O[Vinyl]-O-Csp3Alkyl-9-BBN[Alkyl]-9-BBNPolar4.04Ionic-CO3Cs+
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.286.711.72.530430542.115215273.4538974810.33#REF!19.7503.3213987613.7885441773.5549714696.18653403#REF!#REF!28.2OCB1C2CCCC1CCC2C=CCCC=CCCC1CCC(CC1)P(C2CCCCC2)C3CCCCC3C(=O)([O-])[O-].[Cs+].[Cs+]O(C(C)C)C(C)C
138
14411/5/2021134
Kelly
anie.201607646
C-O Activation
x10.1002/anie.2016076462016
12E-NuOMe
Vinyl9-BBN
AlkylPCy3
#N/A#N/A100Cs2CO3iPr2OiPr2OPPhosphine (Monodentate)PhosphineCsp2-Csp3StrongOO-Csp3BCsp2Csp3Csp2-OCsp3-BVinyl-O[Vinyl]-O-Csp3Alkyl-9-BBN[Alkyl]-9-BBNPolar4.04Ionic-CO3Cs+
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.286.711.72.530430542.115215273.4538974810.33#REF!19.7503.3213987613.7885441773.5549714696.18653403#REF!#REF!28.2OCB1C2CCCC1CCC2C=CCCC=CCCC1CCC(CC1)P(C2CCCCC2)C3CCCCC3C(=O)([O-])[O-].[Cs+].[Cs+]O(C(C)C)C(C)C
139
14511/5/2021134
Kelly
anie.201607646
C-O Activation
xx10.1002/anie.2016076462016
12E-NuOMe
ArylBEt2
AlkylPCy3
#N/A#N/A110CsFiPr2OiPr2OPPhosphine (Monodentate)PhosphineCsp2_ar-Csp3StrongOO-Csp3BCsp2_arCsp3Csp2_ar-OCsp3-BAryl-O[Aryl]-O-Csp3Alkyl-BEt2[Alkyl]-BEt2Polar4.04Ionic-FCs+
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.2812.8603.14#REF!13.8701.9987956073.721056622.8599261146.59817501#REF!#REF!32.6OCB(CC)CCC1=CC=CC=C1CCC1=CC=CC=C1CCC1CCC(CC1)P(C2CCCCC2)C3CCCCC3[Cs]FO(C(C)C)C(C)C
140
14611/5/2021250
Shihong
anie.200801447
C-O Activation
x10.1002/anie.2008014472008
11.5E-NuOMe
ArylB(nep)
ArylPCy3
#N/A#N/A120CsFtoluenetoluenePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
StrongOO-Csp3BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-Csp3Aryl-B(nep)[Aryl]-B(nep)Non-Polar2.38Ionic-FCs+#N/A#N/A
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.2812.8603.14#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OCB1OCC(C)(CO1)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[Cs]FCc1ccccc1
141
14711/5/2021250
Shihong
anie.200801447
C-O Activation
x10.1002/anie.2008014472008
11.5E-NuOMe
ArylB(nep)
ArylPCy3
#N/A#N/A120CsFtoluenetoluenePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
StrongOO-Csp3BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-Csp3Aryl-B(nep)[Aryl]-B(nep)Non-Polar2.38Ionic-FCs+#N/A#N/A
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.2812.8603.14#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OCB1OCC(C)(CO1)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[Cs]FCc1ccccc1
142
15111/5/2021247
Shihong
ja210249h
C-O Activation
xx10.1021/ja210249h2012
1.51E-NuOPiv
ArylH
Hetdcype
#N/A#N/A120Cs2CO3dioxanedioxaneP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
MediumOO-CO-R'HCsp2_arCsp2_arCsp2_ar-OCsp2_ar-HAryl-O[Aryl]-O-CO-R'Het-H[Het]-HPolar2.25Ionic-CO3Cs+
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.3320.281.72.530430542.115215273.4538974810.33#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8OC(=O)C(C)(C)CHC1=CC=CC=C1C1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1P(C1CCCCC1)(C2CCCCC2)CCP(C3CCCCC3)C4CCCCC4C(=O)([O-])[O-].[Cs+].[Cs+]C1COCCO1
143
15211/5/2021200
Shihong
ja2084509
C-O Activation
xx10.1021/ja20845092012
14E-NuOTf
ArylH
VinylDPPF
#N/A#N/A100Cy2NMedioxanedioxaneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp2WeakOO-SO2-R'HCsp2_arCsp2Csp2_ar-OCsp2-HAryl-O[Aryl]-O-SO2-R'Vinyl-H[Vinyl]-HPolar2.25NitrogenNitrogen(neutral)Nitrogen(neutral)
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.531.7105540393.2426955962.4766248184.9733801910.64#REF!6.0701.706749553.2392069642.4729782574.96639928#REF!#REF!115.6OS(=O)(=O)C(F)(F)FHC1=CC=CC=C1C=CC1=CC=CC=C1C=Cc1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1CN(C1CCCCC1)C2CCCCC2C1COCCO1
144
15311/5/202163
Shihong
anie.201710241
C-O Activation
xx10.1002/anie.2017102412017
1.11E-NuOTf
CarbonylH
CarbonylTriphos
#N/A#N/A110toluenetolueneTMPP-P-PPhosphine (Tridentate)PhosphineCsp2-Csp2WeakOO-SO2-R'HCsp2Csp2Csp2-OCsp2-HCarbonyl-O[Carbonyl]-O-SO2-R'Carbonyl-H[Carbonyl]-HNon-Polar2.38No baseNo BaseNo base
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.53#N/A#N/A#N/A#N/A#N/A#REF!4.517.071.706749553.2392069642.4729782574.96639928#REF!#REF!199.9OS(=O)(=O)C(F)(F)FHCC(=O)CCC(=O)CC(=O)CCC(=O)CCCC(CP(C1=CC=CC=C1)C2=CC=CC=C2)(CP(C3=CC=CC=C3)C4=CC=CC=C4)CP(C5=CC=CC=C5)C6=CC=CC=C6#N/ACc1ccccc1
145
15411/5/202186
Shihong
anie.201507494
C-O Activation
xx10.1002/anie.2015074942016
31E-NuOBoc
AllylH
BenzylDPPF
#N/A#N/A24KN(SiMe3)2DMEDMEP-PPhosphine (Bidentate)Phosphine
Csp3-Csp3-ring(s)
MediumOO-CO-R'HCsp3Csp3-ring(s)Csp3-OCsp3-ring(s)-HAllyl-O[Allyl]-O-CO-R'Benzyl-H[Benzyl]-HPolar7.2IonicNitrogen(neutral)K+
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.3114.031.7105540393.2426955962.4766248184.9733801926#REF!12.1701.706749553.2392069642.4729782574.96639928#REF!#REF!21.3OC(=O)OC(C)(C)CHCC=CCC1=CC=CC=C1C=CCCC1=CC=CC=C1c1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1[K]N(C(C)(C)C)C(C)(C)CCOCCOC
146
15511/5/202186
Shihong
anie.201507494
C-O Activation
xx10.1002/anie.2015074942016
31E-NuOBoc
AllylH
BenzylDPPF
#N/A#N/A24KN(SiMe3)2DMEDMEP-PPhosphine (Bidentate)Phosphine
Csp3-Csp3-ring(s)
MediumOO-CO-R'HCsp3Csp3-ring(s)Csp3-OCsp3-ring(s)-HAllyl-O[Allyl]-O-CO-R'Benzyl-H[Benzyl]-HPolar7.2IonicNitrogen(neutral)K+
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.3114.031.7105540393.2426955962.4766248184.9733801926#REF!12.1701.706749553.2392069642.4729782574.96639928#REF!#REF!21.3OC(=O)OC(C)(C)CHCC=CCC1=CC=CC=C1C=CCCC1=CC=CC=C1c1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1[K]N(C(C)(C)C)C(C)(C)CCOCCOC
147
15611/5/202186
Shihong
anie.201507494
C-O Activation
xx10.1002/anie.2015074942016
21E-NuOBoc
AllylH
BenzylDPPF
#N/A#N/A24NaN(SiMe3)2DMEDMEP-PPhosphine (Bidentate)Phosphine
Csp3-Csp3-ring(s)
MediumOO-CO-R'HCsp3Csp3-ring(s)Csp3-OCsp3-ring(s)-HAllyl-O[Allyl]-O-CO-R'Benzyl-H[Benzyl]-HPolar7.2IonicNitrogen(neutral)Na+
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.3114.031.7105540393.2426955962.4766248184.9733801926#REF!12.1701.706749553.2392069642.4729782574.96639928#REF!#REF!21.3OC(=O)OC(C)(C)CHCC=CCC1=CC=CC=C1C=CCCC1=CC=CC=C1c1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1[Na]N([Si](C)(C)C)[Si](C)(C)CCOCCOC
148
15711/5/202186
Shihong
anie.201507494
C-O Activation
xx10.1002/anie.2015074942016
21E-NuOBoc
BenzylH
BenzylDPPF
#N/A#N/A24NaN(SiMe3)2DMEDMEP-PPhosphine (Bidentate)Phosphine
Csp3-ring(s)-Csp3-ring(s)
MediumOO-CO-R'HCsp3-ring(s)Csp3-ring(s)Csp3-ring(s)-OCsp3-ring(s)-HBenzyl-O[Benzyl]-O-CO-R'Benzyl-H[Benzyl]-HPolar7.2IonicNitrogen(neutral)Na+
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.31#N/A1.7105540393.2426955962.4766248184.9733801926#REF!12.1701.706749553.2392069642.4729782574.96639928#REF!#REF!21.3OC(=O)OC(C)(C)CHCC1=CC=CC=C1CC1=CC=CC=C1CC1=CC=CC=C1CC1=CC=CC=C1c1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1[Na]N([Si](C)(C)C)[Si](C)(C)CCOCCOC
149
15811/5/202186
Shihong
anie.201507494
C-O Activation
xx10.1002/anie.2015074942016
21E-NuOBoc
AllylH
BenzylC[C@@H](P(C1CCCCC1)C2CCCCC2)C34=C([Fe]456789%10%11C%12C8=C9C%10=C%12%11)C5C6=C37P(C%13=CC=C(C(F)(F)F)C=C%13)C%14=CC=C(C(F)(F)F)C=C%14
#N/A#N/A24NaN(SiMe3)2DMEDMEP-PPhosphine (Bidentate)Phosphine
Csp3-Csp3-ring(s)
MediumOO-CO-R'HCsp3Csp3-ring(s)Csp3-OCsp3-ring(s)-HAllyl-O[Allyl]-O-CO-R'Benzyl-H[Benzyl]-HPolar7.2IonicNitrogen(neutral)Na+
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.3114.031.7105540393.2426955962.4766248184.9733801926#REF!12.1701.706749553.2392069642.4729782574.96639928#REF!#REF!21.3OC(=O)OC(C)(C)CHCC=CCC1=CC=CC=C1C=CCCC1=CC=CC=C1C[C@@H](P(C1CCCCC1)C2CCCCC2)C34=C([Fe]456789%10%11C%12C8=C9C%10=C%12%11)C5C6=C37P(C%13=CC=C(C(F)(F)F)C=C%13)C%14=CC=C(C(F)(F)F)C=C%14[Na]N([Si](C)(C)C)[Si](C)(C)CCOCCOC
150
15911/5/202186
Shihong
anie.201507494
C-O Activation
xx10.1002/anie.2015074942016
21E-NuOBoc
BenzylH
BenzylC[C@@H](P(C1CCCCC1)C2CCCCC2)C34=C([Fe]456789%10%11C%12C8=C9C%10=C%12%11)C5C6=C37P(C%13=CC=C(C(F)(F)F)C=C%13)C%14=CC=C(C(F)(F)F)C=C%14
#N/A#N/A24NaN(SiMe3)2DMEDMEP-PPhosphine (Bidentate)Phosphine
Csp3-ring(s)-Csp3-ring(s)
MediumOO-CO-R'HCsp3-ring(s)Csp3-ring(s)Csp3-ring(s)-OCsp3-ring(s)-HBenzyl-O[Benzyl]-O-CO-R'Benzyl-H[Benzyl]-HPolar7.2IonicNitrogen(neutral)Na+
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.31#N/A1.7105540393.2426955962.4766248184.9733801926#REF!12.1701.706749553.2392069642.4729782574.96639928#REF!#REF!21.3OC(=O)OC(C)(C)CHCC1=CC=CC=C1CC1=CC=CC=C1CC1=CC=CC=C1CC1=CC=CC=C1C[C@@H](P(C1CCCCC1)C2CCCCC2)C34=C([Fe]456789%10%11C%12C8=C9C%10=C%12%11)C5C6=C37P(C%13=CC=C(C(F)(F)F)C=C%13)C%14=CC=C(C(F)(F)F)C=C%14[Na]N([Si](C)(C)C)[Si](C)(C)CCOCCOC
151
16011/5/2021160
Shihong
anie.201308391
C-O Activation
xx10.1002/anie.2013083912014
11.5E-NuOTs
ArylH
Vinyl1,4-Bis(dicyClopentylphosphonium)butane bis(tetrafluoroborate)
#N/A#N/A60DABCOTESOTftoluenetolueneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp2WeakOO-SO2-R'HCsp2_arCsp2Csp2_ar-OCsp2-HAryl-O[Aryl]-O-SO2-R'Vinyl-H[Vinyl]-HNon-Polar2.38NitrogenNitrogen(neutral)Nitrogen(neutral)
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.361.7105540393.2426955962.4766248184.973380198.8#REF!6.0701.706749553.2392069642.4729782574.96639928#REF!#REF!115.6OS(=O)(=O)(C1=CC=C(C)C=C1)HC1=CC=CC=C1C=CC1=CC=CC=C1C=C[H][P+](C1CCCC1)(CCCC[P+]([H])(C2CCCC2)C3CCCC3)C4CCCC4.F[B-](F)(F)F.F[B-](F)(F)FC1CN2CCN1CC2Cc1ccccc1
152
16111/5/2021160
Shihong
anie.201308391
C-O Activation
xx10.1002/anie.2013083912014
11.5E-NuOTf
ArylH
Vinyl1,4-Bis(dicyClopentylphosphonium)butane bis(tetrafluoroborate)
#N/A#N/A60DABCOTHFTHFP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp2WeakOO-SO2-R'HCsp2_arCsp2Csp2_ar-OCsp2-HAryl-O[Aryl]-O-SO2-R'Vinyl-H[Vinyl]-HPolar7.58NitrogenNitrogen(neutral)Nitrogen(neutral)
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.531.7105540393.2426955962.4766248184.973380198.8#REF!6.0701.706749553.2392069642.4729782574.96639928#REF!#REF!115.6OS(=O)(=O)C(F)(F)FHC1=CC=CC=C1C=CC1=CC=CC=C1C=C[H][P+](C1CCCC1)(CCCC[P+]([H])(C2CCCC2)C3CCCC3)C4CCCC4.F[B-](F)(F)F.F[B-](F)(F)FC1CN2CCN1CC2C1CCOC1
153
16211/5/2021160
Shihong
anie.201308391
C-O Activation
xx10.1002/anie.2013083912014
11.5E-NuOTf
ArylH
Vinyl1,4-Bis(dicyClopentylphosphonium)butane bis(tetrafluoroborate)
#N/A#N/A60DABCOTHFTHFP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp2WeakOO-SO2-R'HCsp2_arCsp2Csp2_ar-OCsp2-HAryl-O[Aryl]-O-SO2-R'Vinyl-H[Vinyl]-HPolar7.58NitrogenNitrogen(neutral)Nitrogen(neutral)
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.531.7105540393.2426955962.4766248184.973380198.8#REF!6.0701.706749553.2392069642.4729782574.96639928#REF!#REF!115.6OS(=O)(=O)C(F)(F)FHC1=CC=CC=C1C=CC1=CC=CC=C1C=C[H][P+](C1CCCC1)(CCCC[P+]([H])(C2CCCC2)C3CCCC3)C4CCCC4.F[B-](F)(F)F.F[B-](F)(F)FC1CN2CCN1CC2C1CCOC1
154
16311/5/202131
Shihong
acscatal.8b03436
C-O Activation
xx10.1021/acscatal.8b034362018
1.51E-NuOMe
ArylH
HetIPr
#N/A#N/A90LiClm-xylenem-xyleneNHCCarbeneCarbene
Csp2_ar-Csp2_ar
StrongOO-Csp3HCsp2_arCsp2_arCsp2_ar-OCsp2_ar-HAryl-O[Aryl]-O-Csp3Het-H[Het]-HNon-Polar2.36No baseNo BaseNo base
ACS CATALYSIS
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8OCHC1=CC=CC=C1C1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1CC(C)C(C=CC=C1C(C)C)=C1N2C=CN(C3=C(C(C)C)C=CC=C3C(C)C)C2#N/ACc1cccc(c1)C
155
16411/5/202131
Shihong
acscatal.8b03436
C-O Activation
xx10.1021/acscatal.8b034362018
11.5E-NuOMe
ArylH
HetIPr
#N/A#N/A90LiClm-xylenem-xyleneNHCCarbeneCarbene
Csp2_ar-Csp2_ar
StrongOO-Csp3HCsp2_arCsp2_arCsp2_ar-OCsp2_ar-HAryl-O[Aryl]-O-Csp3Het-H[Het]-HNon-Polar2.36No baseNo BaseNo base
ACS CATALYSIS
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8OCHC1=CC=CC=C1C1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1CC(C)C(C=CC=C1C(C)C)=C1N2C=CN(C3=C(C(C)C)C=CC=C3C(C)C)C2#N/ACc1cccc(c1)C
156
16511/5/202131
Shihong
acscatal.8b03436
C-O Activation
xx10.1021/acscatal.8b034362018
NANAE-NuOMe
ArylH
HetCDC
#N/A#N/A90LiClm-xylenem-xyleneNHCCarbeneCarbene
Csp2_ar-Csp2_ar
StrongOO-Csp3HCsp2_arCsp2_arCsp2_ar-OCsp2_ar-HAryl-O[Aryl]-O-Csp3Het-H[Het]-HNon-Polar2.36No baseNo BaseNo base
ACS CATALYSIS
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8OCHC1=CC=CC=C1C1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1CC(C)N1C2=CC=CC=C2N(C)C1CC3N(C)C4=C(C=CC=C4)N3C(C)C#N/ACc1cccc(c1)C
157
16611/5/202131
Shihong
acscatal.8b03436
C-O Activation
xx10.1021/acscatal.8b034362018
11.5E-NuOMe
ArylH
HetIPr
#N/A#N/A90LiClm-xylenem-xyleneNHCCarbeneCarbene
Csp2_ar-Csp2_ar
StrongOO-Csp3HCsp2_arCsp2_arCsp2_ar-OCsp2_ar-HAryl-O[Aryl]-O-Csp3Het-H[Het]-HNon-Polar2.36No baseNo BaseNo base
ACS CATALYSIS
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8OCHC1=CC=CC=C1C1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1CC(C)C(C=CC=C1C(C)C)=C1N2C=CN(C3=C(C(C)C)C=CC=C3C(C)C)C2#N/ACc1cccc(c1)C
158
16711/5/202128
Shihong
acscatal.7b02618
C-O Activation
xx10.1021/acscatal.7b026182017
14.8E-NuOTf
ArylH
ArylDMM-DPEPhos
#N/A#N/A40THFdioxaneDMETHF18-crown-6P-O-PP-O-PMixed
Csp2_ar-Csp2_ar
WeakOO-SO2-R'HCsp2_arCsp2_arCsp2_ar-OCsp2_ar-HAryl-O[Aryl]-O-SO2-R'Aryl-H[Aryl]-HPolar7.58No baseNo BaseNo base
ACS CATALYSIS
_0.53#N/A#N/A#N/A#N/A#N/A#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5OS(=O)(=O)C(F)(F)FHC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1CC1=CC(P(C2=CC(C)=C(OC)C(C)=C2)C3=C(C=CC=C3)OC4=C(P(C5=CC(C)=C(OC)C(C)=C5)C6=CC(C)=C(OC)C(C)=C6)C=CC=C4)=CC(C)=C1OC#N/AC1CCOC1
159
16811/5/202128
Shihong
acscatal.7b02618
C-O Activation
xx10.1021/acscatal.7b026182017
14.8E-NuOTf
ArylH
ArylDMM-DPEPhos
#N/A#N/ATHFdioxaneDMETHF18-crown-6P-O-PP-O-PMixed
Csp2_ar-Csp2_ar
WeakOO-SO2-R'HCsp2_arCsp2_arCsp2_ar-OCsp2_ar-HAryl-O[Aryl]-O-SO2-R'Aryl-H[Aryl]-HPolar7.58No baseNo BaseNo base
ACS CATALYSIS
_0.53#N/A#N/A#N/A#N/A#N/A#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5OS(=O)(=O)C(F)(F)FHC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1CC1=CC(P(C2=CC(C)=C(OC)C(C)=C2)C3=C(C=CC=C3)OC4=C(P(C5=CC(C)=C(OC)C(C)=C5)C6=CC(C)=C(OC)C(C)=C6)C=CC=C4)=CC(C)=C1OC#N/AC1CCOC1
160
16911/5/2021228
Shihong
ja710944j
C-O Activation
xx10.1021/ja710944j2008
11.5E-NuOMe
BenzylMgX
Alkyldppf
#N/A#N/A80toluenetolueneP-PPhosphine (Bidentate)Phosphine
Csp3-ring(s)-Csp3
StrongOO-Csp3MgCsp3-ring(s)Csp3Csp3-ring(s)-OCsp3-MgBenzyl-O[Benzyl]-O-Csp3Alkyl-MgX[Alkyl]-MgXNon-Polar2.38No baseNo BaseNo base
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_-0.28#N/A#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OC[Mg]ClCC1=CC=CC=C1CCCC1=CC=CC=C1CCc1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1#N/ACc1ccccc1
161
17011/5/2021230
Shihong
ja108547u
C-O Activation
xx10.1021/ja108547u2011
12E-NuOMe
BenzylMgX
AlkylDPEphos
#N/A#N/ArttoluenetolueneP-O-PP-O-PMixed
Csp3-ring(s)-Csp3
StrongOO-Csp3MgCsp3-ring(s)Csp3Csp3-ring(s)-OCsp3-MgBenzyl-O[Benzyl]-O-Csp3Alkyl-MgX[Alkyl]-MgXNon-Polar2.38No baseNo BaseNo base
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_-0.28#N/A#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OC[Mg]ClCC1=CC=CC=C1CCCC1=CC=CC=C1CCO(c1ccccc1P(c2ccccc2)c3ccccc3)c4ccccc4P(c5ccccc5)c6ccccc6#N/ACc1ccccc1
162
17111/5/2021230
Shihong
ja108547u
C-O Activation
xx10.1021/ja108547u2011
12E-NuOMe
BenzylMgX
AlkylXantphos
#N/A#N/ArttoluenetolueneP-O-PP-O-PMixed
Csp3-ring(s)-Csp3
StrongOO-Csp3MgCsp3-ring(s)Csp3Csp3-ring(s)-OCsp3-MgBenzyl-O[Benzyl]-O-Csp3Alkyl-MgX[Alkyl]-MgXNon-Polar2.38No baseNo BaseNo base
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_-0.28#N/A#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OC[Mg]ClCC1=CC=CC=C1CCCC1=CC=CC=C1CCO6c1c(cccc1P(c2ccccc2)c3ccccc3)C(c7cccc(P(c4ccccc4)c5ccccc5)c67)(C)C#N/ACc1ccccc1
163
17211/5/2021230
Shihong
ja108547u
C-O Activation
xx10.1021/ja108547u2011
12E-NuOMe
ArylMgX
Alkylrac-BINAP
#N/A#N/ArttoluenetolueneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp3StrongOO-Csp3MgCsp2_arCsp3Csp2_ar-OCsp3-MgAryl-O[Aryl]-O-Csp3Alkyl-MgX[Alkyl]-MgXNon-Polar2.38No baseNo BaseNo base
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OC[Mg]ClC1=CC=CC=C1CCC1=CC=CC=C1CCC12=CC=CC=C1C=CC(P(C3=CC=CC=C3)C4=CC=CC=C4)=C2C5=C(C=CC=C6)C6=CC=C5P7C8=CC=CCC98=C7C=CC=C9#N/ACc1ccccc1
164
17311/5/2021230
Shihong
ja108547u
C-O Activation
xx10.1021/ja108547u2011
12.5E-NuOMe
BenzylMgX
AlkylDPEphos
#N/A#N/A50K2CO3tolueneMeItolueneP-O-PP-O-PMixed
Csp3-ring(s)-Csp3
StrongOO-Csp3MgCsp3-ring(s)Csp3Csp3-ring(s)-OCsp3-MgBenzyl-O[Benzyl]-O-Csp3Alkyl-MgX[Alkyl]-MgXNon-Polar2.38Ionic-CO3K+
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_-0.28#N/A1.72.530430542.115215273.4538974810.33#REF!0#REF!#REF!12.2OC[Mg]ClCC1=CC=CC=C1CCCC1=CC=CC=C1CCO(c1ccccc1P(c2ccccc2)c3ccccc3)c4ccccc4P(c5ccccc5)c6ccccc6O=C([O-])[O-].[K+].[K+]Cc1ccccc1
165
17411/5/2021202
Shihong
anie.201308666
C-O Activation
xx10.1002/anie.2013086662014
12E-NuOMe
BenzylMgX
Alkyldppe
#N/A#N/ArttoluenetolueneP-PPhosphine (Bidentate)Phosphine
Csp3-ring(s)-Csp3
StrongOO-Csp3MgCsp3-ring(s)Csp3Csp3-ring(s)-OCsp3-MgBenzyl-O[Benzyl]-O-Csp3Alkyl-MgX[Alkyl]-MgXNon-Polar2.38No baseNo BaseNo base
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.28#N/A#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OC[Mg]ClCC1=CC=CC=C1CCCC1=CC=CC=C1CCc1ccc(cc1)P(CCP(c2ccccc2)c3ccccc3)c4ccccc4#N/ACc1ccccc1
166
17511/5/2021202
Shihong
anie.201308666
C-O Activation
xx10.1002/anie.2013086662014
12E-NuOMe
BenzylMgX
Benzyldppe
#N/A#N/ArttoluenetolueneP-PPhosphine (Bidentate)Phosphine
Csp3-ring(s)-Csp3-ring(s)
StrongOO-Csp3MgCsp3-ring(s)Csp3-ring(s)Csp3-ring(s)-OCsp3-ring(s)-MgBenzyl-O[Benzyl]-O-Csp3Benzyl-MgX[Benzyl]-MgXNon-Polar2.38No baseNo BaseNo base
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.28#N/A#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!29OC[Mg]ClCC1=CC=CC=C1CC1=CC=CC=C1CC1=CC=CC=C1CC1=CC=CC=C1c1ccc(cc1)P(CCP(c2ccccc2)c3ccccc3)c4ccccc4#N/ACc1ccccc1
167
17611/5/202120
Shihong
acscatal.0c00291
C-O Activation
xx10.1021/acscatal.0c002912020
13E-EOH
Arylpyridyl
Carbonyldcypt
#N/A#N/A150KFtoluenetolueneZnP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp2StrongOOHCsp2Csp2_arCsp2Csp2_ar-OCsp2-Csp2Aryl-O[Aryl]-OHCarbonyl-pyridyl[Carbonyl]-pyridylNon-Polar2.38No baseNo BaseNo base
ACS CATALYSIS
_-0.8110.94#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOC1=CN=CC=C1C1=CC=CC=C1CC(=O)CC1=CC=CC=C1C(=O)CCC1(P(C2CCCCC2)C3CCCCC3)=CSC=C1P(C4CCCCC4)C5CCCCC5#N/ACc1ccccc1
168
17711/5/202120
Shihong
acscatal.0c00291
C-O Activation
xx10.1021/acscatal.0c002912020
13E-EOPiv
Arylpyridyl
Carbonyldcype
#N/A#N/A150Na3PO4toluenetolueneZnP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp2MediumOO-CO-R'Csp2Csp2_arCsp2Csp2_ar-OCsp2-Csp2Aryl-O[Aryl]-O-CO-R'Carbonyl-pyridyl[Carbonyl]-pyridylNon-Polar2.38Ionic-PO4Na+
ACS CATALYSIS
_0.3320.282.244780372.9696246982.6072025343.5700586912.37#REF!0#REF!#REF!XOC(=O)C(C)(C)CC1=CN=CC=C1C1=CC=CC=C1CC(=O)CC1=CC=CC=C1C(=O)CCP(C1CCCCC1)(C2CCCCC2)CCP(C3CCCCC3)C4CCCCC4[Na]3PO4Cc1ccccc1
169
17811/5/202137
Shihong
jacs.0c12462
C-O Activation
xx10.1021/jacs.0c124622021
11.5E-EOH
AlkylOAc
Aryldppf
#N/A#N/A80DMFDMODMFMnP-PPhosphine (Bidentate)PhosphineCsp3-Csp2_arStrongOOHOCsp3Csp2_arCsp3-OCsp2_ar-OAlkyl-O[Alkyl]-OHAryl-OAc[Aryl]-OAcPolar36.7No baseNo BaseNo baseMediumOCO-EDG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_-0.813.21#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!OOC(C)=OCCC1=CC=CC=C1CCC1=CC=CC=C1c1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1#N/ACN(C)C=O
170
17911/5/202137
Shihong
jacs.0c12462
C-O Activation
x10.1021/jacs.0c124622021
11E-EOH
AlkylOTf
Aryldppf
#N/A#N/A80DMFDMODMFMnP-PPhosphine (Bidentate)PhosphineCsp3-Csp2_arStrongOOHOCsp3Csp2_arCsp3-OCsp2_ar-OAlkyl-O[Alkyl]-OHAryl-OTf[Aryl]-OTfPolar36.7No baseNo BaseNo baseEasyOSO2-EWG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_-0.813.21#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOOS(=O)(=O)C(F)(F)FCCC1=CC=CC=C1CCC1=CC=CC=C1c1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1#N/ACN(C)C=O
171
18011/5/202137
Shihong
jacs.0c12462
C-O Activation
x10.1021/jacs.0c124622021
11E-EOH
AlkylOTf
Aryldppf
#N/A#N/A80DMFDMODMFMnP-PPhosphine (Bidentate)PhosphineCsp3-Csp2_arStrongOOHOCsp3Csp2_arCsp3-OCsp2_ar-OAlkyl-O[Alkyl]-OHAryl-OTf[Aryl]-OTfPolar36.7No baseNo BaseNo baseEasyOSO2-EWG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_-0.813.21#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOOS(=O)(=O)C(F)(F)FCCC1=CC=CC=C1CCC1=CC=CC=C1c1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1#N/ACN(C)C=O
172
18111/5/202137
Shihong
jacs.0c12462
C-O Activation
x10.1021/jacs.0c124622021
11.5E-EMonomethyl Oxalate
AlkylOTf
Aryldppf
#N/A#N/A80DMFDMFMnP-PPhosphine (Bidentate)PhosphineCsp3-Csp2_arStrongOO-CO-R'OCsp3Csp2_arCsp3-OCsp2_ar-OAlkyl-O[Alkyl]-O-CO-R'Aryl-OTf[Aryl]-OTfPolar36.7No baseNo BaseNo baseEasyOSO2-EWG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.1310.57#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOC(=O)C(=O)OCOS(=O)(=O)C(F)(F)FCCC1=CC=CC=C1CCC1=CC=CC=C1c1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1#N/ACN(C)C=O
173
18211/5/202137
Shihong
jacs.0c12462
C-O Activation
x10.1021/jacs.0c124622021
11E-EOH
AlkylBr
Aryldppf
#N/A#N/A80DMFDMODMFMnP-PPhosphine (Bidentate)PhosphineCsp3-Csp2_arStrongOOHXCsp3Csp2_arCsp3-OCsp2_ar-XAlkyl-O[Alkyl]-OHAryl-Br[Aryl]-BrPolar36.7No baseNo BaseNo base
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_-0.813.21#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOBrCCC1=CC=CC=C1CCC1=CC=CC=C1c1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1#N/ACN(C)C=O
174
18311/5/202137
Shihong
jacs.0c12462
C-O Activation
x10.1021/jacs.0c124622021
11.5E-EOH
AlkylCl
Aryldppf
#N/A#N/A80DMFDMODMFMnP-PPhosphine (Bidentate)PhosphineCsp3-Csp2_arStrongOOHXCsp3Csp2_arCsp3-OCsp2_ar-XAlkyl-O[Alkyl]-OHAryl-Cl[Aryl]-ClPolar36.7No baseNo BaseNo base
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_-0.813.21#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOClCCC1=CC=CC=C1CCC1=CC=CC=C1c1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1#N/ACN(C)C=O
175
18411/5/202125
Shihong
acscatal.9b00744
C-O Activation
x10.1021/acscatal.9b007442019
NANAE-NuOSO2NMe2
ArylSnBu3
ArylPBu3
#N/A#N/A80KFdioxanedioxanePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'SnCsp2_arCsp2_arCsp2_ar-OCsp2_ar-SnAryl-O[Aryl]-O-SO2-R'Aryl-SnBu3[Aryl]-SnBu3Polar2.25No baseNo BaseNo base
ACS CATALYSIS
_0.36#N/A#N/A#N/A#N/A#N/A#REF!XX3.2525238245.1013665634.1769451947.09133556#REF!#REF!XOS(=O)(N(C)C)=O[Sn](CC)(CC)CCC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1CCCCP(CCCC)CCCC#N/AC1COCCO1
176
18511/5/202125
Shihong
acscatal.9b00744
C-O Activation
x10.1021/acscatal.9b007442019
NANAE-NuOMs
ArylSnBu3
ArylPBu3
#N/A#N/A80KFdioxanedioxanePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'SnCsp2_arCsp2_arCsp2_ar-OCsp2_ar-SnAryl-O[Aryl]-O-SO2-R'Aryl-SnBu3[Aryl]-SnBu3Polar2.25No baseNo BaseNo base
ACS CATALYSIS
_0.36#N/A#N/A#N/A#N/A#N/A#REF!XX3.2525238245.1013665634.1769451947.09133556#REF!#REF!XOS(=O)(=O)C[Sn](CC)(CC)CCC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1CCCCP(CCCC)CCCC#N/AC1COCCO1
177
18611/5/202192
Shihong
anie.201705521
C-O Activation
x10.1002/anie.2017055212017
NA12E-EOCO2Me
AllylBr
Alkyldtbbpy
#N/A#N/Artpyridine-2,6-diamineMgCl2DMADMAZnN-NbpyNitrogenCsp3-Csp3MediumOO-CO-R'XCsp3Csp3Csp3-OCsp3-XAllyl-O[Allyl]-O-CO-R'Alkyl-Br[Alkyl]-BrPolar37.8NitrogenNitrogen(neutral)pyridine-2,6-diamine#REF!#REF!
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.318.581.7105540393.2426955962.4766248184.973380196#REF!0#REF!#REF!XOC(=O)OCBrCC=CCCC=CCCCCC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)CC1=CC(=NC(=C1)N)NCN(C)C(C)=O
178
18711/5/202192
Shihong
anie.201705521
C-O Activation
x10.1002/anie.2017055212017
NA21E-EOCO2Me
AllylBr
AlkylCC(C)[C@H]1COC(C2=CC=CC(C3=N[C@H](CO3)C(C)C)=N2)=N1#N/A#N/A#N/A25pyridineMgCl2DMADMAZn#N/A#N/A#N/ACsp3-Csp3MediumOO-CO-R'XCsp3Csp3Csp3-OCsp3-XAllyl-O[Allyl]-O-CO-R'Alkyl-Br[Alkyl]-BrPolar37.8NitrogenNitrogen(neutral)Nitrogen(neutral)
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.318.581.7105540393.2426955962.4766248184.973380195.17#REF!0#REF!#REF!XOC(=O)OCBrCC=CCCC=CCCC#N/AC1=CN=CC=C1CN(C)C(C)=O
179
18811/5/202127
Shihong
acscatal.0c03993
C-O Activation
x10.1021/acscatal.0c039932020
12E-EOTf
VinylBr
Arylbpy
#N/A#N/A100DMADMAZnN-NbpyNitrogenCsp2-Csp2_arWeakOO-SO2-R'XCsp2Csp2_arCsp2-OCsp2_ar-XVinyl-O[Vinyl]-O-SO2-R'Aryl-Br[Aryl]-BrPolar37.8No baseNo BaseNo base
ACS CATALYSIS
_0.53#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOS(=O)(=O)C(F)(F)FBrC=CC1=CC=CC=C1C=CC1=CC=CC=C1C1(C2=NC=CC=C2)=CC=CC=N1#N/ACN(C)C(C)=O
180
18911/5/2021167
Shihong
ja300031w
C-O Activation
x10.1021/ja300031w2012
11.5E-NuOCO2(2,4,6-trimethoxyphenyl)
AlkylZnX
Aryl2,6-bis((3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazol-2-yl)pyridine
#N/A#N/ArtDMETHFDMEN-N-NpyboxNitrogenCsp3-Csp2_arStrongOO-CO-R'ZnCsp3Csp2_arCsp3-OCsp2_ar-ZnAlkyl-O[Alkyl]-O-CO-R'Aryl-ZnX[Aryl]-ZnXPolar7.2No baseNo BaseNo base
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.1323.86#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XOC(OC1=C(OC)C=C(OC)C=C1OC)=O[Zn]ClCCC1=CC=CC=C1CCC1=CC=CC=C1[H][C@]12[C@](CC3=C2C=CC=C3)([H])OC(C4=CC=CC(C5=N[C@](C(C=CC=C6)=C6C7)([H])[C@]7([H])O5)=N4)=N1#N/ACOCCOC
181
19011/5/2021143
Shihong
acscatal.7b00941
C-O Activation
x10.1021/acscatal.7b009412017
12E-NuOPiv
ArylZnX
Alkyldcype
#N/A#N/A70THFiPr2OTHFP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp3MediumOO-CO-R'ZnCsp2_arCsp3Csp2_ar-OCsp3-ZnAryl-O[Aryl]-O-CO-R'Alkyl-ZnX[Alkyl]-ZnXPolar7.58No baseNo BaseNo base
ACS CATALYSIS
_0.3320.28#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XOC(=O)C(C)(C)C[Zn]ClC1=CC=CC=C1CCC1=CC=CC=C1CCP(C1CCCCC1)(C2CCCCC2)CCP(C3CCCCC3)C4CCCCC4#N/AC1CCOC1
182
19111/5/2021143
Shihong
acscatal.7b00941
C-O Activation
x10.1021/acscatal.7b009412017
12E-NuOPiv
ArylZnX
Alkyldcype
#N/A#N/A70THFiPr2OTHFP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp3MediumOO-CO-R'ZnCsp2_arCsp3Csp2_ar-OCsp3-ZnAryl-O[Aryl]-O-CO-R'Alkyl-ZnX[Alkyl]-ZnXPolar7.58No baseNo BaseNo base
ACS CATALYSIS
_0.3320.28#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XOC(=O)C(C)(C)C[Zn]ClC1=CC=CC=C1CCC1=CC=CC=C1CCP(C1CCCCC1)(C2CCCCC2)CCP(C3CCCCC3)C4CCCCC4#N/AC1CCOC1
183
19311/6/2021241
Elaine
acscatal.6b01120
C-H Activation
x10.1021/acscatal.6b011202016
14E-NuH
AlkyneBr
ArylDTBEDA
#N/A#N/A100LiOtBudioxaneN-NN-NNitrogenCsp1-Csp2_arNu-HHXCsp1Csp2_arCsp1-HCsp2_ar-XAlkyne-H[Alkyne]-Aryl-Br[Aryl]-Br#N/A#N/AIonic-OtBuLi+#REF!
ACS CATAL
_2.8589353663.2821934583.0705644124.0077900319#REF!0#REF!#REF!XHBrC#CC1=CC=CC=C1C#CC1=CC=CC=C1CC(C)(C)NCCNC(C)(C)CCC(C)(C)[O-].[Li+]C1COCCO1
184
19411/6/2021241
Elaine
acscatal.6b01120
C-H Activation
x10.1021/acscatal.6b011202016
15E-NuH
ArylBr
AlkyneDTBEDA
#N/A#N/A90-100LiOtBudioxaneN-NN-NNitrogenCsp2_ar-Csp1Nu-HHXCsp2_arCsp1Csp2_ar-HCsp1-XAryl-H[Aryl]-Alkyne-Br[Alkyne]-Br#N/A#N/AIonic-OtBuLi+#REF!
ACS CATAL
_2.8589353663.2821934583.0705644124.0077900319#REF!#N/A#N/A0#REF!#REF!#N/AHBrC1=CC=CC=C1C#CC1=CC=CC=C1C#CCC(C)(C)NCCNC(C)(C)CCC(C)(C)[O-].[Li+]C1COCCO1
185
19911/8/2021241
Elaine
acscatal.6b01120
C-H Activation
x10.1021/acscatal.6b011202016
1:4 in other graph in same artiClesnanaE-NuBr
AlkyneH
ArylDTBEDA
#N/A#N/A90-120LiOtBudioxaneN-NN-NNitrogenCsp1-Csp2_arXHCsp1Csp2_arCsp1-XCsp2_ar-HAlkyne-X[Alkyne]-Aryl-H[Aryl]-H#N/A#N/AIonic-OtBuLi+#REF!
ACS CATAL
_2.8589353663.2821934583.0705644124.0077900319#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5BrHC#CC1=CC=CC=C1C#CC1=CC=CC=C1CC(C)(C)NCCNC(C)(C)CCC(C)(C)[O-].[Li+]C1COCCO1
186
20011/8/2021271
Elaine
jacs.9b00111
C-N Activation
x10.1021/jacs.9b001112019
11.6E-NuTriphenylpyridinium+BF4-
HetZnX
Alkylttbtpy
#N/A#N/A60THFDMATHFZnXN-N-NterpyNitrogenCsp2_ar-Csp3NPyridiniumZnCsp2_arCsp3Csp2_ar-NCsp3-ZnHet-N[Het]-PyridiniumAlkyl-ZnX[Alkyl]-ZnXPolar7.58No baseNo BaseNo base
J AM CHEM SOC
_#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!X[N+]1=C(C=C(C=C1C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.F[B-](F)(F)F[Zn]ClC1=NC=CC=C1CCC1=CC=NC=C1CCCC(C)(C1=CN=C(C2=NC(C3=NC=C(C(C)(C)C)C=C3)=CC(C(C)(C)C)=C2)C=C1)C#N/AC1CCOC1
187
20111/9/2021190
Elaine
sciadv.aaw9516
C-N Activation
x10.1126/sciadv.aaw95162019
c Condition B: Pyridinium salts (0.2 mmol), Ni(acac)2 (0.02 mmol), L1 (0.02 mmol), zinc flake (−325 mesh, 99.9%) (0.5 mmol), bromoalkynes (0.3 mmol), and DMF (1.0 ml), 60°C.
The leaving group deduced from the condition
11.5E-ETriphenylpyridinium+BF4-
AlkylNH2
Alkyldtbbpy
#N/A#N/A60DMFDMFN-NbpyNitrogenCsp3-Csp3NPyridiniumNCsp3Csp3Csp3-NCsp3-NAlkyl-N[Alkyl]-PyridiniumAlkyl-NH2[Alkyl]-NH2Polar36.7No baseNo BaseNo baseMediumNH2SCI ADV_#N/A#N/A#N/A#N/A#N/A#REF!5.9526.020#REF!#REF!X[N+]1=C(C=C(C=C1C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.F[B-](F)(F)FNCCCCCCCCCC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/ACN(C)C=O
188
20211/9/2021190
Elaine
sciadv.aaw9516
C-N Activation
x10.1126/sciadv.aaw95162019
d Condition C: Pyridinium salts (0.2 mmol), Ni(COD)2 (0.04 mmol), L1 (0.04 mmol), tetrabutylammonium iodide (0.1 mmol), zinc flake (−325 mesh, 99.9%) (0.5 mmol), bromoalkanes (0.8 mmol), and dimethylamine (1.0 ml), 60°C.
The leaving group deduced from the condition
11.5E-ETriphenylpyridinium+BF4-
AlkylNH2
Aryldtbbpy
#N/A#N/A60DMFDMFN-NbpyNitrogenCsp3-Csp2_arNPyridiniumNCsp3Csp2_arCsp3-NCsp2_ar-NAlkyl-N[Alkyl]-PyridiniumAryl-NH2[Aryl]-NH2Polar36.7No baseNo BaseNo baseMediumNH2SCI ADV_#N/A#N/A#N/A#N/A#N/A#REF!11.526.020#REF!#REF!X[N+]1=C(C=C(C=C1C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.F[B-](F)(F)FNCCC1=CC=CC=C1CCC1=CC=CC=C1CC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/ACN(C)C=O
189
20311/9/2021190
Elaine
sciadv.aaw9516
C-N Activation
x10.1126/sciadv.aaw95162019
d Condition C: Pyridinium salts (0.2 mmol), Ni(COD)2 (0.04 mmol), L1 (0.04 mmol), tetrabutylammonium iodide (0.1 mmol), zinc flake (−325 mesh, 99.9%) (0.5 mmol), bromoalkanes (0.8 mmol), and dimethylamine (1.0 ml), 60°C.
The leaving group deduced from the condition
11.5E-ETriphenylpyridinium+BF4-
AlkylNH2
Alkynedtbbpy
#N/A#N/A60DMFDMFN-NbpyNitrogenCsp3-Csp1NPyridiniumNCsp3Csp1Csp3-NCsp1-NAlkyl-N[Alkyl]-PyridiniumAlkyne-NH2[Alkyne]-NH2Polar36.7No baseNo BaseNo baseMediumNH2SCI ADV_#N/A#N/A#N/A#N/A#N/A#REF!#N/A#N/A0#REF!#REF!#N/A[N+]1=C(C=C(C=C1C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.F[B-](F)(F)FNCCC#CCCC#CCC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/ACN(C)C=O
190
20411/9/2021190
Elaine
sciadv.aaw9516
C-N Activation
x10.1126/sciadv.aaw95162019
b Condition A: Pyridinium salts (0.2 mmol), NiBr2•diglyme (0.02 mmol), L3 (0.02 mmol), zinc flake (−325 mesh, 99.9%) (0.5 mmol), Aryl iodide 2 (0.3 mmol), and DMF (2.0 ml), 60°C.
The halides leaving group is not sure
11.5E-ETriphenylpyridinium+BF4-
AlkylNH2
Arylterpyridine
#N/A#N/A60DMFDMFN-N-NterpyNitrogenCsp3-Csp2_arNPyridiniumNCsp3Csp2_arCsp3-NCsp2_ar-NAlkyl-N[Alkyl]-PyridiniumAryl-NH2[Aryl]-NH2Polar36.7No baseNo BaseNo baseMediumNH2SCI ADV_#N/A#N/A#N/A#N/A#N/A#REF!11.526.020#REF!#REF!X[N+]1=C(C=C(C=C1C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.F[B-](F)(F)FNCCC1=CC=CC=C1CCC1=CC=CC=C1c1ccnc(c1)c2cccc(n2)c3ccccn3#N/ACN(C)C=O
191
29011/11/202161
Janice
acscatal.9b00884
C-O Activation
x10.1021/acscatal.9b008842019
12E-NuOMe
CarbonylH
MorpholineMe4-1,10-Phen
#N/A#N/A140KOtButoluenetolueneN-NbpyNitrogenCsp2-Nsp3StrongOO-Csp3HCsp2Nsp3Csp2-ONsp3-HCarbonyl-O[Carbonyl]-O-Csp3Morpholine-H[Morpholine]-HNon-Polar2.38Ionic-OtBuK+
ACS CATALYSIS
_-0.286.712.8589353663.2821934583.0705644124.0077900319#REF!9.5921.261.706749553.2392069642.4729782574.96639928#REF!#REF!OCHCC(=O)CN1CCCCC1C(=O)CCC1CCCCC1NCc1ccnc3c1ccc2cccnc23CC(C)(C)[O-].[K+]Cc1ccccc1
192
29111/11/202161
Janice
acscatal.9b00884
C-O Activation
x10.1021/acscatal.9b008842019
12E-NuOMe
CarbonylH
N(H)ArylIpr.HCl
#N/A#N/A140KOtButoluenetolueneNHCCarbeneCarbeneCsp2-Nsp3StrongOO-Csp3HCsp2Nsp3Csp2-ONsp3-HCarbonyl-O[Carbonyl]-O-Csp3N(H)Aryl-H[N(H)Aryl]-HNon-Polar2.38Ionic-OtBuK+
ACS CATALYSIS
_-0.286.712.8589353663.2821934583.0705644124.0077900319#REF!11.526.021.706749553.2392069642.4729782574.96639928#REF!#REF!OCHCC(=O)CNC1=CC=CC=C1C(=O)CCC1=CC=CC=C1NCC(C)c1cccc(C(C)C)c1N2C=[N+](C=C2)c3c(C(C)C)cccc3C(C)C.[Cl-]CC(C)(C)[O-].[K+]Cc1ccccc1
193
29211/11/202161
Janice
acscatal.9b00884
C-O Activation
x10.1021/acscatal.9b008842019
12E-NuOMe
CarbonylH
N(H)Aryl1-(2,6-diisopropylphenyl)-3-(pyridin-2-yl)-1H-imidazol-3-ium bromide
#N/A#N/A140KOtButoluenetolueneNHCCarbeneCarbeneCsp2-Nsp3StrongOO-Csp3HCsp2Nsp3Csp2-ONsp3-HCarbonyl-O[Carbonyl]-O-Csp3N(H)Aryl-H[N(H)Aryl]-HNon-Polar2.38Ionic-OtBuK+
ACS CATALYSIS
_-0.286.712.8589353663.2821934583.0705644124.0077900319#REF!11.526.021.706749553.2392069642.4729782574.96639928#REF!#REF!OCHCC(=O)CNC1=CC=CC=C1C(=O)CCC1=CC=CC=C1NCC(C)C(C=CC=C1C(C)C)=C1N2C=C[N+](C3=NC=CC=C3)=C2.[Br-]CC(C)(C)[O-].[K+]Cc1ccccc1
194
29311/11/202161
Janice
acscatal.9b00884
C-O Activation
x10.1021/acscatal.9b008842019
12E-NuOMe
CarbonylH
N(H)Alkyl1,3-bis(2,4,6-tricyclopentylphenyl)-1H-imidazol-3-ium chloride
#N/A#N/A140KOtButoluenetolueneNHCCarbeneCarbeneCsp2-Nsp3StrongOO-Csp3HCsp2Nsp3Csp2-ONsp3-HCarbonyl-O[Carbonyl]-O-Csp3N(H)Alkyl-H[N(H)Alkyl]-HNon-Polar2.38Ionic-OtBuK+
ACS CATALYSIS
_-0.286.712.8589353663.2821934583.0705644124.0077900319#REF!5.6643.091.706749553.2392069642.4729782574.96639928#REF!#REF!OCHCC(=O)CNCC(=O)CCCN[N+]1(C2=C(C3CCCC3)C=C(C4CCCC4)C=C2C5CCCC5)=CN(C6=C(C7CCCC7)C=C(C8CCCC8)C=C6C9CCCC9)C=C1.[Cl-]CC(C)(C)[O-].[K+]Cc1ccccc1
195
21811/9/2021219
Kelly
anie.201403823
C-O Activation
xx10.1002/anie.2014038232014
11.5E-NuOPiv
ArylH
Alkyldcypt
#N/A#N/A150K3PO4toluenetolueneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp3MediumOO-CO-R'HCsp2_arCsp3Csp2_ar-OCsp3-HAryl-O[Aryl]-O-CO-R'Alkyl-H[Alkyl]-HNon-Polar2.38Ionic-PO4K+
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.3320.282.244780372.9696246982.6072025343.5700586912.37#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5OC(=O)C(C)(C)CHC1=CC=CC=C1CCC1=CC=CC=C1CCC1(P(C2CCCCC2)C3CCCCC3)=CSC=C1P(C4CCCCC4)C5CCCCC5[O-]P(=O)([O-])[O-].[K+].[K+].[K+]Cc1ccccc1
196
21911/9/2021219
Kelly
anie.201403823
C-O Activation
xx10.1002/anie.2014038232014
11.5E-NuOPiv
ArylH
Benzyldcypt
#N/A#N/A150K3PO4toluenetolueneP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp3-ring(s)
MediumOO-CO-R'HCsp2_arCsp3-ring(s)Csp2_ar-OCsp3-ring(s)-HAryl-O[Aryl]-O-CO-R'Benzyl-H[Benzyl]-HNon-Polar2.38Ionic-PO4K+
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.3320.282.244780372.9696246982.6072025343.5700586912.37#REF!12.1701.706749553.2392069642.4729782574.96639928#REF!#REF!21.3OC(=O)C(C)(C)CHC1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1C1(P(C2CCCCC2)C3CCCCC3)=CSC=C1P(C4CCCCC4)C5CCCCC5[O-]P(=O)([O-])[O-].[K+].[K+].[K+]Cc1ccccc1
197
32111/16/2021199
Long
anie.201511486
C-O Activation
x10.1002/anie.2015114862016
NANAE-NuOMe
CarbonylH
N(Alkyl)ArylSIPr
#N/A#N/A60Al(OtBu)3toluenetolueneNHCCarbeneCarbeneCsp2-Nsp3StrongOO-Csp3HCsp2Nsp3Csp2-ONsp3-HCarbonyl-O[Carbonyl]-O-Csp3N(Alkyl)Aryl-H[N(Alkyl)Aryl]-HNon-Polar2.38Ionic-OtBu#N/A
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.286.712.8589353663.2821934583.0705644124.0077900319#REF!15.1912.031.706749553.2392069642.4729782574.96639928#REF!#REF!OCHCC(=O)CN(C)C(C(=O)C)C(=O)CCCC(=O)CN(C)CC(C)c1cccc(C(C)C)c1N2[C]N(CC2)c3c(cccc3C(C)C)C(C)C#N/ACc1ccccc1
198
37012/1/2021155
Shihong
j.tet.2012.04.005
C-O Activation
x10.1016/j.tet.2012.04.0052012
15E-NuOMe
ArylH
MorpholineIPr.HCl
#N/A#N/A100NaOtButoluenetoluene6 equi baseNHCCarbeneCarbeneCsp2_ar-Nsp3StrongOO-Csp3HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-Csp3Morpholine-H[Morpholine]-HNon-Polar2.38Ionic-OtBuNa+HardO-EDG
TETRAHEDRON
_-0.2812.862.8589353663.2821934583.0705644124.0077900319#REF!9.5921.261.706749553.2392069642.4729782574.96639928#REF!#REF!OCHC1=CC=CC=C1N1CCCCC1C1=CC=CC=C1C1CCCCC1NCC(C)c1cccc(C(C)C)c1N2C=[N+](C=C2)c3c(C(C)C)cccc3C(C)C.[Cl-][Na]OC(C)(C)CCc1ccccc1
199
38212/2/2021215
Long
cl.2009.710
C-O Activation
x10.1246/cl.2009.7102009
12E-NuOMe
ArylH
MorpholineIPr.HCl
#N/A#N/A120NaOtButoluenetolueneNHCCarbeneCarbeneCsp2_ar-Nsp3StrongOO-Csp3HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-Csp3Morpholine-H[Morpholine]-HNon-Polar2.38Ionic-OtBuNa+HardO-EDG
CHEMISTRY LETTERS
_-0.2812.862.8589353663.2821934583.0705644124.0077900319#REF!9.5921.261.706749553.2392069642.4729782574.96639928#REF!#REF!OCHC1=CC=CC=C1N1CCCCC1C1=CC=CC=C1C1CCCCC1NCC(C)c1cccc(C(C)C)c1N2C=[N+](C=C2)c3c(C(C)C)cccc3C(C)C.[Cl-][Na]OC(C)(C)CCc1ccccc1
200
22311/9/202189
Kelly
ol4011757
C-O Activation
x10.1021/ol40117572013
11.2E-NuOCONEt2
ArylB(OH)2
ArylPCy3
#N/A#N/A120K2CO3dioxanedioxanePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
MediumOO-CO-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-CO-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar2.25Ionic-CO3K+
ORGANIC LETTERS
_0.3121.411.72.530430542.115215273.4538974810.33#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OC(N(CC)CC)=OB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3O=C([O-])[O-].[K+].[K+]C1COCCO1
201
22411/9/202189
Kelly
ol4011757
C-O Activation
xx10.1021/ol40117572013
13E-NuOMe
ArylMgX
ArylPCy3
#N/A#N/A130toluenetoluenePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
StrongOO-Csp3MgCsp2_arCsp2_arCsp2_ar-OCsp2_ar-MgAryl-O[Aryl]-O-Csp3Aryl-MgX[Aryl]-MgXNon-Polar2.38No baseNo BaseNo base
ORGANIC LETTERS
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2OC[Mg]ClC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/ACc1ccccc1
202
22511/9/2021198
Kelly
ja307045r
C-O Activation
x10.1021/ja307045r2012
R=Aryl, 2a-2i12E-NuOH
BenzylMgX
ArylPCy3
#N/A#N/A60toluenenBu2OtoluenePPhosphine (Monodentate)Phosphine
Csp3-ring(s)-Csp2_ar
StrongOOHMgCsp3-ring(s)Csp2_arCsp3-ring(s)-OCsp2_ar-MgBenzyl-O[Benzyl]-OHAryl-MgX[Aryl]-MgXNon-Polar2.38No baseNo BaseNo base
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_-0.81#N/A#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2O[Mg]ClCC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/ACc1ccccc1
203
22611/9/2021198
Kelly
ja307045r
C-O Activation
xx10.1021/ja307045r2012
12E-NuOH
BenzylMgX
ArylPCy3
#N/A#N/A60toluenenBu2OtoluenePPhosphine (Monodentate)Phosphine
Csp3-ring(s)-Csp2_ar
StrongOOHMgCsp3-ring(s)Csp2_arCsp3-ring(s)-OCsp2_ar-MgBenzyl-O[Benzyl]-OHAryl-MgX[Aryl]-MgXNon-Polar2.38No baseNo BaseNo base
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_-0.81#N/A#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2O[Mg]ClCC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/ACc1ccccc1
204
22711/9/2021198
Kelly
ja307045r
C-O Activation
x10.1021/ja307045r2012
R=Benzyl, 2j12E-NuOH
BenzylMgX
BenzylPCy3
#N/A#N/A60toluenetoluenePPhosphine (Monodentate)Phosphine
Csp3-ring(s)-Csp3-ring(s)
StrongOOHMgCsp3-ring(s)Csp3-ring(s)Csp3-ring(s)-OCsp3-ring(s)-MgBenzyl-O[Benzyl]-OHBenzyl-MgX[Benzyl]-MgXNon-Polar2.38No baseNo BaseNo base
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_-0.81#N/A#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!29O[Mg]ClCC1=CC=CC=C1CC1=CC=CC=C1CC1=CC=CC=C1CC1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/ACc1ccccc1
205
22811/9/2021191
Long
ol502583h
C-O Activation
x10.1021/ol502583h2014
11.5E-NuOMe
BenzylB(nep)
ArylICy.HCl
#N/A#N/A120CsFNaOtButoluenetolueneNHCCarbeneCarbene
Csp3-ring(s)-Csp2_ar
StrongOO-Csp3BCsp3-ring(s)Csp2_arCsp3-ring(s)-OCsp2_ar-BBenzyl-O[Benzyl]-O-Csp3Aryl-B(nep)[Aryl]-B(nep)Non-Polar2.38Ionic-FCs+#N/A#N/A
ORGANIC LETTERS
_-0.28#N/A03.14#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OCB1OCC(C)(CO1)CCC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1[n+]1(C2CCCCC2)cn(C3CCCCC3)cc1.[Cl-][Cs]FCc1ccccc1
206
22911/9/2021191
Long
ol502583h
C-O Activation
x10.1021/ol502583h2014
12E-NuOMe
BenzylB(nep)
ArylICy.HCl
#N/A#N/A120CsFNaOtButoluenetolueneNHCCarbeneCarbene
Csp3-ring(s)-Csp2_ar
StrongOO-Csp3BCsp3-ring(s)Csp2_arCsp3-ring(s)-OCsp2_ar-BBenzyl-O[Benzyl]-O-Csp3Aryl-B(nep)[Aryl]-B(nep)Non-Polar2.38Ionic-FCs+#N/A#N/A
ORGANIC LETTERS
_-0.28#N/A03.14#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OCB1OCC(C)(CO1)CCC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1[n+]1(C2CCCCC2)cn(C3CCCCC3)cc1.[Cl-][Cs]FCc1ccccc1
207
23011/9/2021191
Long
ol502583h
C-O Activation
x10.1021/ol502583h2014
11.5E-NuOMe
ArylB(nep)
ArylICy.HCl
#N/A#N/A120CsFNaOtButoluenetolueneNHCCarbeneCarbene
Csp2_ar-Csp2_ar
StrongOO-Csp3BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-Csp3Aryl-B(nep)[Aryl]-B(nep)Non-Polar2.38Ionic-FCs+#N/A#N/A
ORGANIC LETTERS
_-0.2812.8603.14#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OCB1OCC(C)(CO1)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1[n+]1(C2CCCCC2)cn(C3CCCCC3)cc1.[Cl-][Cs]FCc1ccccc1
208
23111/9/2021156
Long
jo2022982
C-O Activation
x10.1021/jo20229822012
NA
OMs is leaving groupNANAE-NuOMs
ArylB(nep)
ArylPCy3
#N/A#N/A25K3PO4THFTHFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(nep)[Aryl]-B(nep)Polar7.58Ionic-PO4K+#N/A#N/A
JOURNAL OF ORGANIC CHEMISTRY
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OS(=O)(=O)CB1OCC(C)(CO1)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1CCOC1
209
23211/9/2021156
Long
jo2022982
C-O Activation
x10.1021/jo20229822012
OSO2Me is leaving groupNANAE-NuOSO2NMe2
ArylB(nep)
ArylPCy3
#N/A#N/A25K3PO4THFTHFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(nep)[Aryl]-B(nep)Polar7.58Ionic-PO4K+#N/A#N/A
JOURNAL OF ORGANIC CHEMISTRY
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OS(=O)(N(C)C)=OB1OCC(C)(CO1)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1CCOC1
210
10711/4/2021234
Kelly
ja311783k
C-O Activation
x10.1021/ja311783k2013
blue one, not sure LVG2(artiCle did not mention any, assume it is the same as another schme)12E-NuPyrrolidineCarbonylicacid
BenzylB(nep)
ArylSIMes
#N/A#N/ArtKOtBun-BuOHTHFtoluene
THF/toluene
NHCCarbeneCarbene
Csp3-ring(s)-Csp2_ar
MediumOO-CO-R'BCsp3-ring(s)Csp2_arCsp3-ring(s)-OCsp2_ar-BBenzyl-O[Benzyl]-O-CO-R'Aryl-B(nep)[Aryl]-B(nep)Both1.19Ionic-OtBuK+#N/A#N/A
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.31#N/A2.8589353663.2821934583.0705644124.0077900319#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OC(=O)N1CCCC1B1OCC(C)(CO1)CCC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1F[B-](F)(F)F.CC(C)c1cccc(C(C)C)c1N2CC[N+](=C2)c3c(cccc3C(C)C)C(C)CCC(C)(C)[O-].[K+]C1CCOC1
211
10811/4/2021234
Kelly
ja311783k
C-O Activation
x10.1021/ja311783k2013
red one, not sure LVG2(artiCle did not mention any, assume it is the same as another schme)12E-NuPyrrolidineCarbonylicacid
BenzylB(nep)
ArylPCy3
#N/A#N/ArtKOtBun-BuOHTHFtoluene
THF/toluene
PPhosphine (Monodentate)Phosphine
Csp3-ring(s)-Csp2_ar
MediumOO-CO-R'BCsp3-ring(s)Csp2_arCsp3-ring(s)-OCsp2_ar-BBenzyl-O[Benzyl]-O-CO-R'Aryl-B(nep)[Aryl]-B(nep)Both1.19Ionic-OtBuK+#N/A#N/A
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.31#N/A2.8589353663.2821934583.0705644124.0077900319#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OC(=O)N1CCCC1B1OCC(C)(CO1)CCC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3CC(C)(C)[O-].[K+]C1CCOC1
212
23511/9/2021241
Long
ja810157e
C-O Activation
x10.1021/ja810157e2009
NANAE-NuOAc
ArylB(OH)2
ArylPCy3
#N/A#N/A110K3PO4dioxanedioxanePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
MediumOO-CO-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-CO-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar2.25Ionic-PO4K+
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.3114.752.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OC(C)=OB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1COCCO1
213
23611/9/2021208
Long
ol203322v
C-O Activation
xx10.1021/ol203322v2012
12E-NuOPiv
ArylH
Vinyldppf
#N/A#N/A125K3PO4toluenetolueneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp2MediumOO-CO-R'HCsp2_arCsp2Csp2_ar-OCsp2-HAryl-O[Aryl]-O-CO-R'Vinyl-H[Vinyl]-HNon-Polar2.38Ionic-PO4K+
ORGANIC LETTERS
_0.3320.282.244780372.9696246982.6072025343.5700586912.37#REF!6.0701.706749553.2392069642.4729782574.96639928#REF!#REF!115.6OC(=O)C(C)(C)CHC1=CC=CC=C1C=CC1=CC=CC=C1C=Cc1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1[O-]P(=O)([O-])[O-].[K+].[K+].[K+]Cc1ccccc1
214
23711/9/2021208
Long
ol203322v
C-O Activation
xx10.1021/ol203322v2012
12E-NuOPiv
ArylH
Vinyldppf
#N/A#N/A150K3PO4toluenetolueneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp2MediumOO-CO-R'HCsp2_arCsp2Csp2_ar-OCsp2-HAryl-O[Aryl]-O-CO-R'Vinyl-H[Vinyl]-HNon-Polar2.38Ionic-PO4K+
ORGANIC LETTERS
_0.3320.282.244780372.9696246982.6072025343.5700586912.37#REF!6.0701.706749553.2392069642.4729782574.96639928#REF!#REF!115.6OC(=O)C(C)(C)CHC1=CC=CC=C1C=CC1=CC=CC=C1C=Cc1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1[O-]P(=O)([O-])[O-].[K+].[K+].[K+]Cc1ccccc1
215
23811/9/202185
Long
anie.201808560
C-O Activation
x10.1002/anie.2018085602018
11.2E-NuOMe
CarbonylH
MorpholineIPr
#N/A#N/A140toluenetolueneNHCCarbeneCarbeneCsp2-Nsp3StrongOO-Csp3HCsp2Nsp3Csp2-ONsp3-HCarbonyl-O[Carbonyl]-O-Csp3Morpholine-H[Morpholine]-HNon-Polar2.38No baseNo BaseNo base
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.286.71#N/A#N/A#N/A#N/A#N/A#REF!9.5921.261.706749553.2392069642.4729782574.96639928#REF!#REF!OCHCC(=O)CN1CCCCC1C(=O)CCC1CCCCC1NCC(C)C(C=CC=C1C(C)C)=C1N2C=CN(C3=C(C(C)C)C=CC=C3C(C)C)C2#N/ACc1ccccc1
216
23911/9/202185
Long
anie.201808560
C-O Activation
x10.1002/anie.2018085602018
11.2E-NuOMe
CarbonylH
MorpholineIPr
#N/A#N/A140toluenetolueneNHCCarbeneCarbeneCsp2-Nsp3StrongOO-Csp3HCsp2Nsp3Csp2-ONsp3-HCarbonyl-O[Carbonyl]-O-Csp3Morpholine-H[Morpholine]-HNon-Polar2.38No baseNo BaseNo base
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.286.71#N/A#N/A#N/A#N/A#N/A#REF!9.5921.261.706749553.2392069642.4729782574.96639928#REF!#REF!OCHCC(=O)CN1CCCCC1C(=O)CCC1CCCCC1NCC(C)C(C=CC=C1C(C)C)=C1N2C=CN(C3=C(C(C)C)C=CC=C3C(C)C)C2#N/ACc1ccccc1
217
38312/2/2021215
Long
cl.2009.710
C-O Activation
x10.1246/cl.2009.7102009
morpholine is 212.5E-NuOMe
ArylH
MorpholineIPr.HCl
#N/A#N/A120NaOtButoluenetolueneNHCCarbeneCarbeneCsp2_ar-Nsp3StrongOO-Csp3HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-Csp3Morpholine-H[Morpholine]-HNon-Polar2.38Ionic-OtBuNa+HardO-EDG
CHEMISTRY LETTERS
_-0.2812.862.8589353663.2821934583.0705644124.0077900319#REF!9.5921.261.706749553.2392069642.4729782574.96639928#REF!#REF!OCHC1=CC=CC=C1N1CCCCC1C1=CC=CC=C1C1CCCCC1NCC(C)c1cccc(C(C)C)c1N2C=[N+](C=C2)c3c(C(C)C)cccc3C(C)C.[Cl-][Na]OC(C)(C)CCc1ccccc1
218
11211/4/202129
Kelly
anie.201806790
C-O Activation
x10.1002/anie.2018067902018
11.5E-NuOSi(tBu)Me2
ArylH
N(H)AlkylIPrMe.HCl
#N/A#N/A120NaOtButoluenetolueneNHCCarbeneCarbeneCsp2_ar-Nsp3StrongOO-SiR'3HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-SiR'3N(H)Alkyl-H[N(H)Alkyl]-HNon-Polar2.38Ionic-OtBuNa+
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.2725.012.8589353663.2821934583.0705644124.0077900319#REF!5.6643.091.706749553.2392069642.4729782574.96639928#REF!#REF!O[Si](C)(C)C(C)(C)CHC1=CC=CC=C1NCC1=CC=CC=C1CNCC(C)c1cccc(C(C)C)c1N2C=[N+](C(C)=C2C)c3c(C(C)C)cccc3C(C)C.[Cl-][Na]OC(C)(C)CCc1ccccc1
219
11311/4/202129
Kelly
anie.201806790
C-O Activation
x10.1002/anie.2018067902018
11.5E-NuOSi(tBu)Me2
ArylH
MorpholineIPrMe.HCl
#N/A#N/A120NaOtButoluenetolueneNHCCarbeneCarbeneCsp2_ar-Nsp3StrongOO-SiR'3HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-SiR'3Morpholine-H[Morpholine]-HNon-Polar2.38Ionic-OtBuNa+
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.2725.012.8589353663.2821934583.0705644124.0077900319#REF!9.5921.261.706749553.2392069642.4729782574.96639928#REF!#REF!O[Si](C)(C)C(C)(C)CHC1=CC=CC=C1N1CCCCC1C1=CC=CC=C1C1CCCCC1NCC(C)c1cccc(C(C)C)c1N2C=[N+](C(C)=C2C)c3c(C(C)C)cccc3C(C)C.[Cl-][Na]OC(C)(C)CCc1ccccc1
220
11411/4/202129
Kelly
anie.201806790
C-O Activation
x10.1002/anie.2018067902018
11.5E-NuOSi(tBu)Me2
ArylH
N(H)AlkylIPrMe.HCl
#N/A#N/A120NaOtButoluenetolueneNHCCarbeneCarbeneCsp2_ar-Nsp3StrongOO-SiR'3HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-SiR'3N(H)Alkyl-H[N(H)Alkyl]-HNon-Polar2.38Ionic-OtBuNa+
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.2725.012.8589353663.2821934583.0705644124.0077900319#REF!5.6643.091.706749553.2392069642.4729782574.96639928#REF!#REF!O[Si](C)(C)C(C)(C)CHC1=CC=CC=C1NCC1=CC=CC=C1CNCC(C)c1cccc(C(C)C)c1N2C=[N+](C(C)=C2C)c3c(C(C)C)cccc3C(C)C.[Cl-][Na]OC(C)(C)CCc1ccccc1
221
24411/9/202175
Long
chem.201603436
C-O Activation
xx10.1002/chem.2016034362016
11.5E-NuOMe
ArylLi
ArylSIMes.HCl
#N/A#N/ArttoluenetolueneNHCCarbeneCarbene
Csp2_ar-Csp2_ar
StrongOO-Csp3LiCsp2_arCsp2_arCsp2_ar-OCsp2_ar-LiAryl-O[Aryl]-O-Csp3Aryl-Li[Aryl]-LiNon-Polar2.38No baseNo BaseNo base
CHEMISTRY-A EUROPEAN JOURNAL
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!XX1.7061130233.2414063642.4737596946.9930727#REF!#REF!85.3OC[Li]C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1Cc1cc(C)c(N2CCN(c3c(C)cc(C)cc3C)[C]2)c(C)c1.Cl#N/ACc1ccccc1
222
24511/9/202175
Long
chem.201603436
C-O Activation
xx10.1002/chem.2016034362016
11.5E-NuOMe
ArylLi
HetSIMes.HCl
#N/A#N/ArttoluenetolueneNHCCarbeneCarbene
Csp2_ar-Csp2_ar
StrongOO-Csp3LiCsp2_arCsp2_arCsp2_ar-OCsp2_ar-LiAryl-O[Aryl]-O-Csp3Het-Li[Het]-LiNon-Polar2.38No baseNo BaseNo base
CHEMISTRY-A EUROPEAN JOURNAL
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!XX1.7061130233.2414063642.4737596946.9930727#REF!#REF!106.6OC[Li]C1=CC=CC=C1C1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1Cc1cc(C)c(N2CCN(c3c(C)cc(C)cc3C)[C]2)c(C)c1.Cl#N/ACc1ccccc1
223
24611/9/202175
Long
chem.201603436
C-O Activation
xx10.1002/chem.2016034362016
11.5E-NuOMe
ArylLi
HetSIMes.HCl
#N/A#N/ArttoluenetolueneNHCCarbeneCarbene
Csp2_ar-Csp2_ar
StrongOO-Csp3LiCsp2_arCsp2_arCsp2_ar-OCsp2_ar-LiAryl-O[Aryl]-O-Csp3Het-Li[Het]-LiNon-Polar2.38No baseNo BaseNo base
CHEMISTRY-A EUROPEAN JOURNAL
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!XX1.7061130233.2414063642.4737596946.9930727#REF!#REF!106.6OC[Li]C1=CC=CC=C1C1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1Cc1cc(C)c(N2CCN(c3c(C)cc(C)cc3C)[C]2)c(C)c1.Cl#N/ACc1ccccc1
224
24711/9/2021185
Long
ol503707m
C-O Activation
xx10.1021/ol503707m2015
12E-NuOMe
ArylMgX
AlkyneICy.HCl
#N/A#N/A120dioxanedioxaneNHCCarbeneCarbeneCsp2_ar-Csp1StrongOO-Csp3MgCsp2_arCsp1Csp2_ar-OCsp1-MgAryl-O[Aryl]-O-Csp3Alkyne-MgX[Alkyne]-MgXPolar2.25No baseNo BaseNo base
ORGANIC LETTERS
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!#N/A#N/A0#REF!#REF!#N/AOC[Mg]ClC1=CC=CC=C1C#CC1=CC=CC=C1C#C[n+]1(C2CCCCC2)cn(C3CCCCC3)cc1.[Cl-]#N/AC1COCCO1
225
24811/9/2021232
Long
b718998b
C-O Activation
xx10.1039/b718998b2008
OMe as LVG11.2E-NuOMe
ArylMgX
AlkylPCy3
#N/A#N/A80toluenetoluenePPhosphine (Monodentate)PhosphineCsp2_ar-Csp3StrongOO-Csp3MgCsp2_arCsp3Csp2_ar-OCsp3-MgAryl-O[Aryl]-O-Csp3Alkyl-MgX[Alkyl]-MgXNon-Polar2.38No baseNo BaseNo base
CHEMICAL COMMUNICATIONS
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OC[Mg]ClC1=CC=CC=C1CCC1=CC=CC=C1CCC1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/ACc1ccccc1
226
24911/9/2021232
Long
b718998b
C-O Activation
xx10.1039/b718998b2008
OEt as LVG11.2E-NuOEt
ArylMgX
AlkylPCy3
#N/A#N/A80toluenetoluenePPhosphine (Monodentate)PhosphineCsp2_ar-Csp3StrongOO-Csp3MgCsp2_arCsp3Csp2_ar-OCsp3-MgAryl-O[Aryl]-O-Csp3Alkyl-MgX[Alkyl]-MgXNon-Polar2.38No baseNo BaseNo base
CHEMICAL COMMUNICATIONS
_-0.2414.7#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OCC[Mg]ClC1=CC=CC=C1CCC1=CC=CC=C1CCC1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/ACc1ccccc1
227
25011/9/2021232
Long
b718998b
C-O Activation
xx10.1039/b718998b2008
OTMS as LVG11.2E-NuOTMS
ArylMgX
AlkylPCy3
#N/A#N/A80toluenetoluenePPhosphine (Monodentate)PhosphineCsp2_ar-Csp3StrongOO-SiR'3MgCsp2_arCsp3Csp2_ar-OCsp3-MgAryl-O[Aryl]-O-SiR'3Alkyl-MgX[Alkyl]-MgXNon-Polar2.38No baseNo BaseNo base
CHEMICAL COMMUNICATIONS
_-0.2719.47#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2O[Si](C)(C)C[Mg]ClC1=CC=CC=C1CCC1=CC=CC=C1CCC1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/ACc1ccccc1
228
25111/9/2021232
Long
b718998b
C-O Activation
xx10.1039/b718998b2008
OPh as LVG11.2E-NuOPh
ArylMgX
AlkylPCy3
#N/A#N/A80toluenetoluenePPhosphine (Monodentate)PhosphineCsp2_ar-Csp3StrongOO-Csp2MgCsp2_arCsp3Csp2_ar-OCsp3-MgAryl-O[Aryl]-O-Csp2Alkyl-MgX[Alkyl]-MgXNon-Polar2.38No baseNo BaseNo base
CHEMICAL COMMUNICATIONS
_-0.3220.71#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OC1=CC=CC=C1[Mg]ClC1=CC=CC=C1CCC1=CC=CC=C1CCC1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/ACc1ccccc1
229
25211/9/2021232
Long
b718998b
C-O Activation
xx10.1039/b718998b2008
OBun as LVG11.2E-NuOnBu
ArylMgX
AlkylPCy3
#N/A#N/A80toluenetoluenePPhosphine (Monodentate)PhosphineCsp2_ar-Csp3StrongOO-Csp3MgCsp2_arCsp3Csp2_ar-OCsp3-MgAryl-O[Aryl]-O-Csp3Alkyl-MgX[Alkyl]-MgXNon-Polar2.38No baseNo BaseNo base
CHEMICAL COMMUNICATIONS
_-0.2418.4#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OCCCC[Mg]ClC1=CC=CC=C1CCC1=CC=CC=C1CCC1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/ACc1ccccc1
230
25311/9/2021232
Long
b718998b
C-O Activation
xx10.1039/b718998b2008
OBui as LVG11.2E-NuOiBu
ArylMgX
AlkylPCy3
#N/A#N/A80toluenetoluenePPhosphine (Monodentate)PhosphineCsp2_ar-Csp3StrongOO-Csp3MgCsp2_arCsp3Csp2_ar-OCsp3-MgAryl-O[Aryl]-O-Csp3Alkyl-MgX[Alkyl]-MgXNon-Polar2.38No baseNo BaseNo base
CHEMICAL COMMUNICATIONS
_-0.2418.4#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OCC(C)C[Mg]ClC1=CC=CC=C1CCC1=CC=CC=C1CCC1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/ACc1ccccc1
231
25411/9/2021232
Long
b718998b
C-O Activation
xx10.1039/b718998b2008
OBut as LVG11.2E-NuOtBu
ArylMgX
AlkylPCy3
#N/A#N/A80toluenetoluenePPhosphine (Monodentate)PhosphineCsp2_ar-Csp3StrongOO-Csp3MgCsp2_arCsp3Csp2_ar-OCsp3-MgAryl-O[Aryl]-O-Csp3Alkyl-MgX[Alkyl]-MgXNon-Polar2.38No baseNo BaseNo base
CHEMICAL COMMUNICATIONS
_-0.2418.4#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OC(C)(C)C[Mg]ClC1=CC=CC=C1CCC1=CC=CC=C1CCC1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/ACc1ccccc1
232
25511/9/2021168
Long
acs.orglett.5b02200
C-O Activation
x10.1021/acs.orglett.5b022002015
12E-NuOMe
ArylMgX
AlkylICy.HCl
#N/A#N/A100toluenetolueneNHCCarbeneCarbeneCsp2_ar-Csp3StrongOO-Csp3MgCsp2_arCsp3Csp2_ar-OCsp3-MgAryl-O[Aryl]-O-Csp3Alkyl-MgX[Alkyl]-MgXNon-Polar2.38No baseNo BaseNo base
ORGANIC LETTERS
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OC[Mg]ClC1=CC=CC=C1CCC1=CC=CC=C1CC[n+]1(C2CCCCC2)cn(C3CCCCC3)cc1.[Cl-]#N/ACc1ccccc1
233
25611/9/2021168
Long
acs.orglett.5b02200
C-O Activation
x10.1021/acs.orglett.5b022002015
11.5E-NuOMe
ArylMgX
BenzylICy.HCl
#N/A#N/A100toluenetolueneNHCCarbeneCarbene
Csp2_ar-Csp3-ring(s)
StrongOO-Csp3MgCsp2_arCsp3-ring(s)Csp2_ar-OCsp3-ring(s)-MgAryl-O[Aryl]-O-Csp3Benzyl-MgX[Benzyl]-MgXNon-Polar2.38No baseNo BaseNo base
ORGANIC LETTERS
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!29OC[Mg]ClC1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1[n+]1(C2CCCCC2)cn(C3CCCCC3)cc1.[Cl-]#N/ACc1ccccc1
234
25711/9/202147
Long
jacs.9b03280
C-O Activation
xx10.1021/jacs.9b032802019
11.5E-EOTf
ArylOH
ArylTriphos
#N/A#N/A130TMPtolueneacetoneacetoneP-P-PPhosphine (Tridentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'OCsp2_arCsp2_arCsp2_ar-OCsp2_ar-OAryl-O[Aryl]-O-SO2-R'Aryl-OH[Aryl]-OHPolar20.7NitrogenNitrogen(neutral)Nitrogen(neutral)HardOH
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.531.7105540393.2426955962.4766248184.9733801910.92#REF!0#REF!#REF!OS(=O)(=O)C(F)(F)FOC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1CC(CP(C1=CC=CC=C1)C2=CC=CC=C2)(CP(C3=CC=CC=C3)C4=CC=CC=C4)CP(C5=CC=CC=C5)C6=CC=CC=C6CC1(C)CCCC(C)(C)N1Cc1ccccc1
235
25811/9/202147
Long
jacs.9b03280
C-O Activation
xx10.1021/jacs.9b032802019
11.5E-EOTf
ArylOH
HetTriphos
#N/A#N/A130TMPtolueneacetoneacetoneP-P-PPhosphine (Tridentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'OCsp2_arCsp2_arCsp2_ar-OCsp2_ar-OAryl-O[Aryl]-O-SO2-R'Het-OH[Het]-OHPolar20.7NitrogenNitrogen(neutral)Nitrogen(neutral)HardOH
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.531.7105540393.2426955962.4766248184.9733801910.92#REF!0#REF!#REF!XOS(=O)(=O)C(F)(F)FOC1=CC=CC=C1C1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1CC(CP(C1=CC=CC=C1)C2=CC=CC=C2)(CP(C3=CC=CC=C3)C4=CC=CC=C4)CP(C5=CC=CC=C5)C6=CC=CC=C6CC1(C)CCCC(C)(C)N1Cc1ccccc1
236
25911/9/2021176
Long
anie.201503936
C-O Activation
x10.1002/anie.2015039362015
??E-EOMe
Csp3-(Aryl)(OR)I
Arylbpp
#N/A#N/A23DMADMAZnTSMClN-N-NterpyNitrogen
Csp3-ring(s)-Csp2_ar
StrongOO-Csp3XCsp3-ring(s)Csp2_arCsp3-ring(s)-OCsp2_ar-XCsp3-(Aryl)(OR)-O[Csp3-(Aryl)(OR)]-O-Csp3Aryl-I[Aryl]-IPolar37.8No baseNo BaseNo base
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.28#N/A#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOCIC(O)C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C(O)C1=CC=CC=C1C1(N2C=CC=N2)=NC(N3C=CC=N3)=CC=C1#N/ACN(C)C(C)=O
237
26011/9/2021176
Long
anie.201503936
C-O Activation
x10.1002/anie.2015039362015
??E-EOMe
Csp3-(Aryl)(OR)I
Vinylbpp
#N/A#N/A23DMADMAZnTSMClN-N-NterpyNitrogen
Csp3-ring(s)-Csp2
StrongOO-Csp3XCsp3-ring(s)Csp2Csp3-ring(s)-OCsp2-XCsp3-(Aryl)(OR)-O[Csp3-(Aryl)(OR)]-O-Csp3Vinyl-I[Vinyl]-IPolar37.8No baseNo BaseNo base
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.28#N/A#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOCIC(O)C1=CC=CC=C1C=CC1=CC=CC=C1C(O)C=CC1(N2C=CC=N2)=NC(N3C=CC=N3)=CC=C1#N/ACN(C)C(C)=O
238
26111/9/2021176
Long
anie.201503936
C-O Activation
x10.1002/anie.2015039362015
??E-EOMe
Csp3-(Aryl)(OR)I
Arylbpp
#N/A#N/A23DMADMAZnTSMClN-N-NterpyNitrogen
Csp3-ring(s)-Csp2_ar
StrongOO-Csp3XCsp3-ring(s)Csp2_arCsp3-ring(s)-OCsp2_ar-XCsp3-(Aryl)(OR)-O[Csp3-(Aryl)(OR)]-O-Csp3Aryl-I[Aryl]-IPolar37.8No baseNo BaseNo base
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.28#N/A#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOCIC(O)C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C(O)C1=CC=CC=C1C1(N2C=CC=N2)=NC(N3C=CC=N3)=CC=C1#N/ACN(C)C(C)=O
239
26211/9/2021235
Long
ja907700e
C-O Activation
x10.1021/ja907700e2009
LVG2 need to disscuss12.5E-NuOCONEt2
HetB(OH)2
ArylPCy3
#N/A#N/A150K3PO4o-xyleneo-xylenePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
MediumOO-CO-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BHet-O[Het]-O-CO-R'Aryl-B(OH)2[Aryl]-B(OH)2Non-Polar2.57Ionic-PO4K+
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
TM0.3121.412.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OC(N(CC)CC)=OB(O)OC1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]CC1=C(C)C=CC=C1
240
26311/9/2021271
Elaine
jacs.9b00111
C-N Activation
x10.1021/jacs.9b001112019
Alk−ZnX (X = Br or I, 1.6 equiv),
H2o numbers are not fixed
13E-ENH2
AlkylCl
Alkylttbtpy
#N/A#N/A60THFDMATHFN-N-NterpyNitrogenCsp3-Csp3NNH2XCsp3Csp3Csp3-NCsp3-XAlkyl-N[Alkyl]-NH2Alkyl-Cl[Alkyl]-ClPolar7.58No baseNo BaseNo base
J AM CHEM SOC
_#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XNClCCCCCCCCCC(C)(C1=CN=C(C2=NC(C3=NC=C(C(C)(C)C)C=C3)=CC(C(C)(C)C)=C2)C=C1)C#N/AC1CCOC1
241
26411/9/2021271
Elaine
jacs.9b00111
C-N Activation
x10.1021/jacs.9b001112019
Alk−ZnX (X = Br or I, 1.6 equiv),
H2o numbers are not fixed
13E-ENH2
AlkylCl
Alkylbpp
#N/A#N/A60THFDMATHFN-N-NterpyNitrogenCsp3-Csp3NNH2XCsp3Csp3Csp3-NCsp3-XAlkyl-N[Alkyl]-NH2Alkyl-Cl[Alkyl]-ClPolar7.58No baseNo BaseNo base
J AM CHEM SOC
_#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XNClCCCCCCCCC1(N2C=CC=N2)=NC(N3C=CC=N3)=CC=C1#N/AC1CCOC1
242
26511/10/202123
Kelly
s41467-021-25222-1
C-N Activation
xx10.1038/s41467-021-25222-12021
11.5E-NuTriphenylpyridinium+BF4-
AlkylH
Alkyl6-methyl-N-(quinolin-8-yl)picolinamide
#N/A#N/A80K3PO4THFTHFUniqueN-N-NPy-N-PyNitrogenCsp3-Csp3NPyridiniumHCsp3Csp3Csp3-NCsp3-HAlkyl-N[Alkyl]-PyridiniumAlkyl-H[Alkyl]-HPolar7.58Ionic-PO4K+
NAT COMMUN
_2.244780372.9696246982.6072025343.5700586912.37#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5[N+]1=C(C=C(C=C1C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.F[B-](F)(F)FHCCCCCCCCCC1=NC(C(NC2=C(N=CC=C3)C3=CC=C2)=O)=CC=C1[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1CCOC1
243
26611/10/202123
Kelly
s41467-021-25222-1
C-N Activation
xx10.1038/s41467-021-25222-12021
11.5E-NuTriphenylpyridinium+BF4-
AlkylH
Alkyl6-methyl-N-(quinolin-8-yl)picolinamide
#N/A#N/A80THFTHFUniqueN-N-NPy-N-PyNitrogenCsp3-Csp3NPyridiniumHCsp3Csp3Csp3-NCsp3-HAlkyl-N[Alkyl]-PyridiniumAlkyl-H[Alkyl]-HPolar7.58No baseNo BaseNo base
NAT COMMUN
_#N/A#N/A#N/A#N/A#N/A#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5[N+]1=C(C=C(C=C1C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.F[B-](F)(F)FHCCCCCCCCCC1=NC(C(NC2=C(N=CC=C3)C3=CC=C2)=O)=CC=C1#N/AC1CCOC1
244
26711/10/202123
Kelly
s41467-021-25222-1
C-N Activation
xx10.1038/s41467-021-25222-12021
Fig5 does not have general reaction scheme. So, I used Fig3 one in Fig.11.5E-NuTriphenylpyridinium+BF4-
AlkylH
Alkyl6-methyl-N-(quinolin-8-yl)picolinamide
#N/A#N/A80THFTHFUniqueN-N-NPy-N-PyNitrogenCsp3-Csp3NPyridiniumHCsp3Csp3Csp3-NCsp3-HAlkyl-N[Alkyl]-PyridiniumAlkyl-H[Alkyl]-HPolar7.58No baseNo BaseNo base
NAT COMMUN
_#N/A#N/A#N/A#N/A#N/A#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5[N+]1=C(C=C(C=C1C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.F[B-](F)(F)FHCCCCCCCCCC1=NC(C(NC2=C(N=CC=C3)C3=CC=C2)=O)=CC=C1#N/AC1CCOC1
245
26811/10/202156
Kelly
c6ob01299j
C-N Activation
xx10.1039/c6ob01299j2016
??E-NuTriphenylpyridinium+BF4-
ArylH
AlkylIPr.HCl
#N/A#N/A80THFTHFNHCCarbeneCarbeneCsp2_ar-Csp3NPyridiniumHCsp2_arCsp3Csp2_ar-NCsp3-HAryl-N[Aryl]-PyridiniumAlkyl-H[Alkyl]-HPolar7.58No baseNo BaseNo base
ORG BIOMOL CHEM
_#N/A#N/A#N/A#N/A#N/A#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5[N+]1=C(C=C(C=C1C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.F[B-](F)(F)FHC1=CC=CC=C1CCC1=CC=CC=C1CCCC(C)c1cccc(C(C)C)c1N2C=[N+](C=C2)c3c(C(C)C)cccc3C(C)C.[Cl-]#N/AC1CCOC1
246
26911/10/202156
Kelly
c6ob01299j
C-N Activation
xx10.1039/c6ob01299j2016
??E-NuTriphenylpyridinium+BF4-
ArylH
AlkylIPr.HCl
#N/A#N/A80THFTHFNHCCarbeneCarbeneCsp2_ar-Csp3NPyridiniumHCsp2_arCsp3Csp2_ar-NCsp3-HAryl-N[Aryl]-PyridiniumAlkyl-H[Alkyl]-HPolar7.58No baseNo BaseNo base
ORG BIOMOL CHEM
_#N/A#N/A#N/A#N/A#N/A#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5[N+]1=C(C=C(C=C1C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.F[B-](F)(F)FHC1=CC=CC=C1CCC1=CC=CC=C1CCCC(C)c1cccc(C(C)C)c1N2C=[N+](C=C2)c3c(C(C)C)cccc3C(C)C.[Cl-]#N/AC1CCOC1
247
27011/10/2021253
Long
acs.orglett.8b01062
C-N Activation
x10.1021/acs.orglett.8b010622018
EtOH is the solvent13E-NuTriphenylpyridinium+BF4-
ArylB(OH)2
ArylPhen
#N/A#N/A60K3PO4EtOHdioxanedioxaneN-NbpyNitrogen
Csp2_ar-Csp2_ar
NPyridiniumBCsp2_arCsp2_arCsp2_ar-NCsp2_ar-BAryl-N[Aryl]-PyridiniumAryl-B(OH)2[Aryl]-B(OH)2Polar2.25Ionic-PO4K+ORG LETT_2.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6[N+]1=C(C=C(C=C1C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.F[B-](F)(F)FB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1(C(N=CC=C2)=C2C=C3)=C3C=CC=N1[O-]P(=O)([O-])[O-].[K+].[K+].[K+]OCC
248
27111/10/2021249
Long
acs.orglett.7b00831
C-N Activation
x10.1021/acs.orglett.7b008312017
11.5E-Epiperidine-2,6-dione
CarbonylI
Arylterpyridine
#N/A#N/A80KFDMFDMFZnN-N-NterpyNitrogenCsp2-Csp2_arE-HNGlutarimideXCsp2Csp2_arCsp2-NCsp2_ar-XCarbonyl-N[Carbonyl]-GlutarimideAryl-I[Aryl]-IPolar36.7No baseNo BaseNo baseORG LETT_#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XN1C(CCCC1=O)=OICC(=O)CC1=CC=CC=C1C(=O)CCC1=CC=CC=C1c1ccnc(c1)c2cccc(n2)c3ccccn3#N/ACN(C)C=O
249
27211/10/2021196
Kelly
jacs.6b03253
C-O Activation
x10.1021/jacs.6b032532016
X=I, 1a-e,1g,1i-1l11.5E-NuOMe
ArylH
Alkyldcype
#N/A#N/A80toluenetolueneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp3StrongOO-Csp3HCsp2_arCsp3Csp2_ar-OCsp3-HAryl-O[Aryl]-O-Csp3Alkyl-H[Alkyl]-HNon-Polar2.38No baseNo BaseNo base
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5OCHC1=CC=CC=C1CCC1=CC=CC=C1CCP(C1CCCCC1)(C2CCCCC2)CCP(C3CCCCC3)C4CCCCC4#N/ACc1ccccc1
250
27311/10/2021196
Kelly
jacs.6b03253
C-O Activation
x10.1021/jacs.6b032532016
X=Br, 1f11.5E-NuOMe
ArylMgX
Alkyldcype
#N/A#N/A80toluenetolueneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp3StrongOO-Csp3MgCsp2_arCsp3Csp2_ar-OCsp3-MgAryl-O[Aryl]-O-Csp3Alkyl-MgX[Alkyl]-MgXNon-Polar2.38No baseNo BaseNo base
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OC[Mg]ClC1=CC=CC=C1CCC1=CC=CC=C1CCP(C1CCCCC1)(C2CCCCC2)CCP(C3CCCCC3)C4CCCCC4#N/ACc1ccccc1
251
27411/10/2021196
Kelly
jacs.6b03253
C-O Activation
x10.1021/jacs.6b032532016
X=Cl, 1h11.5E-NuOMe
ArylMgX
Alkyldcype
#N/A#N/A120toluenetolueneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp3StrongOO-Csp3MgCsp2_arCsp3Csp2_ar-OCsp3-MgAryl-O[Aryl]-O-Csp3Alkyl-MgX[Alkyl]-MgXNon-Polar2.38No baseNo BaseNo base
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OC[Mg]ClC1=CC=CC=C1CCC1=CC=CC=C1CCP(C1CCCCC1)(C2CCCCC2)CCP(C3CCCCC3)C4CCCCC4#N/ACc1ccccc1
252
27511/10/2021196
Kelly
jacs.6b03253
C-O Activation
x10.1021/jacs.6b032532016
LVG1=OMe, RG1=Aryl11.5E-NuOMe
ArylMgX
Alkyldcype
#N/A#N/A100toluenetolueneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp3StrongOO-Csp3MgCsp2_arCsp3Csp2_ar-OCsp3-MgAryl-O[Aryl]-O-Csp3Alkyl-MgX[Alkyl]-MgXNon-Polar2.38No baseNo BaseNo base
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OC[Mg]ClC1=CC=CC=C1CCC1=CC=CC=C1CCP(C1CCCCC1)(C2CCCCC2)CCP(C3CCCCC3)C4CCCCC4#N/ACc1ccccc1
253
27611/10/2021196
Kelly
jacs.6b03253
C-O Activation
x10.1021/jacs.6b032532016
LVG1=OPh, RG1=Aryl11.5E-NuOPh
ArylMgX
Alkyldcype
#N/A#N/A100toluenetolueneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp3StrongOO-Csp2MgCsp2_arCsp3Csp2_ar-OCsp3-MgAryl-O[Aryl]-O-Csp2Alkyl-MgX[Alkyl]-MgXNon-Polar2.38No baseNo BaseNo base
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_-0.3220.71#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OC1=CC=CC=C1[Mg]ClC1=CC=CC=C1CCC1=CC=CC=C1CCP(C1CCCCC1)(C2CCCCC2)CCP(C3CCCCC3)C4CCCCC4#N/ACc1ccccc1
254
27711/10/2021196
Kelly
jacs.6b03253
C-O Activation
x10.1021/jacs.6b032532016
LVG1=OSiMe3, RG1=Vinyl11.5E-NuOTMS
VinylMgX
Alkyldcype
#N/A#N/A100toluenetolueneP-PPhosphine (Bidentate)PhosphineCsp2-Csp3StrongOO-SiR'3MgCsp2Csp3Csp2-OCsp3-MgVinyl-O[Vinyl]-O-SiR'3Alkyl-MgX[Alkyl]-MgXNon-Polar2.38No baseNo BaseNo base
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_-0.2713.32#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2O[Si](C)(C)C[Mg]ClC=CCCC=CCCP(C1CCCCC1)(C2CCCCC2)CCP(C3CCCCC3)C4CCCCC4#N/ACc1ccccc1
255
27811/10/2021196
Kelly
jacs.6b03253
C-O Activation
x10.1021/jacs.6b032532016
LVG1=OMe, RG1=Vinyl11.5E-NuOMe
VinylMgX
Alkyldcype
#N/A#N/A100toluenetolueneP-PPhosphine (Bidentate)PhosphineCsp2-Csp3StrongOO-Csp3MgCsp2Csp3Csp2-OCsp3-MgVinyl-O[Vinyl]-O-Csp3Alkyl-MgX[Alkyl]-MgXNon-Polar2.38No baseNo BaseNo base
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_-0.286.71#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OC[Mg]ClC=CCCC=CCCP(C1CCCCC1)(C2CCCCC2)CCP(C3CCCCC3)C4CCCCC4#N/ACc1ccccc1
256
27911/10/202122
Kelly
anie.202011036
C-O Activation
xx10.1002/anie.2020110362021
X=OTfNANAE-NuOTf
ArylH
Alkyl(R,R)-QuinoxP*
#N/A#N/A100DMSODMSOP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp3WeakOO-SO2-R'HCsp2_arCsp3Csp2_ar-OCsp3-HAryl-O[Aryl]-O-SO2-R'Alkyl-H[Alkyl]-HPolar46.7No baseNo BaseNo base
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.53#N/A#N/A#N/A#N/A#N/A#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5OS(=O)(=O)C(F)(F)FHC1=CC=CC=C1CCC1=CC=CC=C1CCCP(C(C)(C)C)C1=NC2=CC=CC=C2N=C1P(C(C)(C)C)C#N/ACS(=O)C
257
28011/10/202122
Kelly
anie.202011036
C-O Activation
xx10.1002/anie.2020110362021
X=OMsNANAE-NuOMs
ArylH
Alkyl(R,R)-QuinoxP*
#N/A#N/A100DMFDMFP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp3WeakOO-SO2-R'HCsp2_arCsp3Csp2_ar-OCsp3-HAryl-O[Aryl]-O-SO2-R'Alkyl-H[Alkyl]-HPolar36.7No baseNo BaseNo base
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.36#N/A#N/A#N/A#N/A#N/A#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5OS(=O)(=O)CHC1=CC=CC=C1CCC1=CC=CC=C1CCCP(C(C)(C)C)C1=NC2=CC=CC=C2N=C1P(C(C)(C)C)C#N/ACN(C)C=O
258
28111/10/202122
Kelly
anie.202011036
C-O Activation
xx10.1002/anie.2020110362021
NANAE-NuOTf
ArylH
Alkyl(R,R)-QuinoxP*
#N/A#N/A100DMFDMFP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp3WeakOO-SO2-R'HCsp2_arCsp3Csp2_ar-OCsp3-HAryl-O[Aryl]-O-SO2-R'Alkyl-H[Alkyl]-HPolar36.7No baseNo BaseNo base
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.53#N/A#N/A#N/A#N/A#N/A#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5OS(=O)(=O)C(F)(F)FHC1=CC=CC=C1CCC1=CC=CC=C1CCCP(C(C)(C)C)C1=NC2=CC=CC=C2N=C1P(C(C)(C)C)C#N/ACN(C)C=O
259
28211/10/202122
Kelly
anie.202011036
C-O Activation
xx10.1002/anie.2020110362021
NANAE-NuOTf
VinylH
Alkyl(R,R)-QuinoxP*
#N/A#N/A100DMSODMSOP-PPhosphine (Bidentate)PhosphineCsp2-Csp3WeakOO-SO2-R'HCsp2Csp3Csp2-OCsp3-HVinyl-O[Vinyl]-O-SO2-R'Alkyl-H[Alkyl]-HPolar46.7No baseNo BaseNo base
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.53#N/A#N/A#N/A#N/A#N/A#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5OS(=O)(=O)C(F)(F)FHC=CCCC=CCCCP(C(C)(C)C)C1=NC2=CC=CC=C2N=C1P(C(C)(C)C)C#N/ACS(=O)C
260
28311/10/202122
Kelly
anie.202011036
C-O Activation
xx10.1002/anie.2020110362021
NANAE-NuOTf
ArylH
Alkyl(R,R)-QuinoxP*
#N/A#N/A100DMSODMSOP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp3WeakOO-SO2-R'HCsp2_arCsp3Csp2_ar-OCsp3-HAryl-O[Aryl]-O-SO2-R'Alkyl-H[Alkyl]-HPolar46.7No baseNo BaseNo base
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.53#N/A#N/A#N/A#N/A#N/A#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5OS(=O)(=O)C(F)(F)FHC1=CC=CC=C1CCC1=CC=CC=C1CCCP(C(C)(C)C)C1=NC2=CC=CC=C2N=C1P(C(C)(C)C)C#N/ACS(=O)C
261
28411/10/202122
Kelly
anie.202011036
C-O Activation
xx10.1002/anie.2020110362021
NANAE-NuOTf
ArylH
Alkyl(R,R)-QuinoxP*
#N/A#N/A100DMSODMSOZnP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp3WeakOO-SO2-R'HCsp2_arCsp3Csp2_ar-OCsp3-HAryl-O[Aryl]-O-SO2-R'Alkyl-H[Alkyl]-HPolar46.7No baseNo BaseNo base
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.53#N/A#N/A#N/A#N/A#N/A#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5OS(=O)(=O)C(F)(F)FHC1=CC=CC=C1CCC1=CC=CC=C1CCCP(C(C)(C)C)C1=NC2=CC=CC=C2N=C1P(C(C)(C)C)C#N/ACS(=O)C
262
28511/10/202114
Kelly
anie.202004116
C-O Activation
xx10.1002/anie.2020041162020
11.2E-NuOPiv
ArylSiMe3
Alkyldcype
#N/A#N/A40toluenetolueneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp3MediumOO-CO-R'SiCsp2_arCsp3Csp2_ar-OCsp3-SiAryl-O[Aryl]-O-CO-R'Alkyl-SiMe3[Alkyl]-SiMe3Non-Polar2.38No baseNo BaseNo base#N/A#N/A
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.3320.28#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOC(=O)C(C)(C)C[Si]C(C)(C)C1=CC=CC=C1CCC1=CC=CC=C1CCP(C1CCCCC1)(C2CCCCC2)CCP(C3CCCCC3)C4CCCCC4#N/ACc1ccccc1
263
28611/10/2021213
Kelly
ja202769t
C-O Activation
xx10.1021/ja202769t2011
The condition being put wrong by the author ArBr does not appear in the scheme??E-NuOTf
ArylMgX
Alkyl1,3-dicyclohexyl-1H-imidazol-3-ium tetrafluoroborate
#N/A#N/A-10THFTHFNHCCarbeneCarbeneCsp2_ar-Csp3WeakOO-SO2-R'MgCsp2_arCsp3Csp2_ar-OCsp3-MgAryl-O[Aryl]-O-SO2-R'Alkyl-MgX[Alkyl]-MgXPolar7.58No baseNo BaseNo base
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.53#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OS(=O)(=O)C(F)(F)F[Mg]ClC1=CC=CC=C1CCC1=CC=CC=C1CCC1(N2C=[N+](C3CCCCC3)C=C2)CCCCC1.F[B-](F)(F)F#N/AC1CCOC1
264
28711/11/2021331
Long
jacs.7b03448
C-N Activation
x10.1021/jacs.7b034482017
2 equiv of iodide,ring opening12E-EN(Ring-Opening)
AlkylI
Arylbpy
#N/A#N/A23DMADMAMnN-NbpyNitrogenCsp3-Csp2_arN
N(Ring-Opening)
XCsp3Csp2_arCsp3-NCsp2_ar-XAlkyl-N[Alkyl]-N(Ring-Opening)Aryl-I[Aryl]-IPolar37.8No baseNo BaseNo base
J AM CHEM SOC
_#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XNCICCC1=CC=CC=C1CCC1=CC=CC=C1C1(C2=NC=CC=C2)=CC=CC=N1#N/ACN(C)C(C)=O
265
28811/11/2021331
Long
jacs.7b03448
C-N Activation
x10.1021/jacs.7b034482017
2 equiv of iodide,
For ligand, R=4-Heptyl, ring opening12E-EN(Ring-Opening)
AlkylI
Aryl(4'S)-4,4'-di(heptan-4-yl)-2,4',5,5'-tetrahydro-2,2'-BiOxazole
#N/A#N/A-10THFTHFMnTMSClN-NboxNitrogenCsp3-Csp2_arN
N(Ring-Opening)
XCsp3Csp2_arCsp3-NCsp2_ar-XAlkyl-N[Alkyl]-N(Ring-Opening)Aryl-I[Aryl]-IPolar7.58No baseNo BaseNo base
J AM CHEM SOC
_#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XNCICCC1=CC=CC=C1CCC1=CC=CC=C1CCCC(CCC)[C@@H](CO1)N=C1C2N=C(C(CCC)CCC)CO2#N/AC1CCOC1
266
28911/11/202171
Janice
jacs.8b13403
C-O Activation
x10.1021/jacs.8b134032019
NA
14E-Nu2-(4,6-dimethoxy-1,3,5-triazin-2-yl)benzonitrile
ArylB(OH)2
ArylXantphos
#N/A#N/A120K3PO4toluenetolueneP-O-PP-O-PMixed
Csp2_ar-Csp2_ar
StrongOO-Csp2BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-Csp2Aryl-B(OH)2[Aryl]-B(OH)2Non-Polar2.38Ionic-PO4K+
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_-0.3232.632.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OC1=NC(C2=C(C#N)C=CC=C2)=NC(OC)=N1B(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1O6c1c(cccc1P(c2ccccc2)c3ccccc3)C(c7cccc(P(c4ccccc4)c5ccccc5)c67)(C)C[O-]P(=O)([O-])[O-].[K+].[K+].[K+]Cc1ccccc1
267
11511/4/202129
Kelly
anie.201806790
C-O Activation
x10.1002/anie.2018067902018
11.5E-NuOSi(tBu)Me2
ArylH
N(Alkyl)ArylIPrMe.HCl
#N/A#N/A120NaOtButoluenetolueneNHCCarbeneCarbeneCsp2_ar-Nsp3StrongOO-SiR'3HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-SiR'3N(Alkyl)Aryl-H[N(Alkyl)Aryl]-HNon-Polar2.38Ionic-OtBuNa+
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.2725.012.8589353663.2821934583.0705644124.0077900319#REF!15.1912.031.706749553.2392069642.4729782574.96639928#REF!#REF!O[Si](C)(C)C(C)(C)CHC1=CC=CC=C1N(C)C(C(=O)C)C1=CC=CC=C1CC(=O)CN(C)CC(C)c1cccc(C(C)C)c1N2C=[N+](C(C)=C2C)c3c(C(C)C)cccc3C(C)C.[Cl-][Na]OC(C)(C)CCc1ccccc1
268
42912/15/202129
Kelly
anie.201806790
C-O Activation
x10.1002/anie.2018067902018
11.5E-NuOSi(tBu)Me2
ArylH
N(H)ArylIPrMe.HCl
#N/A#N/A120NaOtButoluenetolueneNHCCarbeneCarbeneCsp2_ar-Nsp3StrongOO-SiR'3HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-SiR'3N(H)Aryl-H[N(H)Aryl]-HNon-Polar2.38Ionic-OtBuNa+#N/A#N/A
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.2725.012.8589353663.2821934583.0705644124.0077900319#REF!11.526.021.706749553.2392069642.4729782574.96639928#REF!#REF!O[Si](C)(C)C(C)(C)CHC1=CC=CC=C1NC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1NCC(C)c1cccc(C(C)C)c1N2C=[N+](C(C)=C2C)c3c(C(C)C)cccc3C(C)C.[Cl-][Na]OC(C)(C)CCc1ccccc1
269
43012/15/202129
Kelly
anie.201806790
C-O Activation
x10.1002/anie.2018067902018
11.5E-NuOSi(tBu)Me2
ArylH
N(Alkyl)AlkylIPrMe.HCl
#N/A#N/A120NaOtButoluenetolueneNHCCarbeneCarbeneCsp2_ar-Nsp3StrongOO-SiR'3HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-SiR'3N(Alkyl)Alkyl-H[N(Alkyl)Alkyl]-HNon-Polar2.38Ionic-OtBuNa+#N/A#N/A
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.2725.012.8589353663.2821934583.0705644124.0077900319#REF!9.6512.031.706749553.2392069642.4729782574.96639928#REF!#REF!O[Si](C)(C)C(C)(C)CHC1=CC=CC=C1N(C)CC1=CC=CC=C1C(C)NCC(C)c1cccc(C(C)C)c1N2C=[N+](C(C)=C2C)c3c(C(C)C)cccc3C(C)C.[Cl-][Na]OC(C)(C)CCc1ccccc1
270
43112/15/202129
Kelly
anie.201806790
C-O Activation
x10.1002/anie.2018067902018
11.5E-NuOSi(tBu)Me2
ArylH
N(Alkyl)AlkylIPrMe.HCl
#N/A#N/A120NaOtButoluenetolueneNHCCarbeneCarbeneCsp2_ar-Nsp3StrongOO-SiR'3HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-SiR'3N(Alkyl)Alkyl-H[N(Alkyl)Alkyl]-HNon-Polar2.38Ionic-OtBuNa+#N/A#N/A
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.2725.012.8589353663.2821934583.0705644124.0077900319#REF!9.6512.031.706749553.2392069642.4729782574.96639928#REF!#REF!O[Si](C)(C)C(C)(C)CHC1=CC=CC=C1N(C)CC1=CC=CC=C1C(C)NCC(C)c1cccc(C(C)C)c1N2C=[N+](C(C)=C2C)c3c(C(C)C)cccc3C(C)C.[Cl-][Na]OC(C)(C)CCc1ccccc1
271
29411/11/2021240
Long
anie.200453765
C-O Activation
x10.1002/anie.2004537652004
PiPr3 as ligandNANAE-NuOMe
ArylMgX
BenzylPiPr3
#N/A#N/A60iPr2OiPr2OPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp3-ring(s)
StrongOO-Csp3MgCsp2_arCsp3-ring(s)Csp2_ar-OCsp3-ring(s)-MgAryl-O[Aryl]-O-Csp3Benzyl-MgX[Benzyl]-MgXPolar4.04No baseNo BaseNo base
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!29OC[Mg]ClC1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1CC(P(C(C)C)C(C)C)C#N/AO(C(C)C)C(C)C
272
29511/11/2021240
Long
anie.200453765
C-O Activation
x10.1002/anie.2004537652004
PCy3 as ligandNANAE-NuOMe
ArylMgX
BenzylPCy3
#N/A#N/A60iPr2OiPr2OPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp3-ring(s)
StrongOO-Csp3MgCsp2_arCsp3-ring(s)Csp2_ar-OCsp3-ring(s)-MgAryl-O[Aryl]-O-Csp3Benzyl-MgX[Benzyl]-MgXPolar4.04No baseNo BaseNo base
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!29OC[Mg]ClC1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/AO(C(C)C)C(C)C
273
29611/11/2021240
Long
anie.200453765
C-O Activation
x10.1002/anie.2004537652004
PhPCy2 as ligandNANAE-NuOMe
ArylMgX
BenzylPhPCy2
#N/A#N/A60iPr2OiPr2O#N/A#N/A#N/A
Csp2_ar-Csp3-ring(s)
StrongOO-Csp3MgCsp2_arCsp3-ring(s)Csp2_ar-OCsp3-ring(s)-MgAryl-O[Aryl]-O-Csp3Benzyl-MgX[Benzyl]-MgXPolar4.04No baseNo BaseNo base
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!29OC[Mg]ClC1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1#N/A#N/AO(C(C)C)C(C)C
274
29711/11/2021240
Long
anie.200453765
C-O Activation
x10.1002/anie.2004537652004
Ph2PCy as ligandNANAE-NuOMe
ArylMgX
BenzylPh2PCy
#N/A#N/A60iPr2OiPr2OPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp3-ring(s)
StrongOO-Csp3MgCsp2_arCsp3-ring(s)Csp2_ar-OCsp3-ring(s)-MgAryl-O[Aryl]-O-Csp3Benzyl-MgX[Benzyl]-MgXPolar4.04No baseNo BaseNo base
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!29OC[Mg]ClC1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1C1(P(C2CCCCC2)C3=CC=CC=C3)=CC=CC=C1#N/AO(C(C)C)C(C)C
275
29811/11/2021138
Long
jacs.9b05461
C-O Activation
xx10.1021/jacs.9b054612019
1.21E-EOTf
ArylOTs
Aryldtbbpy
#N/A#N/A80NMPDMFNMP/DMFZnLiClN-NbpyNitrogen
Csp2_ar-Csp2_ar
WeakOO-SO2-R'OCsp2_arCsp2_arCsp2_ar-OCsp2_ar-OAryl-O[Aryl]-O-SO2-R'Aryl-OTs[Aryl]-OTsPolar28.7No baseNo BaseNo baseEasyOSO2-EDG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.53#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!OS(=O)(=O)C(F)(F)FOS(=O)(=O)(C1=CC=C(C)C=C1)C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1CC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/ACN1CCCC1=O
276
29911/11/2021138
Long
jacs.9b05461
C-O Activation
xx10.1021/jacs.9b054612019
1.21E-EOTf
ArylOTs
Aryldbrbpy
#N/A#N/A80NMPDMFNMP/DMFZnLiClN-NbpyNitrogen
Csp2_ar-Csp2_ar
WeakOO-SO2-R'OCsp2_arCsp2_arCsp2_ar-OCsp2_ar-OAryl-O[Aryl]-O-SO2-R'Aryl-OTs[Aryl]-OTsPolar28.7No baseNo BaseNo baseEasyOSO2-EDG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.53#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!OS(=O)(=O)C(F)(F)FOS(=O)(=O)(C1=CC=C(C)C=C1)C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1BrC1=CC(C2=CC(Br)=CC=N2)=NC=C1#N/ACN1CCCC1=O
277
30011/11/2021138
Long
jacs.9b05461
C-O Activation
xx10.1021/jacs.9b054612019
1.21E-EOTf
HetOTs
Aryldtbbpy
#N/A#N/A80NMPDMFNMP/DMFZnLiClN-NbpyNitrogen
Csp2_ar-Csp2_ar
WeakOO-SO2-R'OCsp2_arCsp2_arCsp2_ar-OCsp2_ar-OHet-O[Het]-O-SO2-R'Aryl-OTs[Aryl]-OTsPolar28.7No baseNo BaseNo baseEasyOSO2-EDG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.53#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!OS(=O)(=O)C(F)(F)FOS(=O)(=O)(C1=CC=C(C)C=C1)C1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1C1=CC=CC=C1CC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/ACN1CCCC1=O
278
30111/11/202140
Long
jacs.0c04670
C-O Activation
xx10.1021/jacs.0c046702020
11E-EOTf
ArylOTs
Aryl4,4'-Diphenyl-2,2'-bipyridine
#N/A#N/A40-60DMFDMFZnN-NbpyNitrogen
Csp2_ar-Csp2_ar
WeakOO-SO2-R'OCsp2_arCsp2_arCsp2_ar-OCsp2_ar-OAryl-O[Aryl]-O-SO2-R'Aryl-OTs[Aryl]-OTsPolar36.7No baseNo BaseNo baseEasyOSO2-EDG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.53#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!OS(=O)(=O)C(F)(F)FOS(=O)(=O)(C1=CC=C(C)C=C1)C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=C(C=C1)C2=CC(=NC=C2)C3=NC=CC(=C3)C4=CC=CC=C4#N/ACN(C)C=O
279
30211/11/2021226
Shihong
nature14676
C-O Activation
x10.1038/nature146762015
dual-catalysis system11E-EOTf
ArylBr
Arylbpy
#N/A#N/A40KFDMFDMFZnN-NbpyNitrogen
Csp2_ar-Csp2_ar
WeakOO-SO2-R'XCsp2_arCsp2_arCsp2_ar-OCsp2_ar-XAryl-O[Aryl]-O-SO2-R'Aryl-Br[Aryl]-BrPolar36.7No baseNo BaseNo baseNATURE_0.53#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOS(=O)(=O)C(F)(F)FBrC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1(C2=NC=CC=C2)=CC=CC=N1#N/ACN(C)C=O
280
30311/12/202194
Long
anie.202002271
C-N Activation
x10.1002/anie.2020022712020
G=OPy1.51E-ETriphenylpyridinium+BF4-
AlkylOPy
Carbonylttbtpy
#N/A#N/A60NMPNMPMnN-N-NterpyNitrogenCsp3-Csp2NPyridiniumOCsp3Csp2Csp3-NCsp2-OAlkyl-N[Alkyl]-PyridiniumCarbonyl-OPy[Carbonyl]-OPyPolar33No baseNo BaseNo baseMediumO-EDG
ANGEW CHEM INT EDIT
_#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!X[N+]1=C(C=C(C=C1C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.F[B-](F)(F)FOC1=NC=CC=C1CCCC(=O)CCCC(=O)CCCC(C)(C1=CN=C(C2=NC(C3=NC=C(C(C)(C)C)C=C3)=CC(C(C)(C)C)=C2)C=C1)C#N/ACN1CCCC1=O
281
30411/12/202194
Long
anie.202002271
C-N Activation
x10.1002/anie.2020022712020
G=OPy1.51E-ETriphenylpyridinium+BF4-
AlkylOPy
Carbonylttbtpy
#N/A#N/A60THFTHFMnN-N-NterpyNitrogenCsp3-Csp2NPyridiniumOCsp3Csp2Csp3-NCsp2-OAlkyl-N[Alkyl]-PyridiniumCarbonyl-OPy[Carbonyl]-OPyPolar7.58No baseNo BaseNo baseMediumO-EDG
ANGEW CHEM INT EDIT
_#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!X[N+]1=C(C=C(C=C1C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.F[B-](F)(F)FOC1=NC=CC=C1CCCC(=O)CCCC(=O)CCCC(C)(C1=CN=C(C2=NC(C3=NC=C(C(C)(C)C)C=C3)=CC(C(C)(C)C)=C2)C=C1)C#N/AC1CCOC1
282
30511/12/202194
Long
anie.202002271
C-N Activation
x10.1002/anie.2020022712020
G=F1.51E-ETriphenylpyridinium+BF4-
AlkylF
Carbonyldtbbpy
#N/A#N/A60NMPNMPMnN-NbpyNitrogenCsp3-Csp2NPyridiniumXCsp3Csp2Csp3-NCsp2-XAlkyl-N[Alkyl]-PyridiniumCarbonyl-F[Carbonyl]-FPolar33No baseNo BaseNo base
ANGEW CHEM INT EDIT
_#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!X[N+]1=C(C=C(C=C1C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.F[B-](F)(F)FFCCCC(=O)CCCC(=O)CCCC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/ACN1CCCC1=O
283
30611/14/2021373
Gerry
ja5095342
C-H Activation
x10.1021/ja50953422014
110E-NuCH3
ArylH
BenzylPPh3
#N/A#N/A110ToluenePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp3-ring(s)
Csp3HCsp2_arCsp3-ring(s)Csp2_ar-Csp3Csp3-ring(s)-HAryl-Csp3[Aryl]-Benzyl-H[Benzyl]-H#N/A#N/ANo baseNo BaseNo base
J AM CHEM SOC
_#N/A#N/A#N/A#N/A#N/A#REF!12.1701.706749553.2392069642.4729782574.96639928#REF!#REF!21.3CHC1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3#N/ACc1ccccc1
284
30711/14/2021213
Long
acs.orglett.9b01014
C-N Activation
x10.1021/acs.orglett.9b010142019
1-1.21-1.1E-ETriphenylpyridinium+BF4-
AlkylBr
Aryl4,4'-Dimethoxy-2,2'-bipyridine
#N/A#N/A24MgCl2NMPNMPMnN-NbpyNitrogenCsp3-Csp2_arNPyridiniumXCsp3Csp2_arCsp3-NCsp2_ar-XAlkyl-N[Alkyl]-PyridiniumAryl-Br[Aryl]-BrPolar33#N/ANo Base#N/AORG LETT_#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!X[N+]1=C(C=C(C=C1C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.F[B-](F)(F)FBrCCC1=CC=CC=C1CCC1=CC=CC=C1COC1=CC=NC(C2=NC=CC(OC)=C2)=C1#N/ACN1CCCC1=O
285
30811/15/202171
Gerry
jacs.7b04312
C-H Activation
x10.1021/jacs.7b043122017
not mentioned but in table1 is 1.1:1nanaE-NuI
AlkylH
AlkylPhenanthroline#N/A#N/A#N/A40KOtBuMTBEdioxaneEt2Zn#N/A#N/A#N/ACsp3-Csp3XHCsp3Csp3Csp3-XCsp3-HAlkyl-X[Alkyl]-Alkyl-H[Alkyl]-H#N/A#N/AIonic-OtBuK+
J AM CHEM SOC
_2.8589353663.2821934583.0705644124.0077900319#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5IHCCCCCCCC#N/ACC(C)(C)[O-].[K+]O(C(C)(C)C)C
286
30911/15/202171
Gerry
jacs.7b04312
C-H Activation
x10.1021/jacs.7b043122017
not mentioned but in table1 is 1.1:1nanaNu-NuH
AlkylH
AlkylPhenanthroline#N/A#N/A#N/A40KOtBuMTBEdioxaneEt2Zn#N/A#N/A#N/ACsp3-Csp3Nu-HHHCsp3Csp3Csp3-HCsp3-HAlkyl-H[Alkyl]-Alkyl-H[Alkyl]-H#N/A#N/AIonic-OtBuK+
J AM CHEM SOC
_2.8589353663.2821934583.0705644124.0077900319#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5HHCCCCCCCC#N/ACC(C)(C)[O-].[K+]O(C(C)(C)C)C
287
31011/15/202171
Gerry
jacs.7b04312
C-H Activation
x10.1021/jacs.7b043122017
not mentioned but in table1 is 1.1:1nanaNu-NuH
AlkylH
AlkylPhenanthroline#N/A#N/A#N/A40KOtBuMTBEdioxaneEt2Zn#N/A#N/A#N/ACsp3-Csp3Nu-HHHCsp3Csp3Csp3-HCsp3-HAlkyl-H[Alkyl]-Alkyl-H[Alkyl]-H#N/A#N/AIonic-OtBuK+
J AM CHEM SOC
_2.8589353663.2821934583.0705644124.0077900319#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5HHCCCCCCCC#N/ACC(C)(C)[O-].[K+]O(C(C)(C)C)C
288
31111/15/202129
Gerry
jacs.1c06614
C-H Activation
x10.1021/jacs.1c066142021
Nu-NuH
AlkylH
Aryl1-(2,6-dipropoxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)pyrrolidine
#N/A#N/A25NaOMeNaHc-hexanePMixed (P, O and N)MixedCsp3-Csp2_arNu-HHHCsp3Csp2_arCsp3-HCsp2_ar-HAlkyl-H[Alkyl]-Aryl-H[Aryl]-H#N/A#N/AIonic-ORNa+
J AM CHEM SOC
_015.1#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5HHCCC1=CC=CC=C1CCC1=CC=CC=C1CCCOC1=CC2=CC=CC=C2C3=C1OP(N4CCCC4)OC5=C3C(C=CC=C6)=C6C=C5OCCC[Na]OCC1CCCCC1
289
31211/15/2021373
Gerry
ja5095342
C-H Activation
x10.1021/ja50953422014
110E-NuCH3
ArylH
BenzylPPh3
#N/A#N/A140Na2CO3ToluenePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp3-ring(s)
Csp3HCsp2_arCsp3-ring(s)Csp2_ar-Csp3Csp3-ring(s)-HAryl-Csp3[Aryl]-Benzyl-H[Benzyl]-H#N/A#N/AIonic-CO3Na+
J AM CHEM SOC
_1.72.530430542.115215273.4538974810.33#REF!12.1701.706749553.2392069642.4729782574.96639928#REF!#REF!21.3CHC1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3[Na+].[Na+].[O-]C([O-])=OCc1ccccc1
290
31311/15/2021125
Gerry
c6sc00702c
C-H Activation
x10.1039/c6sc00702c2016
Nu-NuH
HetH
Aryl1-(2,6-dipropoxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)pyrrolidine
#N/A#N/A-40THFPMixed (P, O and N)Mixed
Csp2_ar-Csp2_ar
Nu-HHHCsp2_arCsp2_arCsp2_ar-HCsp2_ar-HHet-H[Het]-Aryl-H[Aryl]-H#N/A#N/ANo baseNo BaseNo baseCHEM SCI_#N/A#N/A#N/A#N/A#N/A#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5HHC1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1C1=CC=CC=C1CCCOC1=CC2=CC=CC=C2C3=C1OP(N4CCCC4)OC5=C3C(C=CC=C6)=C6C=C5OCCC#N/AC1CCOC1
291
31411/15/2021125
Gerry
c6sc00702c
C-H Activation
x10.1039/c6sc00702c2016
Nu-NuH
HetH
Aryl1-(2,6-dipropoxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)pyrrolidine
#N/A#N/A-40THFPMixed (P, O and N)Mixed
Csp2_ar-Csp2_ar
Nu-HHHCsp2_arCsp2_arCsp2_ar-HCsp2_ar-HHet-H[Het]-Aryl-H[Aryl]-H#N/A#N/ANo baseNo BaseNo baseCHEM SCI_#N/A#N/A#N/A#N/A#N/A#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5HHC1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1C1=CC=CC=C1CCCOC1=CC2=CC=CC=C2C3=C1OP(N4CCCC4)OC5=C3C(C=CC=C6)=C6C=C5OCCC#N/AC1CCOC1
292
31511/15/2021130
Gerry
c5sc01589h
C-H Activation
x10.1039/c5sc01589h2015
E-NuCl
AlkylH
ArylIPr
#N/A#N/A45TolueneNHCCarbeneCarbeneCsp3-Csp2_arXHCsp3Csp2_arCsp3-XCsp2_ar-HAlkyl-X[Alkyl]-Aryl-H[Aryl]-H#N/A#N/ANo baseNo BaseNo baseCHEM SCI_#N/A#N/A#N/A#N/A#N/A#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5ClHCCC1=CC=CC=C1CCC1=CC=CC=C1CC(C)C(C=CC=C1C(C)C)=C1N2C=CN(C3=C(C(C)C)C=CC=C3C(C)C)C2#N/ACc1ccccc1
293
31611/15/2021130
Gerry
c5sc01589h
C-H Activation
x10.1039/c5sc01589h2015
E-NuCl
AlkylH
ArylIPr
#N/A#N/A45TolueneNHCCarbeneCarbeneCsp3-Csp2_arXHCsp3Csp2_arCsp3-XCsp2_ar-HAlkyl-X[Alkyl]-Aryl-H[Aryl]-H#N/A#N/ANo baseNo BaseNo baseCHEM SCI_#N/A#N/A#N/A#N/A#N/A#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5ClHCCC1=CC=CC=C1CCC1=CC=CC=C1CC(C)C(C=CC=C1C(C)C)=C1N2C=CN(C3=C(C(C)C)C=CC=C3C(C)C)C2#N/ACc1ccccc1
294
31711/16/2021186
acs.orglett.9b01016
C-N Activation
x10.1021/acs.orglett.9b010162019
R2 as Ph1.41E-ECl
AlkylBr
Het4,4'-Dimethoxy-2,2'-bipyridine
#N/A#N/A60NMPNMPMnN-NbpyNitrogenCsp3-Csp2_arXXCsp3Csp2_arCsp3-XCsp2_ar-XAlkyl-X[Alkyl]-Het-Br[Het]-BrPolar33No baseNo BaseNo baseORG LETT_#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XClBrCCC1=NC=CC=C1CCC1=CC=NC=C1COC1=CC=NC(C2=NC=CC(OC)=C2)=C1#N/ACN1CCCC1=O
295
31811/16/2021186
acs.orglett.9b01016
C-N Activation
x10.1021/acs.orglett.9b010162019
R2 as p-OMeC6H41.41E-ETriphenylpyridinium+BF4-
AlkylBr
Het4,4'-Dimethoxy-2,2'-bipyridine
#N/A#N/A60NMPNMPMnN-NbpyNitrogenCsp3-Csp2_arNPyridiniumXCsp3Csp2_arCsp3-NCsp2_ar-XAlkyl-N[Alkyl]-PyridiniumHet-Br[Het]-BrPolar33No baseNo BaseNo base#N/A#N/AORG LETT_#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!X[N+]1=C(C=C(C=C1C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.F[B-](F)(F)FBrCCC1=NC=CC=C1CCC1=CC=NC=C1COC1=CC=NC(C2=NC=CC(OC)=C2)=C1#N/ACN1CCCC1=O
296
31911/16/2021216
Long
anie.201101461
C-O Activation
x10.1002/anie.2011014612011
(ArBO)3 as reactant11E-NuOH
ArylB(nep)
ArylPCy3
#N/A#N/A110NaHo-xyleneTHFo-xyleneBEt3PPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
StrongOOHBCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-OHAryl-B(nep)[Aryl]-B(nep)Non-Polar2.57Ionic-HNa+#N/A#N/A
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.8110.94035#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OB1OCC(C)(CO1)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[Na]HCC1=C(C)C=CC=C1
297
32011/16/2021243
Long
ja906477r
C-O Activation
x10.1021/ja906477r2009
OCO2tBu
(OBoc)
as Leaving group
14E-NuOBoc
ArylB(OH)2
ArylPCy3
#N/A#N/A130K3PO4toluenetoluenePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
MediumOO-CO-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-CO-R'Aryl-B(OH)2[Aryl]-B(OH)2Non-Polar2.38Ionic-PO4K+
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
TM0.3120.972.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OC(=O)OC(C)(C)CB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]Cc1ccccc1
298
21211/9/2021212
Kelly
c1sc00230a
C-O Activation
x10.1039/c1sc00230a2011
11.2E-NuOCONEt2
ArylH
MorpholineSIPr.HCl
#N/A#N/A80NaOtBudioxanedioxaneNHCCarbeneCarbeneCsp2_ar-Nsp3MediumOO-CO-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-CO-R'Morpholine-H[Morpholine]-HPolar2.25Ionic-OtBuNa+
CHEMICAL SCIENCE
_0.3121.412.8589353663.2821934583.0705644124.0077900319#REF!9.5921.261.706749553.2392069642.4729782574.96639928#REF!#REF!OC(N(CC)CC)=OHC1=CC=CC=C1N1CCCCC1C1=CC=CC=C1C1CCCCC1NCC(c1c(N2C=[N+](c3c(C(C)C)cccc3C(C)C)CC2)c(C(C)C)ccc1)C.[Cl-][Na]OC(C)(C)CC1COCCO1
299
32211/16/2021182
Long
ja410704d
C-O Activation
x10.1021/ja410704d2014
OTf as leaving group11E-EO(Ring-Opening)
ArylBr
Alkylbpy
#N/A#N/Ar.t.pyridineEt3NDMPUDMPUZnN-NbpyNitrogenCsp2_ar-Csp3WeakO
O(Ring-Opening)
XCsp2_arCsp3Csp2_ar-OCsp3-XAryl-O[Aryl]-O(Ring-Opening)Alkyl-Br[Alkyl]-BrPolar36.12NitrogenNitrogen(neutral)Nitrogen(neutral)#N/A
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_11.7105540393.2426955962.4766248184.973380195.17#REF!0#REF!#REF!XOCBrC1=CC=CC=C1CCC1=CC=CC=C1CCC1(C2=NC=CC=C2)=CC=CC=N1C1=CN=CC=C1O=C1N(C)CCCN1C
300
32311/16/2021182
Long
ja410704d
C-O Activation
x10.1021/ja410704d2014
Br as leavnig group11E-EO(Ring-Opening)
AlkylBr
Arylbpy
#N/A#N/Ar.t.pyridineEt3NDMPUDMPUZnN-NbpyNitrogenCsp3-Csp2_arWeakO
O(Ring-Opening)
XCsp3Csp2_arCsp3-OCsp2_ar-XAlkyl-O[Alkyl]-O(Ring-Opening)Aryl-Br[Aryl]-BrPolar36.12NitrogenNitrogen(neutral)Nitrogen(neutral)#N/A#N/A
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_11.7105540393.2426955962.4766248184.973380195.17#REF!0#REF!#REF!XOCBrCCC1=CC=CC=C1CCC1=CC=CC=C1C1(C2=NC=CC=C2)=CC=CC=N1C1=CN=CC=C1O=C1N(C)CCCN1C
301
32411/16/2021162
Shihong
acscatal.5b00498
C-O Activation
x10.1021/acscatal.5b004982015
14E-NuOBoc
ArylB(nep)
ArylPCy3
#N/A#N/A110K3PO4toluenetoluenePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
MediumOO-CO-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-CO-R'Aryl-B(nep)[Aryl]-B(nep)Non-Polar2.38Ionic-PO4K+#N/A#N/A
ACS CATALYSIS
_0.3120.972.244780372.9696246982.6072025343.5700586912.37#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OC(=O)OC(C)(C)CB1OCC(C)(CO1)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]Cc1ccccc1
302
32611/16/202126
Long
jacs.0c06995
C-O Activation
x10.1021/jacs.0c069952020
OTs as leaving Group11.2E-NuOTs
ArylB(nep)
ArylPMe3
#N/A#N/A60K3PO4dioxanedioxanePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(nep)[Aryl]-B(nep)Polar2.25Ionic-PO4K+#N/A#N/A
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OS(=O)(=O)(C1=CC=C(C)C=C1)B1OCC(C)(CO1)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1CP(C)C[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1COCCO1
303
32711/22/2021387
Gerry
ja306062c
C-H Activation
x10.1021/ja306062c2012
11.5E-NuCO2Ph
ArylH
Hetdcype
#N/A#N/A150K3PO4dioxaneP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
Csp2HCsp2_arCsp2_arCsp2_ar-Csp2Csp2_ar-HAryl-Csp2[Aryl]-Het-H[Het]-H#N/A#N/AIonic-PO4K+#N/A#N/A
J AM CHEM SOC
_2.244780372.9696246982.6072025343.5700586912.37#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8C(OC1=CC=CC=C1)=OHC1=CC=CC=C1C1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1P(C1CCCCC1)(C2CCCCC2)CCP(C3CCCCC3)C4CCCCC4[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1COCCO1
304
32811/22/2021191
Gerry
cs501502u
C-H Activation
x10.1021/cs501502u2015
11.4E-NuX
AlkyneH
Alkyl1,2-Benzenediamine
#N/A#N/ArtLiOtBuDMFN-N-NN-N-NNitrogenCsp1-Csp3XHCsp1Csp3Csp1-XCsp3-HAlkyne-X[Alkyne]-Alkyl-H[Alkyl]-H#N/A#N/AIonic-OtBuLi+
ACS CATAL
_2.8589353663.2821934583.0705644124.0077900319#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5ClHC#CCCC#CCCCN(C)C1=CC=CC=C1NCCN(C)CCC(C)(C)[O-].[Li+]CN(C)C=O
305
32911/22/2021194
Gerry
c5sc03704b
C-H Activation
x10.1039/c5sc03704b2015
3ea,eji11.5E-NuBr
BenzylH
ArylNIXANTPHOS
#N/A#N/A50NaN(SiMe3)2CPMEP-O-PP-O-PMixed
Csp3-ring(s)-Csp2_ar
XHCsp3-ring(s)Csp2_arCsp3-ring(s)-XCsp2_ar-HBenzyl-X[Benzyl]-Aryl-H[Aryl]-H#N/A#N/AIonicNitrogen(neutral)Na+CHEM SCI_#N/A1.7105540393.2426955962.4766248184.9733801926#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5BrHCC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1C1(P(C2=CC=CC=C2)C3=CC=CC=C3)=C4OC5=C(NC4=CC=C1)C=CC=C5P(C6=CC=CC=C6)C7=CC=CC=C7[Na]N([Si](C)(C)C)[Si](C)(C)CCOC1CCCC1
306
33011/22/2021194
Gerry
c5sc03704b
C-H Activation
x10.1039/c5sc03704b2015
11.5E-NuBr
BenzylH
ArylNIXANTPHOS
#N/A#N/ArtNaN(SiMe3)2CPMEP-O-PP-O-PMixed
Csp3-ring(s)-Csp2_ar
XHCsp3-ring(s)Csp2_arCsp3-ring(s)-XCsp2_ar-HBenzyl-X[Benzyl]-Aryl-H[Aryl]-H#N/A#N/AIonicNitrogen(neutral)Na+CHEM SCI_#N/A1.7105540393.2426955962.4766248184.9733801926#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5BrHCC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1C1(P(C2=CC=CC=C2)C3=CC=CC=C3)=C4OC5=C(NC4=CC=C1)C=CC=C5P(C6=CC=CC=C6)C7=CC=CC=C7[Na]N([Si](C)(C)C)[Si](C)(C)CCOC1CCCC1
307
33111/22/2021194
Gerry
c5sc03704b
C-H Activation
x10.1039/c5sc03704b2015
11.5E-NuCl
BenzylH
ArylNIXANTPHOS
#N/A#N/ArtCPMEP-O-PP-O-PMixed
Csp3-ring(s)-Csp2_ar
XHCsp3-ring(s)Csp2_arCsp3-ring(s)-XCsp2_ar-HBenzyl-X[Benzyl]-Aryl-H[Aryl]-H#N/A#N/ANo baseNo BaseNo baseCHEM SCI_#N/A#N/A#N/A#N/A#N/A#N/A#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5ClHCC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1C1(P(C2=CC=CC=C2)C3=CC=CC=C3)=C4OC5=C(NC4=CC=C1)C=CC=C5P(C6=CC=CC=C6)C7=CC=CC=C7#N/ACOC1CCCC1
308
33211/22/2021288
Gerry
anie.201510743
C-H Activation
x10.1002/anie.2015107432016
E-NuBr
ArylH
AlkylDtBEDA
#N/A#N/A100-120LiOtBudioxaneN-NN-NNitrogenCsp2_ar-Csp3XHCsp2_arCsp3Csp2_ar-XCsp3-HAryl-X[Aryl]-Alkyl-H[Alkyl]-H#N/A#N/AIonic-OtBuLi+
ANGEW CHEM INT EDIT
_2.8589353663.2821934583.0705644124.0077900319#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5BrHC1=CC=CC=C1CCC1=CC=CC=C1CCCC(C)(C)NCCNC(C)(C)CCC(C)(C)[O-].[Li+]C1COCCO1
309
33311/22/2021288
Gerry
anie.201510743
C-H Activation
x10.1002/anie.2015107432016
E-NuBr
ArylH
AlkylDtBEDA
#N/A#N/A100-120LiOtBudioxaneN-NN-NNitrogenCsp2_ar-Csp3XHCsp2_arCsp3Csp2_ar-XCsp3-HAryl-X[Aryl]-Alkyl-H[Alkyl]-H#N/A#N/AIonic-OtBuLi+
ANGEW CHEM INT EDIT
_2.8589353663.2821934583.0705644124.0077900319#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5BrHC1=CC=CC=C1CCC1=CC=CC=C1CCCC(C)(C)NCCNC(C)(C)CCC(C)(C)[O-].[Li+]C1COCCO1
310
33411/22/2021327
Gerry
anie.201304492
C-H Activation
x10.1002/anie.2013044922013
R is tBuCOE-NuOPiv
HetH
VInyldcype
#N/A#N/A130K3PO4dioxaneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp2MediumOO-CO-R'HCsp2_arCsp2Csp2_ar-OCsp2-HHet-O[Het]-O-CO-R'VInyl-H[VInyl]-H#N/A#N/AIonic-PO4K+MediumOCO-EDG
ANGEW CHEM INT EDIT
_0.3320.282.244780372.9696246982.6072025343.5700586912.37#REF!6.0701.706749553.2392069642.4729782574.96639928#REF!#REF!115.6OC(=O)C(C)(C)CHC1=NC=CC=C1C=CC1=CC=NC=C1C=CP(C1CCCCC1)(C2CCCCC2)CCP(C3CCCCC3)C4CCCCC4[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1COCCO1
311
33511/22/2021327
Gerry
anie.201304492
C-H Activation
x10.1002/anie.2013044922013
R is Me2NCOE-NuOCONMe2
HetH
VInyldcype
#N/A#N/A130K3PO4dioxaneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp2MediumOO-CO-R'HCsp2_arCsp2Csp2_ar-OCsp2-HHet-O[Het]-O-CO-R'VInyl-H[VInyl]-H#N/A#N/AIonic-PO4K+MediumOCO-EDG
ANGEW CHEM INT EDIT
_0.3117.732.244780372.9696246982.6072025343.5700586912.37#REF!6.0701.706749553.2392069642.4729782574.96639928#REF!#REF!115.6OC(=O)N(C)CHC1=NC=CC=C1C=CC1=CC=NC=C1C=CP(C1CCCCC1)(C2CCCCC2)CCP(C3CCCCC3)C4CCCCC4[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1COCCO1
312
33611/22/2021205
Gerry
jacs.7b13601
C-H Activation
x10.1021/jacs.7b136012018
dual catalyst11E-NuBr
VinylH
Vinyldppp
#N/A#N/A24DMFDMFZnP-PPhosphine (Bidentate)PhosphineCsp2-Csp2XHCsp2Csp2Csp2-XCsp2-HVinyl-X[Vinyl]-Vinyl-H[Vinyl]-HPolar36.7No baseNo BaseNo base
J AM CHEM SOC
_#N/A#N/A#N/A#N/A#N/A#REF!6.0701.706749553.2392069642.4729782574.96639928#REF!#REF!115.6BrHC=CC=CC=CC=CP(c1ccccc1)(c2ccccc2)CCCP(c3ccccc3)c4ccccc4#N/ACN(C)C=O
313
21311/9/2021212
Kelly
c1sc00230a
C-O Activation
x10.1039/c1sc00230a2011
11.2E-NuOCONEt2
ArylH
MorpholineSIPr.HCl
#N/A#N/A80NaOtBudioxanedioxaneNHCCarbeneCarbeneCsp2_ar-Nsp3MediumOO-CO-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-CO-R'Morpholine-H[Morpholine]-HPolar2.25Ionic-OtBuNa+
CHEMICAL SCIENCE
_0.3121.412.8589353663.2821934583.0705644124.0077900319#REF!9.5921.261.706749553.2392069642.4729782574.96639928#REF!#REF!OC(N(CC)CC)=OHC1=CC=CC=C1N1CCCCC1C1=CC=CC=C1C1CCCCC1NCC(c1c(N2C=[N+](c3c(C(C)C)cccc3C(C)C)CC2)c(C(C)C)ccc1)C.[Cl-][Na]OC(C)(C)CC1COCCO1
314
21411/9/2021212
Kelly
c1sc00230a
C-O Activation
x10.1039/c1sc00230a2011
11.2E-NuOCONEt2
HetH
MorpholineSIPr.HCl
#N/A#N/A80NaOtBudioxanedioxaneNHCCarbeneCarbeneCsp2_ar-Nsp3MediumOO-CO-R'HCsp2_arNsp3Csp2_ar-ONsp3-HHet-O[Het]-O-CO-R'Morpholine-H[Morpholine]-HPolar2.25Ionic-OtBuNa+
CHEMICAL SCIENCE
_0.3121.412.8589353663.2821934583.0705644124.0077900319#REF!9.5921.261.706749553.2392069642.4729782574.96639928#REF!#REF!OC(N(CC)CC)=OHC1=NC=CC=C1N1CCCCC1C1=CC=NC=C1C1CCCCC1NCC(c1c(N2C=[N+](c3c(C(C)C)cccc3C(C)C)CC2)c(C(C)C)ccc1)C.[Cl-][Na]OC(C)(C)CC1COCCO1
315
21511/9/2021212
Kelly
c1sc00230a
C-O Activation
x10.1039/c1sc00230a2011
Entry 1,2,711.2E-NuOCONEt2
ArylH
MorpholineSIPr.HCl
#N/A#N/A80NaOtBudioxanedioxaneNHCCarbeneCarbeneCsp2_ar-Nsp3MediumOO-CO-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-CO-R'Morpholine-H[Morpholine]-HPolar2.25Ionic-OtBuNa+
CHEMICAL SCIENCE
_0.3121.412.8589353663.2821934583.0705644124.0077900319#REF!9.5921.261.706749553.2392069642.4729782574.96639928#REF!#REF!OC(N(CC)CC)=OHC1=CC=CC=C1N1CCCCC1C1=CC=CC=C1C1CCCCC1NCC(c1c(N2C=[N+](c3c(C(C)C)cccc3C(C)C)CC2)c(C(C)C)ccc1)C.[Cl-][Na]OC(C)(C)CC1COCCO1
316
21611/9/2021212
Kelly
c1sc00230a
C-O Activation
x10.1039/c1sc00230a2011
Entry 3,511.2E-NuOCONEt2
ArylH
N(Alkyl)AlkylSIPr.HCl
#N/A#N/A80NaOtBudioxanedioxaneNHCCarbeneCarbeneCsp2_ar-Nsp3MediumOO-CO-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-CO-R'N(Alkyl)Alkyl-H[N(Alkyl)Alkyl]-HPolar2.25Ionic-OtBuNa+
CHEMICAL SCIENCE
_0.3121.412.8589353663.2821934583.0705644124.0077900319#REF!9.6512.031.706749553.2392069642.4729782574.96639928#REF!#REF!OC(N(CC)CC)=OHC1=CC=CC=C1N(C)CC1=CC=CC=C1C(C)NCC(c1c(N2C=[N+](c3c(C(C)C)cccc3C(C)C)CC2)c(C(C)C)ccc1)C.[Cl-][Na]OC(C)(C)CC1COCCO1
317
34111/25/2021246
Shihong
ol016526l
C-O Activation
x10.1021/ol016526l2001
11.5E-NuOTs
ArylB(OH)2
ArylPCy3
#N/A#N/A130K3PO4dioxanedioxanePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar2.25Ionic-PO4K+EasyOSO2-EDG
ORGANIC LETTERS
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(=O)(C1=CC=C(C)C=C1)B(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1COCCO1
318
34211/25/2021217
Shihong
ol9029534
C-O Activation
x10.1021/ol90295342010
11.2E-NuOCONMe2
VinylB(OH)2
ArylPCy3
#N/A#N/A110K2CO3dioxanedioxaneH2OPPhosphine (Monodentate)PhosphineCsp2-Csp2_arMediumOO-CO-R'BCsp2Csp2_arCsp2-OCsp2_ar-BVinyl-O[Vinyl]-O-CO-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar2.25Ionic-CO3K+MediumOCO-EDG
ORGANIC LETTERS
_0.3111.631.72.530430542.115215273.4538974810.33#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OC(=O)N(C)CB(O)OC=CC1=CC=CC=C1C=CC1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3O=C([O-])[O-].[K+].[K+]C1COCCO1
319
34311/25/2021217
Shihong
ol9029534
C-O Activation
x10.1021/ol90295342010
11.2E-NuOCONMe2
VinylB(OH)2
ArylPCy3
#N/A#N/A110K2CO3dioxanedioxaneH2OPPhosphine (Monodentate)PhosphineCsp2-Csp2_arMediumOO-CO-R'BCsp2Csp2_arCsp2-OCsp2_ar-BVinyl-O[Vinyl]-O-CO-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar2.25Ionic-CO3K+MediumOCO-EDG
ORGANIC LETTERS
_0.3111.631.72.530430542.115215273.4538974810.33#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OC(=O)N(C)CB(O)OC=CC1=CC=CC=C1C=CC1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3O=C([O-])[O-].[K+].[K+]C1COCCO1
320
34411/25/2021217
Shihong
ol9029534
C-O Activation
x10.1021/ol90295342010
11.2E-NuOCONMe2
ArylB(OH)2
ArylPCy3
#N/A#N/A110K2CO3dioxanedioxaneH2OPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
MediumOO-CO-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-CO-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar2.25Ionic-CO3K+MediumOCO-EDG
ORGANIC LETTERS
_0.3117.731.72.530430542.115215273.4538974810.33#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OC(=O)N(C)CB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3O=C([O-])[O-].[K+].[K+]C1COCCO1
321
34511/25/2021124
Shihong
chem.200902785
C-O Activation
x10.1002/chem.2009027852010
11E-NuOAc
VinylB(OH)2
ArylPCy3
#N/A#N/A110K3PO4toluenedioxane
toluene/dioxane
solvents 1:1
PPhosphine (Monodentate)PhosphineCsp2-Csp2_arMediumOO-CO-R'BCsp2Csp2_arCsp2-OCsp2_ar-BVinyl-O[Vinyl]-O-CO-R'Aryl-B(OH)2[Aryl]-B(OH)2Both#REF!Ionic-PO4K+MediumOCO-EDG
CHEMISTRY-A EUROPEAN JOURNAL
_0.318.642.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OC(C)=OB(O)OC=CC1=CC=CC=C1C=CC1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]Cc1ccccc1
322
34611/25/2021124
Shihong
chem.200902785
C-O Activation
x10.1002/chem.2009027852010
11E-NuOAc
VinylB(OH)2
ArylPCy3
#N/A#N/A110K3PO4toluenedioxane
toluene/dioxane
solvents 1:1
PPhosphine (Monodentate)PhosphineCsp2-Csp2_arMediumOO-CO-R'BCsp2Csp2_arCsp2-OCsp2_ar-BVinyl-O[Vinyl]-O-CO-R'Aryl-B(OH)2[Aryl]-B(OH)2Both#REF!Ionic-PO4K+MediumOCO-EDG
CHEMISTRY-A EUROPEAN JOURNAL
_0.318.642.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OC(C)=OB(O)OC=CC1=CC=CC=C1C=CC1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]Cc1ccccc1
323
34711/25/2021124
Shihong
chem.200902785
C-O Activation
x10.1002/chem.2009027852010
11E-NuOAc
VinylB(OH)2
ArylPCy3
#N/A#N/A110K3PO4toluenedioxane
toluene/dioxane
solvents 1:1
PPhosphine (Monodentate)PhosphineCsp2-Csp2_arMediumOO-CO-R'BCsp2Csp2_arCsp2-OCsp2_ar-BVinyl-O[Vinyl]-O-CO-R'Aryl-B(OH)2[Aryl]-B(OH)2Both#REF!Ionic-PO4K+MediumOCO-EDG
CHEMISTRY-A EUROPEAN JOURNAL
_0.318.642.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OC(C)=OB(O)OC=CC1=CC=CC=C1C=CC1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]Cc1ccccc1
324
21711/9/2021212
Kelly
c1sc00230a
C-O Activation
x10.1039/c1sc00230a2011
Entry 4,6,811.2E-NuOCONEt2
ArylH
N(H)ArylSIPr.HCl
#N/A#N/A80NaOtBudioxanedioxaneNHCCarbeneCarbeneCsp2_ar-Nsp3MediumOO-CO-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-CO-R'N(H)Aryl-H[N(H)Aryl]-HPolar2.25Ionic-OtBuNa+
CHEMICAL SCIENCE
_0.3121.412.8589353663.2821934583.0705644124.0077900319#REF!11.526.021.706749553.2392069642.4729782574.96639928#REF!#REF!OC(N(CC)CC)=OHC1=CC=CC=C1NC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1NCC(c1c(N2C=[N+](c3c(C(C)C)cccc3C(C)C)CC2)c(C(C)C)ccc1)C.[Cl-][Na]OC(C)(C)CC1COCCO1
325
34811/25/2021192
Shihong
ol301847m
C-O Activation
x10.1021/ol301847m2012
11.2E-NuOCONEt2
ArylH
MorpholineSIPr.HCl
#N/A#N/A80NaOtBudioxanedioxaneNHCCarbeneCarbeneCsp2_ar-Nsp3MediumOO-CO-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-CO-R'Morpholine-H[Morpholine]-HPolar2.25Ionic-OtBuNa+MediumOCO-EDG
ORGANIC LETTERS
_0.3121.412.8589353663.2821934583.0705644124.0077900319#REF!9.5921.261.706749553.2392069642.4729782574.96639928#REF!#REF!OC(N(CC)CC)=OHC1=CC=CC=C1N1CCCCC1C1=CC=CC=C1C1CCCCC1NCC(c1c(N2C=[N+](c3c(C(C)C)cccc3C(C)C)CC2)c(C(C)C)ccc1)C.[Cl-][Na]OC(C)(C)CC1COCCO1
326
34911/25/2021192
Shihong
ol301847m
C-O Activation
x10.1021/ol301847m2012
11.2E-NuOCONEt2
ArylH
MorpholineSIPr.HCl
#N/A#N/A80NaOtBudioxanedioxaneNHCCarbeneCarbeneCsp2_ar-Nsp3MediumOO-CO-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-CO-R'Morpholine-H[Morpholine]-HPolar2.25Ionic-OtBuNa+MediumOCO-EDG
ORGANIC LETTERS
_0.3121.412.8589353663.2821934583.0705644124.0077900319#REF!9.5921.261.706749553.2392069642.4729782574.96639928#REF!#REF!OC(N(CC)CC)=OHC1=CC=CC=C1N1CCCCC1C1=CC=CC=C1C1CCCCC1NCC(c1c(N2C=[N+](c3c(C(C)C)cccc3C(C)C)CC2)c(C(C)C)ccc1)C.[Cl-][Na]OC(C)(C)CC1COCCO1
327
35111/25/2021195
Shihong
ol302112q
C-O Activation
xx10.1021/ol302112q2012
11.5E-NuOMe
ArylMgX
ArylIPr
#N/A#N/A60THFTHFNHCCarbeneCarbene
Csp2_ar-Csp2_ar
StrongOO-Csp3MgCsp2_arCsp2_arCsp2_ar-OCsp2_ar-MgAryl-O[Aryl]-O-Csp3Aryl-MgX[Aryl]-MgXPolar7.58No baseNo BaseNo baseHardO-EDG
ORGANIC LETTERS
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2OC[Mg]ClC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1CC(C)C(C=CC=C1C(C)C)=C1N2C=CN(C3=C(C(C)C)C=CC=C3C(C)C)C2#N/AC1CCOC1
328
35211/25/2021126
Shihong
ja5076426
C-O Activation
xx10.1021/ja50764262014
12.5E-NuO(Ring-Opening)
AlkylMgX
Alkylrac-BINAP
#N/A#N/ArttoluenetolueneP-PPhosphine (Bidentate)PhosphineCsp3-Csp3WeakO
O(Ring-Opening)
MgCsp3Csp3Csp3-OCsp3-MgAlkyl-O[Alkyl]-O(Ring-Opening)Alkyl-MgX[Alkyl]-MgXNon-Polar2.38No baseNo BaseNo base#N/A#N/A
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_1#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OC[Mg]ClCCCCCCCCC12=CC=CC=C1C=CC(P(C3=CC=CC=C3)C4=CC=CC=C4)=C2C5=C(C=CC=C6)C6=CC=C5P7C8=CC=CCC98=C7C=CC=C9#N/ACc1ccccc1
329
35311/25/2021126
Shihong
ja5076426
C-O Activation
xx10.1021/ja50764262014
12.5E-NuO(Ring-Opening)
AlkylMgX
Alkylrac-BINAP
#N/A#N/ArttoluenetolueneP-PPhosphine (Bidentate)PhosphineCsp3-Csp3WeakO
O(Ring-Opening)
MgCsp3Csp3Csp3-OCsp3-MgAlkyl-O[Alkyl]-O(Ring-Opening)Alkyl-MgX[Alkyl]-MgXNon-Polar2.38No baseNo BaseNo base#N/A#N/A
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_1#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OC[Mg]ClCCCCCCCCC12=CC=CC=C1C=CC(P(C3=CC=CC=C3)C4=CC=CC=C4)=C2C5=C(C=CC=C6)C6=CC=C5P7C8=CC=CCC98=C7C=CC=C9#N/ACc1ccccc1
330
35411/25/2021126
Shihong
ja5076426
C-O Activation
xx10.1021/ja50764262014
12.5E-NuO(Ring-Opening)
AlkylMgX
Alkylrac-BINAP
#N/A#N/ArttoluenetolueneP-PPhosphine (Bidentate)PhosphineCsp3-Csp3WeakO
O(Ring-Opening)
MgCsp3Csp3Csp3-OCsp3-MgAlkyl-O[Alkyl]-O(Ring-Opening)Alkyl-MgX[Alkyl]-MgXNon-Polar2.38No baseNo BaseNo base#N/A#N/A
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_1#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OC[Mg]ClCCCCCCCCC12=CC=CC=C1C=CC(P(C3=CC=CC=C3)C4=CC=CC=C4)=C2C5=C(C=CC=C6)C6=CC=C5P7C8=CC=CCC98=C7C=CC=C9#N/ACc1ccccc1
331
35511/25/2021126
Shihong
ja5076426
C-O Activation
xx10.1021/ja50764262014
12.5E-NuO(Ring-Opening)
AlkylMgX
Alkylrac-BINAP
#N/A#N/ArttoluenetolueneP-PPhosphine (Bidentate)PhosphineCsp3-Csp3WeakO
O(Ring-Opening)
MgCsp3Csp3Csp3-OCsp3-MgAlkyl-O[Alkyl]-O(Ring-Opening)Alkyl-MgX[Alkyl]-MgXNon-Polar2.38No baseNo BaseNo base#N/A#N/A
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_1#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OC[Mg]ClCCCCCCCCC12=CC=CC=C1C=CC(P(C3=CC=CC=C3)C4=CC=CC=C4)=C2C5=C(C=CC=C6)C6=CC=C5P7C8=CC=CCC98=C7C=CC=C9#N/ACc1ccccc1
332
35611/25/2021164
Shihong
chem.201003731
C-O Activation
xx10.1002/chem.2010037312011
Ligand is I11.5E-NuOMe
ArylMgX
ArylN-((dicyclohexylphosphaneyl)(phenyl)methyl)-2-(3,5-diphenyl-1H-pyrazol-1-yl)aniline
#N/A#N/A25toluenetolueneN-N-PMixed (N and P)Mixed
Csp2_ar-Csp2_ar
StrongOO-Csp3MgCsp2_arCsp2_arCsp2_ar-OCsp2_ar-MgAryl-O[Aryl]-O-Csp3Aryl-MgX[Aryl]-MgXNon-Polar2.38No baseNo BaseNo baseHardO-EDG
CHEMISTRY-A EUROPEAN JOURNAL
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2OC[Mg]ClC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1(C2=CC=CC=C2)=NN(C3=CC=CC=C3NC(C4=CC=CC=C4)P(C5CCCCC5)C6CCCCC6)C(C7=CC=CC=C7)=C1#N/ACc1ccccc1
333
35711/25/2021164
Shihong
chem.201003731
C-O Activation
xx10.1002/chem.2010037312011
Ligand is II11.5E-NuOMe
ArylMgX
ArylN-((diisopropylphosphaneyl)(phenyl)methyl)-2-(3,5-diphenyl-1H-pyrazol-1-yl)aniline
#N/A#N/A25THFTHFN-N-PMixed (N and P)Mixed
Csp2_ar-Csp2_ar
StrongOO-Csp3MgCsp2_arCsp2_arCsp2_ar-OCsp2_ar-MgAryl-O[Aryl]-O-Csp3Aryl-MgX[Aryl]-MgXPolar7.58No baseNo BaseNo baseHardO-EDG
CHEMISTRY-A EUROPEAN JOURNAL
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2OC[Mg]ClC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1CC(C)P(C(C)C)C(C1=CC=CC=C1)NC2=CC=CC=C2N3C(C4=CC=CC=C4)=CC(C5=CC=CC=C5)=N3#N/AC1CCOC1
334
35811/25/2021164
Shihong
chem.201003731
C-O Activation
xx10.1002/chem.2010037312011
Ligand is I 11.5E-NuOMe
ArylMgX
BenzylN-((dicyclohexylphosphaneyl)(phenyl)methyl)-2-(3,5-diphenyl-1H-pyrazol-1-yl)aniline
#N/A#N/A120toluenetolueneN-N-PMixed (N and P)Mixed
Csp2_ar-Csp3-ring(s)
StrongOO-Csp3MgCsp2_arCsp3-ring(s)Csp2_ar-OCsp3-ring(s)-MgAryl-O[Aryl]-O-Csp3Benzyl-MgX[Benzyl]-MgXNon-Polar2.38No baseNo BaseNo baseHardO-EDG
CHEMISTRY-A EUROPEAN JOURNAL
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!29OC[Mg]ClC1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1C1(C2=CC=CC=C2)=NN(C3=CC=CC=C3NC(C4=CC=CC=C4)P(C5CCCCC5)C6CCCCC6)C(C7=CC=CC=C7)=C1#N/ACc1ccccc1
335
35911/25/2021164
Shihong
chem.201003731
C-O Activation
xx10.1002/chem.2010037312011
Ligand is I11.5E-NuOMe
VinylMgX
ArylN-((dicyclohexylphosphaneyl)(phenyl)methyl)-2-(3,5-diphenyl-1H-pyrazol-1-yl)aniline
#N/A#N/A120toluenetolueneN-N-PMixed (N and P)MixedCsp2-Csp2_arStrongOO-Csp3MgCsp2Csp2_arCsp2-OCsp2_ar-MgVinyl-O[Vinyl]-O-Csp3Aryl-MgX[Aryl]-MgXNon-Polar2.38No baseNo BaseNo baseHardO-EDG
CHEMISTRY-A EUROPEAN JOURNAL
_-0.286.71#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2OC[Mg]ClC=CC1=CC=CC=C1C=CC1=CC=CC=C1C1(C2=CC=CC=C2)=NN(C3=CC=CC=C3NC(C4=CC=CC=C4)P(C5CCCCC5)C6CCCCC6)C(C7=CC=CC=C7)=C1#N/ACc1ccccc1
336
36011/25/2021164
Shihong
chem.201003731
C-O Activation
xx10.1002/chem.2010037312011
Ligand is II11.5E-NuOMe
VinylMgX
ArylN-((diisopropylphosphaneyl)(phenyl)methyl)-2-(3,5-diphenyl-1H-pyrazol-1-yl)aniline
#N/A#N/A120toluenetolueneN-N-PMixed (N and P)MixedCsp2-Csp2_arStrongOO-Csp3MgCsp2Csp2_arCsp2-OCsp2_ar-MgVinyl-O[Vinyl]-O-Csp3Aryl-MgX[Aryl]-MgXNon-Polar2.38No baseNo BaseNo baseHardO-EDG
CHEMISTRY-A EUROPEAN JOURNAL
_-0.286.71#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2OC[Mg]ClC=CC1=CC=CC=C1C=CC1=CC=CC=C1CC(C)P(C(C)C)C(C1=CC=CC=C1)NC2=CC=CC=C2N3C(C4=CC=CC=C4)=CC(C5=CC=CC=C5)=N3#N/ACc1ccccc1
337
36111/25/2021222
Shihong
anie.200907359
C-O Activation
xx10.1002/anie.2009073592010
12E-NuOMg
ArylMgX
ArylPCy3
#N/A#N/A120tolueneDIPEtoluenePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
StrongOO-MetalMgCsp2_arCsp2_arCsp2_ar-OCsp2_ar-MgAryl-O[Aryl]-O-MetalAryl-MgX[Aryl]-MgXNon-Polar2.38No baseNo BaseNo baseMediumOMg
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.81#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2O[Mg][Mg]ClC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/ACc1ccccc1
338
36211/30/2021237
Long
jo049940i
C-O Activation
x10.1021/jo049940i2004
NAPCy3dppes as ligand and toluene as solventE-NuOMs
ArylB(OH)2
Aryldppe
#N/A#N/A80K3PO4dioxanedioxaneP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar2.25Ionic-PO4K+EasyOSO2-EDG
JOURNAL OF ORGANIC CHEMISTRY
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(=O)CB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1c1ccc(cc1)P(CCP(c2ccccc2)c3ccccc3)c4ccccc4[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1COCCO1
339
36311/30/2021237
Long
jo049940i
C-O Activation
x10.1021/jo049940i2004
NAPCy3dppes as ligand and dioxanesolventE-NuOMs
ArylB(OH)2
Aryldppe
#N/A#N/A80K3PO4dioxanedioxaneP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar2.25Ionic-PO4K+EasyOSO2-EDG
JOURNAL OF ORGANIC CHEMISTRY
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(=O)CB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1c1ccc(cc1)P(CCP(c2ccccc2)c3ccccc3)c4ccccc4[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1COCCO1
340
36411/30/2021237
Long
jo049940i
C-O Activation
x10.1021/jo049940i2004
NAPCy3PPh3 as ligand and toluene as solvnetE-NuOMs
ArylB(OH)2
ArylPPh3
#N/A#N/A80K3PO4toluenetoluenePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2Non-Polar2.38Ionic-PO4K+EasyOSO2-EDG
JOURNAL OF ORGANIC CHEMISTRY
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(=O)CB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]Cc1ccccc1
341
36511/30/2021237
Long
jo049940i
C-O Activation
x10.1021/jo049940i2004
NAPCy3PCy3 as ligand and dioxane as solventE-NuOMs
ArylB(OH)2
ArylPPh3
#N/A#N/A80K3PO4dioxanedioxanePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar2.25Ionic-PO4K+EasyOSO2-EDG
JOURNAL OF ORGANIC CHEMISTRY
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(=O)CB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1COCCO1
342
36612/1/2021186
Shihong
ol901978e
C-O Activation
x10.1021/ol901978e2009
11.2E-NuOMe
VinylB(nep)
ArylPCy3
#N/A#N/A120CsFtoluenetoluenePPhosphine (Monodentate)PhosphineCsp2-Csp2_arStrongOO-Csp3BCsp2Csp2_arCsp2-OCsp2_ar-BVinyl-O[Vinyl]-O-Csp3Aryl-B(nep)[Aryl]-B(nep)Non-Polar2.38Ionic-FCs+HardO-EDG
ORGANIC LETTERS
_-0.286.7103.14#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OCB1OCC(C)(CO1)CC=CC1=CC=CC=C1C=CC1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[Cs]FCc1ccccc1
343
36712/1/2021186
Shihong
ol901978e
C-O Activation
x10.1021/ol901978e2009
11.2E-NuOMe
VinylB(nep)
ArylPCy3
#N/A#N/A120CsFtoluenetoluenePPhosphine (Monodentate)PhosphineCsp2-Csp2_arStrongOO-Csp3BCsp2Csp2_arCsp2-OCsp2_ar-BVinyl-O[Vinyl]-O-Csp3Aryl-B(nep)[Aryl]-B(nep)Non-Polar2.38Ionic-FCs+HardO-EDG
ORGANIC LETTERS
_-0.286.7103.14#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OCB1OCC(C)(CO1)CC=CC1=CC=CC=C1C=CC1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[Cs]FCc1ccccc1
344
36812/1/2021186
Shihong
ol901978e
C-O Activation
x10.1021/ol901978e2009
11.2E-NuOMe
VinylB(nep)
ArylPCy3
#N/A#N/A120CsFtoluenetoluenePPhosphine (Monodentate)PhosphineCsp2-Csp2_arStrongOO-Csp3BCsp2Csp2_arCsp2-OCsp2_ar-BVinyl-O[Vinyl]-O-Csp3Aryl-B(nep)[Aryl]-B(nep)Non-Polar2.38Ionic-FCs+HardO-EDG
ORGANIC LETTERS
_-0.286.7103.14#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OCB1OCC(C)(CO1)CC=CC1=CC=CC=C1C=CC1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[Cs]FCc1ccccc1
345
36912/1/2021245
Shihong
jo00109a044
C-O Activation
x10.1021/jo00109a0441995
NANAE-NuOTf
ArylB(OH)2
Aryldppf
#N/A#N/A67K3PO4THFTHFZnP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar7.58Ionic-PO4K+EasyOSO2-EWG
JOURNAL OF ORGANIC CHEMISTRY
TM0.532.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(=O)C(F)(F)FB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1c1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1CCOC1
346
6351/5/202234
Kelly
acscatal.7b02014
C-O Activation
x10.1021/acscatal.7b020142017
11.5E-NuOCONEt2
ArylH
N(H)AlkylCyPAd-DalPhos
#N/A#N/A25NaOtButoluenetolueneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Nsp3MediumOO-CO-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-CO-R'N(H)Alkyl-H[N(H)Alkyl]-HNon-Polar2.38Ionic-OtBuNa+MediumOCO-EDG
ACS CATALYSIS
_0.3121.412.8589353663.2821934583.0705644124.0077900319#REF!5.6643.091.706749553.2392069642.4729782574.96639928#REF!#REF!OC(N(CC)CC)=OHC1=CC=CC=C1NCC1=CC=CC=C1CNC[C@@]12C[C@](O3)(C)O[C@@](CC3(C)P1C4=CC=CC=C4P(C5CCCCC5)C6CCCCC6)(O2)C[Na]OC(C)(C)CCc1ccccc1
347
37112/1/2021184
Shihong
anie.201402922
C-O Activation
xx10.1002/anie.2014029222014
11.3E-NuOMe
ArylLi
Csp3-SiPCy3
#N/A#N/A80toluenetoluenePPhosphine (Monodentate)PhosphineCsp2_ar-Csp3StrongOO-Csp3LiCsp2_arCsp3Csp2_ar-OCsp3-LiAryl-O[Aryl]-O-Csp3Csp3-Si-Li[Csp3-Si]-LiNon-Polar2.38No baseNo BaseNo baseHardO-EDG
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!XX1.7061130233.2414063642.4737596946.9930727#REF!#REF!4OC[Li]C1=CC=CC=C1C[Si](C)(C)CC1=CC=CC=C1C[Si](C)(C)CC1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/ACc1ccccc1
348
37212/1/2021242
Shihong
ja903091g
C-O Activation
x10.1021/ja903091g2009
11.1E-NuOTf
ArylMgX
ArylPO
#N/A#N/A25Et2OEt2OP-OPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'MgCsp2_arCsp2_arCsp2_ar-OCsp2_ar-MgAryl-O[Aryl]-O-SO2-R'Aryl-MgX[Aryl]-MgXNon-Polar4.33No baseNo BaseNo baseEasyOSO2-EWG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.53#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2OS(=O)(=O)C(F)(F)F[Mg]ClC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1CC(C1=CC=CC=C1P(C2=CC=CC=C2)C3=CC=CC=C3)O#N/ACCOCC
349
37312/2/2021178
Long
jo2000034
C-O Activation
x10.1021/jo20000342011
11.25E-NuOP(O)(OEt)2
ArylB(OH)2
ArylPCy3
#N/A#N/A110K3PO4dioxanedioxanePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
StrongOO-PO(OR')2BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-PO(OR')2Aryl-B(OH)2[Aryl]-B(OH)2Polar2.25Ionic-PO4K+HardOPO-EDG
JOURNAL OF ORGANIC CHEMISTRY
TM0.0423.072.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OP(OCC)(OCC)=OB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1COCCO1
350
37412/2/2021218
Long
ejoc.200900067
C-O Activation
x10.1002/ejoc.2009000672009
13E-NuOTs
ArylB(OH)2
ArylCN(C=C1)CN1CC2=CC=CC(CN3C=CN(C)C3)=[NH+]2.F[B-](F)(F)F
#N/A#N/A120K3PO4DMEDMEN-N-NCarbene (Bidentate)Nitrogen
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar7.2Ionic-PO4K+EasyOSO2-EDG
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(=O)(C1=CC=C(C)C=C1)B(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1CN(C=C1)CN1CC2=CC=CC(CN3C=CN(C)C3)=[NH+]2.F[B-](F)(F)F[O-]P(=O)([O-])[O-].[K+].[K+].[K+]COCCOC
351
37512/2/2021218
Long
ejoc.200900067
C-O Activation
x10.1002/ejoc.2009000672009
13E-NuOTs
VinylB(OH)2
ArylCN(C=C1)CN1CC2=CC=CC(CN3C=CN(C)C3)=[NH+]2.F[B-](F)(F)F
#N/A#N/A100-120K3PO4DMEDMEN-N-NCarbene (Bidentate)NitrogenCsp2-Csp2_arWeakOO-SO2-R'BCsp2Csp2_arCsp2-OCsp2_ar-BVinyl-O[Vinyl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar7.2Ionic-PO4K+EasyOSO2-EDG
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(=O)(C1=CC=C(C)C=C1)B(O)OC=CC1=CC=CC=C1C=CC1=CC=CC=C1CN(C=C1)CN1CC2=CC=CC(CN3C=CN(C)C3)=[NH+]2.F[B-](F)(F)F[O-]P(=O)([O-])[O-].[K+].[K+].[K+]COCCOC
352
37612/2/2021218
Long
ejoc.200900067
C-O Activation
x10.1002/ejoc.2009000672009
13E-NuOMs
ArylB(OH)2
ArylCN(C=C1)CN1CC2=CC=CC(CN3C=CN(C)C3)=[NH+]2.F[B-](F)(F)F
#N/A#N/A120K3PO4DMEDMEN-N-NCarbene (Bidentate)Nitrogen
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar7.2Ionic-PO4K+EasyOSO2-EDG
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(=O)CB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1CN(C=C1)CN1CC2=CC=CC(CN3C=CN(C)C3)=[NH+]2.F[B-](F)(F)F[O-]P(=O)([O-])[O-].[K+].[K+].[K+]COCCOC
353
37712/2/2021194
Long
ol101592r
C-O Activation
xx10.1021/ol101592r2010
OMs as leaving group11.3E-NuOMs
ArylBF3K
HetPCy3
#N/A#N/A110K3PO4tBuOHH2OH2OPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Het-BF3K[Het]-BF3KPolar80.1Ionic-PO4K+EasyOSO2-EDG
ORGANIC LETTERS
TM0.362.244780372.9696246982.6072025343.5700586912.37#REF!11.1112.892.2294683593.2807152032.7550917816.56810798#REF!#REF!150OS(=O)(=O)C[B-](F)(F)F.[K+]C1=CC=CC=C1C1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]#N/A
354
37812/2/2021194
Long
ol101592r
C-O Activation
xx10.1021/ol101592r2010
OPiv as leaving group11.3E-NuOPiv
ArylBF3K
HetPCy3
#N/A#N/A110K3PO4tBuOHH2OH2OPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
MediumOO-CO-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-CO-R'Het-BF3K[Het]-BF3KPolar80.1Ionic-PO4K+MediumOCO-EDG
ORGANIC LETTERS
TM0.3320.282.244780372.9696246982.6072025343.5700586912.37#REF!11.1112.892.2294683593.2807152032.7550917816.56810798#REF!#REF!150OC(=O)C(C)(C)C[B-](F)(F)F.[K+]C1=CC=CC=C1C1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]#N/A
355
37912/2/2021194
Long
ol101592r
C-O Activation
xx10.1021/ol101592r2010
NA11.3E-NuOMs
ArylBF3K
ArylPCy3
#N/A#N/A110K3PO4tBuOHH2OH2OPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-BF3K[Aryl]-BF3KPolar80.1Ionic-PO4K+EasyOSO2-EDG
ORGANIC LETTERS
TM0.362.244780372.9696246982.6072025343.5700586912.37#REF!11.8902.2294683593.2807152032.7550917816.56810798#REF!#REF!150.1OS(=O)(=O)C[B-](F)(F)F.[K+]C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]#N/A
356
38012/2/2021194
Long
ol101592r
C-O Activation
xx10.1021/ol101592r2010
NA11.3E-NuOMs
ArylBF3K
ArylPCy3
#N/A#N/A110K3PO4tBuOHH2OH2OPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-BF3K[Aryl]-BF3KPolar80.1Ionic-PO4K+EasyOSO2-EDG
ORGANIC LETTERS
TM0.362.244780372.9696246982.6072025343.5700586912.37#REF!11.8902.2294683593.2807152032.7550917816.56810798#REF!#REF!150.1OS(=O)(=O)C[B-](F)(F)F.[K+]C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]#N/A
357
38112/2/2021194
Long
ol101592r
C-O Activation
xx10.1021/ol101592r2010
NA11.3E-NuOMs
HetBF3K
HetPCy3
#N/A#N/A110K3PO4tBuOHH2OH2OPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BHet-O[Het]-O-SO2-R'Het-BF3K[Het]-BF3KPolar80.1Ionic-PO4K+EasyOSO2-EDG
ORGANIC LETTERS
TM0.362.244780372.9696246982.6072025343.5700586912.37#REF!11.1112.892.2294683593.2807152032.7550917816.56810798#REF!#REF!150OS(=O)(=O)C[B-](F)(F)F.[K+]C1=NC=CC=C1C1=NC=CC=C1C1=CC=NC=C1C1=CC=NC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]#N/A
358
22011/9/2021236
Kelly
anie.200907287
C-O Activation
x10.1002/anie.2009072872010
11.2E-NuOPiv
ArylH
MorpholineIPr.HCl
#N/A#N/A80NaOtButoluenetolueneNHCCarbeneCarbeneCsp2_ar-Nsp3MediumOO-CO-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-CO-R'Morpholine-H[Morpholine]-HNon-Polar2.38Ionic-OtBuNa+
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.3320.282.8589353663.2821934583.0705644124.0077900319#REF!9.5921.261.706749553.2392069642.4729782574.96639928#REF!#REF!OC(=O)C(C)(C)CHC1=CC=CC=C1N1CCCCC1C1=CC=CC=C1C1CCCCC1NCC(C)c1cccc(C(C)C)c1N2C=[N+](C=C2)c3c(C(C)C)cccc3C(C)C.[Cl-][Na]OC(C)(C)CCc1ccccc1
359
22111/9/2021236
Kelly
anie.200907287
C-O Activation
x10.1002/anie.2009072872010
11.2E-NuOPiv
ArylH
N(Alkyl)AlkylIPr.HCl
#N/A#N/A80NaOtButoluenetolueneNHCCarbeneCarbeneCsp2_ar-Nsp3MediumOO-CO-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-CO-R'N(Alkyl)Alkyl-H[N(Alkyl)Alkyl]-HNon-Polar2.38Ionic-OtBuNa+
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.3320.282.8589353663.2821934583.0705644124.0077900319#REF!9.6512.031.706749553.2392069642.4729782574.96639928#REF!#REF!OC(=O)C(C)(C)CHC1=CC=CC=C1N(C)CC1=CC=CC=C1C(C)NCC(C)c1cccc(C(C)C)c1N2C=[N+](C=C2)c3c(C(C)C)cccc3C(C)C.[Cl-][Na]OC(C)(C)CCc1ccccc1
360
38512/2/2021238
Long
jo00126a047
C-O Activation
x10.1021/jo00126a0471995
11.8-2E-NuOMs
ArylMgX
Alkyldppf
#N/A#N/ArtTHFTHFZnP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp3WeakOO-SO2-R'MgCsp2_arCsp3Csp2_ar-OCsp3-MgAryl-O[Aryl]-O-SO2-R'Alkyl-MgX[Alkyl]-MgXPolar7.58No baseNo BaseNo baseEasyOSO2-EDG
JOURNAL OF ORGANIC CHEMISTRY
_0.36#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OS(=O)(=O)C[Mg]ClC1=CC=CC=C1CCC1=CC=CC=C1CCc1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1#N/AC1CCOC1
361
38612/2/2021224
Long
jo00106a031
C-O Activation
x10.1021/jo00106a0311995
OTf as leaving groupNANAE-EOTf
ArylOTf
ArylPPh3
#N/A#N/A67Et4NITHFTHFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'OCsp2_arCsp2_arCsp2_ar-OCsp2_ar-OAryl-O[Aryl]-O-SO2-R'Aryl-OTf[Aryl]-OTfPolar7.58NitrogenNitrogen(charged)Nitrogen(charged)EasyOSO2-EWG
JOURNAL OF ORGANIC CHEMISTRY
_0.532.9420199955.1753858444.058702925.8053568710.64#REF!0#REF!#REF!XOS(=O)(=O)C(F)(F)FOS(=O)(=O)C(F)(F)FC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3CC[N+](CC)(CC)CC.[I-]C1CCOC1
362
38712/2/2021224
Long
jo00106a031
C-O Activation
xx10.1021/jo00106a0311995
p-FPhSO2ONANAE-E4-fluorobenzenesulfonic acid
Aryl4-fluorobenzenesulfonic acid
ArylPPh3
#N/A#N/A67Et4NITHFTHFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'OCsp2_arCsp2_arCsp2_ar-OCsp2_ar-OAryl-O[Aryl]-O-SO2-R'Aryl-4-fluorobenzenesulfonic acid[Aryl]-4-fluorobenzenesulfonic acidPolar7.58NitrogenNitrogen(charged)Nitrogen(charged)#N/A#N/A
JOURNAL OF ORGANIC CHEMISTRY
_0.72.9420199955.1753858444.058702925.8053568710.64#REF!0#REF!#REF!XOS(C1=CC=C(F)C=C1)(=O)=OOS(C1=CC=C(F)C=C1)(=O)=OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3CC[N+](CC)(CC)CC.[I-]C1CCOC1
363
38812/2/2021224
Long
jo00106a031
C-O Activation
xx10.1021/jo00106a0311995
p-ClPhSO2O as leaving groupNANAE-E4-chlorobenzenesulfonic acid
Aryl4-chlorobenzenesulfonic acid
ArylPPh3
#N/A#N/A67Et4NITHFTHFZnPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'OCsp2_arCsp2_arCsp2_ar-OCsp2_ar-OAryl-O[Aryl]-O-SO2-R'Aryl-4-chlorobenzenesulfonic acid[Aryl]-4-chlorobenzenesulfonic acidPolar7.58NitrogenNitrogen(charged)Nitrogen(charged)#N/A#N/A
JOURNAL OF ORGANIC CHEMISTRY
_0.72.9420199955.1753858444.058702925.8053568710.64#REF!0#REF!#REF!XOS(C1=CC=C(C=C1)Cl)(=O)=OOS(C1=CC=C(C=C1)Cl)(=O)=OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3CC[N+](CC)(CC)CC.[I-]C1CCOC1
364
38912/2/2021224
Long
jo00106a031
C-O Activation
xx10.1021/jo00106a0311995
PhSO2O as leaving groupNANAE-EOSO2Ph
ArylOSO2Ph
ArylPPh3
#N/A#N/A67Et4NITHFTHFZnPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'OCsp2_arCsp2_arCsp2_ar-OCsp2_ar-OAryl-O[Aryl]-O-SO2-R'Aryl-OSO2Ph[Aryl]-OSO2PhPolar7.58NitrogenNitrogen(charged)Nitrogen(charged)EasyOSO2-EDG
JOURNAL OF ORGANIC CHEMISTRY
_0.72.9420199955.1753858444.058702925.8053568710.64#REF!0#REF!#REF!OS(=O)(=O)(C1=CC=CC=C1)OS(=O)(=O)(C1=CC=CC=C1)C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3CC[N+](CC)(CC)CC.[I-]C1CCOC1
365
39012/2/2021224
Long
jo00106a031
C-O Activation
xx10.1021/jo00106a0311995
p-CH3PhSO2O as leaving groupNANAE-EOTs
ArylOTs
ArylPPh3
#N/A#N/A67Et4NITHFTHFZnPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'OCsp2_arCsp2_arCsp2_ar-OCsp2_ar-OAryl-O[Aryl]-O-SO2-R'Aryl-OTs[Aryl]-OTsPolar7.58NitrogenNitrogen(charged)Nitrogen(charged)EasyOSO2-EDG
JOURNAL OF ORGANIC CHEMISTRY
_0.362.9420199955.1753858444.058702925.8053568710.64#REF!0#REF!#REF!OS(=O)(=O)(C1=CC=C(C)C=C1)OS(=O)(=O)(C1=CC=C(C)C=C1)C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3CC[N+](CC)(CC)CC.[I-]C1CCOC1
366
39112/2/2021224
Long
jo00106a031
C-O Activation
xx10.1021/jo00106a0311995
CH3SO2O as leaving groupNANAE-EOMs
ArylOMs
ArylPPh3
#N/A#N/A67Et4NITHFTHFZnPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'OCsp2_arCsp2_arCsp2_ar-OCsp2_ar-OAryl-O[Aryl]-O-SO2-R'Aryl-OMs[Aryl]-OMsPolar7.58NitrogenNitrogen(charged)Nitrogen(charged)EasyOSO2-EDG
JOURNAL OF ORGANIC CHEMISTRY
_0.362.9420199955.1753858444.058702925.8053568710.64#REF!0#REF!#REF!OS(=O)(=O)COS(=O)(=O)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3CC[N+](CC)(CC)CC.[I-]C1CCOC1
367
39212/2/2021224
Long
jo00106a031
C-O Activation
xx10.1021/jo00106a0311995
NANAE-EOMs
ArylOMs
ArylPPh3
#N/A#N/A67Et4NITHFTHFZnPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'OCsp2_arCsp2_arCsp2_ar-OCsp2_ar-OAryl-O[Aryl]-O-SO2-R'Aryl-OMs[Aryl]-OMsPolar7.58NitrogenNitrogen(charged)Nitrogen(charged)EasyOSO2-EDG
JOURNAL OF ORGANIC CHEMISTRY
_0.362.9420199955.1753858444.058702925.8053568710.64#REF!0#REF!#REF!OS(=O)(=O)COS(=O)(=O)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3CC[N+](CC)(CC)CC.[I-]C1CCOC1
368
39312/2/2021171
Long
jo010452+
C-O Activation
x10.1021/jo010452+2001
NA
11.5E-NuOP(O)(OEt)2
ArylZnX
Vinyldppe
#N/A#N/A25K3PO4benzenebenzeneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp2StrongOO-PO(OR')2ZnCsp2_arCsp2Csp2_ar-OCsp2-ZnAryl-O[Aryl]-O-PO(OR')2Vinyl-ZnX[Vinyl]-ZnXNon-Polar2.27Ionic-PO4K+HardOPO-EDG
JOURNAL OF ORGANIC CHEMISTRY
_0.0423.072.244780372.9696246982.6072025343.5700586912.37#REF!XX0#REF!#REF!XOP(OCC)(OCC)=O[Zn]ClC1=CC=CC=C1C=CC1=CC=CC=C1C=Cc1ccc(cc1)P(CCP(c2ccccc2)c3ccccc3)c4ccccc4[O-]P(=O)([O-])[O-].[K+].[K+].[K+]c1ccccc1
369
39412/2/2021171
Long
jo010452+
C-O Activation
x10.1021/jo010452+2001
NA
11.5E-NuOP(O)(OEt)2
ArylZnX
Aryldppe
#N/A#N/A25K3PO4benzenebenzeneP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
StrongOO-PO(OR')2ZnCsp2_arCsp2_arCsp2_ar-OCsp2_ar-ZnAryl-O[Aryl]-O-PO(OR')2Aryl-ZnX[Aryl]-ZnXNon-Polar2.27Ionic-PO4K+HardOPO-EDG
JOURNAL OF ORGANIC CHEMISTRY
_0.0423.072.244780372.9696246982.6072025343.5700586912.37#REF!XX0#REF!#REF!XOP(OCC)(OCC)=O[Zn]ClC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1c1ccc(cc1)P(CCP(c2ccccc2)c3ccccc3)c4ccccc4[O-]P(=O)([O-])[O-].[K+].[K+].[K+]c1ccccc1
370
39512/2/2021171
Long
jo010452+
C-O Activation
x10.1021/jo010452+2001
NA
11.5E-NuOP(O)(OEt)2
ArylZnX
Hetdppe
#N/A#N/A25K3PO4benzenebenzeneP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
StrongOO-PO(OR')2ZnCsp2_arCsp2_arCsp2_ar-OCsp2_ar-ZnAryl-O[Aryl]-O-PO(OR')2Het-ZnX[Het]-ZnXNon-Polar2.27Ionic-PO4K+HardOPO-EDG
JOURNAL OF ORGANIC CHEMISTRY
_0.0423.072.244780372.9696246982.6072025343.5700586912.37#REF!XX0#REF!#REF!XOP(OCC)(OCC)=O[Zn]ClC1=CC=CC=C1C1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1c1ccc(cc1)P(CCP(c2ccccc2)c3ccccc3)c4ccccc4[O-]P(=O)([O-])[O-].[K+].[K+].[K+]c1ccccc1
371
39612/2/2021171
Long
jo010452+
C-O Activation
xx10.1021/jo010452+2001
NA
11.5E-NuOP(O)(OEt)2
ArylZnX
Aryldppe
#N/A#N/A25K3PO4benzenebenzeneP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
StrongOO-PO(OR')2ZnCsp2_arCsp2_arCsp2_ar-OCsp2_ar-ZnAryl-O[Aryl]-O-PO(OR')2Aryl-ZnX[Aryl]-ZnXNon-Polar2.27Ionic-PO4K+HardOPO-EDG
JOURNAL OF ORGANIC CHEMISTRY
_0.0423.072.244780372.9696246982.6072025343.5700586912.37#REF!XX0#REF!#REF!XOP(OCC)(OCC)=O[Zn]ClC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1c1ccc(cc1)P(CCP(c2ccccc2)c3ccccc3)c4ccccc4[O-]P(=O)([O-])[O-].[K+].[K+].[K+]c1ccccc1
372
39712/3/2021144
Gerry
adsc.200404150
C-O Activation
x10.1002/adsc.2004041502004
11.5E-NuOTs
VinylB(OH)2
ArylPCy3
#N/A#N/A25K3PO4THFPPhosphine (Monodentate)PhosphineCsp2-Csp2_arWeakOO-SO2-R'BCsp2Csp2_arCsp2-OCsp2_ar-BVinyl-O[Vinyl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2#N/A#N/AIonic-PO4K+EasyOSO2-EDG
ADVANCED SYNTHESIS & CATALYSIS
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(=O)(C1=CC=C(C)C=C1)B(O)OC=CC1=CC=CC=C1C=CC1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1CCOC1
373
39812/3/2021144
Gerry
adsc.200404150
C-O Activation
x10.1002/adsc.2004041502004
11.5E-NuOTs
VinylB(OH)2
ArylPCy3
#N/A#N/A25K3PO4THFPPhosphine (Monodentate)PhosphineCsp2-Csp2_arWeakOO-SO2-R'BCsp2Csp2_arCsp2-OCsp2_ar-BVinyl-O[Vinyl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2#N/A#N/AIonic-PO4K+EasyOSO2-EDG
ADVANCED SYNTHESIS & CATALYSIS
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(=O)(C1=CC=C(C)C=C1)B(O)OC=CC1=CC=CC=C1C=CC1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1CCOC1
374
39912/10/2021172
Long
ol801972f
C-O Activation
x10.1021/ol801972f2008
NA11.2E-NuOTs
ArylB(nep)
ArylPCy3
#N/A#N/A25K3PO4THFTHFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(nep)[Aryl]-B(nep)Polar7.58Ionic-PO4K+EasyOSO2-EDG
ORGANIC LETTERS
TM0.362.244780372.9696246982.6072025343.5700586912.37#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OS(=O)(=O)(C1=CC=C(C)C=C1)B1OCC(C)(CO1)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1CCOC1
375
40012/10/2021172
Long
ol801972f
C-O Activation
x10.1021/ol801972f2008
NA11.2E-NuOMs
ArylB(nep)
ArylPCy3
#N/A#N/A25K3PO4THFTHFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(nep)[Aryl]-B(nep)Polar7.58Ionic-PO4K+EasyOSO2-EDG
ORGANIC LETTERS
TM0.362.244780372.9696246982.6072025343.5700586912.37#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OS(=O)(=O)CB1OCC(C)(CO1)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1CCOC1
376
22211/9/2021236
Kelly
anie.200907287
C-O Activation
x10.1002/anie.2009072872010
11.2E-NuOPiv
ArylH
MorpholineIPr.HCl
#N/A#N/A80NaOtButoluenetolueneNHCCarbeneCarbeneCsp2_ar-Nsp3MediumOO-CO-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-CO-R'Morpholine-H[Morpholine]-HNon-Polar2.38Ionic-OtBuNa+
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.3320.282.8589353663.2821934583.0705644124.0077900319#REF!9.5921.261.706749553.2392069642.4729782574.96639928#REF!#REF!OC(=O)C(C)(C)CHC1=CC=CC=C1N1CCCCC1C1=CC=CC=C1C1CCCCC1NCC(C)c1cccc(C(C)C)c1N2C=[N+](C=C2)c3c(C(C)C)cccc3C(C)C.[Cl-][Na]OC(C)(C)CCc1ccccc1
377
35011/25/2021192
Shihong
ol301847m
C-O Activation
x10.1021/ol301847m2012
11.2E-NuOPiv
ArylH
MorpholineSIPr.HCl
#N/A#N/A80NaOtBudioxanedioxaneNHCCarbeneCarbeneCsp2_ar-Nsp3MediumOO-CO-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-CO-R'Morpholine-H[Morpholine]-HPolar2.25Ionic-OtBuNa+MediumOCO-EDG
ORGANIC LETTERS
_0.3320.282.8589353663.2821934583.0705644124.0077900319#REF!9.5921.261.706749553.2392069642.4729782574.96639928#REF!#REF!OC(=O)C(C)(C)CHC1=CC=CC=C1N1CCCCC1C1=CC=CC=C1C1CCCCC1NCC(c1c(N2C=[N+](c3c(C(C)C)cccc3C(C)C)CC2)c(C(C)C)ccc1)C.[Cl-][Na]OC(C)(C)CC1COCCO1
378
40312/10/2021146
Long
c4cc08426h
C-O Activation
xx10.1039/c4cc08426h2015
21E-NuOCONMe2
ArylH
Allyldcypt
#N/A#N/A150K3PO4toluenetolueneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp3MediumOO-CO-R'HCsp2_arCsp3Csp2_ar-OCsp3-HAryl-O[Aryl]-O-CO-R'Allyl-H[Allyl]-HNon-Polar2.38Ionic-PO4K+MediumOCO-EDG
CHEMICAL COMMUNICATIONS
_0.3117.732.244780372.9696246982.6072025343.5700586912.37#REF!4.2301.706749553.2392069642.4729782574.96639928#REF!#REF!123.3OC(=O)N(C)CHC1=CC=CC=C1CC=CC1=CC=CC=C1C=CCC1(P(C2CCCCC2)C3CCCCC3)=CSC=C1P(C4CCCCC4)C5CCCCC5[O-]P(=O)([O-])[O-].[K+].[K+].[K+]Cc1ccccc1
379
40412/10/2021146
Long
c4cc08426h
C-O Activation
xx10.1039/c4cc08426h2015
1.51E-NuOCONMe2
ArylH
Alkyldcypt
#N/A#N/A150K3PO4toluenetolueneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp3MediumOO-CO-R'HCsp2_arCsp3Csp2_ar-OCsp3-HAryl-O[Aryl]-O-CO-R'Alkyl-H[Alkyl]-HNon-Polar2.38Ionic-PO4K+MediumOCO-EDG
CHEMICAL COMMUNICATIONS
_0.3117.732.244780372.9696246982.6072025343.5700586912.37#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5OC(=O)N(C)CHC1=CC=CC=C1CCC1=CC=CC=C1CCC1(P(C2CCCCC2)C3CCCCC3)=CSC=C1P(C4CCCCC4)C5CCCCC5[O-]P(=O)([O-])[O-].[K+].[K+].[K+]Cc1ccccc1
380
40512/10/202193
Long
ol9028308
C-O Activation
xx10.1021/ol90283082010
12E-NuOSO2OPh
ArylMgX
ArylPCy3
#N/A#N/ArtEt2OEt2OPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'MgCsp2_arCsp2_arCsp2_ar-OCsp2_ar-MgAryl-O[Aryl]-O-SO2-R'Aryl-MgX[Aryl]-MgXNon-Polar4.33No baseNo BaseNo base#N/A#N/A
ORGANIC LETTERS
_0.7#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2OS(=O)(=O)O(C1=CC=CC=C1)[Mg]ClC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/ACCOCC
381
40612/15/2021384
Elaine
ja9053509
C-H Activation
x10.1021/ja90535092009
11.5E-NuZn(Ph)
HetH
ArylPCy3
#N/A#N/A80toluenetoluenePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
ZnHCsp2_arCsp2_arCsp2_ar-ZnCsp2_ar-HHet-Zn[Het]-Aryl-H[Aryl]-HNon-Polar2.38No baseNo BaseNo base#N/A#N/A
J AM CHEM SOC
_#N/A#N/A#N/A#N/A#N/A#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5[Zn]C1=CC=CC=C1HC1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/ACc1ccccc1
382
40712/15/2021384
Elaine
ja9053509
C-H Activation
x10.1021/ja90535092009
11.5E-NuZn(Ph)
HetH
ArylPCy3
#N/A#N/A60toluenetoluenePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
ZnHCsp2_arCsp2_arCsp2_ar-ZnCsp2_ar-HHet-Zn[Het]-Aryl-H[Aryl]-HNon-Polar2.38No baseNo BaseNo base#N/A#N/A
J AM CHEM SOC
_#N/A#N/A#N/A#N/A#N/A#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5[Zn]C1=CC=CC=C1HC1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/ACc1ccccc1
383
40812/15/2021384
Elaine
ja9053509
C-H Activation
x10.1021/ja90535092009
13E-NuZn(Et)
HetH
ArylPCy3
#N/A#N/A130toluenetoluenePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
ZnHCsp2_arCsp2_arCsp2_ar-ZnCsp2_ar-HHet-Zn[Het]-Aryl-H[Aryl]-HNon-Polar2.38No baseNo BaseNo base#N/A#N/A
J AM CHEM SOC
_#N/A#N/A#N/A#N/A#N/A#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5[Zn]CCHC1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/ACc1ccccc1
384
41012/15/2021376
Elaine
anie.201309584
C-H Activation
x10.1002/anie.2013095842014
12E-NuBr
ArylH
AlkylBDMAE
#N/A#N/A160LiOtButoluenetolueneN-N-NPy-N-PyNitrogenCsp2_ar-Csp3XHCsp2_arCsp3Csp2_ar-XCsp3-HAryl-X[Aryl]-Alkyl-H[Alkyl]-HNon-Polar2.38Ionic-OtBuLi+
ANGEW CHEM INT EDIT
_2.8589353663.2821934583.0705644124.0077900319#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5BrHC1=CC=CC=C1CCC1=CC=CC=C1CCCc1cc(C)n(CN(CC)Cn2c(C)cc(C)n2)n1CC(C)(C)[O-].[Li+]Cc1ccccc1
385
41112/15/2021376
Elaine
anie.201309584
C-H Activation
x10.1002/anie.2013095842014
12E-NuCl
ArylH
AlkylBDMAE
#N/A#N/A160LiOtButoluenetolueneN-N-NPy-N-PyNitrogenCsp2_ar-Csp3XHCsp2_arCsp3Csp2_ar-XCsp3-HAryl-X[Aryl]-Alkyl-H[Alkyl]-HNon-Polar2.38Ionic-OtBuLi+
ANGEW CHEM INT EDIT
_2.8589353663.2821934583.0705644124.0077900319#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5ClHC1=CC=CC=C1CCC1=CC=CC=C1CCCc1cc(C)n(CN(CC)Cn2c(C)cc(C)n2)n1CC(C)(C)[O-].[Li+]Cc1ccccc1
386
41212/15/2021376
Elaine
anie.201309584
C-H Activation
x10.1002/anie.2013095842014
12E-NuBr
HetH
AlkylBDMAE
#N/A#N/A160LiOtButoluenetolueneN-N-NPy-N-PyNitrogenCsp2_ar-Csp3XHCsp2_arCsp3Csp2_ar-XCsp3-HHet-X[Het]-Alkyl-H[Alkyl]-HNon-Polar2.38Ionic-OtBuLi+
ANGEW CHEM INT EDIT
_2.8589353663.2821934583.0705644124.0077900319#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5BrHC1=NC=CC=C1CCC1=CC=NC=C1CCCc1cc(C)n(CN(CC)Cn2c(C)cc(C)n2)n1CC(C)(C)[O-].[Li+]Cc1ccccc1
387
41312/15/2021376
Elaine
anie.201309584
C-H Activation
x10.1002/anie.2013095842014
12E-NuI
ArylH
AlkylBDMAE
#N/A#N/A160LiOtButoluenetolueneN-N-NPy-N-PyNitrogenCsp2_ar-Csp3XHCsp2_arCsp3Csp2_ar-XCsp3-HAryl-X[Aryl]-Alkyl-H[Alkyl]-HNon-Polar2.38Ionic-OtBuLi+
ANGEW CHEM INT EDIT
_2.8589353663.2821934583.0705644124.0077900319#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5IHC1=CC=CC=C1CCC1=CC=CC=C1CCCc1cc(C)n(CN(CC)Cn2c(C)cc(C)n2)n1CC(C)(C)[O-].[Li+]Cc1ccccc1
388
41412/15/2021382
Elaine
anie.201300459
C-H Activation
x10.1002/anie.2013004592013
16Nu-NuB(OH)2
AlkylH
ArylPPh3
#N/A#N/A100K3PO4DTBPDTBPPPhosphine (Monodentate)PhosphineCsp3-Csp2_arNu-MBHCsp3Csp2_arCsp3-BCsp2_ar-HAlkyl-B[Alkyl]-Aryl-H[Aryl]-H#N/A#N/AIonic-PO4K+
ANGEW CHEM INT EDIT
_2.244780372.9696246982.6072025343.5700586912.37#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5B(O)OHCCC1=CC=CC=C1CCC1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]O(OC(C)(C)C)C(C)(C)C
389
41512/15/2021382
Elaine
anie.201300459
C-H Activation
x10.1002/anie.2013004592013
16Nu-NuB(OH)2
AlkylH
ArylPPh3
#N/A#N/A100K3PO4DTBPDTBPPPhosphine (Monodentate)PhosphineCsp3-Csp2_arNu-MBHCsp3Csp2_arCsp3-BCsp2_ar-HAlkyl-B[Alkyl]-Aryl-H[Aryl]-H#N/A#N/AIonic-PO4K+
ANGEW CHEM INT EDIT
_2.244780372.9696246982.6072025343.5700586912.37#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5B(O)OHCCC1=CC=CC=C1CCC1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]O(OC(C)(C)C)C(C)(C)C
390
41612/15/2021382
Elaine
anie.201300459
C-H Activation
x10.1002/anie.2013004592013
14Nu-NuB(OH)2
AlkylH
ArylPPh3
#N/A#N/A100K3PO4DTBPDTBPPPhosphine (Monodentate)PhosphineCsp3-Csp2_arNu-MBHCsp3Csp2_arCsp3-BCsp2_ar-HAlkyl-B[Alkyl]-Aryl-H[Aryl]-H#N/A#N/AIonic-PO4K+
ANGEW CHEM INT EDIT
_2.244780372.9696246982.6072025343.5700586912.37#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5B(O)OHCCC1=CC=CC=C1CCC1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]O(OC(C)(C)C)C(C)(C)C
391
41712/15/2021382
Elaine
anie.201300459
C-H Activation
x10.1002/anie.2013004592013
16Nu-NuB(OH)2
AlkylH
ArylPPh3
#N/A#N/A100K3PO4DTBPDTBPPPhosphine (Monodentate)PhosphineCsp3-Csp2_arNu-MBHCsp3Csp2_arCsp3-BCsp2_ar-HAlkyl-B[Alkyl]-Aryl-H[Aryl]-H#N/A#N/AIonic-PO4K+
ANGEW CHEM INT EDIT
_2.244780372.9696246982.6072025343.5700586912.37#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5B(O)OHCCC1=CC=CC=C1CCC1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]O(OC(C)(C)C)C(C)(C)C
392
41812/15/2021341
Elaine
anie.200454166
C-H Activation
x10.1002/anie.2004541662004
15Nu-NuH
HetH
VinylPPh3
#N/A#N/A55acetoneTHFacetonePPhosphine (Monodentate)PhosphineCsp2_ar-Csp2Nu-HHHCsp2_arCsp2Csp2_ar-HCsp2-HHet-H[Het]-Vinyl-H[Vinyl]-HPolar20.7No baseNo BaseNo base
ANGEW CHEM INT EDIT
_#N/A#N/A#N/A#N/A#N/A#REF!6.0701.706749553.2392069642.4729782574.96639928#REF!#REF!115.6HHC1=NC=CC=C1C=CC1=CC=NC=C1C=CP(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3#N/ACC(=O)C
393
41912/15/2021341
Elaine
anie.200454166
C-H Activation
x10.1002/anie.2004541662004
15Nu-NuH
HetH
VinylPPh3
#N/A#N/A55acetoneTHFacetonePPhosphine (Monodentate)PhosphineCsp2_ar-Csp2Nu-HHHCsp2_arCsp2Csp2_ar-HCsp2-HHet-H[Het]-Vinyl-H[Vinyl]-HPolar20.7No baseNo BaseNo base
ANGEW CHEM INT EDIT
_#N/A#N/A#N/A#N/A#N/A#REF!6.0701.706749553.2392069642.4729782574.96639928#REF!#REF!115.6HHC1=NC=CC=C1C=CC1=CC=NC=C1C=CP(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3#N/ACC(=O)C
394
42012/15/202164
Elaine
acscatal.8b04267
C-H Activation
x10.1021/acscatal.8b042672019
12E-NuBr
HetH
Vinylbpy
#N/A#N/A120LiOtBudioxanedioxaneN-NbpyNitrogenCsp2_ar-Csp2XHCsp2_arCsp2Csp2_ar-XCsp2-HHet-X[Het]-Vinyl-H[Vinyl]-HPolar2.25Ionic-OtBuLi+
ACS CATAL
_2.8589353663.2821934583.0705644124.0077900319#REF!6.0701.706749553.2392069642.4729782574.96639928#REF!#REF!115.6BrHC1=NC=CC=C1C=CC1=CC=NC=C1C=CC1(C2=NC=CC=C2)=CC=CC=N1CC(C)(C)[O-].[Li+]C1COCCO1
395
42112/15/202164
Elaine
acscatal.8b04267
C-H Activation
x10.1021/acscatal.8b042672019
12E-NuBr
HetH
Vinylbpy
#N/A#N/A120LiOtBudioxanedioxaneN-NbpyNitrogenCsp2_ar-Csp2XHCsp2_arCsp2Csp2_ar-XCsp2-HHet-X[Het]-Vinyl-H[Vinyl]-HPolar2.25Ionic-OtBuLi+
ACS CATAL
_2.8589353663.2821934583.0705644124.0077900319#REF!6.0701.706749553.2392069642.4729782574.96639928#REF!#REF!115.6BrHC1=NC=CC=C1C=CC1=CC=NC=C1C=CC1(C2=NC=CC=C2)=CC=CC=N1CC(C)(C)[O-].[Li+]C1COCCO1
396
42212/15/202164
Elaine
acscatal.8b04267
C-H Activation
x10.1021/acscatal.8b042672019
12E-NuBr
HetH
Vinylbpy
#N/A#N/A120LiOtBudioxanedioxaneN-NbpyNitrogenCsp2_ar-Csp2XHCsp2_arCsp2Csp2_ar-XCsp2-HHet-X[Het]-Vinyl-H[Vinyl]-HPolar2.25Ionic-OtBuLi+
ACS CATAL
_2.8589353663.2821934583.0705644124.0077900319#REF!6.0701.706749553.2392069642.4729782574.96639928#REF!#REF!115.6BrHC1=NC=CC=C1C=CC1=CC=NC=C1C=CC1(C2=NC=CC=C2)=CC=CC=N1CC(C)(C)[O-].[Li+]C1COCCO1
397
42312/15/202164
Elaine
acscatal.8b04267
C-H Activation
x10.1021/acscatal.8b042672019
12E-NuBr
HetH
Vinylbpy
#N/A#N/A120LiOtBudioxanedioxaneN-NbpyNitrogenCsp2_ar-Csp2XHCsp2_arCsp2Csp2_ar-XCsp2-HHet-X[Het]-Vinyl-H[Vinyl]-HPolar2.25Ionic-OtBuLi+
ACS CATAL
_2.8589353663.2821934583.0705644124.0077900319#REF!6.0701.706749553.2392069642.4729782574.96639928#REF!#REF!115.6BrHC1=NC=CC=C1C=CC1=CC=NC=C1C=CC1(C2=NC=CC=C2)=CC=CC=N1CC(C)(C)[O-].[Li+]C1COCCO1
398
42512/15/2021378
Elaine
anie.200906996
C-H Activation
x10.1002/anie.2009069962010
12E-Nu(OMe)3-Si
HetH
Arylbpy
#N/A#N/A150CsFDMADMAN-NbpyNitrogen
Csp2_ar-Csp2_ar
SiHCsp2_arCsp2_arCsp2_ar-SiCsp2_ar-HHet-Si[Het]-Aryl-H[Aryl]-HPolar37.8Ionic-FCs+#N/A#N/A
ANGEW CHEM INT EDIT
_03.14#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5[Si](OC)(OC)OCHC1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1C1=CC=CC=C1C1(C2=NC=CC=C2)=CC=CC=N1[Cs]FCN(C)C(C)=O
399
42612/15/2021378
Elaine
anie.200906996
C-H Activation
x10.1002/anie.2009069962010
12E-Nu(OEt)3-Si
HetH
Arylbpy
#N/A#N/A150CsFDMADMAN-NbpyNitrogen
Csp2_ar-Csp2_ar
SiHCsp2_arCsp2_arCsp2_ar-SiCsp2_ar-HHet-Si[Het]-Aryl-H[Aryl]-HPolar37.8Ionic-FCs+#N/A#N/A
ANGEW CHEM INT EDIT
_03.14#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5[Si](OCC)(OCC)OCCHC1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1C1=CC=CC=C1C1(C2=NC=CC=C2)=CC=CC=N1[Cs]FCN(C)C(C)=O
400
42712/15/2021378
Elaine
anie.200906996
C-H Activation
x10.1002/anie.2009069962010
12E-Nu(OMe)3-Si
HetH
Arylbpy
#N/A#N/A150CsFDMADMAN-NbpyNitrogen
Csp2_ar-Csp2_ar
SiHCsp2_arCsp2_arCsp2_ar-SiCsp2_ar-HHet-Si[Het]-Aryl-H[Aryl]-HPolar37.8Ionic-FCs+#N/A#N/A
ANGEW CHEM INT EDIT
_03.14#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5[Si](OC)(OC)OCHC1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1C1=CC=CC=C1C1(C2=NC=CC=C2)=CC=CC=N1[Cs]FCN(C)C(C)=O
401
42812/15/2021112
Kelly
c3cc46663a
C-O Activation
x10.1039/c3cc46663a2013
NA
E-NuOPiv
ArylB(OH)2
ArylPCy3
#N/A#N/A120K3PO4toluenetoluenePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
MediumOO-CO-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-CO-R'Aryl-B(OH)2[Aryl]-B(OH)2Non-Polar2.38Ionic-PO4K+MediumOCO-EDG
CHEMICAL COMMUNICATIONS
_0.3320.282.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OC(=O)C(C)(C)CB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]Cc1ccccc1
402
33711/22/2021221
Gerry
jo7022558
C-O Activation
x10.1021/jo70225582008
11.5E-NuOTs
ArylH
MorpholineIPr
#N/A#N/A110NaOtBudioxanedioxaneNHCCarbeneCarbeneCsp2_ar-Nsp3WeakOO-SO2-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-SO2-R'Morpholine-H[Morpholine]-HPolar2.25Ionic-OtBuNa+EasyOSO2-EDG
JOURNAL OF ORGANIC CHEMISTRY
_0.362.8589353663.2821934583.0705644124.0077900319#REF!9.5921.261.706749553.2392069642.4729782574.96639928#REF!#REF!OS(=O)(=O)(C1=CC=C(C)C=C1)HC1=CC=CC=C1N1CCCCC1C1=CC=CC=C1C1CCCCC1NCC(C)C(C=CC=C1C(C)C)=C1N2C=CN(C3=C(C(C)C)C=CC=C3C(C)C)C2[Na]OC(C)(C)CC1COCCO1
403
33811/22/2021221
Gerry
jo7022558
C-O Activation
x10.1021/jo70225582008
11.5E-NuOTs
ArylH
N(H)ArylPPh3
#N/A#N/A110NaOtBudioxanedioxanePPhosphine (Monodentate)PhosphineCsp2_ar-Nsp3WeakOO-SO2-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-SO2-R'N(H)Aryl-H[N(H)Aryl]-HPolar2.25Ionic-OtBuNa+EasyOSO2-EDG
JOURNAL OF ORGANIC CHEMISTRY
_0.362.8589353663.2821934583.0705644124.0077900319#REF!11.526.021.706749553.2392069642.4729782574.96639928#REF!#REF!OS(=O)(=O)(C1=CC=C(C)C=C1)HC1=CC=CC=C1NC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1NP(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3[Na]OC(C)(C)CC1COCCO1
404
33911/22/2021214
Gerry
anie.201007325
C-O Activation
x10.1002/anie.2010073252011
11.2E-NuOSO2NMe2
ArylH
MorpholineSIPr
#N/A#N/A80NaOtBudioxanedioxaneNHCCarbeneCarbeneCsp2_ar-Nsp3WeakOO-SO2-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-SO2-R'Morpholine-H[Morpholine]-HPolar2.25Ionic-OtBuNa+MediumOSO2-EDG
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.362.8589353663.2821934583.0705644124.0077900319#REF!9.5921.261.706749553.2392069642.4729782574.96639928#REF!#REF!OS(=O)(N(C)C)=OHC1=CC=CC=C1N1CCCCC1C1=CC=CC=C1C1CCCCC1NCC(C)c1cccc(C(C)C)c1N2[C]N(CC2)c3c(cccc3C(C)C)C(C)C[Na]OC(C)(C)CC1COCCO1
405
43212/15/2021116
Kelly
ol201437g
C-O Activation
x10.1021/ol201437g2011
C-1: NiCl(1-naphthyl)(PPh3)2.11E-NuOPO(OPh)2
ArylH
MorpholineIPr·HCl
#N/A#N/A110NaHdioxanedioxane#N/A#N/A#N/ACsp2_ar-Nsp3StrongOO-PO(OR')2HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-PO(OR')2Morpholine-H[Morpholine]-HPolar2.25Ionic-HNa+#N/A#N/A
ORGANIC LETTERS
_0.0434.8035#REF!9.5921.261.706749553.2392069642.4729782574.96639928#REF!#REF!OP(OC1=CC=CC=C1)(OC2=CC=CC=C2)=OHC1=CC=CC=C1N1CCCCC1C1=CC=CC=C1C1CCCCC1N#N/A[Na]HC1COCCO1
406
43312/15/2021116
Kelly
ol201437g
C-O Activation
x10.1021/ol201437g2011
C-1: NiCl(1-naphthyl)(PPh3)2.11E-NuOPO(OPh)2
ArylH
MorpholineIPr·HCl
#N/A#N/A110NaHdioxanedioxane#N/A#N/A#N/ACsp2_ar-Nsp3StrongOO-PO(OR')2HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-PO(OR')2Morpholine-H[Morpholine]-HPolar2.25Ionic-HNa+#N/A#N/A
ORGANIC LETTERS
_0.0434.8035#REF!9.5921.261.706749553.2392069642.4729782574.96639928#REF!#REF!OP(OC1=CC=CC=C1)(OC2=CC=CC=C2)=OHC1=CC=CC=C1N1CCCCC1C1=CC=CC=C1C1CCCCC1N#N/A[Na]HC1COCCO1
407
43412/15/2021116
Kelly
ol201437g
C-O Activation
x10.1021/ol201437g2011
C-1: NiCl(1-naphthyl)(PPh3)2.11E-NuOPO(OPh)2
ArylH
N(Alkyl)AlkylIPr·HCl
#N/A#N/A110NaHdioxanedioxane#N/A#N/A#N/ACsp2_ar-Nsp3StrongOO-PO(OR')2HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-PO(OR')2N(Alkyl)Alkyl-H[N(Alkyl)Alkyl]-HPolar2.25Ionic-HNa+#N/A#N/A
ORGANIC LETTERS
_0.0434.8035#REF!9.6512.031.706749553.2392069642.4729782574.96639928#REF!#REF!OP(OC1=CC=CC=C1)(OC2=CC=CC=C2)=OHC1=CC=CC=C1N(C)CC1=CC=CC=C1C(C)N#N/A[Na]HC1COCCO1
408
43512/15/2021116
Kelly
ol201437g
C-O Activation
x10.1021/ol201437g2011
C-1: NiCl(1-naphthyl)(PPh3)2.11E-NuOPO(OPh)2
ArylH
N(H)AlkylIPr·HCl
#N/A#N/A110NaHdioxanedioxane#N/A#N/A#N/ACsp2_ar-Nsp3StrongOO-PO(OR')2HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-PO(OR')2N(H)Alkyl-H[N(H)Alkyl]-HPolar2.25Ionic-HNa+#N/A#N/A
ORGANIC LETTERS
_0.0434.8035#REF!5.6643.091.706749553.2392069642.4729782574.96639928#REF!#REF!OP(OC1=CC=CC=C1)(OC2=CC=CC=C2)=OHC1=CC=CC=C1NCC1=CC=CC=C1CN#N/A[Na]HC1COCCO1
409
43612/15/2021116
Kelly
ol201437g
C-O Activation
x10.1021/ol201437g2011
C-1: NiCl(1-naphthyl)(PPh3)2.11E-NuOPO(OPh)2
ArylH
N(Alkyl)AlkylIPr·HCl
#N/A#N/A110NaHdioxanedioxane#N/A#N/A#N/ACsp2_ar-Nsp3StrongOO-PO(OR')2HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-PO(OR')2N(Alkyl)Alkyl-H[N(Alkyl)Alkyl]-HPolar2.25Ionic-HNa+#N/A#N/A
ORGANIC LETTERS
_0.0434.8035#REF!9.6512.031.706749553.2392069642.4729782574.96639928#REF!#REF!OP(OC1=CC=CC=C1)(OC2=CC=CC=C2)=OHC1=CC=CC=C1N(C)CC1=CC=CC=C1C(C)N#N/A[Na]HC1COCCO1
410
43712/15/2021116
Kelly
ol201437g
C-O Activation
x10.1021/ol201437g2011
C-1: NiCl(1-naphthyl)(PPh3)2.11E-NuOP(O)(OEt)2
ArylH
MorpholineIPr·HCl
#N/A#N/A110NaHdioxanedioxane#N/A#N/A#N/ACsp2_ar-Nsp3StrongOO-PO(OR')2HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-PO(OR')2Morpholine-H[Morpholine]-HPolar2.25Ionic-HNa+HardOPO-EDG
ORGANIC LETTERS
_0.0423.07035#REF!9.5921.261.706749553.2392069642.4729782574.96639928#REF!#REF!OP(OCC)(OCC)=OHC1=CC=CC=C1N1CCCCC1C1=CC=CC=C1C1CCCCC1N#N/A[Na]HC1COCCO1
411
43812/15/2021197
Long
ol401727y
C-O Activation
x10.1021/ol401727y2013
E-NuOSO2NMe2
ArylB(OH)2
ArylPCy3
#N/A#N/A100-120K3PO42-Me-THF2-Me-THFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar7.53Ionic-PO4K+MediumOSO2-EDG
ORGANIC LETTERS
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(N(C)C)=OB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]O1C(C)CCC1
412
43912/15/2021197
Long
ol401727y
C-O Activation
x10.1021/ol401727y2013
E-NuOSO2NMe2
ArylB(OH)2
ArylPCy3
#N/A#N/A100-120K3PO42-Me-THF2-Me-THFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar7.53Ionic-PO4K+MediumOSO2-EDG
ORGANIC LETTERS
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(N(C)C)=OB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]O1C(C)CCC1
413
44012/15/2021197
Long
ol401727y
C-O Activation
x10.1021/ol401727y2013
E-NuOPiv
ArylB(OH)2
ArylPCy3
#N/A#N/A100-120K3PO42-Me-THF2-Me-THFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
MediumOO-CO-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-CO-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar7.53Ionic-PO4K+MediumOCO-EDG
ORGANIC LETTERS
_0.3320.282.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OC(=O)C(C)(C)CB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]O1C(C)CCC1
414
44112/15/2021197
Long
ol401727y
C-O Activation
x10.1021/ol401727y2013
E-NuOMs
ArylB(OH)2
ArylPCy3
#N/A#N/A100-120K3PO42-iodobutane2-iodobutanePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2Non-Polar6.35Ionic-PO4K+EasyOSO2-EDG
ORGANIC LETTERS
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(=O)CB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]CCC(C)I
415
44212/15/2021197
Long
ol401727y
C-O Activation
x10.1021/ol401727y2013
E-NuOTs
ArylB(OH)2
ArylPCy3
#N/A#N/A100-120K3PO42-Me-THF2-Me-THFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar7.53Ionic-PO4K+EasyOSO2-EDG
ORGANIC LETTERS
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(=O)(C1=CC=C(C)C=C1)B(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]O1C(C)CCC1
416
44312/15/2021197
Long
ol401727y
C-O Activation
x10.1021/ol401727y2013
E-NuOTf
ArylB(OH)2
ArylPCy3
#N/A#N/A100-120K3PO42-Me-THF2-Me-THFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar7.53Ionic-PO4K+EasyOSO2-EWG
ORGANIC LETTERS
_0.532.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(=O)C(F)(F)FB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]O1C(C)CCC1
417
44412/15/2021197
Long
ol401727y
C-O Activation
x10.1021/ol401727y2013
E-NuOSO2NMe2
ArylB(OH)2
ArylPCy3
#N/A#N/A100-120K3PO4tert-Amyl alcohol tert-Amyl alcohol PPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2#N/A#N/AIonic-PO4K+MediumOSO2-EDG
ORGANIC LETTERS
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(N(C)C)=OB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]CCC(C)(C)O
418
44512/15/2021197
Long
ol401727y
C-O Activation
x10.1021/ol401727y2013
E-NuOPiv
ArylB(OH)2
ArylPCy3
#N/A#N/A100-120K3PO4tert-Amyl alcohol tert-Amyl alcohol PPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
MediumOO-CO-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-CO-R'Aryl-B(OH)2[Aryl]-B(OH)2#N/A#N/AIonic-PO4K+MediumOCO-EDG
ORGANIC LETTERS
_0.3320.282.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OC(=O)C(C)(C)CB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]CCC(C)(C)O
419
44612/15/2021197
Long
ol401727y
C-O Activation
x10.1021/ol401727y2013
E-NuOMs
ArylB(OH)2
ArylPCy3
#N/A#N/A100-120K3PO4tert-Amyl alcohol tert-Amyl alcohol PPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2#N/A#N/AIonic-PO4K+EasyOSO2-EDG
ORGANIC LETTERS
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(=O)CB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]CCC(C)(C)O
420
44712/15/2021197
Long
ol401727y
C-O Activation
x10.1021/ol401727y2013
E-NuOTs
ArylB(OH)2
ArylPCy3
#N/A#N/A100-120K3PO4tert-Amyl alcohol
tert-Amyl alcohol
PPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2#N/A#N/AIonic-PO4K+EasyOSO2-EDG
ORGANIC LETTERS
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(=O)(C1=CC=C(C)C=C1)B(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]CCC(C)(C)O
421
44812/15/2021197
Long
ol401727y
C-O Activation
x10.1021/ol401727y2013
E-NuOTf
ArylB(OH)2
ArylPCy3
#N/A#N/A100-120K3PO4tert-Amyl alcohol tert-Amyl alcohol PPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2#N/A#N/AIonic-PO4K+EasyOSO2-EWG
ORGANIC LETTERS
_0.532.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(=O)C(F)(F)FB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]CCC(C)(C)O
422
44912/15/2021197
Long
ol401727y
C-O Activation
x10.1021/ol401727y2013
E-NuOCONEt2
HetB(OH)2
ArylPCy3
#N/A#N/A100-120K3PO42-Me-THF2-Me-THFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
MediumOO-CO-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BHet-O[Het]-O-CO-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar7.53Ionic-PO4K+MediumOCO-EDG
ORGANIC LETTERS
_0.3121.412.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OC(N(CC)CC)=OB(O)OC1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]O1C(C)CCC1
423
45012/15/2021197
Long
ol401727y
C-O Activation
x10.1021/ol401727y2013
E-NuOSO2NMe2
HetB(OH)2
ArylPCy3
#N/A#N/A100-120K3PO42-Me-THF2-Me-THFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BHet-O[Het]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar7.53Ionic-PO4K+MediumOSO2-EDG
ORGANIC LETTERS
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(N(C)C)=OB(O)OC1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]O1C(C)CCC1
424
45112/15/2021197
Long
ol401727y
C-O Activation
x10.1021/ol401727y2013
E-NuOPiv
HetB(OH)2
ArylPCy3
#N/A#N/A100-120K3PO42-Me-THF2-Me-THFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
MediumOO-CO-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BHet-O[Het]-O-CO-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar7.53Ionic-PO4K+MediumOCO-EDG
ORGANIC LETTERS
_0.3320.282.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OC(=O)C(C)(C)CB(O)OC1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]O1C(C)CCC1
425
45212/15/2021197
Long
ol401727y
C-O Activation
x10.1021/ol401727y2013
E-NuOPiv
HetB(OH)2
ArylPCy3
#N/A#N/A100-120K3PO4tert-Amyl alcohol 2-Me-THFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
MediumOO-CO-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BHet-O[Het]-O-CO-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar7.53Ionic-PO4K+MediumOCO-EDG
ORGANIC LETTERS
_0.3320.282.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OC(=O)C(C)(C)CB(O)OC1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]CCC(C)(C)O
426
45312/15/2021197
Long
ol401727y
C-O Activation
x10.1021/ol401727y2013
E-NuOMs
ArylB(OH)2
HetPCy3
#N/A#N/A100-120K3PO42-Me-THF2-Me-THFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Het-B(OH)2[Het]-B(OH)2Polar7.53Ionic-PO4K+EasyOSO2-EDG
ORGANIC LETTERS
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!12.6451.351.923.2525052362.5862526186.55955503#REF!#REF!150OS(=O)(=O)CB(O)OC1=CC=CC=C1C1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]O1C(C)CCC1
427
45412/15/2021197
Long
ol401727y
C-O Activation
x10.1021/ol401727y2013
E-NuOSO2NMe2
ArylB(OH)2
HetPCy3
#N/A#N/A100-120K3PO42-Me-THF2-Me-THFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Het-B(OH)2[Het]-B(OH)2Polar7.53Ionic-PO4K+MediumOSO2-EDG
ORGANIC LETTERS
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!12.6451.351.923.2525052362.5862526186.55955503#REF!#REF!150OS(=O)(N(C)C)=OB(O)OC1=CC=CC=C1C1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]O1C(C)CCC1
428
45512/15/2021163
Long
jo070912k
C-O Activation
x10.1021/jo070912k2007
NAE-NuOPO(OPh)2
VinylB(OH)2
ArylPCy3
#N/A#N/A75K3PO4THFTHFPPhosphine (Monodentate)PhosphineCsp2-Csp2_arStrongOO-PO(OR')2BCsp2Csp2_arCsp2-OCsp2_ar-BVinyl-O[Vinyl]-O-PO(OR')2Aryl-B(OH)2[Aryl]-B(OH)2Polar7.58Ionic-PO4K+#N/A#N/A
JOURNAL OF ORGANIC CHEMISTRY
_0.0428.682.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OP(OC1=CC=CC=C1)(OC2=CC=CC=C2)=OB(O)OC=CC1=CC=CC=C1C=CC1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1CCOC1
429
45612/15/2021157
Long
jo202037x
C-O Activation
x10.1021/jo202037x2011
11E-NuOMs
ArylB(nep)
ArylPCy3
#N/A#N/A25K3PO4THFTHFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(nep)[Aryl]-B(nep)Polar7.58Ionic-PO4K+EasyOSO2-EDG
JOURNAL OF ORGANIC CHEMISTRY
TM0.362.244780372.9696246982.6072025343.5700586912.37#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OS(=O)(=O)CB1OCC(C)(CO1)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1CCOC1
430
45712/15/2021147
Long
jo300547v
C-O Activation
x10.1021/jo300547v2012
11E-NuOMs
ArylB(OH)2
ArylPCy3
#N/A#N/A23K3PO4THFTHFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar7.58Ionic-PO4K+EasyOSO2-EDG
JOURNAL OF ORGANIC CHEMISTRY
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(=O)CB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1CCOC1
431
45812/15/2021147
Long
jo300547v
C-O Activation
x10.1021/jo300547v2012
11E-NuOMs
ArylB(OH)2
ArylPCy3
#N/A#N/A40K3PO4t-BuOH/H2Ot-BuOH/H2OPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2#N/A#N/AIonic-PO4K+EasyOSO2-EDG
JOURNAL OF ORGANIC CHEMISTRY
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(=O)CB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]#N/A
432
45912/15/2021131
Long
s0040-4039(99)00517-1
C-O Activation
x10.1016/s0040-4039(99)00517-11999
citation 10a show the ligand, which is NI(dppf)E-NuOPO(OPh)2
ArylB(OH)2
Aryldppf
#N/A#N/A90K3PO4toluenetolueneP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
StrongOO-PO(OR')2BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-PO(OR')2Aryl-B(OH)2[Aryl]-B(OH)2Non-Polar2.38Ionic-PO4K+#N/A#N/A
TETRAHEDRON LETTERS
_0.0434.82.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OP(OC1=CC=CC=C1)(OC2=CC=CC=C2)=OB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1c1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1[O-]P(=O)([O-])[O-].[K+].[K+].[K+]Cc1ccccc1
433
46012/15/2021121
Long
ejoc.201001519
C-O Activation
x10.1002/ejoc.2010015192011
C1 is NiCl2(PPh3)2E-NuOTs
ArylB(OH)2
ArylPPh3
#N/A#N/ArtK2CO3toluenetoluenePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2Non-Polar2.38Ionic-CO3K+EasyOSO2-EDG
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
_0.361.72.530430542.115215273.4538974810.33#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(=O)(C1=CC=C(C)C=C1)B(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3O=C([O-])[O-].[K+].[K+]Cc1ccccc1
434
46112/15/2021110
Long
b609064h
C-O Activation
x10.1039/b609064h2006
NAE-NuOPO(OPh)2
VinylB(OH)2
ArylPCy3
#N/A#N/A65K3PO4THFTHFPPhosphine (Monodentate)PhosphineCsp2-Csp2_arStrongOO-PO(OR')2BCsp2Csp2_arCsp2-OCsp2_ar-BVinyl-O[Vinyl]-O-PO(OR')2Aryl-B(OH)2[Aryl]-B(OH)2Polar7.58Ionic-PO4K+#N/A#N/A
CHEMICAL COMMUNICATIONS
TM0.0428.682.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OP(OC1=CC=CC=C1)(OC2=CC=CC=C2)=OB(O)OC=CC1=CC=CC=C1C=CC1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1CCOC1
435
46212/15/2021111
Long
adsc.201100151
C-O Activation
x10.1002/adsc.2011001512011
NAE-NuOTs
ArylB(OH)2
ArylPCy3
#N/A#N/ArtK3PO4THFH2OTHFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar7.58Ionic-PO4K+EasyOSO2-EDG
ADVANCED SYNTHESIS & CATALYSIS
TM0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(=O)(C1=CC=C(C)C=C1)B(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1CCOC1
436
46312/15/2021111
Long
adsc.201100151
C-O Activation
x10.1002/adsc.2011001512011
NAE-NuOMs
ArylB(OH)2
ArylPCy3
#N/A#N/ArtK3PO4THFH2OTHFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar7.58Ionic-PO4K+EasyOSO2-EDG
ADVANCED SYNTHESIS & CATALYSIS
TM0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(=O)CB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1CCOC1
437
46412/15/202185
Long
anie.201808560
C-O Activation
x10.1002/anie.2018085602018
11.2E-NuOMe
CarbonylH
N(Alkyl)AlkylIPr
#N/A#N/A140toluenetolueneNHCCarbeneCarbeneCsp2-Nsp3StrongOO-Csp3HCsp2Nsp3Csp2-ONsp3-HCarbonyl-O[Carbonyl]-O-Csp3N(Alkyl)Alkyl-H[N(Alkyl)Alkyl]-HNon-Polar2.38No baseNo BaseNo baseHardO-EDG
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.286.71#N/A#N/A#N/A#N/A#N/A#REF!9.6512.031.706749553.2392069642.4729782574.96639928#REF!#REF!OCHCC(=O)CN(C)CC(=O)CCC(C)NCC(C)C(C=CC=C1C(C)C)=C1N2C=CN(C3=C(C(C)C)C=CC=C3C(C)C)C2#N/ACc1ccccc1
438
46512/15/202185
Long
anie.201808560
C-O Activation
x10.1002/anie.2018085602018
11.2E-NuOMe
CarbonylH
N(H)AlkylIPr
#N/A#N/A140toluenetolueneNHCCarbeneCarbeneCsp2-Nsp3StrongOO-Csp3HCsp2Nsp3Csp2-ONsp3-HCarbonyl-O[Carbonyl]-O-Csp3N(H)Alkyl-H[N(H)Alkyl]-HNon-Polar2.38No baseNo BaseNo baseHardO-EDG
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.286.71#N/A#N/A#N/A#N/A#N/A#REF!5.6643.091.706749553.2392069642.4729782574.96639928#REF!#REF!OCHCC(=O)CNCC(=O)CCCNCC(C)C(C=CC=C1C(C)C)=C1N2C=CN(C3=C(C(C)C)C=CC=C3C(C)C)C2#N/ACc1ccccc1
439
46612/15/202185
Long
anie.201808560
C-O Activation
x10.1002/anie.2018085602018
11.2E-NuOMe
CarbonylH
N(H)ArylIPr
#N/A#N/A140toluenetolueneNHCCarbeneCarbeneCsp2-Nsp3StrongOO-Csp3HCsp2Nsp3Csp2-ONsp3-HCarbonyl-O[Carbonyl]-O-Csp3N(H)Aryl-H[N(H)Aryl]-HNon-Polar2.38No baseNo BaseNo baseHardO-EDG
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.286.71#N/A#N/A#N/A#N/A#N/A#REF!11.526.021.706749553.2392069642.4729782574.96639928#REF!#REF!OCHCC(=O)CNC1=CC=CC=C1C(=O)CCC1=CC=CC=C1NCC(C)C(C=CC=C1C(C)C)=C1N2C=CN(C3=C(C(C)C)C=CC=C3C(C)C)C2#N/ACc1ccccc1
440
46712/15/202185
Long
anie.201808560
C-O Activation
x10.1002/anie.2018085602018
11.2E-NuOMe
CarbonylH
N(H)ArylIPr
#N/A#N/A140toluenetolueneNHCCarbeneCarbeneCsp2-Nsp3StrongOO-Csp3HCsp2Nsp3Csp2-ONsp3-HCarbonyl-O[Carbonyl]-O-Csp3N(H)Aryl-H[N(H)Aryl]-HNon-Polar2.38No baseNo BaseNo baseHardO-EDG
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.286.71#N/A#N/A#N/A#N/A#N/A#REF!11.526.021.706749553.2392069642.4729782574.96639928#REF!#REF!OCHCC(=O)CNC1=CC=CC=C1C(=O)CCC1=CC=CC=C1NCC(C)C(C=CC=C1C(C)C)=C1N2C=CN(C3=C(C(C)C)C=CC=C3C(C)C)C2#N/ACc1ccccc1
441
46812/16/2021383
Elaine
ja413131m
C-H Activation
x10.1021/ja413131m2014
15E-NuI
AlkylH
Alkyldppbz
#N/A#N/A150Cs2CO3toluenetolueneN2P-PPhosphine (Bidentate)PhosphineCsp3-Csp3XHCsp3Csp3Csp3-XCsp3-HAlkyl-X[Alkyl]-Alkyl-H[Alkyl]-HNon-Polar2.38Ionic-CO3Cs+
J AM CHEM SOC
_1.72.530430542.115215273.4538974810.33#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5IHCCCCCCCCC1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3P(C4=CC=CC=C4)C5=CC=CC=C5C(=O)([O-])[O-].[Cs+].[Cs+]Cc1ccccc1
442
46912/16/2021383
Elaine
ja413131m
C-H Activation
x10.1021/ja413131m2014
15E-NuI
AlkylH
Alkyldppbz
#N/A#N/A150Cs2CO3toluenetolueneN2P-PPhosphine (Bidentate)PhosphineCsp3-Csp3XHCsp3Csp3Csp3-XCsp3-HAlkyl-X[Alkyl]-Alkyl-H[Alkyl]-HNon-Polar2.38Ionic-CO3Cs+
J AM CHEM SOC
_1.72.530430542.115215273.4538974810.33#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5IHCCCCCCCCC1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3P(C4=CC=CC=C4)C5=CC=CC=C5C(=O)([O-])[O-].[Cs+].[Cs+]Cc1ccccc1
443
47012/16/2021383
Elaine
ja413131m
C-H Activation
x10.1021/ja413131m2014
15E-NuI
AlkylH
Alkyldppbz
#N/A#N/A150Cs2CO3toluenetolueneTEMPOP-PPhosphine (Bidentate)PhosphineCsp3-Csp3XHCsp3Csp3Csp3-XCsp3-HAlkyl-X[Alkyl]-Alkyl-H[Alkyl]-HNon-Polar2.38Ionic-CO3Cs+
J AM CHEM SOC
_1.72.530430542.115215273.4538974810.33#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5IHCCCCCCCCC1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3P(C4=CC=CC=C4)C5=CC=CC=C5C(=O)([O-])[O-].[Cs+].[Cs+]Cc1ccccc1
444
47112/16/2021396
Elaine
ja401344e
C-H Activation
x10.1021/ja401344e2013
12E-NuBr
AlkylH
ArylPPh3
#N/A#N/A160Na2CO3toluenetoluenePPhosphine (Monodentate)PhosphineCsp3-Csp2_arXHCsp3Csp2_arCsp3-XCsp2_ar-HAlkyl-X[Alkyl]-Aryl-H[Aryl]-HNon-Polar2.38Ionic-CO3Na+
J AM CHEM SOC
_1.72.530430542.115215273.4538974810.33#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5BrHCCC1=CC=CC=C1CCC1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3[Na+].[Na+].[O-]C([O-])=OCc1ccccc1
445
47212/16/2021396
Elaine
ja401344e
C-H Activation
x10.1021/ja401344e2013
12E-NuBr
AlkylH
ArylPPh3
#N/A#N/A140Na2CO3toluenetoluenePPhosphine (Monodentate)PhosphineCsp3-Csp2_arXHCsp3Csp2_arCsp3-XCsp2_ar-HAlkyl-X[Alkyl]-Aryl-H[Aryl]-HNon-Polar2.38Ionic-CO3Na+
J AM CHEM SOC
_1.72.530430542.115215273.4538974810.33#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5BrHCCC1=CC=CC=C1CCC1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3[Na+].[Na+].[O-]C([O-])=OCc1ccccc1
446
47312/16/2021396
Elaine
ja401344e
C-H Activation
x10.1021/ja401344e2013
12E-NuBr
ArylH
ArylPPh3
#N/A#N/A140Na2CO3toluenetoluenePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
XHCsp2_arCsp2_arCsp2_ar-XCsp2_ar-HAryl-X[Aryl]-Aryl-H[Aryl]-HNon-Polar2.38Ionic-CO3Na+
J AM CHEM SOC
_1.72.530430542.115215273.4538974810.33#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5BrHC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3[Na+].[Na+].[O-]C([O-])=OCc1ccccc1
447
47412/16/2021136
Elaine
c8sc05445b
C-H Activation
x10.1039/c8sc05445b2019
PMHS is not a ligand (comment and changed by Gerry)12E-NuI
ArylH
Vinyl#N/A#N/A#N/A25NaOtBubenzenebenzene#N/A#N/A#N/ACsp2_ar-Csp2XHCsp2_arCsp2Csp2_ar-XCsp2-HAryl-X[Aryl]-Vinyl-H[Vinyl]-HNon-Polar2.27Ionic-OtBuNa+CHEM SCI_2.8589353663.2821934583.0705644124.0077900319#REF!6.0701.706749553.2392069642.4729782574.96639928#REF!#REF!115.6IHC1=CC=CC=C1C=CC1=CC=CC=C1C=C#N/A[Na]OC(C)(C)Cc1ccccc1
448
47512/16/2021136
Elaine
c8sc05445b
C-H Activation
x10.1039/c8sc05445b2019
PMHS is not a ligand (comment and changed by Gerry)12E-NuX
ArylH
Vinyl#N/A#N/A#N/A25NaOtBubenzenebenzene#N/A#N/A#N/ACsp2_ar-Csp2XHCsp2_arCsp2Csp2_ar-XCsp2-HAryl-X[Aryl]-Vinyl-H[Vinyl]-HNon-Polar2.27Ionic-OtBuNa+CHEM SCI_2.8589353663.2821934583.0705644124.0077900319#REF!6.0701.706749553.2392069642.4729782574.96639928#REF!#REF!115.6ClHC1=CC=CC=C1C=CC1=CC=CC=C1C=C#N/A[Na]OC(C)(C)Cc1ccccc1
449
47612/16/2021136
Elaine
c8sc05445b
C-H Activation
x10.1039/c8sc05445b2019
PMHS is not a ligand (comment and changed by Gerry)12E-NuX
ArylH
Vinyl#N/A#N/A#N/A25NaOtBubenzenebenzene#N/A#N/A#N/ACsp2_ar-Csp2XHCsp2_arCsp2Csp2_ar-XCsp2-HAryl-X[Aryl]-Vinyl-H[Vinyl]-HNon-Polar2.27Ionic-OtBuNa+CHEM SCI_2.8589353663.2821934583.0705644124.0077900319#REF!6.0701.706749553.2392069642.4729782574.96639928#REF!#REF!115.6ClHC1=CC=CC=C1C=CC1=CC=CC=C1C=C#N/A[Na]OC(C)(C)Cc1ccccc1
450
47712/16/2021136
Elaine
c8sc05445b
C-H Activation
x10.1039/c8sc05445b2019
PMHS is not a ligand (comment and changed by Gerry)12E-NuX
ArylH
Vinyl#N/A#N/A#N/A25NaOtBubenzenebenzene#N/A#N/A#N/ACsp2_ar-Csp2XHCsp2_arCsp2Csp2_ar-XCsp2-HAryl-X[Aryl]-Vinyl-H[Vinyl]-HNon-Polar2.27Ionic-OtBuNa+CHEM SCI_2.8589353663.2821934583.0705644124.0077900319#REF!6.0701.706749553.2392069642.4729782574.96639928#REF!#REF!115.6ClHC1=CC=CC=C1C=CC1=CC=CC=C1C=C#N/A[Na]OC(C)(C)Cc1ccccc1
451
47812/16/2021136
Elaine
c8sc05445b
C-H Activation
x10.1039/c8sc05445b2019
PMHS is not a ligand (comment and changed by Gerry)12E-NuX
ArylH
Vinyl#N/A#N/A#N/A25NaOtBubenzenebenzene#N/A#N/A#N/ACsp2_ar-Csp2XHCsp2_arCsp2Csp2_ar-XCsp2-HAryl-X[Aryl]-Vinyl-H[Vinyl]-HNon-Polar2.27Ionic-OtBuNa+CHEM SCI_2.8589353663.2821934583.0705644124.0077900319#REF!6.0701.706749553.2392069642.4729782574.96639928#REF!#REF!115.6ClHC1=CC=CC=C1C=CC1=CC=CC=C1C=C#N/A[Na]OC(C)(C)Cc1ccccc1
452
47912/16/2021311
William
b314246a
C-H Activation
x10.1039/b314246a2004
11E-NuI
ArylH
VinylPPh3
#N/A#N/A80KOHisopropanolisopropanolPPhosphine (Monodentate)PhosphineCsp2_ar-Csp2XHCsp2_arCsp2Csp2_ar-XCsp2-HAryl-X[Aryl]-Vinyl-H[Vinyl]-H#N/A#N/AIonic-ORK+
CHEM COMMUN
_015.74#REF!6.0701.706749553.2392069642.4729782574.96639928#REF!#REF!115.6IHC1=CC=CC=C1C=CC1=CC=CC=C1C=CP(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3[K+].[OH-]CC(O)C
453
48012/16/202172
Elaine
anie.201102092
C-H Activation
x10.1002/anie.2011020922011
3aa13Nu-NuB(nep)
ArylH
BenzylIPr·HCl
#N/A#N/A60CsFtoluene/dioxanetoluene/dioxane#N/A#N/A#N/A
Csp2_ar-Csp3-ring(s)
Nu-MBHCsp2_arCsp3-ring(s)Csp2_ar-BCsp3-ring(s)-HAryl-B[Aryl]-Benzyl-H[Benzyl]-HBoth#REF!Ionic-FCs+#N/A#N/A
ANGEW CHEM INT EDIT
_03.14#REF!12.1701.706749553.2392069642.4729782574.96639928#REF!#REF!21.3B1OCC(C)(CO1)CHC1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1#N/A[Cs]F#N/A
454
48112/16/202172
Elaine
anie.201102092
C-H Activation
x10.1002/anie.2011020922011
13Nu-NuB(nep)
ArylH
CarbonylIPr·HCl
#N/A#N/A69CsFtoluene/dioxanetoluene/dioxane#N/A#N/A#N/ACsp2_ar-Csp2Nu-MBHCsp2_arCsp2Csp2_ar-BCsp2-HAryl-B[Aryl]-Carbonyl-H[Carbonyl]-HBoth#REF!Ionic-FCs+#N/A#N/A
ANGEW CHEM INT EDIT
_03.14#REF!4.517.071.706749553.2392069642.4729782574.96639928#REF!#REF!199.9B1OCC(C)(CO1)CHC1=CC=CC=C1CC(=O)CC1=CC=CC=C1C(=O)CC#N/A[Cs]F#N/A
455
48212/16/202172
Elaine
anie.201102092
C-H Activation
x10.1002/anie.2011020922011
16Nu-NuB(nep)
ArylH
CarbonylIPr·HCl
#N/A#N/A60-80CsFtoluene/dioxanetoluene/dioxane#N/A#N/A#N/ACsp2_ar-Csp2Nu-MBHCsp2_arCsp2Csp2_ar-BCsp2-HAryl-B[Aryl]-Carbonyl-H[Carbonyl]-HBoth#REF!Ionic-FCs+#N/A#N/A
ANGEW CHEM INT EDIT
_03.14#REF!4.517.071.706749553.2392069642.4729782574.96639928#REF!#REF!199.9B1OCC(C)(CO1)CHC1=CC=CC=C1CC(=O)CC1=CC=CC=C1C(=O)CC#N/A[Cs]F#N/A
456
48312/16/2021225
Elaine
jo300209d
C-N Activation
x10.1021/jo300209d2012
11.5E-NuNMe3+I-
ArylZnX
Aryl(E)-N-(2-(l1-phosphaneyl)phenyl)-N'-(p-tolyl)benzimidamide
#N/A#N/A85THFNMPTHFN-N-PMixed (N and P)Mixed
Csp2_ar-Csp2_ar
E-HNN(+)Me3ZnCsp2_arCsp2_arCsp2_ar-NCsp2_ar-ZnAryl-N[Aryl]-N(+)Me3Aryl-ZnX[Aryl]-ZnXPolar7.58No baseNo BaseNo base#N/A#N/A
J ORG CHEM
_#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!X[N+](C)(C)C.[I-][Zn]ClC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1[P]C1=CC=CC=C1N/C(C2=CC=CC=C2)=N/C3=CC=C(C)C=C3.C4(C5=CC=CC=C5)=CC=CC=C4#N/AC1CCOC1
457
48412/16/2021225
Elaine
jo300209d
C-N Activation
x10.1021/jo300209d2012
11.5E-NuNMe3+I-
ArylZnX
Aryl(E)-N-(2-(l1-phosphaneyl)phenyl)-N'-(p-tolyl)benzimidamide
#N/A#N/A85THFNMPTHFN-N-PMixed (N and P)Mixed
Csp2_ar-Csp2_ar
E-HNN(+)Me3ZnCsp2_arCsp2_arCsp2_ar-NCsp2_ar-ZnAryl-N[Aryl]-N(+)Me3Aryl-ZnX[Aryl]-ZnXPolar7.58No baseNo BaseNo base#N/A#N/A
J ORG CHEM
_#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!X[N+](C)(C)C.[I-][Zn]ClC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1[P]C1=CC=CC=C1N/C(C2=CC=CC=C2)=N/C3=CC=C(C)C=C3.C4(C5=CC=CC=C5)=CC=CC=C4#N/AC1CCOC1
458
48512/16/202184
Elaine
ejoc.201000147
C-O Activation
x10.1002/ejoc.2010001472010
11.5E-NuOTs
ArylB(OH)2
ArylPPh3
#N/A#N/A100K2CO3toluenetoluenePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2Non-Polar2.38Ionic-CO3K+EasyOSO2-EDG
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
_0.361.72.530430542.115215273.4538974810.33#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(=O)(C1=CC=C(C)C=C1)B(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3O=C([O-])[O-].[K+].[K+]Cc1ccccc1
459
48612/16/202184
Elaine
ejoc.201000147
C-O Activation
x10.1002/ejoc.2010001472010
11.5E-NuOTs
ArylB(OH)2
ArylPPh3
#N/A#N/A100K2CO3toluenetoluenePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2Non-Polar2.38Ionic-CO3K+EasyOSO2-EDG
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
_0.361.72.530430542.115215273.4538974810.33#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(=O)(C1=CC=C(C)C=C1)B(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3O=C([O-])[O-].[K+].[K+]Cc1ccccc1
460
48712/16/202184
Elaine
ejoc.201000147
C-O Activation
x10.1002/ejoc.2010001472010
11.5E-NuOTs
ArylB(OH)2
ArylPPh3
#N/A#N/A100K2CO3toluenetoluenePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2Non-Polar2.38Ionic-CO3K+EasyOSO2-EDG
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
_0.361.72.530430542.115215273.4538974810.33#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(=O)(C1=CC=C(C)C=C1)B(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3O=C([O-])[O-].[K+].[K+]Cc1ccccc1
461
48812/16/202172
Elaine
adsc.201000710
C-O Activation
x10.1002/adsc.2010007102011
12E-NuOMs
ArylB(OH)2
Aryldppp
#N/A#N/A100K3PO4dioxanedioxaneP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar2.25Ionic-PO4K+EasyOSO2-EDG
ADVANCED SYNTHESIS & CATALYSIS
TM0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(=O)CB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(c1ccccc1)(c2ccccc2)CCCP(c3ccccc3)c4ccccc4[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1COCCO1
462
48912/16/202172
Elaine
adsc.201000710
C-O Activation
x10.1002/adsc.2010007102011
12E-NuOMs
ArylB(OH)2
Aryldppp
#N/A#N/A100K3PO4dioxanedioxaneP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar2.25Ionic-PO4K+EasyOSO2-EDG
ADVANCED SYNTHESIS & CATALYSIS
TM0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(=O)CB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(c1ccccc1)(c2ccccc2)CCCP(c3ccccc3)c4ccccc4[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1COCCO1
463
49012/16/202172
Elaine
adsc.201000710
C-O Activation
x10.1002/adsc.2010007102011
12E-NuOTs
ArylB(OH)2
Aryldppp
#N/A#N/A100-110K3PO4dioxanedioxaneP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar2.25Ionic-PO4K+EasyOSO2-EDG
ADVANCED SYNTHESIS & CATALYSIS
TM0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(=O)(C1=CC=C(C)C=C1)B(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(c1ccccc1)(c2ccccc2)CCCP(c3ccccc3)c4ccccc4[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1COCCO1
464
49112/16/202159
Elaine
ejoc.201200444
C-O Activation
x10.1002/ejoc.2012004442012
11.2E-NuOSO2NMe2
ArylB(OH)2
Aryldppp
#N/A#N/A100-110K3PO4dioxanedioxaneP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar2.25Ionic-PO4K+MediumOSO2-EDG
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
TM0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(N(C)C)=OB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(c1ccccc1)(c2ccccc2)CCCP(c3ccccc3)c4ccccc4[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1COCCO1
465
49212/16/202159
Elaine
ejoc.201200444
C-O Activation
x10.1002/ejoc.2012004442012
11.2E-NuOSO2NMe2
HetB(OH)2
Aryldppp
#N/A#N/A100-110K3PO4dioxanedioxaneP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BHet-O[Het]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar2.25Ionic-PO4K+MediumOSO2-EDG
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
TM0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(N(C)C)=OB(O)OC1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1C1=CC=CC=C1P(c1ccccc1)(c2ccccc2)CCCP(c3ccccc3)c4ccccc4[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1COCCO1
466
49312/16/202159
Elaine
ejoc.201200444
C-O Activation
x10.1002/ejoc.2012004442012
The results showed that in the presence of only 1.0 equiv.of boronic acid and 1 mol-% of NiCl2(dppp) as catalyst, thetwo different substrates display equally high reactivity withca. 55% yield of product3aobserved for both reactionsafter heating the reaction mixture for 0.5 h
11E-NuOSO2NMe2
ArylB(OH)2
Aryldppp
#N/A#N/A110K3PO4dioxanedioxaneP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar2.25Ionic-PO4K+MediumOSO2-EDG
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
TM0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(N(C)C)=OB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(c1ccccc1)(c2ccccc2)CCCP(c3ccccc3)c4ccccc4[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1COCCO1
467
49412/16/202159
Elaine
ejoc.201200444
C-O Activation
x10.1002/ejoc.2012004442012
The results showed that in the presence of only 1.0 equiv.of boronic acid and 1 mol-% of NiCl2(dppp) as catalyst, thetwo different substrates display equally high reactivity withca. 55% yield of product3aobserved for both reactionsafter heating the reaction mixture for 0.5 h
11E-NuOTs
ArylB(OH)2
Aryldppp
#N/A#N/A110K3PO4dioxanedioxaneP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar2.25Ionic-PO4K+EasyOSO2-EDG
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
TM0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(=O)(C1=CC=C(C)C=C1)B(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(c1ccccc1)(c2ccccc2)CCCP(c3ccccc3)c4ccccc4[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1COCCO1
468
49512/16/202155
Elaine
jo501291y
C-O Activation
x10.1021/jo501291y2014
11.5E-NuOSO2NMe2
ArylB(OH)2
ArylPPh3
#N/A#N/A110K3PO4 · 3H2OtoluenetolueneN2PPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2Non-Polar2.38Ionic-PO4K+MediumOSO2-EDG
JOURNAL OF ORGANIC CHEMISTRY
TM0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(N(C)C)=OB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3[O-]P([O-])([O-])=O.[K+].[K+].[K+].O.O.OCc1ccccc1
469
49612/16/202155
Elaine
jo501291y
C-O Activation
x10.1021/jo501291y2014
11.5E-NuOSO2NMe2
ArylB(OH)2
ArylPPh3
#N/A#N/A110K3PO4 · 3H2OtoluenetolueneN2PPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2Non-Polar2.38Ionic-PO4K+MediumOSO2-EDG
JOURNAL OF ORGANIC CHEMISTRY
TM0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(N(C)C)=OB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3[O-]P([O-])([O-])=O.[K+].[K+].[K+].O.O.OCc1ccccc1
470
49712/16/2021133
Elaine
jo3001194
C-O Activation
x10.1021/jo30011942012
11E-NuOMs
ArylB(nep)
ArylPCy3
#N/A#N/A25K3PO4THFTHFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(nep)[Aryl]-B(nep)Polar7.58Ionic-PO4K+EasyOSO2-EDG
JOURNAL OF ORGANIC CHEMISTRY
TM0.362.244780372.9696246982.6072025343.5700586912.37#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OS(=O)(=O)CB1OCC(C)(CO1)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1CCOC1
471
49812/16/2021133
Elaine
jo3001194
C-O Activation
x10.1021/jo30011942012
11E-NuOMs
ArylB(nep)
ArylPCy3
#N/A#N/A25K3PO4THFTHFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(nep)[Aryl]-B(nep)Polar7.58Ionic-PO4K+EasyOSO2-EDG
JOURNAL OF ORGANIC CHEMISTRY
TM0.362.244780372.9696246982.6072025343.5700586912.37#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OS(=O)(=O)CB1OCC(C)(CO1)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1CCOC1
472
49912/16/2021133
Elaine
jo3001194
C-O Activation
x10.1021/jo30011942012
11E-NuOSO2NMe2
ArylB(nep)
ArylPCy3
#N/A#N/A25K3PO4THFTHFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(nep)[Aryl]-B(nep)Polar7.58Ionic-PO4K+MediumOSO2-EDG
JOURNAL OF ORGANIC CHEMISTRY
TM0.362.244780372.9696246982.6072025343.5700586912.37#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OS(=O)(N(C)C)=OB1OCC(C)(CO1)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1CCOC1
473
50012/16/2021133
Elaine
jo3001194
C-O Activation
x10.1021/jo30011942012
11E-NuOSO2NMe2
HetB(nep)
HetPCy3
#N/A#N/A25K3PO4THFTHFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BHet-O[Het]-O-SO2-R'Het-B(nep)[Het]-B(nep)Polar7.58Ionic-PO4K+MediumOSO2-EDG
JOURNAL OF ORGANIC CHEMISTRY
TM0.362.244780372.9696246982.6072025343.5700586912.37#REF!21.2631.352.3360584073.6882909043.0121746566.54875338#REF!#REF!150OS(=O)(N(C)C)=OB1OCC(C)(CO1)CC1=NC=CC=C1C1=NC=CC=C1C1=CC=NC=C1C1=CC=NC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1CCOC1
474
50112/22/2021336
Long
ja3013825
C-N Activation
x10.1021/ja30138252012
Ligand in this case is Bpy13E-NuN(Ring-Opening)
AlkylZnX
AlkylBpy
#N/A#N/A23dioxaneDMAdioxaneN-NbpyNitrogenCsp3-Csp3N
N(Ring-Opening)
ZnCsp3Csp3Csp3-NCsp3-ZnAlkyl-N[Alkyl]-N(Ring-Opening)Alkyl-ZnX[Alkyl]-ZnXPolar2.25No baseNo BaseNo base#N/A#N/A
J AM CHEM SOC
_#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XNC[Zn]ClCCCCCCCCC1(C2=NC=CC=C2)=CC=CC=N1#N/AC1COCCO1
475
50212/22/2021336
Long
ja3013825
C-N Activation
x10.1021/ja30138252012
Ligand in this case is Bpy13E-NuN(Ring-Opening)
AlkylZnX
ArylBpy
#N/A#N/A23dioxaneDMAdioxaneN-NbpyNitrogenCsp3-Csp2_arN
N(Ring-Opening)
ZnCsp3Csp2_arCsp3-NCsp2_ar-ZnAlkyl-N[Alkyl]-N(Ring-Opening)Aryl-ZnX[Aryl]-ZnXPolar2.25No baseNo BaseNo base#N/A#N/A
J AM CHEM SOC
_#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XNC[Zn]ClCCC1=CC=CC=C1CCC1=CC=CC=C1C1(C2=NC=CC=C2)=CC=CC=N1#N/AC1COCCO1
476
50312/22/2021268
Long
chem.201602202
C-N Activation
x10.1002/chem.2016022022016
11.5E-Nupiperidine-2,6-dione
CarbonylZnX
ArylPPh3
#N/A#N/A23THFEt2OTHF/Et2OPPhosphine (Monodentate)PhosphineCsp2-Csp2_arE-HNGlutarimideZnCsp2Csp2_arCsp2-NCsp2_ar-ZnCarbonyl-N[Carbonyl]-GlutarimideAryl-ZnX[Aryl]-ZnXPolar#REF!No baseNo BaseNo base
CHEM-EUR J
_#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XN1C(CCCC1=O)=O[Zn]ClCC(=O)CC1=CC=CC=C1C(=O)CCC1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3#N/AC1CCOC1
477
50412/22/2021124
Shihong
c2dt30886j
C-N Activation
x10.1039/c2dt30886j2012
11.5E-NuNMe3+Br-
ArylZnX
ArylC1(N=P(C2=CC=CC=C2)(CC3=CC=CC=N3)C4=CC=CC=C4)=C5N=CC=CC5=CC=C1
#N/A#N/A85THFTHFN-N-NPy-N-PyNitrogen
Csp2_ar-Csp2_ar
E-HNN(+)Me3ZnCsp2_arCsp2_arCsp2_ar-NCsp2_ar-ZnAryl-N[Aryl]-N(+)Me3Aryl-ZnX[Aryl]-ZnXPolar7.58No baseNo BaseNo base#N/A#N/ADALTON T_#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!X[N+](C)(C)C.[Br-][Zn]ClC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1(N=P(C2=CC=CC=C2)(CC3=CC=CC=N3)C4=CC=CC=C4)=C5N=CC=CC5=CC=C1#N/AC1CCOC1
478
50512/22/2021109
Shihong
c4qo00321g
C-N Activation
x10.1039/c4qo00321g2015
11.5E-NuNMe3+OTf-
ArylZnX
ArylN1-(2-(diphenylphosphaneyl)phenyl)-N2,N2-dimethylbenzene-1,2-diamine
#N/A#N/A65THFNMPTHFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
E-HNN(+)Me3ZnCsp2_arCsp2_arCsp2_ar-NCsp2_ar-ZnAryl-N[Aryl]-N(+)Me3Aryl-ZnX[Aryl]-ZnXPolar7.58No baseNo BaseNo base#N/A#N/A
ORG CHEM FRONT
_#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!X[N+]C(C)(C).[O-]S(=O)(=O)C(F)(F)F[Zn]ClC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1CN(C1=C(C=CC=C1)NC2=CC=CC=C2P(C3=CC=CC=C3)C4=CC=CC=C4)C#N/AC1CCOC1
479
50612/22/2021109
Shihong
c4qo00321g
C-N Activation
x10.1039/c4qo00321g2015
11.5E-NuNMe3+OTf-
ArylZnX
HetN1-(2-(diphenylphosphaneyl)phenyl)-N2,N2-dimethylbenzene-1,2-diamine
#N/A#N/A65THFNMPTHFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
E-HNN(+)Me3ZnCsp2_arCsp2_arCsp2_ar-NCsp2_ar-ZnAryl-N[Aryl]-N(+)Me3Het-ZnX[Het]-ZnXPolar7.58No baseNo BaseNo base#N/A#N/A
ORG CHEM FRONT
_#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!X[N+]C(C)(C).[O-]S(=O)(=O)C(F)(F)F[Zn]ClC1=CC=CC=C1C1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1CN(C1=C(C=CC=C1)NC2=CC=CC=C2P(C3=CC=CC=C3)C4=CC=CC=C4)C#N/AC1CCOC1
480
50712/22/202176
Shihong
acs.orglett.9b00242
C-N Activation
x10.1021/acs.orglett.9b002422019
11.1E-NuN(Ph)Boc
ArylMgX
ArylPCy3
#N/A#N/A25toluenetoluenePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
NMgCsp2_arCsp2_arCsp2_ar-NCsp2_ar-MgAryl-N[Aryl]-Aryl-MgX[Aryl]-MgXNon-Polar2.38No baseNo BaseNo base#N/A#N/AORG LETT_#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2N(C1=CC=CC=C1)C(OC(C)(C)C)=O[Mg]ClC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/ACc1ccccc1
481
50912/22/202153
Shihong
j.tet.2017.06.004
C-N Activation
x10.1016/j.tet.2017.06.0042017
11.5E-NuNMe3+OTf-
ArylAlMe2
Alkyldppp
#N/A#N/A110dioxanedioxaneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp3E-HNN(+)Me3AlCsp2_arCsp3Csp2_ar-NCsp3-AlAryl-N[Aryl]-N(+)Me3Alkyl-AlMe2[Alkyl]-AlMe2Polar2.25No baseNo BaseNo base#N/A#N/A
TETRAHEDRON
_#N/A#N/A#N/A#N/A#N/A#REF!XX1.7950157593.6203448952.7076803276.94866248#REF!#REF!6.1[N+]C(C)(C).[O-]S(=O)(=O)C(F)(F)F[Al](C)CC1=CC=CC=C1CCC1=CC=CC=C1CCP(c1ccccc1)(c2ccccc2)CCCP(c3ccccc3)c4ccccc4#N/AC1COCCO1
482
51012/22/202153
Shihong
j.tet.2017.06.004
C-N Activation
x10.1016/j.tet.2017.06.0042017
11.5E-NuNMe3+OTf-
BenzylAlMe2
Alkyldppp
#N/A#N/A110dioxanedioxaneP-PPhosphine (Bidentate)Phosphine
Csp3-ring(s)-Csp3
E-HNN(+)Me3AlCsp3-ring(s)Csp3Csp3-ring(s)-NCsp3-AlBenzyl-N[Benzyl]-N(+)Me3Alkyl-AlMe2[Alkyl]-AlMe2Polar2.25No baseNo BaseNo base#N/A#N/A
TETRAHEDRON
_#N/A#N/A#N/A#N/A#N/A#N/A#REF!XX1.7950157593.6203448952.7076803276.94866248#REF!#REF!6.1[N+]C(C)(C).[O-]S(=O)(=O)C(F)(F)F[Al](C)CCC1=CC=CC=C1CCCC1=CC=CC=C1CCP(c1ccccc1)(c2ccccc2)CCCP(c3ccccc3)c4ccccc4#N/AC1COCCO1
483
51212/22/2021166
Long
chem.201103784
C-O Activation
x10.1002/chem.2011037842012
12E-NuOMe
ArylZnMe3Li2
ArylPCy3
#N/A#N/ArttoluenetoluenePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
StrongOO-Csp3ZnCsp2_arCsp2_arCsp2_ar-OCsp2_ar-ZnAryl-O[Aryl]-O-Csp3Aryl-ZnMe3Li2[Aryl]-ZnMe3Li2Non-Polar2.38No baseNo BaseNo base
CHEMISTRY-A EUROPEAN JOURNAL
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XOC[Zn](C)(C)([Li])([Li])CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/ACc1ccccc1
484
51312/22/202195
Shihong
jo4005537
C-O Activation
x10.1021/jo40055372013
14E-NuODMT
ArylB(OH)2
Aryldppf
#N/A#N/A110K3PO4toluenetolueneP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
StrongOO-Csp2BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-Csp2Aryl-B(OH)2[Aryl]-B(OH)2Non-Polar2.38Ionic-PO4K+#N/A#N/A
JOURNAL OF ORGANIC CHEMISTRY
TM-0.3225.22.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6O(C1=NC(CC)=NC(CC)=N1)B(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1c1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1[O-]P(=O)([O-])[O-].[K+].[K+].[K+]Cc1ccccc1
485
51412/22/202154
Shihong
cl.2011.1001
C-O Activation
x10.1246/cl.2011.10012011
12E-NuOTMS
ArylMgX
ArylPCy3
#N/A#N/A30toluenetoluenePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
StrongOO-SiR'3MgCsp2_arCsp2_arCsp2_ar-OCsp2_ar-MgAryl-O[Aryl]-O-SiR'3Aryl-MgX[Aryl]-MgXNon-Polar2.38No baseNo BaseNo baseMediumOSiMe2-EDG
CHEMISTRY LETTERS
_-0.2719.47#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2O[Si](C)(C)C[Mg]ClC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/ACc1ccccc1
486
51512/22/2021229
Shihong
ja510653n
C-O Activation
x10.1021/ja510653n2014
1..71E-EOH
CarbonylBr
Alkylbpy
#N/A#N/A30iPr2NEtMgCl2DMSODMEDMEZnBoc2ON-NbpyNitrogenCsp2-Csp3StrongOOHXCsp2Csp3Csp2-OCsp3-XCarbonyl-O[Carbonyl]-OHAlkyl-Br[Alkyl]-BrPolar7.2NitrogenNitrogen(neutral)NHardOH
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_-0.814.791.7105540393.2426955962.4766248184.9733801910.5#REF!0#REF!#REF!XOBrCC(=O)CCCC(=O)CCCCC1(C2=NC=CC=C2)=CC=CC=N1CC(C)N(CC)C(C)CCS(=O)C
487
51612/22/2021271
Elaine
jacs.9b00111
C-N Activation
x10.1021/jacs.9b001112019
11.6E-NuTriphenylpyridinium+BF4-
HetZnX
Alkylbpp
#N/A#N/A60THFDMATHFZnXN-N-NterpyNitrogenCsp2_ar-Csp3NPyridiniumZnCsp2_arCsp3Csp2_ar-NCsp3-ZnHet-N[Het]-PyridiniumAlkyl-ZnX[Alkyl]-ZnXPolar7.58No baseNo BaseNo base
J AM CHEM SOC
_#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!X[N+]1=C(C=C(C=C1C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.F[B-](F)(F)F[Zn]ClC1=NC=CC=C1CCC1=CC=NC=C1CCC1(N2C=CC=N2)=NC(N3C=CC=N3)=CC=C1#N/AC1CCOC1
488
51712/22/2021271
Elaine
jacs.9b00111
C-N Activation
x10.1021/jacs.9b001112019
The number of water molecules in ligand image are not fixed11.6E-NuTriphenylpyridinium+BF4-
HetZnX
Alkylttbtpy
#N/A#N/A60THFDMATHFZnXN-N-NterpyNitrogenCsp2_ar-Csp3NPyridiniumZnCsp2_arCsp3Csp2_ar-NCsp3-ZnHet-N[Het]-PyridiniumAlkyl-ZnX[Alkyl]-ZnXPolar7.58No baseNo BaseNo base
J AM CHEM SOC
_#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!X[N+]1=C(C=C(C=C1C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.F[B-](F)(F)F[Zn]ClC1=NC=CC=C1CCC1=CC=NC=C1CCCC(C)(C1=CN=C(C2=NC(C3=NC=C(C(C)(C)C)C=C3)=CC(C(C)(C)C)=C2)C=C1)C#N/AC1CCOC1
489
51812/28/2021227
Gerry
bcsj.20140387
C-H Activation
x10.1246/bcsj.201403872015
21E-NuOTs
AlkylH
ArylPPh3
#N/A#N/ANa2CO3toluenetoluenePPhosphine (Monodentate)PhosphineCsp3-Csp2_arWeakOO-SO2-R'HCsp3Csp2_arCsp3-OCsp2_ar-HAlkyl-O[Alkyl]-O-SO2-R'Aryl-H[Aryl]-HNon-Polar2.38Ionic-CO3Na+EasyOSO2-EDG
B CHEM SOC JPN
_0.361.72.530430542.115215273.4538974810.33#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5OS(=O)(=O)(C1=CC=C(C)C=C1)HCCC1=CC=CC=C1CCC1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3[Na+].[Na+].[O-]C([O-])=OCc1ccccc1
490
51912/28/2021227
Gerry
bcsj.20140387
C-H Activation
x10.1246/bcsj.201403872015
21E-NuBr
AlkylH
ArylPPh3
#N/A#N/A140Na2CO3toluenetoluenePPhosphine (Monodentate)PhosphineCsp3-Csp2_arXHCsp3Csp2_arCsp3-XCsp2_ar-HAlkyl-X[Alkyl]-Aryl-H[Aryl]-HNon-Polar2.38Ionic-CO3Na+
B CHEM SOC JPN
_1.72.530430542.115215273.4538974810.33#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5BrHCCC1=CC=CC=C1CCC1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3[Na+].[Na+].[O-]C([O-])=OCc1ccccc1
491
52012/28/2021227
Gerry
bcsj.20140387
C-H Activation
x10.1246/bcsj.201403872015
21E-NuBr
AlkylH
ArylPPh3
#N/A#N/A140Na2CO3toluenetoluenePPhosphine (Monodentate)PhosphineCsp3-Csp2_arXHCsp3Csp2_arCsp3-XCsp2_ar-HAlkyl-X[Alkyl]-Aryl-H[Aryl]-HNon-Polar2.38Ionic-CO3Na+
B CHEM SOC JPN
_1.72.530430542.115215273.4538974810.33#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5BrHCCC1=CC=CC=C1CCC1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3[Na+].[Na+].[O-]C([O-])=OCc1ccccc1
492
52112/28/2021227
Gerry
bcsj.20140387
C-H Activation
x10.1246/bcsj.201403872015
21E-NuBr
AlkylH
ArylPPh3
#N/A#N/A140Na2CO3toluenetoluenePPhosphine (Monodentate)PhosphineCsp3-Csp2_arXHCsp3Csp2_arCsp3-XCsp2_ar-HAlkyl-X[Alkyl]-Aryl-H[Aryl]-HNon-Polar2.38Ionic-CO3Na+
B CHEM SOC JPN
_1.72.530430542.115215273.4538974810.33#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5BrHCCC1=CC=CC=C1CCC1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3[Na+].[Na+].[O-]C([O-])=OCc1ccccc1
493
52212/28/2021227
Gerry
bcsj.20140387
C-H Activation
x10.1246/bcsj.201403872015
21E-NuBr
AlkylH
ArylPPh3
#N/A#N/A140Na2CO3toluenetoluenePPhosphine (Monodentate)PhosphineCsp3-Csp2_arXHCsp3Csp2_arCsp3-XCsp2_ar-HAlkyl-X[Alkyl]-Aryl-H[Aryl]-HNon-Polar2.38Ionic-CO3Na+
B CHEM SOC JPN
_1.72.530430542.115215273.4538974810.33#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5BrHCCC1=CC=CC=C1CCC1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3[Na+].[Na+].[O-]C([O-])=OCc1ccccc1
494
52312/28/2021138
Gerry
c2cc32396f
C-H Activation
x10.1039/c2cc32396f2012
81Nu-NuMgX
AlkylH
Hetdppp
#N/A#N/A25THFTHFP-PPhosphine (Bidentate)PhosphineCsp3-Csp2_arNu-MMgHCsp3Csp2_arCsp3-MgCsp2_ar-HAlkyl-Mg[Alkyl]-Het-H[Het]-HPolar7.58No baseNo BaseNo base
CHEM COMMUN
_#N/A#N/A#N/A#N/A#N/A#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8[Mg]ClHCCC1=NC=CC=C1CCC1=CC=NC=C1P(c1ccccc1)(c2ccccc2)CCCP(c3ccccc3)c4ccccc4#N/AC1CCOC1
495
52412/28/2021138
Gerry
c2cc32396f
C-H Activation
x10.1039/c2cc32396f2012
81Nu-NuMgX
AlkylH
Hetdppp
#N/A#N/A25THFTHFP-PPhosphine (Bidentate)PhosphineCsp3-Csp2_arNu-MMgHCsp3Csp2_arCsp3-MgCsp2_ar-HAlkyl-Mg[Alkyl]-Het-H[Het]-HPolar7.58No baseNo BaseNo base
CHEM COMMUN
_#N/A#N/A#N/A#N/A#N/A#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8[Mg]ClHCCC1=NC=CC=C1CCC1=CC=NC=C1P(c1ccccc1)(c2ccccc2)CCCP(c3ccccc3)c4ccccc4#N/AC1CCOC1
496
52512/28/202177
Gerry
acs.organomet.6b00201
C-H Activation
x10.1021/acs.organomet.6b002012016
1.51E-NuBr
AlkylH
Het2-(Dimethylamino)phenyl(8-quinolinyl)amine
#N/A#N/A120LiOtBuNaIdioxanedioxaneN-N-NPy-N-NNitrogenCsp3-Csp2_arXHCsp3Csp2_arCsp3-XCsp2_ar-HAlkyl-X[Alkyl]-Het-H[Het]-HPolar2.25Ionic-OtBuLi+
ORGANOMETALLICS
_2.8589353663.2821934583.0705644124.0077900319#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8BrHCCC1=NC=CC=C1CCC1=CC=NC=C1CN(C)C1=CC=CC=C1NC2=CC=CC3=C2N=CC=C3CC(C)(C)[O-].[Li+]C1COCCO1
497
52612/28/2021325
Long
c4cc00716f
C-H Activation
x10.1039/c4cc00716f2014
X=I give yield > 80%
21E-NuI
ArylH
AlkylPPh3
#N/A#N/A160Na2CO3dioxanePPhosphine (Monodentate)PhosphineCsp2_ar-Csp3XHCsp2_arCsp3Csp2_ar-XCsp3-HAryl-X[Aryl]-Alkyl-H[Alkyl]-H#N/A#N/AIonic-CO3Na+
CHEM COMMUN
_1.72.530430542.115215273.4538974810.33#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5IHC1=CC=CC=C1CCC1=CC=CC=C1CCP(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3[Na+].[Na+].[O-]C([O-])=OC1COCCO1
498
52712/28/2021303
Long
ol702058e
C-H Activation
x10.1021/ol702058e2007
NANAE-NuBr
ArylH
Carbonylbis(2,4-di-tert-butylphenyl) (3,4-di-tert-butylphenyl) phosphite
#N/A#N/A110NaOMedioxanePPhosphine (Monodentate)PhosphineCsp2_ar-Csp2XHCsp2_arCsp2Csp2_ar-XCsp2-HAryl-X[Aryl]-Carbonyl-H[Carbonyl]-H#N/A#N/AIonic-ORNa+ORG LETT_015.1#REF!4.517.071.706749553.2392069642.4729782574.96639928#REF!#REF!199.9BrHC1=CC=CC=C1CC(=O)CC1=CC=CC=C1C(=O)CCCC(C)(C)C(C=C1C(C)(C)C)=CC=C1OP(OC2=CC=C(C(C)(C)C)C(C(C)(C)C)=C2)OC3=CC=C(C(C)(C)C)C=C3C(C)(C)C[Na]OCC1COCCO1
499
52812/28/2021388
Shihong
ol9001587
C-H Activation
x10.1021/ol90015872009
1.51E-NuX
ArylH
Hetbpy
#N/A#N/A85LiOtBudioxaneN-NbpyNitrogen
Csp2_ar-Csp2_ar
XHCsp2_arCsp2_arCsp2_ar-XCsp2_ar-HAryl-X[Aryl]-Het-H[Het]-H#N/A#N/AIonic-OtBuLi+ORG LETT_2.8589353663.2821934583.0705644124.0077900319#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8ClHC1=CC=CC=C1C1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1C1(C2=NC=CC=C2)=CC=CC=N1CC(C)(C)[O-].[Li+]C1COCCO1
500
52912/28/2021388
Shihong
ol9001587
C-H Activation
x10.1021/ol90015872009
11.5E-NuX
ArylH
Hetdppf
#N/A#N/A140LiOtBudioxaneP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
XHCsp2_arCsp2_arCsp2_ar-XCsp2_ar-HAryl-X[Aryl]-Het-H[Het]-H#N/A#N/AIonic-OtBuLi+ORG LETT_2.8589353663.2821934583.0705644124.0077900319#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8ClHC1=CC=CC=C1C1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1c1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1CC(C)(C)[O-].[Li+]C1COCCO1
501
53012/28/2021367
Shihong
ol900159a
C-H Activation
x10.1021/ol900159a2009
12Nu-NuMgX
ArylH
Het2,9-dimethyl-1,10-phenanthroline hydrate#N/A#N/A#N/A150LiOtBuo-xyleneo-xyleneZn#N/A#N/A#N/A
Csp2_ar-Csp2_ar
Nu-MMgHCsp2_arCsp2_arCsp2_ar-MgCsp2_ar-HAryl-Mg[Aryl]-Het-H[Het]-HNon-Polar2.57Ionic-OtBuLi+ORG LETT_2.8589353663.2821934583.0705644124.0077900319#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8[Mg]ClHC1=CC=CC=C1C1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1#N/ACC(C)(C)[O-].[Li+]CC1=C(C)C=CC=C1
502
53212/28/2021175
Gerry
c3ob41989d
C-N Activation
x10.1039/c3ob41989d2013
11.7E-NuNMe3+OTf-
ArylH
MorpholineIPr·HCl
#N/A#N/A75NaOtBudioxanedioxaneNHC#N/A#N/ACsp2_ar-Nsp3E-HNN(+)Me3HCsp2_arNsp3Csp2_ar-NNsp3-HAryl-N[Aryl]-N(+)Me3Morpholine-H[Morpholine]-HPolar2.25Ionic-OtBuNa+#N/A#N/A
ORG BIOMOL CHEM
_2.8589353663.2821934583.0705644124.0077900319#REF!9.5921.261.706749553.2392069642.4729782574.96639928#REF!#REF![N+]C(C)(C).[O-]S(=O)(=O)C(F)(F)FHC1=CC=CC=C1N1CCCCC1C1=CC=CC=C1C1CCCCC1N#N/A[Na]OC(C)(C)CC1COCCO1
503
53312/28/2021175
Gerry
c3ob41989d
C-N Activation
x10.1039/c3ob41989d2013
11.7E-NuNMe3+OTf-
ArylH
N(Alkyl)AlkylIPr·HCl
#N/A#N/A75NaOtBudioxanedioxaneNHC#N/A#N/ACsp2_ar-Nsp3E-HNN(+)Me3HCsp2_arNsp3Csp2_ar-NNsp3-HAryl-N[Aryl]-N(+)Me3N(Alkyl)Alkyl-H[N(Alkyl)Alkyl]-HPolar2.25Ionic-OtBuNa+#N/A#N/A
ORG BIOMOL CHEM
_2.8589353663.2821934583.0705644124.0077900319#REF!9.6512.031.706749553.2392069642.4729782574.96639928#REF!#REF![N+]C(C)(C).[O-]S(=O)(=O)C(F)(F)FHC1=CC=CC=C1N(C)CC1=CC=CC=C1C(C)N#N/A[Na]OC(C)(C)CC1COCCO1
504
53412/28/2021174
Gerry
ol501707z
C-O Activation
x10.1021/ol501707z2014
31E-NuOP(O)(OEt)2
AllylH
ArylPCy3
#N/A#N/A140Na2CO3toluenetoluenePPhosphine (Monodentate)PhosphineCsp3-Csp2_arStrongOO-PO(OR')2HCsp3Csp2_arCsp3-OCsp2_ar-HAllyl-O[Allyl]-O-PO(OR')2Aryl-H[Aryl]-HNon-Polar2.38Ionic-CO3Na+HardOPO-EDG
ORGANIC LETTERS
_0.0415.441.72.530430542.115215273.4538974810.33#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5OP(OCC)(OCC)=OHCC=CC1=CC=CC=C1C=CCC1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[Na+].[Na+].[O-]C([O-])=OCc1ccccc1
505
53512/28/2021174
Gerry
ol501707z
C-O Activation
x10.1021/ol501707z2014
31E-NuOP(O)(OEt)2
AllylH
ArylPCy3
#N/A#N/A140Na2CO3toluenetoluenePPhosphine (Monodentate)PhosphineCsp3-Csp2_arStrongOO-PO(OR')2HCsp3Csp2_arCsp3-OCsp2_ar-HAllyl-O[Allyl]-O-PO(OR')2Aryl-H[Aryl]-HNon-Polar2.38Ionic-CO3Na+HardOPO-EDG
ORGANIC LETTERS
_0.0415.441.72.530430542.115215273.4538974810.33#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5OP(OCC)(OCC)=OHCC=CC1=CC=CC=C1C=CCC1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[Na+].[Na+].[O-]C([O-])=OCc1ccccc1
506
53612/28/2021174
Gerry
ol501707z
C-O Activation
x10.1021/ol501707z2014
3-61E-NuOP(O)(OEt)2
AllylH
ArylPCy3
#N/A#N/A140Na2CO3toluenetoluenePPhosphine (Monodentate)PhosphineCsp3-Csp2_arStrongOO-PO(OR')2HCsp3Csp2_arCsp3-OCsp2_ar-HAllyl-O[Allyl]-O-PO(OR')2Aryl-H[Aryl]-HNon-Polar2.38Ionic-CO3Na+HardOPO-EDG
ORGANIC LETTERS
_0.0415.441.72.530430542.115215273.4538974810.33#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5OP(OCC)(OCC)=OHCC=CC1=CC=CC=C1C=CCC1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[Na+].[Na+].[O-]C([O-])=OCc1ccccc1
507
53712/28/202146
Gerry
cl.2011.913
C-O Activation
x10.1246/cl.2011.9132011
11.2E-NuOCO2Me
ArylB(OH)2
ArylDCyPF
#N/A#N/A60K2CO3toluenetolueneP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
MediumOO-CO-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-CO-R'Aryl-B(OH)2[Aryl]-B(OH)2Non-Polar2.38Ionic-CO3K+#N/A#N/A
CHEMISTRY LETTERS
_0.3115.461.72.530430542.115215273.4538974810.33#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OC(=O)OCB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)[C]3[CH][CH][CH][CH]3.C1CCC(CC1)P(C2CCCCC2)[C]3[CH][CH][CH][CH]3.[Fe]O=C([O-])[O-].[K+].[K+]Cc1ccccc1
508
53812/28/202177
Gerry
cl.150936
C-O Activation
x10.1246/cl.1509362015
11E-NuOMe
ArylAlMe2
AlkylIcy
#N/A#N/A80NaOtButoluenetolueneNHCCarbeneCarbeneCsp2_ar-Csp3StrongOO-Csp3AlCsp2_arCsp3Csp2_ar-OCsp3-AlAryl-O[Aryl]-O-Csp3Alkyl-AlMe2[Alkyl]-AlMe2Non-Polar2.38Ionic-OtBuNa+HardO-EDG
CHEMISTRY LETTERS
_-0.2812.862.8589353663.2821934583.0705644124.0077900319#REF!XX1.7950157593.6203448952.7076803276.94866248#REF!#REF!6.1OC[Al](C)CC1=CC=CC=C1CCC1=CC=CC=C1CCN1(C2CCCCC2)C=CN(C3CCCCC3)[C]1[Na]OC(C)(C)CCc1ccccc1
509
53912/29/2021133
Gerry
anie.201709087
C-H Activation
x10.1002/anie.2017090872017
11.6Nu-NuH
HetH
VinylIPr
#N/A#N/A100PhMeNHCCarbeneCarbeneCsp2_ar-Csp2Nu-HHHCsp2_arCsp2Csp2_ar-HCsp2-HHet-H[Het]-Vinyl-H[Vinyl]-H#N/A#N/ANo baseNo BaseNo base
ANGEW CHEM INT EDIT
_#N/A#N/A#N/A#N/A#N/A#REF!6.0701.706749553.2392069642.4729782574.96639928#REF!#REF!115.6HHC1=NC=CC=C1C=CC1=CC=NC=C1C=CCC(C)C(C=CC=C1C(C)C)=C1N2C=CN(C3=C(C(C)C)C=CC=C3C(C)C)C2#N/A#N/A
510
54012/29/2021133
Gerry
anie.201709087
C-H Activation
x10.1002/anie.2017090872017
11.6Nu-NuH
HetH
VinylIPr
#N/A#N/A100PhMeNHCCarbeneCarbeneCsp2_ar-Csp2Nu-HHHCsp2_arCsp2Csp2_ar-HCsp2-HHet-H[Het]-Vinyl-H[Vinyl]-H#N/A#N/ANo baseNo BaseNo base
ANGEW CHEM INT EDIT
_#N/A#N/A#N/A#N/A#N/A#REF!6.0701.706749553.2392069642.4729782574.96639928#REF!#REF!115.6HHC1=NC=CC=C1C=CC1=CC=NC=C1C=CCC(C)C(C=CC=C1C(C)C)=C1N2C=CN(C3=C(C(C)C)C=CC=C3C(C)C)C2#N/A#N/A
511
54112/29/2021275
Gerry
anie.201511197
C-H Activation
xx10.1002/anie.2015111972016
12E-NuNMe3+I-
AlkylH
ArylPPh3
#N/A#N/A160Na2CO3toluenePPhosphine (Monodentate)PhosphineCsp3-Csp2_arE-HNN(+)Me3HCsp3Csp2_arCsp3-NCsp2_ar-HAlkyl-N[Alkyl]-N(+)Me3Aryl-H[Aryl]-H#N/A#N/AIonic-CO3Na+#N/A#N/A
ANGEW CHEM INT EDIT
_1.72.530430542.115215273.4538974810.33#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5[N+](C)(C)C.[I-]HCCC1=CC=CC=C1CCC1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3[Na+].[Na+].[O-]C([O-])=OCc1ccccc1
512
54212/29/2021364
Gerry
ol100699g
C-H Activation
x10.1021/ol100699g2010
12Nu-NuH
HetH
Alkynedtbbpy
#N/A#N/A100LiOtButoluenetolueneN-NbpyNitrogenCsp2_ar-Csp1Nu-HHHCsp2_arCsp1Csp2_ar-HCsp1-HHet-H[Het]-Alkyne-H[Alkyne]-HNon-Polar2.38Ionic-OtBuLi+ORG LETT_2.8589353663.2821934583.0705644124.0077900319#REF!#N/A#N/A1.706749553.2392069642.4729782574.96639928#REF!#REF!#N/AHHC1=NC=CC=C1C#CC1=CC=NC=C1C#CCC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)CCC(C)(C)[O-].[Li+]Cc1ccccc1
513
54312/29/2021364
Gerry
ol100699g
C-H Activation
x10.1021/ol100699g2010
12Nu-NuH
HetH
Alkynedtbbpy
#N/A#N/A100LiOtButoluenetolueneN-NbpyNitrogenCsp2_ar-Csp1Nu-HHHCsp2_arCsp1Csp2_ar-HCsp1-HHet-H[Het]-Alkyne-H[Alkyne]-HNon-Polar2.38Ionic-OtBuLi+ORG LETT_2.8589353663.2821934583.0705644124.0077900319#REF!#N/A#N/A1.706749553.2392069642.4729782574.96639928#REF!#REF!#N/AHHC1=NC=CC=C1C#CC1=CC=NC=C1C#CCC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)CCC(C)(C)[O-].[Li+]Cc1ccccc1
514
54412/29/2021147
Gerry
acs.organomet.6b00529
C-H Activation
x10.1021/acs.organomet.6b005292017
Nu-NuH
AlkylH
AlkyneDavePhos
#N/A#N/A140Cs2CO3PhCNNMPPPhosphine (Monodentate)PhosphineCsp3-Csp1Nu-HHHCsp3Csp1Csp3-HCsp1-HAlkyl-H[Alkyl]-Alkyne-H[Alkyne]-H#N/A#N/AIonic-CO3Cs+
ORGANOMETALLICS
_1.72.530430542.115215273.4538974810.33#REF!#N/A#N/A1.706749553.2392069642.4729782574.96639928#REF!#REF!#N/AHHCCC#CCCC#CCN(C)C1=CC=CC=C1C2=CC=CC=C2P(C3CCCCC3)C4CCCCC4C(=O)([O-])[O-].[Cs+].[Cs+]diglyme
515
54512/29/2021224
Gerry
acs.joc.5b00669
C-H Activation
x10.1021/acs.joc.5b006692015
11.2Nu-NuH
ArylH
AlkyneBDMAE
#N/A#N/A120Na2CO3toluenetolueneN-N-NPy-N-PyNitrogenCsp2_ar-Csp1Nu-HHHCsp2_arCsp1Csp2_ar-HCsp1-HAryl-H[Aryl]-Alkyne-H[Alkyne]-HNon-Polar2.38Ionic-CO3Na+
J ORG CHEM
_1.72.530430542.115215273.4538974810.33#REF!#N/A#N/A1.706749553.2392069642.4729782574.96639928#REF!#REF!#N/AHHC1=CC=CC=C1C#CC1=CC=CC=C1C#CCc1cc(C)n(CN(CC)Cn2c(C)cc(C)n2)n1[Na+].[Na+].[O-]C([O-])=OCc1ccccc1
516
54612/29/2021224
Gerry
acs.joc.5b00669
C-H Activation
x10.1021/acs.joc.5b006692015
11.2Nu-NuH
HetH
AlkyneBDMAE
#N/A#N/A120Na2CO3o-xyleneo-xyleneN-N-NPy-N-PyNitrogenCsp2_ar-Csp1Nu-HHHCsp2_arCsp1Csp2_ar-HCsp1-HHet-H[Het]-Alkyne-H[Alkyne]-HNon-Polar2.57Ionic-CO3Na+
J ORG CHEM
_1.72.530430542.115215273.4538974810.33#REF!#N/A#N/A1.706749553.2392069642.4729782574.96639928#REF!#REF!#N/AHHC1=NC=CC=C1C#CC1=CC=NC=C1C#CCc1cc(C)n(CN(CC)Cn2c(C)cc(C)n2)n1[Na+].[Na+].[O-]C([O-])=OCC1=C(C)C=CC=C1
517
54712/29/2021224
Gerry
acs.joc.5b00669
C-H Activation
x10.1021/acs.joc.5b006692015
11.2Nu-NuH
VinylH
AlkyneBDMAE
#N/A#N/A120Na2CO3toluenetolueneN-N-NPy-N-PyNitrogenCsp2-Csp1Nu-HHHCsp2Csp1Csp2-HCsp1-HVinyl-H[Vinyl]-Alkyne-H[Alkyne]-HNon-Polar2.38Ionic-CO3Na+
J ORG CHEM
_1.72.530430542.115215273.4538974810.33#REF!#N/A#N/A1.706749553.2392069642.4729782574.96639928#REF!#REF!#N/AHHC=CC#CC=CC#CCc1cc(C)n(CN(CC)Cn2c(C)cc(C)n2)n1[Na+].[Na+].[O-]C([O-])=OCc1ccccc1
518
55112/29/2021354
Gerry
chem.201101091
C-H Activation
x10.1002/chem.2011010912011
11.5E-NuX
ArylH
Hetbpy
#N/A#N/A85LiOtBudioxanedioxaneN-NbpyNitrogen
Csp2_ar-Csp2_ar
XHCsp2_arCsp2_arCsp2_ar-XCsp2_ar-HAryl-X[Aryl]-Het-H[Het]-HPolar2.25Ionic-OtBuLi+
CHEM-EUR J
_2.8589353663.2821934583.0705644124.0077900319#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8ClHC1=CC=CC=C1C1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1C1(C2=NC=CC=C2)=CC=CC=N1CC(C)(C)[O-].[Li+]C1COCCO1
519
55212/29/2021354
Gerry
chem.201101091
C-H Activation
x10.1002/chem.2011010912011
11.5E-NuX
ArylH
Hetdppf
#N/A#N/A140LiOtBudioxanedioxaneP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
XHCsp2_arCsp2_arCsp2_ar-XCsp2_ar-HAryl-X[Aryl]-Het-H[Het]-HPolar2.25Ionic-OtBuLi+
CHEM-EUR J
_2.8589353663.2821934583.0705644124.0077900319#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8ClHC1=CC=CC=C1C1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1c1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1CC(C)(C)[O-].[Li+]C1COCCO1
520
55312/29/2021354
Gerry
chem.201101091
C-H Activation
x10.1002/chem.2011010912011
11.5E-NuI
ArylH
Hetbpy
#N/A#N/A85LiOtBudioxanedioxaneN-NbpyNitrogen
Csp2_ar-Csp2_ar
XHCsp2_arCsp2_arCsp2_ar-XCsp2_ar-HAryl-X[Aryl]-Het-H[Het]-HPolar2.25Ionic-OtBuLi+
CHEM-EUR J
_2.8589353663.2821934583.0705644124.0077900319#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8IHC1=CC=CC=C1C1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1C1(C2=NC=CC=C2)=CC=CC=N1CC(C)(C)[O-].[Li+]C1COCCO1
521
55412/29/2021330
Gerry
ol900778m
C-H Activation
x10.1021/ol900778m2009
E-NuX
ArylH
HetPPh3
#N/A#N/A100KOtBupyridinepyridinePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
XHCsp2_arCsp2_arCsp2_ar-XCsp2_ar-HAryl-X[Aryl]-Het-H[Het]-H#N/A#N/AIonic-OtBuK+ORG LETT_2.8589353663.2821934583.0705644124.0077900319#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8ClHC1=CC=CC=C1C1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3CC(C)(C)[O-].[K+]C1=NC=CC=C1
522
55512/29/2021237
Gerry
cctc.201000223
C-H Activation
x10.1002/cctc.2010002232010
21Nu-NuB(OH)2
VinylH
Hetbpy
#N/A#N/A120K3PO4DMADMAN-NbpyNitrogenCsp2-Csp2_arNu-MBHCsp2Csp2_arCsp2-BCsp2_ar-HVinyl-B[Vinyl]-Het-H[Het]-HPolar37.8Ionic-PO4K+
CHEMCATCHEM
_2.244780372.9696246982.6072025343.5700586912.37#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8B(O)OHC=CC1=NC=CC=C1C=CC1=CC=NC=C1C1(C2=NC=CC=C2)=CC=CC=N1[O-]P(=O)([O-])[O-].[K+].[K+].[K+]CN(C)C(C)=O
523
55612/29/2021237
Gerry
cctc.201000223
C-H Activation
x10.1002/cctc.2010002232010
21Nu-NuB(OH)2
ArylH
Hetphen
#N/A#N/A120NaOtBuDMADMAN-NbpyNitrogen
Csp2_ar-Csp2_ar
Nu-MBHCsp2_arCsp2_arCsp2_ar-BCsp2_ar-HAryl-B[Aryl]-Het-H[Het]-HPolar37.8Ionic-OtBuNa+
CHEMCATCHEM
_2.8589353663.2821934583.0705644124.0077900319#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8B(O)OHC1=CC=CC=C1C1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1C1(C(N=CC=C2)=C2C=C3)=C3C=CC=N1[Na]OC(C)(C)CCN(C)C(C)=O
524
55712/29/2021108
Gerry
c1cc14558d
C-H Activation
x10.1039/c1cc14558d2011
51Nu-NuMgX
ArylH
Hetdppp
#N/A#N/A25THFTHFDCEP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
Nu-MMgHCsp2_arCsp2_arCsp2_ar-MgCsp2_ar-HAryl-Mg[Aryl]-Het-H[Het]-HPolar7.58No baseNo BaseNo base
CHEM COMMUN
_#N/A#N/A#N/A#N/A#N/A#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8[Mg]ClHC1=CC=CC=C1C1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1P(c1ccccc1)(c2ccccc2)CCCP(c3ccccc3)c4ccccc4#N/AC1CCOC1
525
55812/29/2021108
Gerry
c1cc14558d
C-H Activation
x10.1039/c1cc14558d2011
51Nu-NuMgX
ArylH
Hetdppp
#N/A#N/A25THFTHFDCEP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
Nu-MMgHCsp2_arCsp2_arCsp2_ar-MgCsp2_ar-HAryl-Mg[Aryl]-Het-H[Het]-HPolar7.58No baseNo BaseNo base
CHEM COMMUN
_#N/A#N/A#N/A#N/A#N/A#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8[Mg]ClHC1=CC=CC=C1C1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1P(c1ccccc1)(c2ccccc2)CCCP(c3ccccc3)c4ccccc4#N/AC1CCOC1
526
55912/29/2021223
Gerry
asia.201100971
C-H Activation
x10.1002/asia.2011009712012
1.51E-NuZn(Ph)
ArylH
HetPCy3
#N/A#N/AtoluenetoluenePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
ZnHCsp2_arCsp2_arCsp2_ar-ZnCsp2_ar-HAryl-Zn[Aryl]-Het-H[Het]-HNon-Polar2.38No baseNo BaseNo base#N/A#N/A
CHEM-ASIAN J
_#N/A#N/A#N/A#N/A#N/A#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8[Zn]C1=CC=CC=C1HC1=CC=CC=C1C1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/ACc1ccccc1
527
56012/29/2021223
Gerry
asia.201100971
C-H Activation
x10.1002/asia.2011009712012
21E-NuZn(Ph)
ArylH
HetPCy3
#N/A#N/AtoluenetoluenePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
ZnHCsp2_arCsp2_arCsp2_ar-ZnCsp2_ar-HAryl-Zn[Aryl]-Het-H[Het]-HNon-Polar2.38No baseNo BaseNo base#N/A#N/A
CHEM-ASIAN J
_#N/A#N/A#N/A#N/A#N/A#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8[Zn]C1=CC=CC=C1HC1=CC=CC=C1C1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/ACc1ccccc1
528
56112/29/2021223
Gerry
asia.201100971
C-H Activation
x10.1002/asia.2011009712012
31E-NuZn(Et)
ArylH
HetPCy3
#N/A#N/A130toluenetoluenePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
ZnHCsp2_arCsp2_arCsp2_ar-ZnCsp2_ar-HAryl-Zn[Aryl]-Het-H[Het]-HNon-Polar2.38No baseNo BaseNo base#N/A#N/A
CHEM-ASIAN J
_#N/A#N/A#N/A#N/A#N/A#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8[Zn]CCHC1=CC=CC=C1C1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/ACc1ccccc1
529
56212/29/202179
Gerry
ejoc.201403234
C-H Activation
x10.1002/ejoc.2014032342014
31E-NuCOOH
ArylH
HetIPr·HCl
#N/A#N/A170Ag2CO3PhCF3PhCF3BQNHC#N/A#N/A
Csp2_ar-Csp2_ar
Csp2HCsp2_arCsp2_arCsp2_ar-Csp2Csp2_ar-HAryl-Csp2[Aryl]-Het-H[Het]-H#N/A#N/A#N/A#N/A#N/A#N/A#N/A
EUR J ORG CHEM
_#N/A#N/A#N/A#N/A#N/A#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8C(=O)OHC1=CC=CC=C1C1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1#N/A#N/AFC(F)(F)C1=CC=CC=C1
530
56312/29/202179
Gerry
ejoc.201403234
C-H Activation
x10.1002/ejoc.2014032342014
31E-NuCOOH
ArylH
HetIPr·HCl
#N/A#N/A170Ag2CO3PhCF3PhCF3BQNHC#N/A#N/A
Csp2_ar-Csp2_ar
Csp2HCsp2_arCsp2_arCsp2_ar-Csp2Csp2_ar-HAryl-Csp2[Aryl]-Het-H[Het]-H#N/A#N/A#N/A#N/A#N/A#N/A#N/A
EUR J ORG CHEM
_#N/A#N/A#N/A#N/A#N/A#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8C(=O)OHC1=CC=CC=C1C1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1#N/A#N/AFC(F)(F)C1=CC=CC=C1
531
56412/29/2021180
Gerry
acs.orglett.6b02236
C-H Activation
x10.1021/acs.orglett.6b022362016
21E-Nu(OEt)3-Si
ArylH
ArylPPh3
#N/A#N/A150Na2CO3Ag3PO4dioxanedioxanePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
SiHCsp2_arCsp2_arCsp2_ar-SiCsp2_ar-HAryl-Si[Aryl]-Aryl-H[Aryl]-HPolar2.25Ionic-CO3Na+#N/A#N/AORG LETT_1.72.530430542.115215273.4538974810.33#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5[Si](OCC)(OCC)OCCHC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3[Na+].[Na+].[O-]C([O-])=OC1COCCO1
532
56512/29/2021180
Gerry
acs.orglett.6b02236
C-H Activation
x10.1021/acs.orglett.6b022362016
21E-Nu(OEt)3-Si
ArylH
HetPPh3
#N/A#N/A150Na2CO3Ag3PO4dioxanedioxanePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
SiHCsp2_arCsp2_arCsp2_ar-SiCsp2_ar-HAryl-Si[Aryl]-Het-H[Het]-HPolar2.25Ionic-CO3Na+#N/A#N/AORG LETT_1.72.530430542.115215273.4538974810.33#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8[Si](OCC)(OCC)OCCHC1=CC=CC=C1C1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3[Na+].[Na+].[O-]C([O-])=OC1COCCO1
533
56612/29/2021173
Gerry
jacs.9b03863
C-O Activation
x10.1021/jacs.9b038632019
11E-EOTf
VinylI
Aryl2-[(4R)-4-(1,1-diMethylethyl)-4,5-dihydro-2-oxazolyl]-5-(trifluoroMethyl)-Pyridine
#N/A#N/A25DMFTHFMnN-Npy-oxNitrogenCsp2-Csp2_arWeakOO-SO2-R'XCsp2Csp2_arCsp2-OCsp2_ar-XVinyl-O[Vinyl]-O-SO2-R'Aryl-I[Aryl]-I#N/A#N/ANo baseNo BaseNo baseEasyOSO2-EWG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.53#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOS(=O)(=O)C(F)(F)FIC=CC1=CC=CC=C1C=CC1=CC=CC=C1CC(C)(C)C1COC(=N1)C2=NC=C(C=C2)C(F)(F)F#N/ACN(C)C=O
534
56712/29/2021173
Gerry
jacs.9b03863
C-O Activation
x10.1021/jacs.9b038632019
11E-EOTf
VinylI
Aryl2-[(4R)-4-(1,1-diMethylethyl)-4,5-dihydro-2-oxazolyl]-5-(trifluoroMethyl)-Pyridine
#N/A#N/A25DMFTHFMnN-Npy-oxNitrogenCsp2-Csp2_arWeakOO-SO2-R'XCsp2Csp2_arCsp2-OCsp2_ar-XVinyl-O[Vinyl]-O-SO2-R'Aryl-I[Aryl]-I#N/A#N/ANo baseNo BaseNo baseEasyOSO2-EWG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.53#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOS(=O)(=O)C(F)(F)FIC=CC1=CC=CC=C1C=CC1=CC=CC=C1CC(C)(C)C1COC(=N1)C2=NC=C(C=C2)C(F)(F)F#N/ACN(C)C=O
535
56812/29/2021173
Gerry
jacs.9b03863
C-O Activation
x10.1021/jacs.9b038632019
11E-EOTf
VinylI
Aryl2-[(4R)-4-(1,1-diMethylethyl)-4,5-dihydro-2-oxazolyl]-5-(trifluoroMethyl)-Pyridine
#N/A#N/A25DMFMnN-Npy-oxNitrogenCsp2-Csp2_arWeakOO-SO2-R'XCsp2Csp2_arCsp2-OCsp2_ar-XVinyl-O[Vinyl]-O-SO2-R'Aryl-I[Aryl]-I#N/A#N/ANo baseNo BaseNo baseEasyOSO2-EWG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.53#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOS(=O)(=O)C(F)(F)FIC=CC1=CC=CC=C1C=CC1=CC=CC=C1CC(C)(C)C1COC(=N1)C2=NC=C(C=C2)C(F)(F)F#N/ACN(C)C=O
536
56912/29/2021173
Gerry
jacs.9b03863
C-O Activation
x10.1021/jacs.9b038632019
11E-EOTf
VinylI
Aryl4-(tert-butyl)-5,5-dimethyl-2-(5-(trifluoromethyl)pyridin-2-yl)-4,5-dihydrooxazole
#N/A#N/A25DMFMn#N/Apy-oxNitrogenCsp2-Csp2_arWeakOO-SO2-R'XCsp2Csp2_arCsp2-OCsp2_ar-XVinyl-O[Vinyl]-O-SO2-R'Aryl-I[Aryl]-I#N/A#N/ANo baseNo BaseNo baseEasyOSO2-EWG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.53#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOS(=O)(=O)C(F)(F)FIC=CC1=CC=CC=C1C=CC1=CC=CC=C1CC(C)(C1C(C)(C)OC(C2=NC=C(C(F)(F)F)C=C2)=N1)C#N/ACN(C)C=O
537
57012/29/2021173
Gerry
jacs.9b03863
C-O Activation
x10.1021/jacs.9b038632019
11E-EOTf
VinylI
Aryl2-[(4R)-4-(1,1-diMethylethyl)-4,5-dihydro-2-oxazolyl]-5-(trifluoroMethyl)-Pyridine
#N/A#N/A25DMFMnN-Npy-oxNitrogenCsp2-Csp2_arWeakOO-SO2-R'XCsp2Csp2_arCsp2-OCsp2_ar-XVinyl-O[Vinyl]-O-SO2-R'Aryl-I[Aryl]-I#N/A#N/ANo baseNo BaseNo baseEasyOSO2-EWG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.53#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOS(=O)(=O)C(F)(F)FIC=CC1=CC=CC=C1C=CC1=CC=CC=C1CC(C)(C)C1COC(=N1)C2=NC=C(C=C2)C(F)(F)F#N/ACN(C)C=O
538
57112/29/2021173
Gerry
jacs.9b03863
C-O Activation
x10.1021/jacs.9b038632019
11E-EOTf
VinylI
Aryl4-(tert-butyl)-5,5-dimethyl-2-(5-(trifluoromethyl)pyridin-2-yl)-4,5-dihydrooxazole
#N/A#N/A25DMFMn#N/Apy-oxNitrogenCsp2-Csp2_arWeakOO-SO2-R'XCsp2Csp2_arCsp2-OCsp2_ar-XVinyl-O[Vinyl]-O-SO2-R'Aryl-I[Aryl]-I#N/A#N/ANo baseNo BaseNo baseEasyOSO2-EWG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.53#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOS(=O)(=O)C(F)(F)FIC=CC1=CC=CC=C1C=CC1=CC=CC=C1CC(C)(C1C(C)(C)OC(C2=NC=C(C(F)(F)F)C=C2)=N1)C#N/ACN(C)C=O
539
57212/29/2021114
Shihong
j.tetlet.2006.01.145
C-O Activation
x10.1016/j.tetlet.2006.01.1452006
11.5E-NuOTs
ArylB(OH)2
Arylferrocenylmethylphosphine
#N/A#N/A25K3PO4THFTHFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar7.58Ionic-PO4K+EasyOSO2-EDG
TETRAHEDRON LETTERS
TM0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(=O)(C1=CC=C(C)C=C1)B(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C12C3(C4C5C1[Fe]23546789C%10C6C7C8C%109)C(C%11=CC=CC=C%11)P(C%12=CC=CC=C%12)C%13=CC=CC=C%13[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1CCOC1
540
57312/29/2021251
Long
acscatal.1c04800
C-O Activation
x10.1021/acscatal.1c048002021
NA
11.05E-NuOP(O)(OEt)2
CarbonylMgX
Vinyldppe
#N/A#N/A23THFTHFP-PPhosphine (Bidentate)PhosphineCsp2-Csp2StrongOO-PO(OR')2MgCsp2Csp2Csp2-OCsp2-MgCarbonyl-O[Carbonyl]-O-PO(OR')2Vinyl-MgX[Vinyl]-MgXPolar7.58No baseNo BaseNo baseHardOPO-EDG
ACS CATALYSIS
_0.0417#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!150OP(OCC)(OCC)=O[Mg]ClCC(=O)CC=CC(=O)CCC=Cc1ccc(cc1)P(CCP(c2ccccc2)c3ccccc3)c4ccccc4#N/AC1CCOC1
541
57412/29/2021251
Long
acscatal.1c04800
C-O Activation
x10.1021/acscatal.1c048002021
NA
11.05E-NuOP(O)(OEt)2
CarbonylMgX
Vinyldppe
#N/A#N/A23THFTHFP-PPhosphine (Bidentate)PhosphineCsp2-Csp2StrongOO-PO(OR')2MgCsp2Csp2Csp2-OCsp2-MgCarbonyl-O[Carbonyl]-O-PO(OR')2Vinyl-MgX[Vinyl]-MgXPolar7.58No baseNo BaseNo baseHardOPO-EDG
ACS CATALYSIS
_0.0417#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!150OP(OCC)(OCC)=O[Mg]ClCC(=O)CC=CC(=O)CCC=Cc1ccc(cc1)P(CCP(c2ccccc2)c3ccccc3)c4ccccc4#N/AC1CCOC1
542
57512/30/2021180
Long
s0040-4039(01)82980-4
C-O Activation
x10.1016/s0040-4039(01)82980-41981
12-3E-NuOP(O)(OEt)2
ArylAl(Et)2
Alkyldppp
#N/A#N/ATHFP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp3StrongOO-PO(OR')2AlCsp2_arCsp3Csp2_ar-OCsp3-AlAryl-O[Aryl]-O-PO(OR')2Alkyl-Al(Et)2[Alkyl]-Al(Et)2#N/A#N/ANo baseNo BaseNo baseHardOPO-EDG
TETRAHEDRON LETTERS
_0.0423.07#N/A#N/A#N/A#N/A#N/A#REF!XX2.2180516525.7671396463.9925956497.89806807#REF!#REF!1.1OP(OCC)(OCC)=O[Al](CC)CCC1=CC=CC=C1CCC1=CC=CC=C1CCP(c1ccccc1)(c2ccccc2)CCCP(c3ccccc3)c4ccccc4#N/AC1CCOC1
543
57612/30/2021180
Long
s0040-4039(01)82980-4
C-O Activation
x10.1016/s0040-4039(01)82980-41981
12-3E-NuOP(O)(OEt)2
ArylMgX
AlkylPPh3
#N/A#N/ATHFPPhosphine (Monodentate)PhosphineCsp2_ar-Csp3StrongOO-PO(OR')2MgCsp2_arCsp3Csp2_ar-OCsp3-MgAryl-O[Aryl]-O-PO(OR')2Alkyl-MgX[Alkyl]-MgX#N/A#N/ANo baseNo BaseNo baseHardOPO-EDG
TETRAHEDRON LETTERS
_0.0423.07#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OP(OCC)(OCC)=O[Mg]ClC1=CC=CC=C1CCC1=CC=CC=C1CCP(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3#N/AC1CCOC1
544
57712/30/2021180
Long
s0040-4039(01)82980-4
C-O Activation
x10.1016/s0040-4039(01)82980-41981
12-3E-NuOP(O)(OEt)2
ArylMgX
Alkyldppp
#N/A#N/ATHFP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp3StrongOO-PO(OR')2MgCsp2_arCsp3Csp2_ar-OCsp3-MgAryl-O[Aryl]-O-PO(OR')2Alkyl-MgX[Alkyl]-MgX#N/A#N/ANo baseNo BaseNo baseHardOPO-EDG
TETRAHEDRON LETTERS
_0.0423.07#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OP(OCC)(OCC)=O[Mg]ClC1=CC=CC=C1CCC1=CC=CC=C1CCP(c1ccccc1)(c2ccccc2)CCCP(c3ccccc3)c4ccccc4#N/AC1CCOC1
545
57812/30/2021209
Long
ol050393c
C-O Activation
x10.1021/ol050393c2005
typical procedure
11E-NuOSO2NEt2
ArylB(OH)2
ArylPPh3
#N/A#N/A80Na2CO3DMEPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2#N/A#N/AIonic-CO3Na+MediumOCO-EDG
ORGANIC LETTERS
_0.331.72.530430542.115215273.4538974810.33#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(N(CC)CC)=OB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3[Na+].[Na+].[O-]C([O-])=OCOCCOC
546
57912/30/2021209
Long
ol050393c
C-O Activation
x10.1021/ol050393c2005
typical procedure
1
1.2-2.5
E-NuOSO2NEt2
ArylMgX
ArylIMes
#N/A#N/A0-140Et2ONHCCarbeneCarbene
Csp2_ar-Csp2_ar
WeakOO-SO2-R'MgCsp2_arCsp2_arCsp2_ar-OCsp2_ar-MgAryl-O[Aryl]-O-SO2-R'Aryl-MgX[Aryl]-MgX#N/A#N/ANo baseNo BaseNo baseMediumOCO-EDG
ORGANIC LETTERS
_0.33#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2OS(=O)(N(CC)CC)=O[Mg]ClC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1CC1=CC(=C(C(=C1)C)N2C=C[N+](=C2)C3=C(C=C(C=C3C)C)C)C.[Cl-]#N/ACCOCC
547
5801/3/2022187
Kelly
anie.200900329
C-O Activation
x10.1002/anie.2009003292009
11E-NuOPiv
ArylB(OH)2
ArylPCy3
#N/A#N/A80-130K3PO4toluenetoluene
PPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
MediumOO-CO-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-CO-R'Aryl-B(OH)2[Aryl]-B(OH)2Non-Polar2.38Ionic-PO4K+MediumOCO-EDG
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
TM0.3320.282.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OC(=O)C(C)(C)CB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]Cc1ccccc1
548
5811/3/2022187
Kelly
anie.200900329
C-O Activation
x10.1002/anie.2009003292009
R=Ac11E-NuOAc
ArylB(OH)2
ArylPCy3
#N/A#N/A80-130K3PO4dioxaneH2Odioxane
PPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
MediumOO-CO-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-CO-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar2.25Ionic-PO4K+MediumOCO-EDG
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
TM0.3114.752.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OC(C)=OB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1COCCO1
549
5821/3/2022187
Kelly
anie.200900329
C-O Activation
x10.1002/anie.2009003292009
R=Piv11E-NuOPiv
ArylB(OH)2
ArylPCy3
#N/A#N/AK3PO4dioxaneH2Odioxane
PPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
MediumOO-CO-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-CO-R'Aryl-B(OH)2[Aryl]-B(OH)2Polar2.25Ionic-PO4K+MediumOCO-EDG
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
TM0.3320.282.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OC(=O)C(C)(C)CB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1COCCO1
550
5831/3/202250
Kelly
cl.2005.796
C-O Activation
x10.1246/cl.2005.7962005
R=aryl ; X=I12E-NuOTs
VinylZnX
Aryldppe
#N/A#N/A50-60THFTHFP-PPhosphine (Bidentate)PhosphineCsp2-Csp2_arWeakOO-SO2-R'ZnCsp2Csp2_arCsp2-OCsp2_ar-ZnVinyl-O[Vinyl]-O-SO2-R'Aryl-ZnX[Aryl]-ZnXPolar7.58No baseNo BaseNo baseEasyOSO2-EDG
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.36#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XOS(=O)(=O)(C1=CC=C(C)C=C1)[Zn]ClC=CC1=CC=CC=C1C=CC1=CC=CC=C1c1ccc(cc1)P(CCP(c2ccccc2)c3ccccc3)c4ccccc4#N/AC1CCOC1
551
5841/3/202250
Kelly
cl.2005.796
C-O Activation
x10.1246/cl.2005.7962005
R=het ; X=Br12E-NuOTs
VinylZnX
Hetdppe
#N/A#N/A50-60THFTHFP-PPhosphine (Bidentate)PhosphineCsp2-Csp2_arWeakOO-SO2-R'ZnCsp2Csp2_arCsp2-OCsp2_ar-ZnVinyl-O[Vinyl]-O-SO2-R'Het-ZnX[Het]-ZnXPolar7.58No baseNo BaseNo baseEasyOSO2-EDG
CHEMISTRY LETTERS
_0.36#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XOS(=O)(=O)(C1=CC=C(C)C=C1)[Zn]ClC=CC1=NC=CC=C1C=CC1=CC=NC=C1c1ccc(cc1)P(CCP(c2ccccc2)c3ccccc3)c4ccccc4#N/AC1CCOC1
552
5851/3/202250
Kelly
cl.2005.796
C-O Activation
x10.1246/cl.2005.7962005
R=vinyl ; X=Br12E-NuOTs
VinylZnX
Vinyldppe
#N/A#N/A50-60THFTHFP-PPhosphine (Bidentate)PhosphineCsp2-Csp2WeakOO-SO2-R'ZnCsp2Csp2Csp2-OCsp2-ZnVinyl-O[Vinyl]-O-SO2-R'Vinyl-ZnX[Vinyl]-ZnXPolar7.58No baseNo BaseNo baseEasyOSO2-EDG
CHEMISTRY LETTERS
_0.36#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XOS(=O)(=O)(C1=CC=C(C)C=C1)[Zn]ClC=CC=CC=CC=Cc1ccc(cc1)P(CCP(c2ccccc2)c3ccccc3)c4ccccc4#N/AC1CCOC1
553
5861/3/202250
Kelly
cl.2005.796
C-O Activation
x10.1246/cl.2005.7962005
R=alkyl ; X=Br12E-NuOTs
VinylZnX
Alkyldppe
#N/A#N/A50-60THFTHFP-PPhosphine (Bidentate)PhosphineCsp2-Csp3WeakOO-SO2-R'ZnCsp2Csp3Csp2-OCsp3-ZnVinyl-O[Vinyl]-O-SO2-R'Alkyl-ZnX[Alkyl]-ZnXPolar7.58No baseNo BaseNo baseEasyOSO2-EDG
CHEMISTRY LETTERS
_0.36#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XOS(=O)(=O)(C1=CC=C(C)C=C1)[Zn]ClC=CCCC=CCCc1ccc(cc1)P(CCP(c2ccccc2)c3ccccc3)c4ccccc4#N/AC1CCOC1
554
5871/3/202250
Kelly
cl.2005.796
C-O Activation
x10.1246/cl.2005.7962005
R=benzyl ; X=Cl
12E-NuOTs
VinylZnX
Benzyldppe
#N/A#N/A50-60THFTHFP-PPhosphine (Bidentate)Phosphine
Csp2-Csp3-ring(s)
WeakOO-SO2-R'ZnCsp2Csp3-ring(s)Csp2-OCsp3-ring(s)-ZnVinyl-O[Vinyl]-O-SO2-R'Benzyl-ZnX[Benzyl]-ZnXPolar7.58No baseNo BaseNo baseEasyOSO2-EDG
CHEMISTRY LETTERS
_0.36#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XOS(=O)(=O)(C1=CC=C(C)C=C1)[Zn]ClC=CCC1=CC=CC=C1C=CCC1=CC=CC=C1c1ccc(cc1)P(CCP(c2ccccc2)c3ccccc3)c4ccccc4#N/AC1CCOC1
555
5881/3/202251
Kelly
s0040-4039(00)94062-0
C-O Activation
x10.1016/s0040-4039(00)94062-01983
R=alkyl ; X=Cl ; ligand=dppp
12.7E-NuOP(O)(OEt)2
VinylMgX
Alkyldppp
#N/A#N/AP-PPhosphine (Bidentate)PhosphineCsp2-Csp3StrongOO-PO(OR')2MgCsp2Csp3Csp2-OCsp3-MgVinyl-O[Vinyl]-O-PO(OR')2Alkyl-MgX[Alkyl]-MgX#N/A#N/ANo baseNo BaseNo baseHardOPO-EDG
TETRAHEDRON LETTERS
_0.0417#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OP(OCC)(OCC)=O[Mg]ClC=CCCC=CCCP(c1ccccc1)(c2ccccc2)CCCP(c3ccccc3)c4ccccc4#N/A#N/A
556
5891/3/2022152
Gerry
s0040-4020(98)00809-6
C-O Activation
x10.1016/s0040-4020(98)00809-61998
11.3E-NuOMs
ArylB(OH)2
Aryldppf
#N/A#N/AK3PO4tolueneP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2#N/A#N/AIonic-PO4K+EasyOSO2-EDG
TETRAHEDRON
TM0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(=O)CB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1c1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1[O-]P(=O)([O-])[O-].[K+].[K+].[K+]Cc1ccccc1
557
5901/3/2022204
Gerry
s-2000-6287
C-O Activation
x10.1055/s-2000-62872000
1.21E-NuOTf
ArylH
thionitrosyl(R)-BINAP
#N/A#N/A110Cs2CO3tolueneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Nsp2WeakOO-SO2-R'HCsp2_arNsp2Csp2_ar-ONsp2-HAryl-O[Aryl]-O-SO2-R'thionitrosyl-H[thionitrosyl]-H#N/A#N/AIonic-CO3Cs+EasyOSO2-EWG
SYNTHESIS
_0.531.72.530430542.115215273.4538974810.33#REF!11.5#N/A1.706749553.2392069642.4729782574.96639928#REF!#REF!#N/AOS(=O)(=O)C(F)(F)FHC1=CC=CC=C1N=SC1=CC=CC=C1S=Nc1ccc(cc1)P(c2ccccc2)c3ccc4ccccc4c3-c5c(ccc6ccccc56)P(c7ccccc7)c8ccccc8C(=O)([O-])[O-].[Cs+].[Cs+]Cc1ccccc1
558
5931/4/2022148
Long
jo982060h
C-O Activation
x10.1021/jo982060h1999
11.5E-NuOPO(OPh)2
VinylMgX
Alkyldppe
#N/A#N/ArtEt2OP-PPhosphine (Bidentate)PhosphineCsp2-Csp3StrongOO-PO(OR')2MgCsp2Csp3Csp2-OCsp3-MgVinyl-O[Vinyl]-O-PO(OR')2Alkyl-MgX[Alkyl]-MgX#N/A#N/ANo baseNo BaseNo base#N/A#N/A
J ORG CHEM
_0.0428.68#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OP(OC1=CC=CC=C1)(OC2=CC=CC=C2)=O[Mg]ClC=CCCC=CCCc1ccc(cc1)P(CCP(c2ccccc2)c3ccccc3)c4ccccc4#N/ACCOCC
559
5951/4/2022205
Long
0040-4039(80)80215-2
C-O Activation
x10.1016/0040-4039(80)80215-21980
12-3E-NuOTMS
VinylMgX
AlkylPPh3
#N/A#N/APPhosphine (Monodentate)PhosphineCsp2-Csp3StrongOO-SiR'3MgCsp2Csp3Csp2-OCsp3-MgVinyl-O[Vinyl]-O-SiR'3Alkyl-MgX[Alkyl]-MgX#N/A#N/ANo baseNo BaseNo baseMediumOSiMe2-EDG
TETRAHEDRON LETTERS
_-0.2713.32#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2O[Si](C)(C)C[Mg]ClC=CCCC=CCCP(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3#N/A#N/A
560
5961/4/2022205
Long
0040-4039(80)80215-2
C-O Activation
x10.1016/0040-4039(80)80215-21980
12-3E-NuOTMS
VinylMgX
ArylPPh3
#N/A#N/APPhosphine (Monodentate)PhosphineCsp2-Csp2_arStrongOO-SiR'3MgCsp2Csp2_arCsp2-OCsp2_ar-MgVinyl-O[Vinyl]-O-SiR'3Aryl-MgX[Aryl]-MgX#N/A#N/ANo baseNo BaseNo baseMediumOSiMe2-EDG
TETRAHEDRON LETTERS
_-0.2713.32#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2O[Si](C)(C)C[Mg]ClC=CC1=CC=CC=C1C=CC1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3#N/A#N/A
561
5971/4/2022165
Long
anie.201508757
C-O Activation
x10.1002/anie.2015087572016
E-NuOH
ArylH
AlkylH8-BINAP
#N/A#N/AP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp3StrongOOHHCsp2_arCsp3Csp2_ar-OCsp3-HAryl-O[Aryl]-OHAlkyl-H[Alkyl]-H#N/A#N/ANo baseNo BaseNo baseHardOH
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.8110.94#N/A#N/A#N/A#N/A#N/A#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5OHC1=CC=CC=C1CCC1=CC=CC=C1CCc1(P(c2c(c3c4c(CCCC4)ccc3P(c5ccccc5)c6ccccc6)c7c(CCCC7)cc2)c8ccccc8)ccccc1#N/A#N/A
562
5981/4/202233
Long
jacs.9b00097
C-O Activation
x10.1021/jacs.9b000972019
12E-NuO(Ring-Opening)
AlkylMgX
Alkylrac-BINAP
#N/A#N/ArttolueneP-PPhosphine (Bidentate)PhosphineCsp3-Csp3WeakO
O(Ring-Opening)
MgCsp3Csp3Csp3-OCsp3-MgAlkyl-O[Alkyl]-O(Ring-Opening)Alkyl-MgX[Alkyl]-MgX#N/A#N/ANo baseNo BaseNo base#N/A#N/A
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_1#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OC[Mg]ClCCCCCCCCC12=CC=CC=C1C=CC(P(C3=CC=CC=C3)C4=CC=CC=C4)=C2C5=C(C=CC=C6)C6=CC=C5P7C8=CC=CCC98=C7C=CC=C9#N/ACc1ccccc1
563
5991/5/2022225
Shihong
anie.200803814
C-O Activation
x10.1002/anie.2008038142008
13E-NuOPiv
ArylZnX
ArylPCy3
#N/A#N/A70DMETHFDMEPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
MediumOO-CO-R'ZnCsp2_arCsp2_arCsp2_ar-OCsp2_ar-ZnAryl-O[Aryl]-O-CO-R'Aryl-ZnX[Aryl]-ZnXPolar7.2No baseNo BaseNo baseMediumOCO-EDG
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.3320.28#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XOC(=O)C(C)(C)C[Zn]ClC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/ACOCCOC
564
6001/5/2022225
Shihong
anie.200803814
C-O Activation
x10.1002/anie.2008038142008
13E-NuOPiv
ArylZnX
BenzylPCy3
#N/A#N/A50DMETHFDMEPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp3-ring(s)
MediumOO-CO-R'ZnCsp2_arCsp3-ring(s)Csp2_ar-OCsp3-ring(s)-ZnAryl-O[Aryl]-O-CO-R'Benzyl-ZnX[Benzyl]-ZnXPolar7.2No baseNo BaseNo baseMediumOCO-EDG
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.3320.28#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XOC(=O)C(C)(C)C[Zn]ClC1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/ACOCCOC
565
6021/5/2022239
Gerry
acs.orglett.5b02217
C-H Activation
x10.1021/acs.orglett.5b022172015
Nu-NuH
AlkylH
HetPPh3
#N/A#N/A120DTBPPPhosphine (Monodentate)PhosphineCsp3-Csp2_arNu-HHHCsp3Csp2_arCsp3-HCsp2_ar-HAlkyl-H[Alkyl]-Het-H[Het]-H#N/A#N/ANo baseNo BaseNo baseORG LETT_#N/A#N/A#N/A#N/A#N/A#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8HHCCC1=NC=CC=C1CCC1=CC=NC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3#N/AO(OC(C)(C)C)C(C)(C)C
566
6031/5/2022263
Gerry
acs.orglett.6b02166
C-H Activation
x10.1021/acs.orglett.6b021662016
21E-NuBr
AlkylH
Aryldppf
#N/A#N/A150KHCO3dioxaneP-PPhosphine (Bidentate)PhosphineCsp3-Csp2_arXHCsp3Csp2_arCsp3-XCsp2_ar-HAlkyl-X[Alkyl]-Aryl-H[Aryl]-H#N/A#N/AIonic-HCO3ORG LETT_0#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5BrHCCC1=CC=CC=C1CCC1=CC=CC=C1c1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1O=C([O-])O.[K+]C1COCCO1
567
6041/5/2022263
Gerry
acs.orglett.6b02166
C-H Activation
x10.1021/acs.orglett.6b021662016
21E-NuBr
AlkylH
Aryldppf
#N/A#N/A150KHCO3dioxaneP-PPhosphine (Bidentate)PhosphineCsp3-Csp2_arXHCsp3Csp2_arCsp3-XCsp2_ar-HAlkyl-X[Alkyl]-Aryl-H[Aryl]-H#N/A#N/AIonic-HCO3ORG LETT_0#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5BrHCCC1=CC=CC=C1CCC1=CC=CC=C1c1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1O=C([O-])O.[K+]C1COCCO1
568
6051/5/2022135
Gerry
ol4031815
C-O Activation
x10.1021/ol40318152013
12E-NuO(Ring-Opening)
VinylMgX
AlkylSiPr.HCl
#N/A#N/A-30LiClTHFNHCCarbeneCarbeneCsp2-Csp3WeakO
O(Ring-Opening)
MgCsp2Csp3Csp2-OCsp3-MgVinyl-O[Vinyl]-O(Ring-Opening)Alkyl-MgX[Alkyl]-MgX#N/A#N/ANo baseNo BaseNo base#N/A#N/A
ORGANIC LETTERS
_1#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OC[Mg]ClC=CCCC=CCCCC(c1c(N2C=[N+](c3c(C(C)C)cccc3C(C)C)CC2)c(C(C)C)ccc1)C.[Cl-]#N/AC1CCOC1
569
6061/5/2022135
Gerry
ol4031815
C-O Activation
x10.1021/ol40318152013
12E-NuO(Ring-Opening)
VinylMgX
ArylSiPr.HCl
#N/A#N/A-30LiClTHFNHCCarbeneCarbeneCsp2-Csp2_arWeakO
O(Ring-Opening)
MgCsp2Csp2_arCsp2-OCsp2_ar-MgVinyl-O[Vinyl]-O(Ring-Opening)Aryl-MgX[Aryl]-MgX#N/A#N/ANo baseNo BaseNo base#N/A#N/A
ORGANIC LETTERS
_1#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2OC[Mg]ClC=CC1=CC=CC=C1C=CC1=CC=CC=C1CC(c1c(N2C=[N+](c3c(C(C)C)cccc3C(C)C)CC2)c(C(C)C)ccc1)C.[Cl-]#N/AC1CCOC1
570
6071/5/2022139
Gerry
ol300364s
C-O Activation
x10.1021/ol300364s2012
12E-NuOEt
AllylB(OH)2
ArylPPh3
#N/A#N/A23/40dioxanet-AmylOHdioxanePPhosphine (Monodentate)PhosphineCsp3-Csp2_arStrongOO-Csp3BCsp3Csp2_arCsp3-OCsp2_ar-BAllyl-O[Allyl]-O-Csp3Aryl-B(OH)2[Aryl]-B(OH)2Polar2.25No baseNo BaseNo baseHardO-EDG
ORGANIC LETTERS
_-0.246.95#N/A#N/A#N/A#N/A#N/A#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OCCB(O)OCC=CC1=CC=CC=C1C=CCC1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3#N/AC1COCCO1
571
6081/5/2022139
Gerry
ol300364s
C-O Activation
x10.1021/ol300364s2012
12E-NuOEt
AllylB(OH)2
ArylPPh3
#N/A#N/A40dioxanet-AmylOHdioxanePPhosphine (Monodentate)PhosphineCsp3-Csp2_arStrongOO-Csp3BCsp3Csp2_arCsp3-OCsp2_ar-BAllyl-O[Allyl]-O-Csp3Aryl-B(OH)2[Aryl]-B(OH)2Polar2.25No baseNo BaseNo baseHardO-EDG
ORGANIC LETTERS
_-0.246.95#N/A#N/A#N/A#N/A#N/A#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OCCB(O)OCC=CC1=CC=CC=C1C=CCC1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3#N/AC1COCCO1
572
6091/5/2022183
Gerry
ol200267b
C-O Activation
x10.1021/ol200267b2011
11.5E-NuOSO2NMe2
ArylH
N(H)Aryldppf
#N/A#N/A105NaOtBuPhMeP-PPhosphine (Bidentate)PhosphineCsp2_ar-Nsp3WeakOO-SO2-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-SO2-R'N(H)Aryl-H[N(H)Aryl]-H#N/A#N/AIonic-OtBuNa+MediumOSO2-EDG
ORGANIC LETTERS
_0.362.8589353663.2821934583.0705644124.0077900319#REF!11.526.021.706749553.2392069642.4729782574.96639928#REF!#REF!OS(=O)(N(C)C)=OHC1=CC=CC=C1NC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1Nc1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1[Na]OC(C)(C)C#N/A
573
34011/22/2021214
Gerry
anie.201007325
C-O Activation
x10.1002/anie.2010073252011
11.2E-NuOSO2NMe2
ArylH
MorpholineSIPr
#N/A#N/A80NaOtBudioxanedioxaneNHCCarbeneCarbeneCsp2_ar-Nsp3WeakOO-SO2-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-SO2-R'Morpholine-H[Morpholine]-HPolar2.25Ionic-OtBuNa+MediumOSO2-EDG
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.362.8589353663.2821934583.0705644124.0077900319#REF!9.5921.261.706749553.2392069642.4729782574.96639928#REF!#REF!OS(=O)(N(C)C)=OHC1=CC=CC=C1N1CCCCC1C1=CC=CC=C1C1CCCCC1NCC(C)c1cccc(C(C)C)c1N2[C]N(CC2)c3c(cccc3C(C)C)C(C)C[Na]OC(C)(C)CC1COCCO1
574
40112/10/202199
Long
cs501045v
C-O Activation
x10.1021/cs501045v2014
NANAE-NuOSO2NMe2
HetH
MorpholineSiPr.HCl
#N/A#N/A80NaOtBu2-Me-THF2-Me-THFPH-B(Bin)NHCCarbeneCarbeneCsp2_ar-Nsp3WeakOO-SO2-R'HCsp2_arNsp3Csp2_ar-ONsp3-HHet-O[Het]-O-SO2-R'Morpholine-H[Morpholine]-HPolar7.53Ionic-OtBuNa+MediumOSO2-EDG
ACS CATALYSIS
_0.362.8589353663.2821934583.0705644124.0077900319#REF!9.5921.261.706749553.2392069642.4729782574.96639928#REF!#REF!OS(=O)(N(C)C)=OHC1=NC=CC=C1N1CCCCC1C1=CC=NC=C1C1CCCCC1NCC(c1c(N2C=[N+](c3c(C(C)C)cccc3C(C)C)CC2)c(C(C)C)ccc1)C.[Cl-][Na]OC(C)(C)CO1C(C)CCC1
575
6121/5/2022134
Gerry
c7cc07457c
C-N Activation
x10.1039/c7cc07457c2017
12E-NuN-pyrrolyl
CarbonylB(nep)
Aryl1,1'-((2,4,6-trimethyl-1,3-phenylene)bis(methylene))bis(3-(2,6-diisopropylphenyl)-1H-imidazol-3-ium) chloride
#N/A#N/A60K3PO4tolueneNHCCarbene (Bidentate)CarbeneCsp2-Csp2_arNBCsp2Csp2_arCsp2-NCsp2_ar-BCarbonyl-N[Carbonyl]-Aryl-B(nep)[Aryl]-B(nep)#N/A#N/AIonic-PO4K+#N/A#N/A
CHEM COMMUN
_2.244780372.9696246982.6072025343.5700586912.37#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5N1C=CC=C1B1OCC(C)(CO1)CCC(=O)CC1=CC=CC=C1C(=O)CCC1=CC=CC=C1CC1=C(CN2C=C[N+](C3=C(C(C)C)C=CC=C3C(C)C)=C2)C(C)=C(CN4C=C[N+](C5=C(C(C)C)C=CC=C5C(C)C)=C4)C(C)=C1.[Cl-].[Cl-][O-]P(=O)([O-])[O-].[K+].[K+].[K+]Cc1ccccc1
576
6131/5/2022134
Gerry
c7cc07457c
C-N Activation
x10.1039/c7cc07457c2017
12E-NuN-pyrrolyl
CarbonylB(nep)
Aryl1,1'-((2,4,6-trimethyl-1,3-phenylene)bis(methylene))bis(3-(2,6-diisopropylphenyl)-1H-imidazol-3-ium) chloride
#N/A#N/A60K3PO4tolueneNHCCarbene (Bidentate)CarbeneCsp2-Csp2_arNBCsp2Csp2_arCsp2-NCsp2_ar-BCarbonyl-N[Carbonyl]-Aryl-B(nep)[Aryl]-B(nep)#N/A#N/AIonic-PO4K+#N/A#N/A
CHEM COMMUN
_2.244780372.9696246982.6072025343.5700586912.37#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5N1C=CC=C1B1OCC(C)(CO1)CCC(=O)CC1=CC=CC=C1C(=O)CCC1=CC=CC=C1CC1=C(CN2C=C[N+](C3=C(C(C)C)C=CC=C3C(C)C)=C2)C(C)=C(CN4C=C[N+](C5=C(C(C)C)C=CC=C5C(C)C)=C4)C(C)=C1.[Cl-].[Cl-][O-]P(=O)([O-])[O-].[K+].[K+].[K+]Cc1ccccc1
577
6141/5/202283
Gerry
c8sc00609a
C-O Activation
x10.1039/c8sc00609a2018
NA12E-EMonomethyl Oxalate
BenzylBr
AlkylP(4-CF3Ph)3
#N/A#N/A30DMSODMF1:1PPhosphine (Monodentate)Phosphine
Csp3-ring(s)-Csp3
StrongOO-CO-R'XCsp3-ring(s)Csp3Csp3-ring(s)-OCsp3-XBenzyl-O[Benzyl]-O-CO-R'Alkyl-Br[Alkyl]-Br#N/A#N/ANo baseNo BaseNo base#N/A#N/A
CHEMICAL SCIENCE
_0.13#N/A#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOC(=O)C(=O)OCBrCC1=CC=CC=C1CCCC1=CC=CC=C1CCFC(C(C=C1)=CC=C1P(C2=CC=C(C(F)(F)F)C=C2)C3=CC=C(C(F)(F)F)C=C3)(F)F#N/ACS(=O)C
578
6151/5/202283
Gerry
c8sc00609a
C-O Activation
x10.1039/c8sc00609a2018
NA12E-EMonomethyl Oxalate
BenzylBr
AlkylP(4-CF3Ph)3
#N/A#N/A30DMSODMF1:1PPhosphine (Monodentate)Phosphine
Csp3-ring(s)-Csp3
StrongOO-CO-R'XCsp3-ring(s)Csp3Csp3-ring(s)-OCsp3-XBenzyl-O[Benzyl]-O-CO-R'Alkyl-Br[Alkyl]-Br#N/A#N/ANo baseNo BaseNo base#N/A#N/A
CHEMICAL SCIENCE
_0.13#N/A#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOC(=O)C(=O)OCBrCC1=CC=CC=C1CCCC1=CC=CC=C1CCFC(C(C=C1)=CC=C1P(C2=CC=C(C(F)(F)F)C=C2)C3=CC=C(C(F)(F)F)C=C3)(F)F#N/ACS(=O)C
579
6161/5/2022115
Gerry
acs.orglett.8b01021
C-N Activation
x10.1021/acs.orglett.8b010212018
12E-NuN(Me)Ph
Carbonyl9-BBN
AlkylIPr·HCl
#N/A#N/A90K2CO3LiCliPr2ONHC#N/A#N/ACsp2-Csp3NN(Ph)AlkylBCsp2Csp3Csp2-NCsp3-BCarbonyl-N[Carbonyl]-N(Ph)AlkylAlkyl-9-BBN[Alkyl]-9-BBN#N/A#N/AIonic-CO3K+#N/A#N/AORG LETT_1.72.530430542.115215273.4538974810.33#REF!19.7503.3213987613.7885441773.5549714696.18653403#REF!#REF!28.2N(C1=CC=CC=C1)B1C2CCCC1CCC2CC(=O)CCCC(=O)CCCC#N/AO=C([O-])[O-].[K+].[K+]O(C(C)C)C(C)C
580
6171/5/2022115
Gerry
acs.orglett.8b01021
C-N Activation
x10.1021/acs.orglett.8b010212018
12E-NuN(Me)Ph
Carbonyl9-BBN
AlkylIPr·HCl
#N/A#N/A90K2CO3LiCliPr2ONHC#N/A#N/ACsp2-Csp3NN(Ph)AlkylBCsp2Csp3Csp2-NCsp3-BCarbonyl-N[Carbonyl]-N(Ph)AlkylAlkyl-9-BBN[Alkyl]-9-BBN#N/A#N/AIonic-CO3K+#N/A#N/AORG LETT_1.72.530430542.115215273.4538974810.33#REF!19.7503.3213987613.7885441773.5549714696.18653403#REF!#REF!28.2N(C1=CC=CC=C1)B1C2CCCC1CCC2CC(=O)CCCC(=O)CCCC#N/AO=C([O-])[O-].[K+].[K+]O(C(C)C)C(C)C
581
6181/5/202270
Gerry
jacs.7b02326
C-O Activation
x10.1021/jacs.7b023262017
11E-EOPh
BenzylOPh
Benzyldppb
#N/A#N/A115PhMeTHF1:1P-PPhosphine (Bidentate)Phosphine
Csp3-ring(s)-Csp3-ring(s)
StrongOO-Csp2OCsp3-ring(s)Csp3-ring(s)Csp3-ring(s)-OCsp3-ring(s)-OBenzyl-O[Benzyl]-O-Csp2Benzyl-OPh[Benzyl]-OPh#N/A#N/ANo baseNo BaseNo baseHardO-EDG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_-0.32#N/A#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOC1=CC=CC=C1OC1=CC=CC=C1CC1=CC=CC=C1CC1=CC=CC=C1CC1=CC=CC=C1CC1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)CCCCP(C3=CC=CC=C3)C4=CC=CC=C4#N/A#N/A
582
6191/5/202276
Gerry
ol503061c
C-O Activation
x10.1021/ol503061c2014
11E-NuOSO2NMe2
ArylB(nep)
ArylPCy3
#N/A#N/A23K3PO4 · 3H2OTHFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(nep)[Aryl]-B(nep)#N/A#N/AIonic-PO4K+MediumOSO2-EDG
ORGANIC LETTERS
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OS(=O)(N(C)C)=OB1OCC(C)(CO1)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P([O-])([O-])=O.[K+].[K+].[K+].O.O.OC1CCOC1
583
6201/5/202276
Gerry
ol503061c
C-O Activation
x10.1021/ol503061c2014
11E-NuOSO2NMe2
ArylB(nep)
ArylPCy3
#N/A#N/A23K3PO4THFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(nep)[Aryl]-B(nep)#N/A#N/AIonic-PO4K+MediumOSO2-EDG
ORGANIC LETTERS
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OS(=O)(N(C)C)=OB1OCC(C)(CO1)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1CCOC1
584
6211/5/202276
Gerry
ol503061c
C-O Activation
x10.1021/ol503061c2014
11E-NuOSO2NMe2
ArylB(nep)
ArylPCy3
#N/A#N/A23K3PO4 · 3H2OTHFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(nep)[Aryl]-B(nep)#N/A#N/AIonic-PO4K+MediumOSO2-EDG
ORGANIC LETTERS
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OS(=O)(N(C)C)=OB1OCC(C)(CO1)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P([O-])([O-])=O.[K+].[K+].[K+].O.O.OC1CCOC1
585
6221/5/202276
Gerry
ol503061c
C-O Activation
x10.1021/ol503061c2014
11E-NuOSO2NMe2
ArylB(nep)
ArylPCy3
#N/A#N/A23K3PO4 · 3H2OTHFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(nep)[Aryl]-B(nep)#N/A#N/AIonic-PO4K+MediumOSO2-EDG
ORGANIC LETTERS
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OS(=O)(N(C)C)=OB1OCC(C)(CO1)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P([O-])([O-])=O.[K+].[K+].[K+].O.O.OC1CCOC1
586
6231/5/202274
Gerry
adsc.201400460
C-O Activation
x10.1002/adsc.2014004602014
11.5E-NuOH
ArylH
Morpholinedppf
#N/A#N/A100K3PO4dioxaneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Nsp3StrongOOHHCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-OHMorpholine-H[Morpholine]-H#N/A#N/AIonic-PO4K+HardOH
ADVANCED SYNTHESIS & CATALYSIS
_-0.8110.942.244780372.9696246982.6072025343.5700586912.37#REF!9.5921.261.706749553.2392069642.4729782574.96639928#REF!#REF!OHC1=CC=CC=C1N1CCCCC1C1=CC=CC=C1C1CCCCC1Nc1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1COCCO1
587
6231/5/202274
Gerry
adsc.201400460
C-O Activation
x10.1002/adsc.2014004602014
11.5E-NuOH
ArylH
N(Alkyl)Alkyldppf
#N/A#N/A100K3PO4dioxaneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Nsp3StrongOOHHCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-OHN(Alkyl)Alkyl-H[N(Alkyl)Alkyl]-H#N/A#N/AIonic-PO4K+HardOH
ADVANCED SYNTHESIS & CATALYSIS
_-0.8110.942.244780372.9696246982.6072025343.5700586912.37#REF!9.6512.031.706749553.2392069642.4729782574.96639928#REF!#REF!OHC1=CC=CC=C1N(C)CC1=CC=CC=C1C(C)Nc1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1COCCO1
588
6241/5/202241
Gerry
acs.orglett.6b02656
C-O Activation
x10.1021/acs.orglett.6b026562016
NA11.5E-EOMe
ArylBr
ArylItBu
#N/A#N/A60THFNHCCarbeneCarbene
Csp2_ar-Csp2_ar
StrongOO-Csp3XCsp2_arCsp2_arCsp2_ar-OCsp2_ar-XAryl-O[Aryl]-O-Csp3Aryl-Br[Aryl]-Br#N/A#N/ANo baseNo BaseNo baseHardO-EDG
ORGANIC LETTERS
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOCBrC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1CC(C)(N1C=C[N+](C(C)(C)C)=C1)C#N/AC1CCOC1
589
6251/5/202241
Gerry
acs.orglett.6b02656
C-O Activation
x10.1021/acs.orglett.6b026562016
NA11.5E-EOMe
ArylBr
ArylItBu
#N/A#N/A60THFNHCCarbeneCarbene
Csp2_ar-Csp2_ar
StrongOO-Csp3XCsp2_arCsp2_arCsp2_ar-OCsp2_ar-XAryl-O[Aryl]-O-Csp3Aryl-Br[Aryl]-Br#N/A#N/ANo baseNo BaseNo baseHardO-EDG
ORGANIC LETTERS
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOCBrC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1CC(C)(N1C=C[N+](C(C)(C)C)=C1)C#N/AC1CCOC1
590
6261/5/202241
Gerry
acs.orglett.6b02656
C-O Activation
x10.1021/acs.orglett.6b026562016
NA13E-EOH
ArylBr
ArylItBu
#N/A#N/A60PhMeTHFPhMeNHCCarbeneCarbene
Csp2_ar-Csp2_ar
StrongOOHXCsp2_arCsp2_arCsp2_ar-OCsp2_ar-XAryl-O[Aryl]-OHAryl-Br[Aryl]-Br#N/A#N/ANo baseNo BaseNo baseHardOH
ORGANIC LETTERS
_-0.8110.94#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOBrC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1CC(C)(N1C=C[N+](C(C)(C)C)=C1)C#N/A#N/A
591
6271/5/2022115
Gerry
acs.orglett.8b01021
C-N Activation
x10.1021/acs.orglett.8b010212018
12E-NuNMePh
Carbonyl9-BBN
AlkylIPr·HCl
#N/A#N/A90K2CO3LiCliPr2OiPr2ONHC#N/A#N/ACsp2-Csp3NBCsp2Csp3Csp2-NCsp3-BCarbonyl-N[Carbonyl]-Alkyl-9-BBN[Alkyl]-9-BBNPolar4.04Ionic-CO3K+#N/A#N/AORG LETT_1.72.530430542.115215273.4538974810.33#REF!19.7503.3213987613.7885441773.5549714696.18653403#REF!#REF!28.2N(C)C1=CC=CC=C1B1C2CCCC1CCC2CC(=O)CCCC(=O)CCCC#N/AO=C([O-])[O-].[K+].[K+]O(C(C)C)C(C)C
592
6281/5/202257
Shihong
cssc.201801443
C-O Activation
xx10.1002/cssc.2018014432018
12E-NuOH
BenzylH
Alkyl2,6-bis(morpholinomethyl)pyridine
#N/A#N/A110KOtBun-octanen-octaneN-N-NN-py-NNitrogen
Csp3-ring(s)-Csp3
StrongOOHHCsp3-ring(s)Csp3Csp3-ring(s)-OCsp3-HBenzyl-O[Benzyl]-OHAlkyl-H[Alkyl]-H#N/A#N/AIonic-OtBuK+HardOH
CHEMSUSCHEM
_-0.81#N/A2.8589353663.2821934583.0705644124.0077900319#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5OHCC1=CC=CC=C1CCCC1=CC=CC=C1CCC1(CN2CCOCC2)=CC=CC(CN3CCOCC3)=N1CC(C)(C)[O-].[K+]CCCCCCCC
593
6301/5/2022105
Shihong
om500452c
C-N Activation
x10.1021/om500452c2014
11.5E-NuNMe3+I-
ArylZnX
Aryl(E)-N-(2-((4-((2-(((E)-(1H-pyrrol-2-yl)methylene)amino)phenyl)(phenyl)phosphaneyl)butyl)(phenyl)phosphaneyl)phenyl)-1-(pyrrolidin-2-yl)methanimine
#N/A#N/A65THFTHFN-P-P-NMixed (N and P)Mixed
Csp2_ar-Csp2_ar
E-HNN(+)Me3ZnCsp2_arCsp2_arCsp2_ar-NCsp2_ar-ZnAryl-N[Aryl]-N(+)Me3Aryl-ZnX[Aryl]-ZnXPolar7.58No baseNo BaseNo base#N/A#N/A
ORGANOMETALLICS
_#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!X[N+](C)(C)C.[I-][Zn]ClC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1[H]N1CCCC1/C=N/C2=CC=CC=C2P(CCCCP(C3=C(/N=C/C4=CC=CN4[H])C=CC=C3)C5=CC=CC=C5)C6=CC=CC=C6#N/AC1CCOC1
594
6311/5/2022105
Shihong
om500452c
C-N Activation
x10.1021/om500452c2014
11.5E-NuOSO2NMe2
ArylMgX
Aryl(E)-N-(2-((4-((2-(((E)-(1H-pyrrol-2-yl)methylene)amino)phenyl)(phenyl)phosphaneyl)butyl)(phenyl)phosphaneyl)phenyl)-1-(pyrrolidin-2-yl)methanimine
#N/A#N/A35THFTHFN-P-P-NMixed (N and P)Mixed
Csp2_ar-Csp2_ar
WeakOO-SO2-R'MgCsp2_arCsp2_arCsp2_ar-OCsp2_ar-MgAryl-O[Aryl]-O-SO2-R'Aryl-MgX[Aryl]-MgXPolar7.58No baseNo BaseNo baseMediumOSO2-EDG
ORGANOMETALLICS
_0.36#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2OS(=O)(N(C)C)=O[Mg]ClC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1[H]N1CCCC1/C=N/C2=CC=CC=C2P(CCCCP(C3=C(/N=C/C4=CC=CN4[H])C=CC=C3)C5=CC=CC=C5)C6=CC=CC=C6#N/AC1CCOC1
595
40212/10/202199
Long
cs501045v
C-O Activation
x10.1021/cs501045v2014
NANAE-NuOSO2NMe2
ArylH
MorpholineSiPr.HCl
#N/A#N/A80NaOtBu2-Me-THF2-Me-THFPH-B(Bin)NHCCarbeneCarbeneCsp2_ar-Nsp3WeakOO-SO2-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-SO2-R'Morpholine-H[Morpholine]-HPolar7.53Ionic-OtBuNa+MediumOSO2-EDG
ACS CATALYSIS
_0.362.8589353663.2821934583.0705644124.0077900319#REF!9.5921.261.706749553.2392069642.4729782574.96639928#REF!#REF!OS(=O)(N(C)C)=OHC1=CC=CC=C1N1CCCCC1C1=CC=CC=C1C1CCCCC1NCC(c1c(N2C=[N+](c3c(C(C)C)cccc3C(C)C)CC2)c(C(C)C)ccc1)C.[Cl-][Na]OC(C)(C)CO1C(C)CCC1
596
6341/5/202253
Shihong
acs.orglett.7b00556
C-O Activation
x10.1021/acs.orglett.7b005562017
11.5E-NuOPiv
ArylH
NH2dcype
#N/A#N/A100Cs2CO3toluenetolueneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Nsp3MediumOO-CO-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-CO-R'NH2-H[NH2]-HNon-Polar2.38Ionic-CO3Cs+MediumOCO-EDG
ORGANIC LETTERS
_0.3320.281.72.530430542.115215273.4538974810.33#REF!2.26#N/A1.706749553.2392069642.4729782574.96639928#REF!#REF!#N/AOC(=O)C(C)(C)CHC1=CC=CC=C1NC1=CC=CC=C1NP(C1CCCCC1)(C2CCCCC2)CCP(C3CCCCC3)C4CCCCC4C(=O)([O-])[O-].[Cs+].[Cs+]Cc1ccccc1
597
6101/5/2022183
Gerry
ol200267b
C-O Activation
x10.1021/ol200267b2011
11.5E-NuOSO2NMe2
ArylH
MorpholineIPr·HCl#N/A#N/A#N/A105NaOtBuPhMeNHC#N/A#N/ACsp2_ar-Nsp3WeakOO-SO2-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-SO2-R'Morpholine-H[Morpholine]-H#N/A#N/AIonic-OtBuNa+MediumOSO2-EDG
ORGANIC LETTERS
_0.362.8589353663.2821934583.0705644124.0077900319#REF!9.5921.261.706749553.2392069642.4729782574.96639928#REF!#REF!OS(=O)(N(C)C)=OHC1=CC=CC=C1N1CCCCC1C1=CC=CC=C1C1CCCCC1N#N/A[Na]OC(C)(C)C#N/A
598
6111/5/2022154
Gerry
anie.201410875
C-O Activation
x10.1002/anie.2014108752015
13E-NuOTs
HetH
NH2C[C@@H](P(C1CCCCC1)C2CCCCC2)C34=C([Fe]456789%10%11C%12C8=C9C%10=C%12%11)C5C6=C37P(C%13=CC=C(C(F)(F)F)C=C%13)C%14=CC=C(C(F)(F)F)C=C%14
#N/A#N/A110NaOtButoluene/dioxanetolueneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Nsp3WeakOO-SO2-R'HCsp2_arNsp3Csp2_ar-ONsp3-HHet-O[Het]-O-SO2-R'NH2-H[NH2]-HNon-Polar2.38Ionic-OtBuNa+EasyOSO2-EDG
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.362.8589353663.2821934583.0705644124.0077900319#REF!2.26#N/A1.706749553.2392069642.4729782574.96639928#REF!#REF!#N/AOS(=O)(=O)(C1=CC=C(C)C=C1)HC1=NC=CC=C1NC1=CC=NC=C1NC[C@@H](P(C1CCCCC1)C2CCCCC2)C34=C([Fe]456789%10%11C%12C8=C9C%10=C%12%11)C5C6=C37P(C%13=CC=C(C(F)(F)F)C=C%13)C%14=CC=C(C(F)(F)F)C=C%14[Na]OC(C)(C)C#N/A
599
6321/5/202234
Kelly
acscatal.7b02014
C-O Activation
x10.1021/acscatal.7b020142017
X=OTs11.5E-NuOTs
ArylH
N(H)AlkylCyPAd-DalPhos
#N/A#N/A25NaOtButoluenetolueneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Nsp3WeakOO-SO2-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-SO2-R'N(H)Alkyl-H[N(H)Alkyl]-HNon-Polar2.38Ionic-OtBuNa+EasyOSO2-EDG
ACS CATALYSIS
_0.362.8589353663.2821934583.0705644124.0077900319#REF!5.6643.091.706749553.2392069642.4729782574.96639928#REF!#REF!OS(=O)(=O)(C1=CC=C(C)C=C1)HC1=CC=CC=C1NCC1=CC=CC=C1CNC[C@@]12C[C@](O3)(C)O[C@@](CC3(C)P1C4=CC=CC=C4P(C5CCCCC5)C6CCCCC6)(O2)C[Na]OC(C)(C)CCc1ccccc1
600
6371/5/202234
Kelly
acscatal.7b02014
C-O Activation
x10.1021/acscatal.7b020142017
11.5E-NuOSO2NMe2
ArylH
N(H)AlkylCyPAd-DalPhos
#N/A#N/A25NaOtButoluenetolueneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Nsp3WeakOO-SO2-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-SO2-R'N(H)Alkyl-H[N(H)Alkyl]-HNon-Polar2.38Ionic-OtBuNa+MediumOSO2-EDG
ACS CATALYSIS
_0.362.8589353663.2821934583.0705644124.0077900319#REF!5.6643.091.706749553.2392069642.4729782574.96639928#REF!#REF!OS(=O)(N(C)C)=OHC1=CC=CC=C1NCC1=CC=CC=C1CNC[C@@]12C[C@](O3)(C)O[C@@](CC3(C)P1C4=CC=CC=C4P(C5CCCCC5)C6CCCCC6)(O2)C[Na]OC(C)(C)CCc1ccccc1
601
6391/5/202292
Shihong
s41467-019-12949-1
C-H Activation
x10.1038/s41467-019-12949-12019
21Nu-NuB(OH)2
ArylH
VinylPBu3
#N/A#N/A70CsOPivt-AmylOHt-AmylOH(E)-3-(3,4,5-trimethoxyphenyl)acrylaldehyde (A18)PPhosphine (Monodentate)PhosphineCsp2_ar-Csp2Nu-MBHCsp2_arCsp2Csp2_ar-BCsp2-HAryl-B[Aryl]-Vinyl-H[Vinyl]-HPolar5.82Ionic-OR
NAT COMMUN
_0#REF!6.0701.706749553.2392069642.4729782574.96639928#REF!#REF!115.6B(O)OHC1=CC=CC=C1C=CC1=CC=CC=C1C=CCCCCP(CCCC)CCCCO=C(O[Cs])C(C)(C)CCCC(C)(C)O
602
6401/5/2022137
Shihong
c7sc03140h
C-O Activation
x10.1039/c7sc03140h2018
11.5E-EOH
AllylBr
Aryldppp
#N/A#N/A25ZrCl4DMADMAMnP-PPhosphine (Bidentate)PhosphineCsp3-Csp2_arStrongOOHXCsp3Csp2_arCsp3-OCsp2_ar-XAllyl-O[Allyl]-OHAryl-Br[Aryl]-BrPolar37.8No baseNo BaseNo baseHardOH
CHEMICAL SCIENCE
_-0.813.21#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOBrCC=CC1=CC=CC=C1C=CCC1=CC=CC=C1P(c1ccccc1)(c2ccccc2)CCCP(c3ccccc3)c4ccccc4#N/ACN(C)C(C)=O
603
6411/6/2022105
Long
ol5016724
C-O Activation
x10.1021/ol50167242014
11E-NuOPiv
AllylB(OH)2
ArylBenzyldiphenylphosphine
#N/A#N/ArtNaOMeMeCNPPhosphine (Monodentate)PhosphineCsp3-Csp2_arMediumOO-CO-R'BCsp3Csp2_arCsp3-OCsp2_ar-BAllyl-O[Allyl]-O-CO-R'Aryl-B(OH)2[Aryl]-B(OH)2#N/A#N/AIonic-ORNa+MediumOCO-EDG
ORGANIC LETTERS
_0.3313.3015.1#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OC(=O)C(C)(C)CB(O)OCC=CC1=CC=CC=C1C=CCC1=CC=CC=C1P(C1=CC=CC=C1)(CC2=CC=CC=C2)C3=CC=CC=C3[Na]OCCC#N
604
6421/6/2022234
Long
jacs.8b13524
C-H Activation
x10.1021/jacs.8b135242019
NANANu-NuB(OH)2
ArylH
Benzyl(4S,4'S)-2,2'-Cyclohexylidenebis[4,5-dihydro-4-phenyloxazole]
#N/A#N/A50LiOEtMeOHN-NboxNitrogen
Csp2_ar-Csp3-ring(s)
Nu-MBHCsp2_arCsp3-ring(s)Csp2_ar-BCsp3-ring(s)-HAryl-B[Aryl]-Benzyl-H[Benzyl]-H#N/A#N/AIonic-ORLi+
J AM CHEM SOC
_016#REF!12.1701.706749553.2392069642.4729782574.96639928#REF!#REF!21.3B(O)OHC1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1C1(C2(CCCCC2)C3=N[C@@H](C4=CC=CC=C4)CO3)=N[C@@H](C5=CC=CC=C5)CO1[Li]OCCCO
605
6431/6/2022182
Long
s41467-019-11392-6
C-H Activation
x10.1038/s41467-019-11392-62019
E-EBr
BenzylBr
Aryl(4R,4'S)-1,1'-bis(3-(tert-butyl)phenyl)-4,4'-diisopropyl-4,4',5,5'-tetrahydro-1H,1'H-2,2'-biimidazole
#N/A#N/AN-NN-NNitrogen
Csp3-ring(s)-Csp2_ar
XXCsp3-ring(s)Csp2_arCsp3-ring(s)-XCsp2_ar-XBenzyl-X[Benzyl]-Aryl-Br[Aryl]-Br#N/A#N/ANo baseNo BaseNo base
NAT COMMUN
_#N/A#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XBrBrCC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1CC(C)(C)C1=CC=CC(N2C[C@@H](C(C)C)N=C2C3=N[C@@H](C(C)C)CN3C4=CC=CC(C(C)(C)C)=C4)=C1#N/A#N/A
606
6441/6/202290
Long
jacs.8b01800
C-O Activation
x10.1021/jacs.8b018002018
11-5E-NuOTs
ArylH
ORPAd2-DalPhos
#N/A#N/A110Cs2CO3tolueneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Osp2WeakOO-SO2-R'HCsp2_arOsp2Csp2_ar-OOsp2-HAryl-O[Aryl]-O-SO2-R'OR-H[OR]-H#N/A#N/AIonic-CO3Cs+EasyOSO2-EDG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.361.72.530430542.115215273.4538974810.33#REF!3.2120.231.706749553.2392069642.4729782574.96639928#REF!#REF!OS(=O)(=O)(C1=CC=C(C)C=C1)HC1=CC=CC=C1OC1=CC=CC=C1OC[C@@]1(C[C@](O[C@@](C)(C2)O1)(O3)C)P(C32C)C4=CC=CC=C4P([C@]56C)C7(CC(O[C@@](C6)(C)O7)(O5)C)CC(=O)([O-])[O-].[Cs+].[Cs+]Cc1ccccc1
607
6451/6/202281
Long
chem.201505106
C-O Activation
x10.1002/chem.2015051062016
11.5E-NuOMe
ArylLi
AryliPr/PPh3
#N/A#N/ArtNHC/PTwo ligand (Carbene and monophosphine)Mixed
Csp2_ar-Csp2_ar
StrongOO-Csp3LiCsp2_arCsp2_arCsp2_ar-OCsp2_ar-LiAryl-O[Aryl]-O-Csp3Aryl-Li[Aryl]-Li#N/A#N/ANo baseNo BaseNo baseHardO-EDG
CHEMISTRY-A EUROPEAN JOURNAL
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!XX1.7061130233.2414063642.4737596946.9930727#REF!#REF!85.3OC[Li]C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1#N/A#N/A
608
6461/6/202273
Long
acs.organomet.5b00874
C-O Activation
x10.1021/acs.organomet.5b008742015
11.5E-NuOMe
ArylMgX
Aryl1,3-ditert-butyl-2H-imidazole/PCy3
#N/A#N/A25-1102-Me-THFNHC/PTwo ligand (Carbene and monophosphine)Mixed
Csp2_ar-Csp2_ar
StrongOO-Csp3MgCsp2_arCsp2_arCsp2_ar-OCsp2_ar-MgAryl-O[Aryl]-O-Csp3Aryl-MgX[Aryl]-MgX#N/A#N/ANo baseNo BaseNo baseHardO-EDG
ORGANOMETALLICS
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2OC[Mg]ClC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1#N/AO1C(C)CCC1
609
6471/6/202212
Long
jacs.1c09797
C-O Activation
x10.1021/jacs.1c097972021
E-NuO(Ring-Opening)
AlkylMgX
Aryl1,3-bis(1-(naphthalen-2-yl)ethyl)-1H-imidazol-3-ium
#N/A#N/ArtMTBENHCCarbeneCarbeneCsp3-Csp2_arWeakO
O(Ring-Opening)
MgCsp3Csp2_arCsp3-OCsp2_ar-MgAlkyl-O[Alkyl]-O(Ring-Opening)Aryl-MgX[Aryl]-MgX#N/A#N/ANo baseNo BaseNo base#N/A#N/A
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_1#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2OC[Mg]ClCCC1=CC=CC=C1CCC1=CC=CC=C1CC(C1=CC=C(C=CC=C2)C2=C1)[N+]3=CN(C(C)C4=CC(C=CC=C5)=C5C=C4)C=C3#N/AO(C(C)(C)C)C
610
6481/6/202267
Gerry
c9sc01446b
C-H Activation
x10.1039/c9sc01446b2019
21E-NuCl
AlkylH
Hetbpy
#N/A#N/A60LiHMDStolueneN-NbpyNitrogenCsp3-Csp2_arXHCsp3Csp2_arCsp3-XCsp2_ar-HAlkyl-X[Alkyl]-Het-H[Het]-H#N/A#N/AIonicNitrogen(neutral)Li+CHEM SCI_1.7105540393.2426955962.4766248184.9733801926#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8ClHCCC1=NC=CC=C1CCC1=CC=NC=C1C1(C2=NC=CC=C2)=CC=CC=N1[Li]N([Si](C)(C)C)[Si](C)(C)CCc1ccccc1
611
6491/6/202267
Gerry
c9sc01446b
C-H Activation
x10.1039/c9sc01446b2019
21E-NuCl
AlkylH
Hetbpy
#N/A#N/A60LiHMDStolueneN-NbpyNitrogenCsp3-Csp2_arXHCsp3Csp2_arCsp3-XCsp2_ar-HAlkyl-X[Alkyl]-Het-H[Het]-H#N/A#N/AIonicNitrogen(neutral)Li+CHEM SCI_1.7105540393.2426955962.4766248184.9733801926#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8ClHCCC1=NC=CC=C1CCC1=CC=NC=C1C1(C2=NC=CC=C2)=CC=CC=N1[Li]N([Si](C)(C)C)[Si](C)(C)CCc1ccccc1
612
6501/6/202267
Gerry
c9sc01446b
C-H Activation
x10.1039/c9sc01446b2019
21E-NuX
AlkylH
Hetbpy
#N/A#N/A60LiHMDStolueneN-NbpyNitrogenCsp3-Csp2_arXHCsp3Csp2_arCsp3-XCsp2_ar-HAlkyl-X[Alkyl]-Het-H[Het]-H#N/A#N/AIonicNitrogen(neutral)Li+CHEM SCI_1.7105540393.2426955962.4766248184.9733801926#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8ClHCCC1=NC=CC=C1CCC1=CC=NC=C1C1(C2=NC=CC=C2)=CC=CC=N1[Li]N([Si](C)(C)C)[Si](C)(C)CCc1ccccc1
613
6551/6/2022333
Shihong
ja501093m
C-N Activation
x10.1021/ja501093m2014
NaNaE-NuOMe
ArylMgX
ArylPCy3
#N/A#N/A100t-AmylOEtt-AmylOEtPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
StrongOO-Csp3MgCsp2_arCsp2_arCsp2_ar-OCsp2_ar-MgAryl-O[Aryl]-O-Csp3Aryl-MgX[Aryl]-MgX#N/A#N/ANo baseNo BaseNo baseHardO-EDG
J AM CHEM SOC
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2OC[Mg]ClC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/ACCC(C)(OCC)C
614
6571/6/202268
Long
j.tet.2013.04.096
C-O Activation
x10.1016/j.tet.2013.04.0962013
NANAE-NuOPiv
ArylH
Aryldcype
#N/A#N/ACs2CO3m-xyleneP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
MediumOO-CO-R'HCsp2_arCsp2_arCsp2_ar-OCsp2_ar-HAryl-O[Aryl]-O-CO-R'Aryl-H[Aryl]-H#N/A#N/AIonic-CO3Cs+MediumOCO-EDG
TETRAHEDRON
_0.3320.281.72.530430542.115215273.4538974810.33#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5OC(=O)C(C)(C)CHC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(C1CCCCC1)(C2CCCCC2)CCP(C3CCCCC3)C4CCCCC4C(=O)([O-])[O-].[Cs+].[Cs+]Cc1cccc(c1)C
615
6581/6/202224
Long
jacs.0c01330
C-O Activation
x10.1021/jacs.0c013302020
NA
DCM is main solvent in support information
NANAE-EOMs
AlkylOMs
Alkynerac-BINAP
#N/A#N/ADCMtolueneDCMP-PPhosphine (Bidentate)PhosphineCsp3-Csp1WeakOO-SO2-R'OCsp3Csp1Csp3-OCsp1-OAlkyl-O[Alkyl]-O-SO2-R'Alkyne-OMs[Alkyne]-OMsPolar8.93No baseNo BaseNo baseEasyOSO2-EDG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.36#N/A#N/A#N/A#N/A#N/A#REF!#N/A#N/A0#REF!#REF!#N/AOS(=O)(=O)COS(=O)(=O)CCCC#CCCC#CC12=CC=CC=C1C=CC(P(C3=CC=CC=C3)C4=CC=CC=C4)=C2C5=C(C=CC=C6)C6=CC=C5P7C8=CC=CCC98=C7C=CC=C9#N/AClCCl
616
6591/6/202224
Long
jacs.0c01330
C-O Activation
x10.1021/jacs.0c013302020
NA
DCM is main solvent in support information
NANAE-EOMs
AlkylOMs
Alkynerac-BINAP
#N/A#N/ADCMtolueneDCMP-PPhosphine (Bidentate)PhosphineCsp3-Csp1WeakOO-SO2-R'OCsp3Csp1Csp3-OCsp1-OAlkyl-O[Alkyl]-O-SO2-R'Alkyne-OMs[Alkyne]-OMsPolar8.93No baseNo BaseNo baseEasyOSO2-EDG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.36#N/A#N/A#N/A#N/A#N/A#REF!#N/A#N/A0#REF!#REF!#N/AOS(=O)(=O)COS(=O)(=O)CCCC#CCCC#CC12=CC=CC=C1C=CC(P(C3=CC=CC=C3)C4=CC=CC=C4)=C2C5=C(C=CC=C6)C6=CC=C5P7C8=CC=CCC98=C7C=CC=C9#N/AClCCl
617
6601/6/2022115
Shihong
acs.orglett.5b03151
C-O Activation
x10.1021/acs.orglett.5b031512015
NA11E-EOMe
ArylOMe
ArylICy.HCl
#N/A#N/A120NaOtButoluenetolueneNHCCarbeneCarbene
Csp2_ar-Csp2_ar
StrongOO-Csp3OCsp2_arCsp2_arCsp2_ar-OCsp2_ar-OAryl-O[Aryl]-O-Csp3Aryl-OMe[Aryl]-OMeNon-Polar2.38Ionic-OtBuNa+HardO-EDG
ORGANIC LETTERS
_-0.2812.862.8589353663.2821934583.0705644124.0077900319#REF!0#REF!#REF!OCOCC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1[n+]1(C2CCCCC2)cn(C3CCCCC3)cc1.[Cl-][Na]OC(C)(C)CCc1ccccc1
618
13211/5/2021108
Shihong
jacs.7b04279
C-O Activation
x10.1021/jacs.7b042792017
11.5E-NuOMe
ArylB(nep)
ArylICy
#N/A#N/A120NaOtButoluenetolueneNHCCarbeneCarbene
Csp2_ar-Csp2_ar
StrongOO-Csp3BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-Csp3Aryl-B(nep)[Aryl]-B(nep)Non-Polar2.38Ionic-OtBuNa+#N/A#N/A
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_-0.2812.862.8589353663.2821934583.0705644124.0077900319#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OCB1OCC(C)(CO1)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1N1(C2CCCCC2)C=CN(C3CCCCC3)[C]1[Na]OC(C)(C)CCc1ccccc1
619
6611/6/2022104
Long
jacs.8b02134
C-O Activation
x10.1021/jacs.8b021342018
12E-NuOMe
VinylMgX
ArylIPr
#N/A#N/A70-1202-Me-THFNHCCarbeneCarbeneCsp2-Csp2_arStrongOO-Csp3MgCsp2Csp2_arCsp2-OCsp2_ar-MgVinyl-O[Vinyl]-O-Csp3Aryl-MgX[Aryl]-MgX#N/A#N/ANo baseNo BaseNo baseHardO-EDG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_-0.286.71#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2OC[Mg]ClC=CC1=CC=CC=C1C=CC1=CC=CC=C1CC(C)C(C=CC=C1C(C)C)=C1N2C=CN(C3=C(C(C)C)C=CC=C3C(C)C)C2#N/AO1C(C)CCC1
620
6621/6/2022104
Long
jacs.8b02134
C-O Activation
x10.1021/jacs.8b021342018
12E-NuOMe
VinylMgX
ArylIcy
#N/A#N/A70-1202-Me-THFNHCCarbeneCarbeneCsp2-Csp2_arStrongOO-Csp3MgCsp2Csp2_arCsp2-OCsp2_ar-MgVinyl-O[Vinyl]-O-Csp3Aryl-MgX[Aryl]-MgX#N/A#N/ANo baseNo BaseNo baseHardO-EDG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_-0.286.71#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2OC[Mg]ClC=CC1=CC=CC=C1C=CC1=CC=CC=C1N1(C2CCCCC2)C=CN(C3CCCCC3)[C]1#N/AO1C(C)CCC1
621
6631/6/202278
Shihong
acs.orglett.6b01398
C-O Activation
x10.1021/acs.orglett.6b013982016
NaNaE-NuOTs
AlkylBF3K
Aryl2,4-Bis(diisopropylphosphinoamino)-6-(dimethylamino)-1,3,5-triazine
#N/A#N/A120K3PO4toluenetolueneN-N-NMixed (N and P)NitrogenCsp3-Csp2_arWeakOO-SO2-R'BCsp3Csp2_arCsp3-OCsp2_ar-BAlkyl-O[Alkyl]-O-SO2-R'Aryl-BF3K[Aryl]-BF3KNon-Polar2.38Ionic-PO4K+EasyOSO2-EDG
ORGANIC LETTERS
TM0.362.244780372.9696246982.6072025343.5700586912.37#REF!11.8902.2294683593.2807152032.7550917816.56810798#REF!#REF!150.1OS(=O)(=O)(C1=CC=C(C)C=C1)[B-](F)(F)F.[K+]CCC1=CC=CC=C1CCC1=CC=CC=C1CN(C1=NC(NP(C(C)C)C(C)C)=NC(NP(C(C)C)C(C)C)=N1)C[O-]P(=O)([O-])[O-].[K+].[K+].[K+]Cc1ccccc1
622
6641/6/2022159
Long
anie.201101191
C-O Activation
x10.1002/anie.2011011912011
NANAE-NuO(Ring-Opening)
AlkylB(OH)2
ArylBrettPhos
#N/A#N/AK3PO4toluenePPhosphine (Monodentate)PhosphineCsp3-Csp2_arWeakO
O(Ring-Opening)
BCsp3Csp2_arCsp3-OCsp2_ar-BAlkyl-O[Alkyl]-O(Ring-Opening)Aryl-B(OH)2[Aryl]-B(OH)2#N/A#N/AIonic-PO4K+#N/A#N/A
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
TM12.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OCB(O)OCCC1=CC=CC=C1CCC1=CC=CC=C1[O-]P(=O)([O-])[O-].[K+].[K+].[K+]Cc1ccccc1
623
6671/6/202215
Shihong
anie.202006826
C-O Activation
x10.1002/anie.2020068262020
130E-NuOPiv
ArylH
Carbonylcyclopentane;dicyclohexyl-[2-(1-diphenylphosphanylethyl)cyclopenta-2,4-dien-1-yl]phosphane;iron
#N/A#N/ACs2CO3PhCF3PhCF3P-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp2MediumOO-CO-R'HCsp2_arCsp2Csp2_ar-OCsp2-HAryl-O[Aryl]-O-CO-R'Carbonyl-H[Carbonyl]-H#N/A#N/AIonic-CO3Cs+MediumOCO-EDG
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.3320.281.72.530430542.115215273.4538974810.33#REF!4.517.071.706749553.2392069642.4729782574.96639928#REF!#REF!199.9OC(=O)C(C)(C)CHC1=CC=CC=C1CC(=O)CC1=CC=CC=C1C(=O)CCCC(C1(C23P(C4CCCCC4)C5CCCCC5)C6C7C2[Fe]71689%10%113C%12C8C9C%10C%12%11)P(C%13=CC=CC=C%13)C%14=CC=CC=C%14C(=O)([O-])[O-].[Cs+].[Cs+]FC(F)(F)C1=CC=CC=C1
624
6681/6/2022231
jo00041a004
C-O Activation
x10.1021/jo00041a0041992
R is Ph11-2E-NuOTf
ArylMgX
Aryldppp
#N/A#N/Art2-Me-THFP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'MgCsp2_arCsp2_arCsp2_ar-OCsp2_ar-MgAryl-O[Aryl]-O-SO2-R'Aryl-MgX[Aryl]-MgX#N/A#N/ANo baseNo BaseNo baseEasyOSO2-EWG
JOURNAL OF ORGANIC CHEMISTRY
_0.53#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2OS(=O)(=O)C(F)(F)F[Mg]ClC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(c1ccccc1)(c2ccccc2)CCCP(c3ccccc3)c4ccccc4#N/AO1C(C)CCC1
625
6691/6/2022231
jo00041a004
C-O Activation
x10.1021/jo00041a0041992
R is n-Bu11-2E-NuOTf
ArylMgX
Alkyldppp
#N/A#N/Art2-Me-THFP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp3WeakOO-SO2-R'MgCsp2_arCsp3Csp2_ar-OCsp3-MgAryl-O[Aryl]-O-SO2-R'Alkyl-MgX[Alkyl]-MgX#N/A#N/ANo baseNo BaseNo baseEasyOSO2-EWG
JOURNAL OF ORGANIC CHEMISTRY
_0.53#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OS(=O)(=O)C(F)(F)F[Mg]ClC1=CC=CC=C1CCC1=CC=CC=C1CCP(c1ccccc1)(c2ccccc2)CCCP(c3ccccc3)c4ccccc4#N/AO1C(C)CCC1
626
6601/6/2022115
Shihong
acs.orglett.5b03151
C-O Activation
x10.1021/acs.orglett.5b031512015
11E-NuOMe
ArylB(nep)
ArylICy.HCl
#N/A#N/A120NaOtButoluenetolueneNHCCarbeneCarbene
Csp2_ar-Csp2_ar
StrongOO-Csp3BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-Csp3Aryl-B(nep)[Aryl]-B(nep)Non-Polar2.38Ionic-OtBuNa+HardO-EDG
ORGANIC LETTERS
_-0.2812.862.8589353663.2821934583.0705644124.0077900319#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OCB1OCC(C)(CO1)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1[n+]1(C2CCCCC2)cn(C3CCCCC3)cc1.[Cl-][Na]OC(C)(C)CCc1ccccc1
627
6711/6/2022206
Shihong
jo1024464
C-O Activation
x10.1021/jo10244642011
12.5E-NuOCONEt2
ArylB(OH)2
ArylPCy3
#N/A#N/A180K3PO4toluenetoluene
heat by microwave
PPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
MediumOO-CO-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-CO-R'Aryl-B(OH)2[Aryl]-B(OH)2Non-Polar2.38Ionic-PO4K+MediumOCO-EDG
JOURNAL OF ORGANIC CHEMISTRY
TM0.3121.412.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OC(N(CC)CC)=OB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]Cc1ccccc1
628
6721/6/20228
Shihong
anie.202114556
C-O Activation
x10.1002/anie.2021145562022
13.5E-EOAc
VinylBr
Alkyldiglyme#N/A#N/A#N/A40DMADMAZn#N/A#N/A#N/ACsp2-Csp3MediumOO-CO-R'XCsp2Csp3Csp2-OCsp3-XVinyl-O[Vinyl]-O-CO-R'Alkyl-Br[Alkyl]-BrPolar37.8No baseNo BaseNo baseMediumOCO-EDG
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.318.64#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOC(C)=OBrC=CCCC=CCC#N/A#N/ACN(C)C(C)=O
629
6731/10/2022140
Gerry
anie.201601206
C-O Activation
x10.1002/anie.2016012062016
11E-NuOPiv
AlkylH
Arylbphen
#N/A#N/A25/45DMAN-NbpyNitrogenCsp3-Csp2_arMediumOO-CO-R'HCsp3Csp2_arCsp3-OCsp2_ar-HAlkyl-O[Alkyl]-O-CO-R'Aryl-H[Aryl]-H#N/A#N/ANo baseNo BaseNo baseMediumOCO-EDG
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.3313.3#N/A#N/A#N/A#N/A#N/A#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5OC(=O)C(C)(C)CHCCC1=CC=CC=C1CCC1=CC=CC=C1C1(C2=CC=CC=C2)=CC=NC3=C1C=CC4=C3N=CC=C4C5=CC=CC=C5#N/ACN(C)C(C)=O
630
6741/10/2022140
Gerry
anie.201601206
C-O Activation
x10.1002/anie.2016012062016
NA12.2E-EOPiv
BenzylI
Aryldppf
#N/A#N/A25/40DMAP-PPhosphine (Bidentate)Phosphine
Csp3-ring(s)-Csp2_ar
MediumOO-CO-R'XCsp3-ring(s)Csp2_arCsp3-ring(s)-OCsp2_ar-XBenzyl-O[Benzyl]-O-CO-R'Aryl-I[Aryl]-I#N/A#N/ANo baseNo BaseNo baseMediumOCO-EDG
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.33#N/A#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOC(=O)C(C)(C)CICC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1c1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1#N/ACN(C)C(C)=O
631
6381/5/202234
Kelly
acscatal.7b02014
C-O Activation
x10.1021/acscatal.7b020142017
11.5E-NuOMs
ArylH
N(H)AlkylCyPAd-DalPhos
#N/A#N/A110NaOtBudioxanedioxaneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Nsp3WeakOO-SO2-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-SO2-R'N(H)Alkyl-H[N(H)Alkyl]-HPolar2.25Ionic-OtBuNa+EasyOSO2-EDG
ACS CATALYSIS
_0.362.8589353663.2821934583.0705644124.0077900319#REF!5.6643.091.706749553.2392069642.4729782574.96639928#REF!#REF!OS(=O)(=O)CHC1=CC=CC=C1NCC1=CC=CC=C1CNC[C@@]12C[C@](O3)(C)O[C@@](CC3(C)P1C4=CC=CC=C4P(C5CCCCC5)C6CCCCC6)(O2)C[Na]OC(C)(C)CC1COCCO1
632
6751/10/2022117
Gerry
om300566m
C-O Activation
x10.1021/om300566m2012
11.5E-NuOTs
ArylH
MorpholineIPr
#N/A#N/A110LiOtBudioxaneNHCCarbeneCarbeneCsp2_ar-Nsp3WeakOO-SO2-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-SO2-R'Morpholine-H[Morpholine]-H#N/A#N/AIonic-OtBuLi+EasyOSO2-EDG
ORGANOMETALLICS
_0.362.8589353663.2821934583.0705644124.0077900319#REF!9.5921.261.706749553.2392069642.4729782574.96639928#REF!#REF!OS(=O)(=O)(C1=CC=C(C)C=C1)HC1=CC=CC=C1N1CCCCC1C1=CC=CC=C1C1CCCCC1NCC(C)C(C=CC=C1C(C)C)=C1N2C=CN(C3=C(C(C)C)C=CC=C3C(C)C)C2CC(C)(C)[O-].[Li+]C1COCCO1
633
6751/10/2022117
Gerry
om300566m
C-O Activation
x10.1021/om300566m2012
11.5E-NuOTs
ArylH
N(H)ArylIPr
#N/A#N/A110LiOtBudioxaneNHCCarbeneCarbeneCsp2_ar-Nsp3WeakOO-SO2-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-SO2-R'N(H)Aryl-H[N(H)Aryl]-H#N/A#N/AIonic-OtBuLi+EasyOSO2-EDG
ORGANOMETALLICS
_0.362.8589353663.2821934583.0705644124.0077900319#REF!11.526.021.706749553.2392069642.4729782574.96639928#REF!#REF!OS(=O)(=O)(C1=CC=C(C)C=C1)HC1=CC=CC=C1NC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1NCC(C)C(C=CC=C1C(C)C)=C1N2C=CN(C3=C(C(C)C)C=CC=C3C(C)C)C2CC(C)(C)[O-].[Li+]C1COCCO1
634
6751/10/2022117
Gerry
om300566m
C-O Activation
x10.1021/om300566m2012
11.5E-NuOTs
ArylH
N(Alkyl)ArylIPr
#N/A#N/A110LiOtBudioxaneNHCCarbeneCarbeneCsp2_ar-Nsp3WeakOO-SO2-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-SO2-R'N(Alkyl)Aryl-H[N(Alkyl)Aryl]-H#N/A#N/AIonic-OtBuLi+EasyOSO2-EDG
ORGANOMETALLICS
_0.362.8589353663.2821934583.0705644124.0077900319#REF!15.1912.031.706749553.2392069642.4729782574.96639928#REF!#REF!OS(=O)(=O)(C1=CC=C(C)C=C1)HC1=CC=CC=C1N(C)C(C(=O)C)C1=CC=CC=C1CC(=O)CN(C)CC(C)C(C=CC=C1C(C)C)=C1N2C=CN(C3=C(C(C)C)C=CC=C3C(C)C)C2CC(C)(C)[O-].[Li+]C1COCCO1
635
6771/10/202245
Gerry
acs.joc.6b01627
C-O Activation
x10.1021/acs.joc.6b016272016
11.5E-NuOCONEt2
ArylB(nep)
Aryl1,3-Di(2-adamantyl)-1H-imidazole-3-ium
#N/A#N/A150K3PO4tolueneNHCCarbeneCarbene
Csp2_ar-Csp2_ar
MediumOO-CO-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-CO-R'Aryl-B(nep)[Aryl]-B(nep)#N/A#N/AIonic-PO4K+MediumOCO-EDG
JOURNAL OF ORGANIC CHEMISTRY
TM0.3121.412.244780372.9696246982.6072025343.5700586912.37#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OC(N(CC)CC)=OB1OCC(C)(CO1)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1CC1C[C@H]2C[C@@H](C1[N+]3=CN(C=C3)C4C5C[C@H](C6)C[C@@H]4C[C@H]6C5)C[C@H](C2)C[O-]P(=O)([O-])[O-].[K+].[K+].[K+]Cc1ccccc1
636
6781/10/202245
Gerry
acs.joc.6b01627
C-O Activation
x10.1021/acs.joc.6b016272016
11.5E-NuOCONEt2
ArylB(nep)
Aryl1,3-Di(2-adamantyl)-1H-imidazole-3-ium
#N/A#N/A150K3PO4tolueneNHCCarbeneCarbene
Csp2_ar-Csp2_ar
MediumOO-CO-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-CO-R'Aryl-B(nep)[Aryl]-B(nep)#N/A#N/AIonic-PO4K+MediumOCO-EDG
JOURNAL OF ORGANIC CHEMISTRY
TM0.3121.412.244780372.9696246982.6072025343.5700586912.37#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OC(N(CC)CC)=OB1OCC(C)(CO1)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1CC1C[C@H]2C[C@@H](C1[N+]3=CN(C=C3)C4C5C[C@H](C6)C[C@@H]4C[C@H]6C5)C[C@H](C2)C[O-]P(=O)([O-])[O-].[K+].[K+].[K+]Cc1ccccc1
637
6791/10/202211
Gerry
acscatal.1c05208
C-O Activation
x10.1021/acscatal.1c052082022
NA
11E-EOH
AlkylBr
Aryl4,4'-di-tert-butyl-N-cyano-[2,2'-bipyridine]-6-carboximidamide
#N/A#N/A80Barton's base
POP/TBAB
CH3CNN-NbpyNitrogenCsp3-Csp2_arStrongOOHXCsp3Csp2_arCsp3-OCsp2_ar-XAlkyl-O[Alkyl]-OHAryl-Br[Aryl]-Br#N/A#N/A#N/A#N/A#N/AHardOH
ACS CATALYSIS
_-0.813.21#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOBrCCC1=CC=CC=C1CCC1=CC=CC=C1N=C(NC#N)C1=NC(C2=NC=CC(C(C)(C)C)=C2)=CC(C(C)(C)C)=C1#N/ACH3CN
638
6801/10/202211
Gerry
acscatal.1c05208
C-O Activation
x10.1021/acscatal.1c052082022
NA
11E-EOH
AlkylX
Aryl4,4'-di-tert-butyl-N-cyano-[2,2'-bipyridine]-6-carboximidamide
#N/A#N/A80Barton's base
POP/TBAB
CH3CNN-NbpyNitrogenCsp3-Csp2_arStrongOOHXCsp3Csp2_arCsp3-OCsp2_ar-XAlkyl-O[Alkyl]-OHAryl-X[Aryl]-X#N/A#N/A#N/A#N/A#N/AHardOH
ACS CATALYSIS
_-0.813.21#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOClCCC1=CC=CC=C1CCC1=CC=CC=C1N=C(NC#N)C1=NC(C2=NC=CC(C(C)(C)C)=C2)=CC(C(C)(C)C)=C1#N/ACH3CN
639
6811/10/202296
Gerry
c4cc08187k
C-O Activation
x10.1039/c4cc08187k2015
No ligand11.3E-NuOMe
VinylLi
Csp3-Si#N/A#N/A#N/A60toluene#N/A#N/A#N/ACsp2-Csp3StrongOO-Csp3LiCsp2Csp3Csp2-OCsp3-LiVinyl-O[Vinyl]-O-Csp3Csp3-Si-Li[Csp3-Si]-Li#N/A#N/ANo baseNo BaseNo baseHardO-EDG
CHEMICAL COMMUNICATIONS
_-0.286.71#N/A#N/A#N/A#N/A#N/A#REF!XX1.7061130233.2414063642.4737596946.9930727#REF!#REF!4OC[Li]C=CC[Si](C)(C)CC=CC[Si](C)(C)C#N/A#N/ACc1ccccc1
640
6821/10/202296
Gerry
c4cc08187k
C-O Activation
x10.1039/c4cc08187k2015
No ligand11.3E-NuOTMS
VinylLi
Csp3-Si#N/A#N/A#N/A60toluene#N/A#N/A#N/ACsp2-Csp3StrongOO-SiR'3LiCsp2Csp3Csp2-OCsp3-LiVinyl-O[Vinyl]-O-SiR'3Csp3-Si-Li[Csp3-Si]-Li#N/A#N/ANo baseNo BaseNo baseMediumOSiMe2-EDG
CHEMICAL COMMUNICATIONS
_-0.2713.32#N/A#N/A#N/A#N/A#N/A#REF!XX1.7061130233.2414063642.4737596946.9930727#REF!#REF!4O[Si](C)(C)C[Li]C=CC[Si](C)(C)CC=CC[Si](C)(C)C#N/A#N/ACc1ccccc1
641
6831/10/202296
Gerry
c4cc08187k
C-O Activation
x10.1039/c4cc08187k2015
11.3E-NuO(Ring-Opening)
VinylLi
Csp3-SiSiPr.HCl
#N/A#N/A-10tolueneNHCCarbeneCarbeneCsp2-Csp3WeakO
O(Ring-Opening)
LiCsp2Csp3Csp2-OCsp3-LiVinyl-O[Vinyl]-O(Ring-Opening)Csp3-Si-Li[Csp3-Si]-Li#N/A#N/ANo baseNo BaseNo base#N/A#N/A
CHEMICAL COMMUNICATIONS
_1#N/A#N/A#N/A#N/A#N/A#REF!XX1.7061130233.2414063642.4737596946.9930727#REF!#REF!4OC[Li]C=CC[Si](C)(C)CC=CC[Si](C)(C)CCC(c1c(N2C=[N+](c3c(C(C)C)cccc3C(C)C)CC2)c(C(C)C)ccc1)C.[Cl-]#N/ACc1ccccc1
642
6841/10/202239
Gerry
acs.orglett.5b00241
C-O Activation
x10.1021/acs.orglett.5b002412015
11.5E-EOTf
ArylCO2K
Aryldppf
#N/A#N/A140diglymeP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'Csp2Csp2_arCsp2_arCsp2_ar-OCsp2_ar-Csp2Aryl-O[Aryl]-O-SO2-R'Aryl-CO2K[Aryl]-CO2K#N/A#N/ANo baseNo BaseNo baseEasyOSO2-EWG
ORGANIC LETTERS
_0.53#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOS(=O)(=O)C(F)(F)FC([O-])=O.[K+]C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1c1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1#N/ACOCCOCCOC
643
6851/10/202239
Gerry
acs.orglett.5b00241
C-O Activation
x10.1021/acs.orglett.5b002412015
11.5E-EOTs
ArylCO2K
Aryldppf
#N/A#N/A140-160diglymeP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'Csp2Csp2_arCsp2_arCsp2_ar-OCsp2_ar-Csp2Aryl-O[Aryl]-O-SO2-R'Aryl-CO2K[Aryl]-CO2K#N/A#N/ANo baseNo BaseNo baseEasyOSO2-EDG
ORGANIC LETTERS
_0.36#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOS(=O)(=O)(C1=CC=C(C)C=C1)C([O-])=O.[K+]C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1c1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1#N/ACOCCOCCOC
644
6861/11/2022203
Gerry
c0cc03107k
C-O Activation
x10.1039/c0cc03107k2010
E-NuOTs
ArylB(OH)2
ArylPPh3
#N/A#N/A100K3PO4dioxanePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2#N/A#N/AIonic-PO4K+EasyOSO2-EDG
CHEMICAL COMMUNICATIONS
TM0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(=O)(C1=CC=C(C)C=C1)B(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1COCCO1
645
6871/11/2022203
Gerry
c0cc03107k
C-O Activation
x10.1039/c0cc03107k2010
E-NuOMs
ArylB(OH)2
ArylPPh3
#N/A#N/A100K3PO4dioxanePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2#N/A#N/AIonic-PO4K+EasyOSO2-EDG
CHEMICAL COMMUNICATIONS
TM0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(=O)CB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1COCCO1
646
6901/11/2022181
Kelly
ol300891k
C-O Activation
x10.1021/ol300891k2012
12E-NuOCCOMe
ArylMgX
AlkylDPEphos
#N/A#N/A0toluenetolueneP-O-PP-O-PMixedCsp2_ar-Csp3StrongOO-Csp3MgCsp2_arCsp3Csp2_ar-OCsp3-MgAryl-O[Aryl]-O-Csp3Alkyl-MgX[Alkyl]-MgXNon-Polar2.38No baseNo BaseNo base#N/A#N/A
ORGANIC LETTERS
_-0.2417.22#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OCCOC[Mg]ClC1=CC=CC=C1CCC1=CC=CC=C1CCO(c1ccccc1P(c2ccccc2)c3ccccc3)c4ccccc4P(c5ccccc5)c6ccccc6#N/ACc1ccccc1
647
6911/11/2022181
Kelly
ol300891k
C-O Activation
x10.1021/ol300891k2012
12E-NuOCCOMe
BenzylMgX
AlkylDPEphos
#N/A#N/A0toluenetolueneP-O-PP-O-PMixed
Csp3-ring(s)-Csp3
StrongOO-Csp3MgCsp3-ring(s)Csp3Csp3-ring(s)-OCsp3-MgBenzyl-O[Benzyl]-O-Csp3Alkyl-MgX[Alkyl]-MgXNon-Polar2.38No baseNo BaseNo base#N/A#N/A
ORGANIC LETTERS
_-0.24#N/A#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OCCOC[Mg]ClCC1=CC=CC=C1CCCC1=CC=CC=C1CCO(c1ccccc1P(c2ccccc2)c3ccccc3)c4ccccc4P(c5ccccc5)c6ccccc6#N/ACc1ccccc1
648
6921/11/2022181
Kelly
ol300891k
C-O Activation
x10.1021/ol300891k2012
12E-NuOCCOMe
ArylMgX
AlkylDPEphos
#N/A#N/A5toluenetolueneP-O-PP-O-PMixedCsp2_ar-Csp3StrongOO-Csp3MgCsp2_arCsp3Csp2_ar-OCsp3-MgAryl-O[Aryl]-O-Csp3Alkyl-MgX[Alkyl]-MgXNon-Polar2.38No baseNo BaseNo base#N/A#N/A
ORGANIC LETTERS
_-0.2417.22#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OCCOC[Mg]ClC1=CC=CC=C1CCC1=CC=CC=C1CCO(c1ccccc1P(c2ccccc2)c3ccccc3)c4ccccc4P(c5ccccc5)c6ccccc6#N/ACc1ccccc1
649
6931/11/2022181
Kelly
ol300891k
C-O Activation
x10.1021/ol300891k2012
Entry311.5E-NuOCCOMe
BenzylMgX
AlkylDPEphos
#N/A#N/A0toluenetolueneP-O-PP-O-PMixed
Csp3-ring(s)-Csp3
StrongOO-Csp3MgCsp3-ring(s)Csp3Csp3-ring(s)-OCsp3-MgBenzyl-O[Benzyl]-O-Csp3Alkyl-MgX[Alkyl]-MgXNon-Polar2.38No baseNo BaseNo base#N/A#N/A
ORGANIC LETTERS
_-0.24#N/A#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OCCOC[Mg]ClCC1=CC=CC=C1CCCC1=CC=CC=C1CCO(c1ccccc1P(c2ccccc2)c3ccccc3)c4ccccc4P(c5ccccc5)c6ccccc6#N/ACc1ccccc1
650
6941/11/2022181
Kelly
ol300891k
C-O Activation
x10.1021/ol300891k2012
Entry513E-NuOCCOMe
BenzylMgX
AlkylDPEphos
#N/A#N/A0toluenetolueneP-O-PP-O-PMixed
Csp3-ring(s)-Csp3
StrongOO-Csp3MgCsp3-ring(s)Csp3Csp3-ring(s)-OCsp3-MgBenzyl-O[Benzyl]-O-Csp3Alkyl-MgX[Alkyl]-MgXNon-Polar2.38No baseNo BaseNo base#N/A#N/A
ORGANIC LETTERS
_-0.24#N/A#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OCCOC[Mg]ClCC1=CC=CC=C1CCCC1=CC=CC=C1CCO(c1ccccc1P(c2ccccc2)c3ccccc3)c4ccccc4P(c5ccccc5)c6ccccc6#N/ACc1ccccc1
651
6951/11/2022142
Kelly
chem.201102984
C-O Activation
x10.1002/chem.2011029842012
X=I21E-EOCO2Me
AllylI
AlkylCC(C)[C@H]1COC(C2=CC=CC(C3=N[C@H](CO3)C(C)C)=N2)=N1#N/A#N/A#N/A35CuIDMADMAZn#N/A#N/A#N/ACsp3-Csp3MediumOO-CO-R'XCsp3Csp3Csp3-OCsp3-XAllyl-O[Allyl]-O-CO-R'Alkyl-I[Alkyl]-IPolar37.8#N/ANo Base#N/A#N/A#N/A
CHEMISTRY-A EUROPEAN JOURNAL
_0.318.58#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOC(=O)OCICC=CCCC=CCCC#N/A#N/ACN(C)C(C)=O
652
6961/11/2022142
Kelly
chem.201102984
C-O Activation
x10.1002/chem.2011029842012
X=Br21E-EOCO2Me
AllylBr
Alkyl2,6-bis((3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazol-2-yl)pyridine
#N/A#N/A80MgCl2DMADMAZnN-N-NpyboxNitrogenCsp3-Csp3MediumOO-CO-R'XCsp3Csp3Csp3-OCsp3-XAllyl-O[Allyl]-O-CO-R'Alkyl-Br[Alkyl]-BrPolar37.8#N/ANo Base#N/A#N/A#N/A
CHEMISTRY-A EUROPEAN JOURNAL
_0.318.58#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOC(=O)OCBrCC=CCCC=CCCC[H][C@]12[C@](CC3=C2C=CC=C3)([H])OC(C4=CC=CC(C5=N[C@](C(C=CC=C6)=C6C7)([H])[C@]7([H])O5)=N4)=N1#N/ACN(C)C(C)=O
653
6971/11/2022142
Kelly
chem.201102984
C-O Activation
x10.1002/chem.2011029842012
X=I21E-EOCO2Me
AllylI
Alkyl2,2'-(4-methoxypyridine-2,6-diyl)bis(4,5-dihydrooxazole)
#N/A#N/A35CuIDMADMAZnN-N-NpyboxNitrogenCsp3-Csp3MediumOO-CO-R'XCsp3Csp3Csp3-OCsp3-XAllyl-O[Allyl]-O-CO-R'Alkyl-I[Alkyl]-IPolar37.8#N/ANo Base#N/A#N/A#N/A
CHEMISTRY-A EUROPEAN JOURNAL
_0.318.58#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOC(=O)OCICC=CCCC=CCCCCOC1=CC(C2=NC([H])CO2)=NC(C3=NC([H])CO3)=C1#N/ACN(C)C(C)=O
654
6981/11/2022142
Kelly
chem.201102984
C-O Activation
x10.1002/chem.2011029842012
X=Br21E-EOCO2Me
AllylBr
Alkyl2,2'-(4-methoxypyridine-2,6-diyl)bis(4,5-dihydrooxazole)
#N/A#N/A80MgCl2DMADMAZnN-N-NpyboxNitrogenCsp3-Csp3MediumOO-CO-R'XCsp3Csp3Csp3-OCsp3-XAllyl-O[Allyl]-O-CO-R'Alkyl-Br[Alkyl]-BrPolar37.8#N/ANo Base#N/A#N/A#N/A
CHEMISTRY-A EUROPEAN JOURNAL
_0.318.58#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOC(=O)OCBrCC=CCCC=CCCCCOC1=CC(C2=NC([H])CO2)=NC(C3=NC([H])CO3)=C1#N/ACN(C)C(C)=O
655
6991/11/2022128
Kelly
c39940001789
C-O Activation
x10.1039/c399400017891994
L=PPh3E-NuOCO2Et
AllylB(OMe)3-Li+
ArylPPh3
#N/A#N/A50-60THFTHFPPhosphine (Monodentate)PhosphineCsp3-Csp2_arMediumOO-CO-R'BCsp3Csp2_arCsp3-OCsp2_ar-BAllyl-O[Allyl]-O-CO-R'Aryl-B(OMe)3-Li+[Aryl]-B(OMe)3-Li+Polar7.58No baseNo BaseNo base#N/A#N/A
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS
_0.3110.39#N/A#N/A#N/A#N/A#N/A#REF!20.2927.690#REF!#REF!XOC(OCC)=O[B-](OC)(OC)OC.[Li+]CC=CC1=CC=CC=C1C=CCC1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3#N/AC1CCOC1
656
7001/11/2022128
Kelly
c39940001789
C-O Activation
x10.1039/c399400017891994
L=dppf, R=arylE-NuOCO2Et
AllylB(OMe)3-Li+
Aryldppf
#N/A#N/A50-60THFTHFP-PPhosphine (Bidentate)PhosphineCsp3-Csp2_arMediumOO-CO-R'BCsp3Csp2_arCsp3-OCsp2_ar-BAllyl-O[Allyl]-O-CO-R'Aryl-B(OMe)3-Li+[Aryl]-B(OMe)3-Li+Polar7.58No baseNo BaseNo base#N/A#N/A
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS
_0.3110.39#N/A#N/A#N/A#N/A#N/A#REF!20.2927.690#REF!#REF!XOC(OCC)=O[B-](OC)(OC)OC.[Li+]CC=CC1=CC=CC=C1C=CCC1=CC=CC=C1c1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1#N/AC1CCOC1
657
7011/11/2022128
Kelly
c39940001789
C-O Activation
x10.1039/c399400017891994
L=dppf, R=vinyl
E-NuOCO2Et
AllylB(OMe)3-Li+
Vinyldppf
#N/A#N/A50-60THFTHFP-PPhosphine (Bidentate)PhosphineCsp3-Csp2MediumOO-CO-R'BCsp3Csp2Csp3-OCsp2-BAllyl-O[Allyl]-O-CO-R'Vinyl-B(OMe)3-Li+[Vinyl]-B(OMe)3-Li+Polar7.58No baseNo BaseNo base#N/A#N/A
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS
_0.3110.39#N/A#N/A#N/A#N/A#N/A#REF!15.9727.690#REF!#REF!XOC(OCC)=O[B-](OC)(OC)OC.[Li+]CC=CC=CC=CCC=Cc1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1#N/AC1CCOC1
658
7021/11/2022127
Kelly
acs.joc.5b00135
C-O Activation
x10.1021/acs.joc.5b001352015
NA11E-EOTs
AlkylBr
Aryldtbbpy
#N/A#N/A80KIDMADMA
4-ethylpyridine
MnN-NbpyNitrogenCsp3-Csp2_arWeakOO-SO2-R'XCsp3Csp2_arCsp3-OCsp2_ar-XAlkyl-O[Alkyl]-O-SO2-R'Aryl-Br[Aryl]-BrPolar37.8#N/ANo Base#N/AEasyOSO2-EDG
JOURNAL OF ORGANIC CHEMISTRY
_0.36#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOS(=O)(=O)(C1=CC=C(C)C=C1)BrCCC1=CC=CC=C1CCC1=CC=CC=C1CC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/ACN(C)C(C)=O
659
7031/11/2022127
Kelly
acs.joc.5b00135
C-O Activation
x10.1021/acs.joc.5b001352015
NA11E-EOTs
AlkylBr
Hetdtbbpy
#N/A#N/A80KIDMADMA
4-ethylpyridine
MnN-NbpyNitrogenCsp3-Csp2_arWeakOO-SO2-R'XCsp3Csp2_arCsp3-OCsp2_ar-XAlkyl-O[Alkyl]-O-SO2-R'Het-Br[Het]-BrPolar37.8#N/ANo Base#N/AEasyOSO2-EDG
JOURNAL OF ORGANIC CHEMISTRY
_0.36#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOS(=O)(=O)(C1=CC=C(C)C=C1)BrCCC1=NC=CC=C1CCC1=CC=NC=C1CC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/ACN(C)C(C)=O
660
7041/11/2022122
Kelly
c1sc00026h
C-O Activation
x10.1039/c1sc00026h2011
21E-NuOEt
AllylB(OH)2
ArylPPh3
#N/A#N/A40dioxanet-AmylOHdioxanePPhosphine (Monodentate)PhosphineCsp3-Csp2_arStrongOO-Csp3BCsp3Csp2_arCsp3-OCsp2_ar-BAllyl-O[Allyl]-O-Csp3Aryl-B(OH)2[Aryl]-B(OH)2Polar2.25No baseNo BaseNo baseHardO-EDG
CHEMICAL SCIENCE
_-0.246.95#N/A#N/A#N/A#N/A#N/A#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OCCB(O)OCC=CC1=CC=CC=C1C=CCC1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3#N/AC1COCCO1
661
7051/11/2022106
Kelly
chem.201000420
C-O Activation
x10.1002/chem.2010004202010
Ligand=dppb12E-NuOBOP
ArylB(OH)2
Aryldppb
#N/A#N/A100K2CO3dioxanedioxaneP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
StrongOO-PO(OR')2BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-PO(OR')2Aryl-B(OH)2[Aryl]-B(OH)2Polar2.25No baseNo BaseNo base#N/A#N/A
CHEMISTRY-A EUROPEAN JOURNAL
_0.0427.92#N/A#N/A#N/A#N/A#N/A#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OP(N1CCOC1=O)(N2CCOC2=O)=OB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)CCCCP(C3=CC=CC=C3)C4=CC=CC=C4#N/AC1COCCO1
662
7061/11/2022106
Kelly
chem.201000420
C-O Activation
x10.1002/chem.2010004202010
Ligand=dppe12E-NuOBOP
ArylB(OH)2
Aryldppe
#N/A#N/A100K2CO3dioxanedioxaneP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
StrongOO-PO(OR')2BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-PO(OR')2Aryl-B(OH)2[Aryl]-B(OH)2Polar2.25No baseNo BaseNo base#N/A#N/A
CHEMISTRY-A EUROPEAN JOURNAL
_0.0427.92#N/A#N/A#N/A#N/A#N/A#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OP(N1CCOC1=O)(N2CCOC2=O)=OB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1c1ccc(cc1)P(CCP(c2ccccc2)c3ccccc3)c4ccccc4#N/AC1COCCO1
663
7071/11/2022106
Kelly
chem.201000420
C-O Activation
x10.1002/chem.2010004202010
Ligand=dppp12E-NuOBOP
ArylB(OH)2
Aryldppp
#N/A#N/A100K2CO3dioxanedioxaneP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
StrongOO-PO(OR')2BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-PO(OR')2Aryl-B(OH)2[Aryl]-B(OH)2Polar2.25No baseNo BaseNo base#N/A#N/A
CHEMISTRY-A EUROPEAN JOURNAL
_0.0427.92#N/A#N/A#N/A#N/A#N/A#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OP(N1CCOC1=O)(N2CCOC2=O)=OB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(c1ccccc1)(c2ccccc2)CCCP(c3ccccc3)c4ccccc4#N/AC1COCCO1
664
7081/11/2022106
Kelly
chem.201000420
C-O Activation
x10.1002/chem.2010004202010
12E-NuOBOP
ArylB(OH)2
Aryldppp
#N/A#N/A100K2CO3dioxanedioxaneP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
StrongOO-PO(OR')2BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-PO(OR')2Aryl-B(OH)2[Aryl]-B(OH)2Polar2.25No baseNo BaseNo base#N/A#N/A
CHEMISTRY-A EUROPEAN JOURNAL
_0.0427.92#N/A#N/A#N/A#N/A#N/A#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OP(N1CCOC1=O)(N2CCOC2=O)=OB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(c1ccccc1)(c2ccccc2)CCCP(c3ccccc3)c4ccccc4#N/AC1COCCO1
665
7091/14/2022170
Gerry
0040-4039(96)01984-3
C-O Activation
x10.1016/0040-4039(96)01984-31996
13E-NuOTs
ArylB(nep)
ArylPPh3
#N/A#N/A20/60THFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(nep)[Aryl]-B(nep)#N/A#N/ANo baseNo BaseNo baseEasyOSO2-EDG
TETRAHEDRON LETTERS
_0.36#N/A#N/A#N/A#N/A#N/A#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OS(=O)(=O)(C1=CC=C(C)C=C1)B1OCC(C)(CO1)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3#N/AC1CCOC1
666
7101/14/2022170
Gerry
0040-4039(96)01984-3
C-O Activation
x10.1016/0040-4039(96)01984-31996
13E-NuOMs
ArylB(nep)
Aryldppf
#N/A#N/A25THFP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(nep)[Aryl]-B(nep)#N/A#N/ANo baseNo BaseNo baseEasyOSO2-EDG
TETRAHEDRON LETTERS
_0.36#N/A#N/A#N/A#N/A#N/A#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OS(=O)(=O)CB1OCC(C)(CO1)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1c1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1#N/AC1CCOC1
667
7111/14/202216
Gerry
s41467-020-20725-9
C-O Activation
x10.1038/s41467-020-20725-92021
12E-NuOCOPh
VinylB(OH)2
Aryldppf
#N/A#N/A60-100K2CO3dioxaneP-PPhosphine (Bidentate)PhosphineCsp2-Csp2_arStrongOO-CO-R'BCsp2Csp2_arCsp2-OCsp2_ar-BVinyl-O[Vinyl]-O-CO-R'Aryl-B(OH)2[Aryl]-B(OH)2#N/A#N/AIonic-CO3K+#N/A#N/A
NATURE COMMUNICATIONS
_0.1316.341.72.530430542.115215273.4538974810.33#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OC(=O)C1=CC=CC=C1B(O)OC=CC1=CC=CC=C1C=CC1=CC=CC=C1c1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1#N/AC1COCCO1
668
7121/14/202232
Gerry
jacs.9b02751
C-O Activation
x10.1021/jacs.9b027512019
11E-EOCONMe2
ArylPhenyl Formate
MorpholinePS-DPPBz
#N/A#N/A160tolueneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Nsp3MediumOO-CO-R'Csp2Csp2_arNsp3Csp2_ar-ONsp3-Csp2Aryl-O[Aryl]-O-CO-R'Morpholine-Phenyl Formate[Morpholine]-Phenyl Formate#N/A#N/ANo baseNo BaseNo baseMediumOCO-EDG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.3117.73#N/A#N/A#N/A#N/A#N/A#REF!XX1.9062301575.4149849213.6606075396.65201005#REF!#REF!OC(=O)N(C)CC(=O)OCC1=CC=CC=C1C1=CC=CC=C1N1CCCCC1C1=CC=CC=C1C1CCCCC1NNA#N/ACc1ccccc1
669
7121/14/202232
Gerry
jacs.9b02751
C-O Activation
x10.1021/jacs.9b027512019
11E-EOCONMe2
ArylPhenyl Formate
N(Alkyl)AlkylPS-DPPBz
#N/A#N/A160tolueneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Nsp3MediumOO-CO-R'Csp2Csp2_arNsp3Csp2_ar-ONsp3-Csp2Aryl-O[Aryl]-O-CO-R'N(Alkyl)Alkyl-Phenyl Formate[N(Alkyl)Alkyl]-Phenyl Formate#N/A#N/ANo baseNo BaseNo baseMediumOCO-EDG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.3117.73#N/A#N/A#N/A#N/A#N/A#REF!XX1.9062301575.4149849213.6606075396.65201005#REF!#REF!OC(=O)N(C)CC(=O)OCC1=CC=CC=C1C1=CC=CC=C1N(C)CC1=CC=CC=C1C(C)NNA#N/ACc1ccccc1
670
7131/14/202262
Gerry
s0022-328x(02)01174-9
C-O Activation
x10.1016/s0022-328x(02)01174-92002
13E-NuOTs
ArylB(nep)
ArylPPh3
#N/A#N/A20/60THFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(nep)[Aryl]-B(nep)#N/A#N/ANo baseNo BaseNo baseEasyOSO2-EDG
JOURNAL OF ORGANOMETALLIC CHEMISTRY
_0.36#N/A#N/A#N/A#N/A#N/A#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OS(=O)(=O)(C1=CC=C(C)C=C1)B1OCC(C)(CO1)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3#N/AC1CCOC1
671
7141/14/202262
Gerry
s0022-328x(02)01174-9
C-O Activation
x10.1016/s0022-328x(02)01174-92002
13E-NuOMs
ArylB(nep)
Aryldppf
#N/A#N/A25THFP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(nep)[Aryl]-B(nep)#N/A#N/ANo baseNo BaseNo baseEasyOSO2-EDG
JOURNAL OF ORGANOMETALLIC CHEMISTRY
_0.36#N/A#N/A#N/A#N/A#N/A#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OS(=O)(=O)CB1OCC(C)(CO1)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1c1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1#N/AC1CCOC1
672
7151/14/2022150
Gerry
ncomms14878
C-O Activation
x10.1038/ncomms148782017
11.2E-EOMe
CarbonylOH
N(H)Arylphen
#N/A#N/A90NMPN-NbpyNitrogenCsp2-Nsp3StrongOO-Csp3OCsp2Nsp3Csp2-ONsp3-OCarbonyl-O[Carbonyl]-O-Csp3N(H)Aryl-OH[N(H)Aryl]-OH#N/A#N/ANo baseNo BaseNo baseHardO-EDG
NATURE COMMUNICATIONS
_-0.286.71#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOCOCC(=O)CNC1=CC=CC=C1C(=O)CCC1=CC=CC=C1NC1(C(N=CC=C2)=C2C=C3)=C3C=CC=N1#N/ACN1CCCC1=O
673
6761/10/2022117
Gerry
om300566m
C-O Activation
x10.1021/om300566m2012
11.5E-NuOTs
ArylH
N(H)ArylIPr
#N/A#N/A110LiOtBudioxaneNHCCarbeneCarbeneCsp2_ar-Nsp3WeakOO-SO2-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-SO2-R'N(H)Aryl-H[N(H)Aryl]-H#N/A#N/AIonic-OtBuLi+EasyOSO2-EDG
ORGANOMETALLICS
_0.362.8589353663.2821934583.0705644124.0077900319#REF!11.526.021.706749553.2392069642.4729782574.96639928#REF!#REF!OS(=O)(=O)(C1=CC=C(C)C=C1)HC1=CC=CC=C1NC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1NCC(C)C(C=CC=C1C(C)C)=C1N2C=CN(C3=C(C(C)C)C=CC=C3C(C)C)C2#N/AC1COCCO1
674
8733/10/2022261
Gerry
ncomms11073
C-O Activation
x10.1038/ncomms110732016
11.1E-NuOTs
ArylH
N(Alkyl)AlkylPAd-DalPhos
#N/A#N/A25NaOtButoluene#N/APhosphine (Bidentate)PhosphineCsp2_ar-Nsp3WeakOO-SO2-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-SO2-R'N(Alkyl)Alkyl-H[N(Alkyl)Alkyl]-H#N/A#N/AIonic-OtBuNa+EasyOSO2-EDG
NATURE COMMUNICATIONS
_0.362.8589353663.2821934583.0705644124.0077900319#REF!9.6512.031.706749553.2392069642.4729782574.96639928#REF!#REF!OS(=O)(=O)(C1=CC=C(C)C=C1)HC1=CC=CC=C1N(C)CC1=CC=CC=C1C(C)NC[C@@]12C[C@@]3(C)OC(C)(P1C4=CC=CC=C4P(C5=C(C)C=CC=C5)C6=C(C)C=CC=C6)C[C@](O2)(C)O3#N/ACc1ccccc1
675
610/31/2021107
Long
acscatal.6b00865
C-O Activation
x10.1021/acscatal.6b008652016
2.53E-NuOFs
ArylH
N(H)Aryldppf
#N/A#N/A100LiOtBuMeCNtoluenetolueneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Nsp3WeakOO-SO2-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-SO2-R'N(H)Aryl-H[N(H)Aryl]-HNon-Polar2.38Ionic-OtBuLi+EasyOSO2-EWG
ACS CATALYSIS
_0.532.8589353663.2821934583.0705644124.0077900319#REF!11.526.021.706749553.2392069642.4729782574.96639928#REF!#REF!OS(=O)(F)=OHC1=CC=CC=C1NC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1Nc1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1#N/ACC#N
676
710/31/2021107
Long
acscatal.6b00865
C-O Activation
x10.1021/acscatal.6b008652016
NA2.53E-NuOFs
ArylH
Morpholinedppf
#N/A#N/A100LiOtBuMeCNtoluenetolueneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Nsp3WeakOO-SO2-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-SO2-R'Morpholine-H[Morpholine]-HNon-Polar2.38Ionic-OtBuLi+EasyOSO2-EWG
ACS CATALYSIS
_0.532.8589353663.2821934583.0705644124.0077900319#REF!9.5921.261.706749553.2392069642.4729782574.96639928#REF!#REF!OS(=O)(F)=OHC1=CC=CC=C1N1CCCCC1C1=CC=CC=C1C1CCCCC1Nc1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1#N/ACC#N
677
7201/16/202236
Kelly
c9sc03347e
C-O Activation
x10.1039/c9sc03347e2019
11.8E-EOTf
VinylOMs
Arylterpyridine
#N/A#N/A100DMADMAMnN-N-NterpyNitrogenCsp2-Csp2_arWeakOO-SO2-R'OCsp2Csp2_arCsp2-OCsp2_ar-OVinyl-O[Vinyl]-O-SO2-R'Aryl-OMs[Aryl]-OMsPolar37.8No baseNo BaseNo baseEasyOSO2-EWG
CHEMICAL SCIENCE
_0.53#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!OS(=O)(=O)C(F)(F)FOS(=O)(=O)CC=CC1=CC=CC=C1C=CC1=CC=CC=C1c1ccnc(c1)c2cccc(n2)c3ccccn3#N/ACN(C)C(C)=O
678
7211/16/202236
Kelly
c9sc03347e
C-O Activation
x10.1039/c9sc03347e2019
primary alcohol derivatives
11.8E-EOTf
VinylOMs
Arylterpyridine
#N/A#N/A100DMADMAMnN-N-NterpyNitrogenCsp2-Csp2_arWeakOO-SO2-R'OCsp2Csp2_arCsp2-OCsp2_ar-OVinyl-O[Vinyl]-O-SO2-R'Aryl-OMs[Aryl]-OMsPolar37.8No baseNo BaseNo baseEasyOSO2-EWG
CHEMICAL SCIENCE
_0.53#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!OS(=O)(=O)C(F)(F)FOS(=O)(=O)CC=CC1=CC=CC=C1C=CC1=CC=CC=C1c1ccnc(c1)c2cccc(n2)c3ccccn3#N/ACN(C)C(C)=O
679
7221/16/202236
Kelly
c9sc03347e
C-O Activation
x10.1039/c9sc03347e2019
secondary alcohol derivatives
11.8E-EOTf
VinylOMs
Arylterpyridine
#N/A#N/A100DMADMAMnN-N-NterpyNitrogenCsp2-Csp2_arWeakOO-SO2-R'OCsp2Csp2_arCsp2-OCsp2_ar-OVinyl-O[Vinyl]-O-SO2-R'Aryl-OMs[Aryl]-OMsPolar37.8No baseNo BaseNo baseEasyOSO2-EWG
CHEMICAL SCIENCE
_0.53#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!OS(=O)(=O)C(F)(F)FOS(=O)(=O)CC=CC1=CC=CC=C1C=CC1=CC=CC=C1c1ccnc(c1)c2cccc(n2)c3ccccn3#N/ACN(C)C(C)=O
680
7231/16/202236
Kelly
c9sc03347e
C-O Activation
x10.1039/c9sc03347e2019
b11.8E-EOTf
VinylOTs
Arylterpyridine
#N/A#N/A100DMADMAMnN-N-NterpyNitrogenCsp2-Csp2_arWeakOO-SO2-R'OCsp2Csp2_arCsp2-OCsp2_ar-OVinyl-O[Vinyl]-O-SO2-R'Aryl-OTs[Aryl]-OTsPolar37.8No baseNo BaseNo baseEasyOSO2-EWG
CHEMICAL SCIENCE
_0.53#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!OS(=O)(=O)C(F)(F)FOS(=O)(=O)(C1=CC=C(C)C=C1)C=CC1=CC=CC=C1C=CC1=CC=CC=C1c1ccnc(c1)c2cccc(n2)c3ccccn3#N/ACN(C)C(C)=O
681
7241/16/202236
Kelly
c9sc03347e
C-O Activation
x10.1039/c9sc03347e2019
c11.8E-EOTf
VinylOTs
Arylterpyridine
#N/A#N/A40DMADMAMnN-N-NterpyNitrogenCsp2-Csp2_arWeakOO-SO2-R'OCsp2Csp2_arCsp2-OCsp2_ar-OVinyl-O[Vinyl]-O-SO2-R'Aryl-OTs[Aryl]-OTsPolar37.8No baseNo BaseNo baseEasyOSO2-EWG
CHEMICAL SCIENCE
_0.53#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!OS(=O)(=O)C(F)(F)FOS(=O)(=O)(C1=CC=C(C)C=C1)C=CC1=CC=CC=C1C=CC1=CC=CC=C1c1ccnc(c1)c2cccc(n2)c3ccccn3#N/ACN(C)C(C)=O
682
7251/16/202236
Kelly
c9sc03347e
C-O Activation
x10.1039/c9sc03347e2019
12E-EOTf
ArylOTs
Arylbphen
#N/A#N/ArtLiBrKBrCH3CNDMSOCH3CNMnStyreneN-NbpyNitrogen
Csp2_ar-Csp2_ar
WeakOO-SO2-R'OCsp2_arCsp2_arCsp2_ar-OCsp2_ar-OAryl-O[Aryl]-O-SO2-R'Aryl-OTs[Aryl]-OTs#N/A#N/A#N/ANo Base#N/AEasyOSO2-EWG
CHEMICAL SCIENCE
_0.53#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!OS(=O)(=O)C(F)(F)FOS(=O)(=O)(C1=CC=C(C)C=C1)C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1(C2=CC=CC=C2)=CC=NC3=C1C=CC4=C3N=CC=C4C5=CC=CC=C5#N/ACH3CN
683
7261/16/202236
Kelly
c9sc03347e
C-O Activation
x10.1039/c9sc03347e2019
12E-EOTf
ArylOTs
Arylbphen
#N/A#N/ArtLiBrKBrCH3CNDMSOCH3CNMnStyreneN-NbpyNitrogen
Csp2_ar-Csp2_ar
WeakOO-SO2-R'OCsp2_arCsp2_arCsp2_ar-OCsp2_ar-OAryl-O[Aryl]-O-SO2-R'Aryl-OTs[Aryl]-OTs#N/A#N/A#N/ANo Base#N/AEasyOSO2-EWG
CHEMICAL SCIENCE
_0.53#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!OS(=O)(=O)C(F)(F)FOS(=O)(=O)(C1=CC=C(C)C=C1)C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1(C2=CC=CC=C2)=CC=NC3=C1C=CC4=C3N=CC=C4C5=CC=CC=C5#N/ACH3CN
684
7271/16/202235
Kelly
acscatal.9b03352
C-O Activation
x10.1021/acscatal.9b033522019
11.5E-EOTs
AlkylBr
Alkyldtbbpy
#N/A#N/A30DMFDMFMnVitamin B12N-NbpyNitrogenCsp3-Csp3WeakOO-SO2-R'XCsp3Csp3Csp3-OCsp3-XAlkyl-O[Alkyl]-O-SO2-R'Alkyl-Br[Alkyl]-BrPolar36.7No baseNo BaseNo baseEasyOSO2-EDG
ACS CATALYSIS
_0.36#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOS(=O)(=O)(C1=CC=C(C)C=C1)BrCCCCCCCCCC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/ACN(C)C=O
685
7281/16/202235
Kelly
acscatal.9b03352
C-O Activation
x10.1021/acscatal.9b033522019
R-Cl1.51E-EOTs
AlkylCl
Alkyldtbbpy
#N/A#N/A30DMFDMFpyrazineMnVitamin B12N-NbpyNitrogenCsp3-Csp3WeakOO-SO2-R'XCsp3Csp3Csp3-OCsp3-XAlkyl-O[Alkyl]-O-SO2-R'Alkyl-Cl[Alkyl]-ClPolar36.7No baseNo BaseNo baseEasyOSO2-EDG
ACS CATALYSIS
_0.36#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOS(=O)(=O)(C1=CC=C(C)C=C1)ClCCCCCCCCCC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/ACN(C)C=O
686
7291/16/202235
Kelly
acscatal.9b03352
C-O Activation
x10.1021/acscatal.9b033522019
1.51E-EOTs
AlkylCl
Alkyldtbbpy
#N/A#N/A30DMFDMFpyrazineMnVitamin B12N-NbpyNitrogenCsp3-Csp3WeakOO-SO2-R'XCsp3Csp3Csp3-OCsp3-XAlkyl-O[Alkyl]-O-SO2-R'Alkyl-Cl[Alkyl]-ClPolar36.7No baseNo BaseNo baseEasyOSO2-EDG
ACS CATALYSIS
_0.36#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOS(=O)(=O)(C1=CC=C(C)C=C1)ClCCCCCCCCCC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/ACN(C)C=O
687
7301/16/202235
Kelly
acscatal.9b03352
C-O Activation
x10.1021/acscatal.9b033522019
R=Br, without pyrazine
11.5E-EOTs
AlkylBr
Alkyldtbbpy
#N/A#N/A30DMFDMFMnVitamin B12N-NbpyNitrogenCsp3-Csp3WeakOO-SO2-R'XCsp3Csp3Csp3-OCsp3-XAlkyl-O[Alkyl]-O-SO2-R'Alkyl-Br[Alkyl]-BrPolar36.7No baseNo BaseNo baseEasyOSO2-EDG
ACS CATALYSIS
_0.36#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOS(=O)(=O)(C1=CC=C(C)C=C1)BrCCCCCCCCCC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/ACN(C)C=O
688
7321/16/202249
Kelly
acs.joc.6b02564
C-O Activation
x10.1021/acs.joc.6b025642017
12E-NuOH
AllylZnX
Aryldppe
#N/A#N/A120toluenenBu2OtolueneP-PPhosphine (Bidentate)PhosphineCsp3-Csp2_arStrongOOHZnCsp3Csp2_arCsp3-OCsp2_ar-ZnAllyl-O[Allyl]-OHAryl-ZnX[Aryl]-ZnXNon-Polar2.38No baseNo BaseNo baseHardOH
JOURNAL OF ORGANIC CHEMISTRY
_-0.813.21#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XO[Zn]ClCC=CC1=CC=CC=C1C=CCC1=CC=CC=C1c1ccc(cc1)P(CCP(c2ccccc2)c3ccccc3)c4ccccc4#N/ACc1ccccc1
689
7331/16/202249
Kelly
acs.joc.6b02564
C-O Activation
x10.1021/acs.joc.6b025642017
12E-NuOH
BenzylZnX
Vinyldppe
#N/A#N/A120toluenenBu2OtolueneP-PPhosphine (Bidentate)Phosphine
Csp3-ring(s)-Csp2
StrongOOHZnCsp3-ring(s)Csp2Csp3-ring(s)-OCsp2-ZnBenzyl-O[Benzyl]-OHVinyl-ZnX[Vinyl]-ZnXNon-Polar2.38No baseNo BaseNo baseHardOH
JOURNAL OF ORGANIC CHEMISTRY
_-0.81#N/A#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XO[Zn]ClCC1=CC=CC=C1C=CCC1=CC=CC=C1C=Cc1ccc(cc1)P(CCP(c2ccccc2)c3ccccc3)c4ccccc4#N/ACc1ccccc1
690
7341/16/202249
Kelly
acs.joc.6b02564
C-O Activation
x10.1021/acs.joc.6b025642017
12E-NuOH
AllylZnX
Aryldppe
#N/A#N/A120toluenenBu2OtolueneP-PPhosphine (Bidentate)PhosphineCsp3-Csp2_arStrongOOHZnCsp3Csp2_arCsp3-OCsp2_ar-ZnAllyl-O[Allyl]-OHAryl-ZnX[Aryl]-ZnXNon-Polar2.38No baseNo BaseNo baseHardOH
JOURNAL OF ORGANIC CHEMISTRY
_-0.813.21#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XO[Zn]ClCC=CC1=CC=CC=C1C=CCC1=CC=CC=C1c1ccc(cc1)P(CCP(c2ccccc2)c3ccccc3)c4ccccc4#N/ACc1ccccc1
691
7351/16/202249
Kelly
acs.joc.6b02564
C-O Activation
x10.1021/acs.joc.6b025642017
12E-NuOH
AllylZnX
Vinyldppe
#N/A#N/A120toluenenBu2OtolueneP-PPhosphine (Bidentate)PhosphineCsp3-Csp2StrongOOHZnCsp3Csp2Csp3-OCsp2-ZnAllyl-O[Allyl]-OHVinyl-ZnX[Vinyl]-ZnXNon-Polar2.38No baseNo BaseNo baseHardOH
JOURNAL OF ORGANIC CHEMISTRY
_-0.813.21#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XO[Zn]ClCC=CC=CC=CCC=Cc1ccc(cc1)P(CCP(c2ccccc2)c3ccccc3)c4ccccc4#N/ACc1ccccc1
692
7361/16/2022132
Kelly
s0040-4039(97)00178-0
C-O Activation
x10.1016/s0040-4039(97)00178-01997
Lv=OMe13E-NuOMe
AllylMgX
Alkyl(S,S)-Chiraphos
#N/A#N/A25Et2OEt2O#N/APhosphine (Bidentate)PhosphineCsp3-Csp3StrongOO-Csp3MgCsp3Csp3Csp3-OCsp3-MgAllyl-O[Allyl]-O-Csp3Alkyl-MgX[Alkyl]-MgXNon-Polar4.33No baseNo BaseNo baseHardO-EDG
TETRAHEDRON LETTERS
_-0.285.11#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OC[Mg]ClCC=CCCC=CCCC
C[C@@H]([C@H](C)P(c1ccccc1)c2ccccc2)P(c3ccccc3)c4ccccc4
#N/ACCOCC
693
7371/16/2022132
Kelly
s0040-4039(97)00178-0
C-O Activation
x10.1016/s0040-4039(97)00178-01997
Lv=OPh13E-NuOPh
AllylMgX
Alkyl(S,S)-Chiraphos
#N/A#N/A25Et2OEt2O#N/APhosphine (Bidentate)PhosphineCsp3-Csp3StrongOO-Csp2MgCsp3Csp3Csp3-OCsp3-MgAllyl-O[Allyl]-O-Csp2Alkyl-MgX[Alkyl]-MgXNon-Polar4.33No baseNo BaseNo baseHardO-EDG
TETRAHEDRON LETTERS
_-0.3212.86#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OC1=CC=CC=C1[Mg]ClCC=CCCC=CCCC
C[C@@H]([C@H](C)P(c1ccccc1)c2ccccc2)P(c3ccccc3)c4ccccc4
#N/ACCOCC
694
7381/16/2022132
Kelly
s0040-4039(97)00178-0
C-O Activation
x10.1016/s0040-4039(97)00178-01997
Lv=OMe, Ligand=(R,R)-Me-DuPhos
13E-NuOMe
AllylMgX
Alkyl(R,R)-Me-DUPHOS
#N/A#N/A25Et2OEt2O#N/APhosphine (Bidentate)PhosphineCsp3-Csp3StrongOO-Csp3MgCsp3Csp3Csp3-OCsp3-MgAllyl-O[Allyl]-O-Csp3Alkyl-MgX[Alkyl]-MgXNon-Polar4.33No baseNo BaseNo baseHardO-EDG
TETRAHEDRON LETTERS
_-0.285.11#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OC[Mg]ClCC=CCCC=CCCC
C[C@@H]1CC[C@@H](C)P1c2ccccc2P3[C@H](C)CC[C@H]3C
#N/ACCOCC
695
7391/16/2022132
Kelly
s0040-4039(97)00178-0
C-O Activation
x10.1016/s0040-4039(97)00178-01997
Lv=OH13E-NuOH
AllylMgX
Alkyl(S,S)-Chiraphos
#N/A#N/A25Et2OEt2O#N/APhosphine (Bidentate)PhosphineCsp3-Csp3StrongOOHMgCsp3Csp3Csp3-OCsp3-MgAllyl-O[Allyl]-OHAlkyl-MgX[Alkyl]-MgXNon-Polar4.33No baseNo BaseNo baseHardOH
TETRAHEDRON LETTERS
_-0.813.21#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2O[Mg]ClCC=CCCC=CCCC
C[C@@H]([C@H](C)P(c1ccccc1)c2ccccc2)P(c3ccccc3)c4ccccc4
#N/ACCOCC
696
7401/16/202210
Kelly
acscatal.1c03010
C-O Activation
x10.1021/acscatal.1c030102021
X=OMs13E-NuOMs
ArylH
ORCgPhen-DalPhos
#N/A#N/A120NaOtButoluenetoluene#N/APhosphine (Bidentate)PhosphineCsp2_ar-Osp2WeakOO-SO2-R'HCsp2_arOsp2Csp2_ar-OOsp2-HAryl-O[Aryl]-O-SO2-R'OR-H[OR]-HNon-Polar2.38Ionic-OtBuNa+EasyOSO2-EDG
ACS CATALYSIS
_0.362.8589353663.2821934583.0705644124.0077900319#REF!3.2120.231.706749553.2392069642.4729782574.96639928#REF!#REF!OS(=O)(=O)CHC1=CC=CC=C1OC1=CC=CC=C1OCC1=C(C)C2=C(C(C(C)(C)C)=C1)OP(C3=CC=CC=C3P4[C@]5(C)O[C@]6(C)C[C@@]4(C)OC(C)(O6)C5)OC7=C2C(C)=C(C)C=C7C(C)(C)C#N/ACc1ccccc1
697
7411/16/202210
Kelly
acscatal.1c03010
C-O Activation
x10.1021/acscatal.1c030102021
X=OPiv13E-NuOPiv
ArylH
ORCgPhen-DalPhos
#N/A#N/A120NaOtButoluenetoluene#N/APhosphine (Bidentate)PhosphineCsp2_ar-Osp2MediumOO-CO-R'HCsp2_arOsp2Csp2_ar-OOsp2-HAryl-O[Aryl]-O-CO-R'OR-H[OR]-HNon-Polar2.38Ionic-OtBuNa+MediumOCO-EDG
ACS CATALYSIS
_0.3320.282.8589353663.2821934583.0705644124.0077900319#REF!3.2120.231.706749553.2392069642.4729782574.96639928#REF!#REF!OC(=O)C(C)(C)CHC1=CC=CC=C1OC1=CC=CC=C1OCC1=C(C)C2=C(C(C(C)(C)C)=C1)OP(C3=CC=CC=C3P4[C@]5(C)O[C@]6(C)C[C@@]4(C)OC(C)(O6)C5)OC7=C2C(C)=C(C)C=C7C(C)(C)C#N/ACc1ccccc1
698
7451/19/2022129
Gerry
ol201248c
C-O Activation
x10.1021/ol201248c2011
11E-NuOMe
AlkylH
Aryldppf
#N/A#N/A95PhMeP-PPhosphine (Bidentate)PhosphineCsp3-Csp2_arStrongOO-Csp3HCsp3Csp2_arCsp3-OCsp2_ar-HAlkyl-O[Alkyl]-O-Csp3Aryl-H[Aryl]-H#N/A#N/ANo baseNo BaseNo baseHardO-EDG
ORGANIC LETTERS
_-0.285.11#N/A#N/A#N/A#N/A#N/A#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5OCHCCC1=CC=CC=C1CCC1=CC=CC=C1c1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1#N/A#N/A
699
7461/19/202298
Long
s0022-328x(00)98073-2
C-O Activation
X10.1016/s0022-328x(00)98073-21977
13-4E-NuOH
AllylMgX
AlkylPPh3
#N/A#N/Art?PPhosphine (Monodentate)PhosphineCsp3-Csp3StrongOOHMgCsp3Csp3Csp3-OCsp3-MgAllyl-O[Allyl]-OHAlkyl-MgX[Alkyl]-MgX#N/A#N/ANo baseNo BaseNo baseHardOH
JOURNAL OF ORGANOMETALLIC CHEMISTRY
_-0.813.21#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2O[Mg]ClCC=CCCC=CCCCP(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3#N/A#N/A
700
7491/19/202297
Long
s-1989-34703
C-O Activation
x10.1055/s-1989-347031989
E-NuOPiv
AlkylMgX
Allyldppe
#N/A#N/AP-PPhosphine (Bidentate)PhosphineCsp3-Csp3MediumOO-CO-R'MgCsp3Csp3Csp3-OCsp3-MgAlkyl-O[Alkyl]-O-CO-R'Allyl-MgX[Allyl]-MgX#N/A#N/ANo baseNo BaseNo baseMediumOCO-EDGSYNLETT_0.3313.3#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!58.1OC(=O)C(C)(C)C[Mg]ClCCCC=CCCC=CCc1ccc(cc1)P(CCP(c2ccccc2)c3ccccc3)c4ccccc4#N/A#N/A
701
7501/19/2022227
Gerry
anie.201202527
C-O Activation
x10.1002/anie.2012025272012
12E-NuOCCOMe
BenzylMgX
Aryldppo
#N/A#N/A25PhMe#N/AMixed (P and O)Mixed
Csp3-ring(s)-Csp2_ar
StrongOO-Csp3MgCsp3-ring(s)Csp2_arCsp3-ring(s)-OCsp2_ar-MgBenzyl-O[Benzyl]-O-Csp3Aryl-MgX[Aryl]-MgX#N/A#N/ANo baseNo BaseNo base#N/A#N/A
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.24#N/A#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2OCCOC[Mg]ClCC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1C1=CC=C(C=C1)[P+](=O)C2=CC=CC=C2#N/A#N/A
702
7511/19/2022175
Gerry
jacs.5b01909
C-O Activation
x10.1021/jacs.5b019092015
E-EO(Ring-Opening)
AlkylX
Arylbpy
#N/A#N/A25Et3NDMPUN-NbpyNitrogenCsp3-Csp2_arWeakO
O(Ring-Opening)
XCsp3Csp2_arCsp3-OCsp2_ar-XAlkyl-O[Alkyl]-O(Ring-Opening)Aryl-X[Aryl]-X#N/A#N/ANitrogenNitrogen(neutral)Nitrogen(neutral)#N/A#N/A
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_11.7105540393.2426955962.4766248184.9733801910.8#REF!0#REF!#REF!XOCClCCC1=CC=CC=C1CCC1=CC=CC=C1C1(C2=NC=CC=C2)=CC=CC=N1#N/AO=C1N(C)CCCN1C
703
7521/19/2022145
Gerry
jo302086g
C-O Activation
x10.1021/jo302086g2012
11.5E-EOAc
AllylX
Aryl4,4',4''-tri-tert-butyl-2,2':6',2''-terpyridine
#N/A#N/A40THFNEPTHF#N/AterpyNitrogenCsp3-Csp2_arMediumOO-CO-R'XCsp3Csp2_arCsp3-OCsp2_ar-XAllyl-O[Allyl]-O-CO-R'Aryl-X[Aryl]-XPolar7.58No baseNo BaseNo baseMediumOCO-EDG
JOURNAL OF ORGANIC CHEMISTRY
_0.317.81#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOC(C)=OClCC=CC1=CC=CC=C1C=CCC1=CC=CC=C1CC(C)(C)C1=CC(C2=CC(C(C)(C)C)=CC(C3=CC(C(C)(C)C)=CC=N3)=N2)=NC=C1#N/AC1CCOC1
704
7531/19/2022145
Gerry
jo302086g
C-O Activation
x10.1021/jo302086g2012
11.5E-EOAc
AllylI
Aryl4,4',4''-tri-tert-butyl-2,2':6',2''-terpyridine
#N/A#N/A40THFNEPTHF#N/AterpyNitrogenCsp3-Csp2_arMediumOO-CO-R'XCsp3Csp2_arCsp3-OCsp2_ar-XAllyl-O[Allyl]-O-CO-R'Aryl-I[Aryl]-IPolar7.58No baseNo BaseNo baseMediumOCO-EDG
JOURNAL OF ORGANIC CHEMISTRY
_0.317.81#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOC(C)=OICC=CC1=CC=CC=C1C=CCC1=CC=CC=C1CC(C)(C)C1=CC(C2=CC(C(C)(C)C)=CC(C3=CC(C(C)(C)C)=CC=N3)=N2)=NC=C1#N/AC1CCOC1
705
7541/19/2022145
Gerry
jo302086g
C-O Activation
x10.1021/jo302086g2012
11E-EOAc
AllylBr
Aryl4,4',4''-tri-tert-butyl-2,2':6',2''-terpyridine
#N/A#N/A40THFNEPTHF#N/AterpyNitrogenCsp3-Csp2_arMediumOO-CO-R'XCsp3Csp2_arCsp3-OCsp2_ar-XAllyl-O[Allyl]-O-CO-R'Aryl-Br[Aryl]-BrPolar7.58No baseNo BaseNo baseMediumOCO-EDG
JOURNAL OF ORGANIC CHEMISTRY
_0.317.81#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOC(C)=OBrCC=CC1=CC=CC=C1C=CCC1=CC=CC=C1CC(C)(C)C1=CC(C2=CC(C(C)(C)C)=CC(C3=CC(C(C)(C)C)=CC=N3)=N2)=NC=C1#N/AC1CCOC1
706
7551/19/202267
Gerry
c3ob40232k
C-O Activation
x10.1039/c3ob40232k2013
21E-EOAc
AllylBr
Aryl4-chloro-2-(4,5-dihydro-1H-imidazol-2-yl)pyridine
#N/A#N/A60pyridineDMA#N/Apy-imNitrogenCsp3-Csp2_arMediumOO-CO-R'XCsp3Csp2_arCsp3-OCsp2_ar-XAllyl-O[Allyl]-O-CO-R'Aryl-Br[Aryl]-Br#N/A#N/ANitrogenNitrogen(neutral)Nitrogen(neutral)MediumOCO-EDG
ORGANIC & BIOMOLECULAR CHEMISTRY
_0.317.811.7105540393.2426955962.4766248184.973380195.17#REF!0#REF!#REF!XOC(C)=OBrCC=CC1=CC=CC=C1C=CCC1=CC=CC=C1C1CN=C(N1)C2=NC=CC(=C2)Cl#N/ACN(C)C(C)=O
707
7561/19/202267
Gerry
c3ob40232k
C-O Activation
x10.1039/c3ob40232k2013
21E-EOAc
AllylBr
Aryl4-chloro-2-(4,5-dihydro-1H-imidazol-2-yl)pyridine
#N/A#N/A60pyridineDMA#N/Apy-imNitrogenCsp3-Csp2_arMediumOO-CO-R'XCsp3Csp2_arCsp3-OCsp2_ar-XAllyl-O[Allyl]-O-CO-R'Aryl-Br[Aryl]-Br#N/A#N/ANitrogenNitrogen(neutral)Nitrogen(neutral)MediumOCO-EDG
ORGANIC & BIOMOLECULAR CHEMISTRY
_0.317.811.7105540393.2426955962.4766248184.973380195.17#REF!0#REF!#REF!XOC(C)=OBrCC=CC1=CC=CC=C1C=CCC1=CC=CC=C1C1CN=C(N1)C2=NC=CC(=C2)Cl#N/ACN(C)C(C)=O
708
7601/20/2022123
Gerry
jo00109a045
C-O Activation
x10.1021/jo00109a0451995
NAE-EOMs
ArylOMs
ArylPPh3
#N/A#N/A67Et4NITHFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'OCsp2_arCsp2_arCsp2_ar-OCsp2_ar-OAryl-O[Aryl]-O-SO2-R'Aryl-OMs[Aryl]-OMs#N/A#N/ANitrogenNitrogen(charged)Nitrogen(charged)EasyOSO2-EDG
JOURNAL OF ORGANIC CHEMISTRY
_0.362.9420199955.1753858444.058702925.8053568710.64#REF!0#REF!#REF!OS(=O)(=O)COS(=O)(=O)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3#N/AC1CCOC1
709
7611/20/2022109
Gerry
ma951840e
C-O Activation
x10.1021/ma951840e1996
NA
E-EOMs
ArylOMs
ArylPPh3
#N/A#N/A67Et4NITHFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'OCsp2_arCsp2_arCsp2_ar-OCsp2_ar-OAryl-O[Aryl]-O-SO2-R'Aryl-OMs[Aryl]-OMs#N/A#N/ANitrogenNitrogen(charged)Nitrogen(charged)EasyOSO2-EDG
MACROMOLECULES
_0.362.9420199955.1753858444.058702925.8053568710.64#REF!0#REF!#REF!OS(=O)(=O)COS(=O)(=O)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3#N/AC1CCOC1
710
7621/20/2022113
Gerry
chem.201601320
C-O Activation
x10.1002/chem.2016013202016
NA
E-EOTf
AlkylBr
Vinylbpy
#N/A#N/A25DMPUN-NbpyNitrogenCsp3-Csp2WeakOO-SO2-R'XCsp3Csp2Csp3-OCsp2-XAlkyl-O[Alkyl]-O-SO2-R'Vinyl-Br[Vinyl]-Br#N/A#N/ANo baseNo BaseNo baseEasyOSO2-EWG
CHEMISTRY-A EUROPEAN JOURNAL
_0.53#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOS(=O)(=O)C(F)(F)FBrCCC=CCCC=CC1(C2=NC=CC=C2)=CC=CC=N1#N/AO=C1N(C)CCCN1C
711
7631/20/2022220
Gerry
ol3013342
C-O Activation
x10.1021/ol30133422012
NA
E-EOAc
AllylBr
Aryldtbbpy
#N/A#N/A60DMAN-NbpyNitrogenCsp3-Csp2_arMediumOO-CO-R'XCsp3Csp2_arCsp3-OCsp2_ar-XAllyl-O[Allyl]-O-CO-R'Aryl-Br[Aryl]-Br#N/A#N/ANo baseNo BaseNo baseMediumOCO-EDG
ORGANIC LETTERS
_0.317.81#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOC(C)=OBrCC=CC1=CC=CC=C1C=CCC1=CC=CC=C1CC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/ACN(C)C(C)=O
712
7641/20/2022188
Gerry
ol3011198
C-O Activation
x10.1021/ol30111982012
NA
E-EOH
CarbonylX
Alkylbphen
#N/A#N/A25MeCNN-NbpyNitrogenCsp2-Csp3StrongOOHXCsp2Csp3Csp2-OCsp3-XCarbonyl-O[Carbonyl]-OHAlkyl-X[Alkyl]-X#N/A#N/ANo baseNo BaseNo baseHardOH
ORGANIC LETTERS
_-0.814.79#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOClCC(=O)CCCC(=O)CCCCC1(C2=CC=CC=C2)=CC=NC3=C1C=CC4=C3N=CC=C4C5=CC=CC=C5#N/ACC#N
713
7671/20/2022149
Gerry
jacs.8b12801
C-O Activation
x10.1021/jacs.8b128012019
NA12E-EOCOCO2tBu
AlkylCl
Aryl4-Methoxypyridine
#N/A#N/A25DMA#N/ACsp3-Csp2_arStrongOO-CO-R'XCsp3Csp2_arCsp3-OCsp2_ar-XAlkyl-O[Alkyl]-O-CO-R'Aryl-Cl[Aryl]-Cl#N/A#N/ANo baseNo BaseNo base#N/A#N/A
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.1315.99#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOC(C(OC(C)(C)C)=O)=OClCCC1=CC=CC=C1CCC1=CC=CC=C1COC1=CC=NC=C1#N/ACN(C)C(C)=O
714
7681/20/202288
Gerry
c7cc06106d
C-O Activation
x10.1039/c7cc06106d2017
NA
21E-EOTs
AlkylBr
ArylMe2bpy
#N/A#N/A25TBAIDMA#N/AbpyNitrogenCsp3-Csp2_arWeakOO-SO2-R'XCsp3Csp2_arCsp3-OCsp2_ar-XAlkyl-O[Alkyl]-O-SO2-R'Aryl-Br[Aryl]-Br#N/A#N/ANitrogenNitrogen(charged)EasyOSO2-EDG
CHEMICAL COMMUNICATIONS
_0.362.9420199955.1753858444.058702925.80535687#REF!0#REF!#REF!XOS(=O)(=O)(C1=CC=C(C)C=C1)BrCCC1=CC=CC=C1CCC1=CC=CC=C1Cc1ccnc(c2nccc(C)c2)c1#N/ACN(C)C(C)=O
715
7691/20/202288
Gerry
c7cc06106d
C-O Activation
x10.1039/c7cc06106d2017
NA31E-EOTs
AlkylOTs
Aryldppf
#N/A#N/A40TBAIDMAP-PPhosphine (Bidentate)PhosphineCsp3-Csp2_arWeakOO-SO2-R'OCsp3Csp2_arCsp3-OCsp2_ar-OAlkyl-O[Alkyl]-O-SO2-R'Aryl-OTs[Aryl]-OTs#N/A#N/ANitrogenNitrogen(charged)EasyOSO2-EDG
CHEMICAL COMMUNICATIONS
_0.362.9420199955.1753858444.058702925.80535687#REF!0#REF!#REF!OS(=O)(=O)(C1=CC=C(C)C=C1)OS(=O)(=O)(C1=CC=C(C)C=C1)CCC1=CC=CC=C1CCC1=CC=CC=C1c1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1#N/ACN(C)C(C)=O
716
7701/20/202218
Gerry
d0sc05452f
C-O Activation
x10.1039/d0sc05452f2021
11.5E-EOPiv
AlkylBr
Vinyldtbbpy
#N/A#N/A60TBAIdioxaneN-NbpyNitrogenCsp3-Csp2MediumOO-CO-R'XCsp3Csp2Csp3-OCsp2-XAlkyl-O[Alkyl]-O-CO-R'Vinyl-Br[Vinyl]-Br#N/A#N/ANitrogenNitrogen(charged)MediumOCO-EDG
CHEMICAL SCIENCE
_0.3313.32.9420199955.1753858444.058702925.80535687#REF!0#REF!#REF!XOC(=O)C(C)(C)CBrCCC=CCCC=CCC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/AC1COCCO1
717
7711/20/202218
Gerry
d0sc05452f
C-O Activation
x10.1039/d0sc05452f2021
11.5E-EOPiv
AlkylOTf
Vinyldtbbpy
#N/A#N/A60TBAIdioxaneN-NbpyNitrogenCsp3-Csp2MediumOO-CO-R'OCsp3Csp2Csp3-OCsp2-OAlkyl-O[Alkyl]-O-CO-R'Vinyl-OTf[Vinyl]-OTf#N/A#N/ANitrogenNitrogen(charged)MediumOCO-EDG
CHEMICAL SCIENCE
_0.3313.32.9420199955.1753858444.058702925.80535687#REF!0#REF!#REF!XOC(=O)C(C)(C)COS(=O)(=O)C(F)(F)FCCC=CCCC=CCC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/AC1COCCO1
718
7751/24/2022118
Shihong
ol4031364
C-O Activation
x10.1021/ol40313642014
10.75E-NuOEt
HetB(OH)2
Aryl(3aR,8aR)-2,2-dimethyl-4,4,8,8-tetra(naphthalen-2-yl)-6-phenyltetrahydro-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepine
#N/A#N/A25NaOPhdioxanet-AmylOH#N/AMixed (P and O)Mixed
Csp2_ar-Csp2_ar
StrongOO-Csp3BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BHet-O[Het]-O-Csp3Aryl-B(OH)2[Aryl]-B(OH)2#N/A#N/AIonic-ORNa+HardO-EDG
ORGANIC LETTERS
_-0.2414.7024.7#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OCCB(O)OC1=NC=CC=C1C1=CC=CC=C1C1=CC=NC=C1C1=CC=CC=C1CC1(C)O[C@H]2C(C3=CC4=C(C=CC=C4)C=C3)(OP(C5=CC=CC=C5)OC([C@@H]2O1)(C6=CC7=C(C=CC=C7)C=C6)C8=CC=C9C=CC=CC9=C8)C%10=CC=C%11C=CC=CC%11=C%10#N/AC1COCCO1
719
7761/25/2022103
Shihong
c39810000313
C-O Activation
x10.1039/c398100003131981
12E-NuOSiEt3
AllylMgX
Aryldppf
#N/A#N/A25P-PPhosphine (Bidentate)PhosphineCsp3-Csp2_arStrongOO-SiR'3MgCsp3Csp2_arCsp3-OCsp2_ar-MgAllyl-O[Allyl]-O-SiR'3Aryl-MgX[Aryl]-MgX#N/A#N/ANo baseNo BaseNo base#N/A#N/A
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS
_-0.2717.25#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2O[Si](CC)(CC)CC[Mg]ClCC=CC1=CC=CC=C1C=CCC1=CC=CC=C1c1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1#N/A#N/A
720
7771/25/2022103
Shihong
c39810000313
C-O Activation
x10.1039/c398100003131981
12E-NuOSiEt3
AllylMgX
ArylPPh3
#N/A#N/A25PPhosphine (Monodentate)PhosphineCsp3-Csp2_arStrongOO-SiR'3MgCsp3Csp2_arCsp3-OCsp2_ar-MgAllyl-O[Allyl]-O-SiR'3Aryl-MgX[Aryl]-MgX#N/A#N/ANo baseNo BaseNo base#N/A#N/A
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS
_-0.2717.25#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2O[Si](CC)(CC)CC[Mg]ClCC=CC1=CC=CC=C1C=CCC1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3#N/A#N/A
721
7781/25/2022103
Shihong
c39810000313
C-O Activation
x10.1039/c398100003131981
12E-NuOTMS
AllylMgX
Aryldppf
#N/A#N/A25P-PPhosphine (Bidentate)PhosphineCsp3-Csp2_arStrongOO-SiR'3MgCsp3Csp2_arCsp3-OCsp2_ar-MgAllyl-O[Allyl]-O-SiR'3Aryl-MgX[Aryl]-MgX#N/A#N/ANo baseNo BaseNo baseMediumOSiMe2-EDG
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS
_-0.2711.72#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2O[Si](C)(C)C[Mg]ClCC=CC1=CC=CC=C1C=CCC1=CC=CC=C1c1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1#N/A#N/A
722
7811/25/202287
Shihong
s-1994-22850
C-O Activation
x10.1055/s-1994-228501994
NANAE-NuOTf
ArylZnX
ArylPPh3
#N/A#N/A25THFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'ZnCsp2_arCsp2_arCsp2_ar-OCsp2_ar-ZnAryl-O[Aryl]-O-SO2-R'Aryl-ZnX[Aryl]-ZnX#N/A#N/ANo baseNo BaseNo baseEasyOSO2-EWGSYNLETT_0.53#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XOS(=O)(=O)C(F)(F)F[Zn]ClC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3#N/AC1CCOC1
723
7821/25/2022153
Shihong
jacs.7b11707
C-O Activation
x10.1021/jacs.7b117072018
NA
12E-EOMs
BenzylBr
Vinyl(3aR,3a'R,8aS,8a'S)-2,2'-(pentane-3,3-diyl)bis(3a,8a-dihydro-8H-indeno[1,2-d]oxazole)
#N/A#N/A10NMPMnCoPc
CoPc as the co-catalysts
#N/AboxNitrogen
Csp3-ring(s)-Csp2
WeakOO-SO2-R'XCsp3-ring(s)Csp2Csp3-ring(s)-OCsp2-XBenzyl-O[Benzyl]-O-SO2-R'Vinyl-Br[Vinyl]-Br#N/A#N/ANo baseNo BaseNo baseEasyOSO2-EDG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.36#N/A#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOS(=O)(=O)CBrCC1=CC=CC=C1C=CCC1=CC=CC=C1C=CCCC(C1=N[C@H](C2=C(C=CC=C2)C3)[C@H]3O1)(CC)C4=N[C@@H]5C6=C(C=CC=C6)C[C@@H]5O4#N/ACN1CCCC1=O
724
7831/25/2022153
Shihong
jacs.7b11707
C-O Activation
x10.1021/jacs.7b117072018
NA21E-EOTf
VinylCl
Benzyl(3aR,3a'R,8aS,8a'S)-2,2'-(pentane-3,3-diyl)bis(3a,8a-dihydro-8H-indeno[1,2-d]oxazole)
#N/A#N/A5NMPMnCoPc
CoPc as the co-catalysts
#N/AboxNitrogen
Csp2-Csp3-ring(s)
WeakOO-SO2-R'XCsp2Csp3-ring(s)Csp2-OCsp3-ring(s)-XVinyl-O[Vinyl]-O-SO2-R'Benzyl-Cl[Benzyl]-Cl#N/A#N/ANo baseNo BaseNo baseEasyOSO2-EWG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.53#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOS(=O)(=O)C(F)(F)FClC=CCC1=CC=CC=C1C=CCC1=CC=CC=C1CCC(C1=N[C@H](C2=C(C=CC=C2)C3)[C@H]3O1)(CC)C4=N[C@@H]5C6=C(C=CC=C6)C[C@@H]5O4#N/ACN1CCCC1=O
725
7851/25/202266
Gerry
ol800335v
C-O Activation
x10.1021/ol800335v2008
R3=iPr11.2E-NuOBoc
AllylC(OH)(Me)2
AllylP(OEt)3
#N/A#N/Atoluene#N/APhosphine (Monodentate)PhosphineCsp3-Csp3MediumOO-CO-R'Csp3Csp3Csp3Csp3-OCsp3-Csp3Allyl-O[Allyl]-O-CO-R'Allyl-C(OH)(Me)2[Allyl]-C(OH)(Me)2#N/A#N/ANo baseNo BaseNo baseMediumOCO2-EDG
ORGANIC LETTERS
_0.3114.03#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOC(=O)OC(C)(C)CC(O)(C)CCC=CCC=CC=CCC=CCCCOP(OCC)OCC#N/ACc1ccccc1
726
7861/25/202258
Kelly
s0022-328x(00)00164-9
C-O Activation
x10.1016/s0022-328x(00)00164-92000
Solvent: MeCN/THF(1:1)
11.2E-NuOCO2Et
AllylB(OMe)3-Li+
Alkynedppe
#N/A#N/A60MeCNMeCNP-PPhosphine (Bidentate)PhosphineCsp3-Csp1MediumOO-CO-R'BCsp3Csp1Csp3-OCsp1-BAllyl-O[Allyl]-O-CO-R'Alkyne-B(OMe)3-Li+[Alkyne]-B(OMe)3-Li+Polar36.6No baseNo BaseNo base#N/A#N/A
JOURNAL OF ORGANOMETALLIC CHEMISTRY
_0.3110.39#N/A#N/A#N/A#N/A#N/A#REF!#N/A#N/A0#REF!#REF!#N/AOC(OCC)=O[B-](OC)(OC)OC.[Li+]CC=CC#CC=CCC#Cc1ccc(cc1)P(CCP(c2ccccc2)c3ccccc3)c4ccccc4#N/ACC#N
727
7871/25/202258
Kelly
s0022-328x(00)00164-9
C-O Activation
x10.1016/s0022-328x(00)00164-92000
Solvent: THF11.2E-NuOCO2Et
AllylB(OMe)3-Li+
Alkynedppe
#N/A#N/A60THFTHFP-PPhosphine (Bidentate)PhosphineCsp3-Csp1MediumOO-CO-R'BCsp3Csp1Csp3-OCsp1-BAllyl-O[Allyl]-O-CO-R'Alkyne-B(OMe)3-Li+[Alkyne]-B(OMe)3-Li+Polar7.58No baseNo BaseNo base#N/A#N/A
JOURNAL OF ORGANOMETALLIC CHEMISTRY
_0.3110.39#N/A#N/A#N/A#N/A#N/A#REF!#N/A#N/A0#REF!#REF!#N/AOC(OCC)=O[B-](OC)(OC)OC.[Li+]CC=CC#CC=CCC#Cc1ccc(cc1)P(CCP(c2ccccc2)c3ccccc3)c4ccccc4#N/AC1CCOC1
728
7881/25/202258
Kelly
s0022-328x(00)00164-9
C-O Activation
x10.1016/s0022-328x(00)00164-92000
NANAE-NuOCO2Et
AllylB(OMe)3-Li+
Alkyne(S,S)-Chiraphos
#N/A#N/ATHFTHF#N/APhosphine (Bidentate)PhosphineCsp3-Csp1MediumOO-CO-R'BCsp3Csp1Csp3-OCsp1-BAllyl-O[Allyl]-O-CO-R'Alkyne-B(OMe)3-Li+[Alkyne]-B(OMe)3-Li+Polar7.58No baseNo BaseNo base#N/A#N/A
JOURNAL OF ORGANOMETALLIC CHEMISTRY
_0.3110.39#N/A#N/A#N/A#N/A#N/A#REF!#N/A#N/A0#REF!#REF!#N/AOC(OCC)=O[B-](OC)(OC)OC.[Li+]CC=CC#CC=CCC#C
C[C@@H]([C@H](C)P(c1ccccc1)c2ccccc2)P(c3ccccc3)c4ccccc4
#N/AC1CCOC1
729
7891/25/202266
Gerry
ol800335v
C-O Activation
x10.1021/ol800335v2008
11.2E-NuOBoc
AllylC(OH)(iPr)2
AllylP(OEt)3
#N/A#N/Atoluene#N/APhosphine (Monodentate)PhosphineCsp3-Csp3MediumOO-CO-R'Csp3Csp3Csp3Csp3-OCsp3-Csp3Allyl-O[Allyl]-O-CO-R'Allyl-C(OH)(iPr)2[Allyl]-C(OH)(iPr)2#N/A#N/ANo baseNo BaseNo baseMediumOCO2-EDG
ORGANIC LETTERS
_0.3114.03#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOC(=O)OC(C)(C)CC(O)(C(C)C)C(C)CCC=CCC=CC=CCC=CCCCOP(OCC)OCC#N/ACc1ccccc1
730
7901/25/202282
Gerry
ol901429g
C-O Activation
x10.1021/ol901429g2009
11E-NuO(Ring-Opening)
AlkylH
Alkylrac-BINAP
#N/A#N/AK3PO4tolueneP-PPhosphine (Bidentate)PhosphineCsp3-Csp3WeakO
O(Ring-Opening)
HCsp3Csp3Csp3-OCsp3-HAlkyl-O[Alkyl]-O(Ring-Opening)Alkyl-H[Alkyl]-H#N/A#N/AIonic-PO4K+#N/A#N/A
ORGANIC LETTERS
_12.244780372.9696246982.6072025343.5700586912.37#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5OCHCCCCCCCCC12=CC=CC=C1C=CC(P(C3=CC=CC=C3)C4=CC=CC=C4)=C2C5=C(C=CC=C6)C6=CC=C5P7C8=CC=CCC98=C7C=CC=C9#N/ACc1ccccc1
731
7911/25/202279
Gerry
s0040-4020(97)10211-3
C-O Activation
x10.1016/s0040-4020(97)10211-31998
11E-NuO(Ring-Opening)
AlkylH
Alkyl(R)-BINAP
#N/A#N/APhMeTHFP-PPhosphine (Bidentate)PhosphineCsp3-Csp3WeakO
O(Ring-Opening)
HCsp3Csp3Csp3-OCsp3-HAlkyl-O[Alkyl]-O(Ring-Opening)Alkyl-H[Alkyl]-H#N/A#N/ANo baseNo BaseNo base#N/A#N/A
TETRAHEDRON
_1#N/A#N/A#N/A#N/A#N/A#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5OCHCCCCCCCCc1ccc(cc1)P(c2ccccc2)c3ccc4ccccc4c3-c5c(ccc6ccccc56)P(c7ccccc7)c8ccccc8#N/A#N/A
732
7921/25/202264
Gerry
jacs.5b01005
C-O Activation
x10.1021/jacs.5b010052015
12E-NuO(Ring-Opening)
AlkylH
N(H)ArylNC1=CC=C2C(C=CC=C2)=C1C3=C4C(C=CC=C4)=CC=C3NCC5=CC=C(C=CC=C6)C6=C5
#N/A#N/ACHCl3#N/AN-NNitrogenCsp3-Nsp3WeakO
O(Ring-Opening)
HCsp3Nsp3Csp3-ONsp3-HAlkyl-O[Alkyl]-O(Ring-Opening)N(H)Aryl-H[N(H)Aryl]-H#N/A#N/ANo baseNo BaseNo base#N/A#N/A
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_1#N/A#N/A#N/A#N/A#N/A#REF!11.526.021.706749553.2392069642.4729782574.96639928#REF!#REF!OCHCCNC1=CC=CC=C1CCC1=CC=CC=C1NNC1=CC=C2C(C=CC=C2)=C1C3=C4C(C=CC=C4)=CC=C3NCC5=CC=C(C=CC=C6)C6=C5#N/ACC(Cl)(Cl)Cl
733
7931/25/202264
Gerry
jacs.5b01005
C-O Activation
x10.1021/jacs.5b010052015
No ligand11.5E-NuO(Ring-Opening)
AlkylH
N(H)Aryl#N/A#N/A#N/AtBuOH#N/A#N/A#N/ACsp3-Nsp3WeakO
O(Ring-Opening)
HCsp3Nsp3Csp3-ONsp3-HAlkyl-O[Alkyl]-O(Ring-Opening)N(H)Aryl-H[N(H)Aryl]-H#N/A#N/ANo baseNo BaseNo base#N/A#N/A
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_1#N/A#N/A#N/A#N/A#N/A#REF!11.526.021.706749553.2392069642.4729782574.96639928#REF!#REF!OCHCCNC1=CC=CC=C1CCC1=CC=CC=C1N#N/A#N/AOC(C)(C)C
734
7941/25/202264
Gerry
jacs.5b01005
C-O Activation
x10.1021/jacs.5b010052015
2.31E-NuO(Ring-Opening)
AlkylH
N(H)ArylNC1=CC=C2C(C=CC=C2)=C1C3=C4C(C=CC=C4)=CC=C3NCC5=CC=C(C=CC=C6)C6=C5
#N/A#N/ACHCl3#N/AN-NNitrogenCsp3-Nsp3WeakO
O(Ring-Opening)
HCsp3Nsp3Csp3-ONsp3-HAlkyl-O[Alkyl]-O(Ring-Opening)N(H)Aryl-H[N(H)Aryl]-H#N/A#N/ANo baseNo BaseNo base#N/A#N/A
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_1#N/A#N/A#N/A#N/A#N/A#REF!11.526.021.706749553.2392069642.4729782574.96639928#REF!#REF!OCHCCNC1=CC=CC=C1CCC1=CC=CC=C1NNC1=CC=C2C(C=CC=C2)=C1C3=C4C(C=CC=C4)=CC=C3NCC5=CC=C(C=CC=C6)C6=C5#N/ACC(Cl)(Cl)Cl
735
7951/25/202291
Gerry
jo00205a042
C-O Activation
x10.1021/jo00205a0421985
E-NuO(Ring-Opening)
AlkylMgX
Alkyldppp
#N/A#N/AP-PPhosphine (Bidentate)PhosphineCsp3-Csp3WeakO
O(Ring-Opening)
MgCsp3Csp3Csp3-OCsp3-MgAlkyl-O[Alkyl]-O(Ring-Opening)Alkyl-MgX[Alkyl]-MgX#N/A#N/ANo baseNo BaseNo base#N/A#N/A
JOURNAL OF ORGANIC CHEMISTRY
_1#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OC[Mg]ClCCCCCCCCP(c1ccccc1)(c2ccccc2)CCCP(c3ccccc3)c4ccccc4#N/A#N/A
736
7962/7/202256
Kelly
hlca.19800630427
C-O Activation
x10.1002/hlca.198006304271980
E-NuOH
AllylMgX
Alkyl(R)-(1-phenylethane-1,2-diyl)bis(diphenylphosphane)
#N/A#N/A#N/APhosphine (Bidentate)PhosphineCsp3-Csp3StrongOOHMgCsp3Csp3Csp3-OCsp3-MgAllyl-O[Allyl]-OHAlkyl-MgX[Alkyl]-MgX#N/A#N/ANo baseNo BaseNo baseHardOH
HELVETICA CHIMICA ACTA
_-0.813.21#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2O[Mg]ClCC=CCCC=CCCC[C@H](C1=CC=CC=C1)(P(C2=CC=CC=C2)C3=CC=CC=C3)CP(C4=CC=CC=C4)C5=CC=CC=C5#N/A#N/A
737
7972/7/2022101
Kelly
j.tet.2006.03.123
C-O Activation
x10.1016/j.tet.2006.03.1232006
E-NuONf
ArylZnX
Aryl(EtO)2P(O)H
#N/A#N/ATHFNEPTHF#N/APhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'ZnCsp2_arCsp2_arCsp2_ar-OCsp2_ar-ZnAryl-O[Aryl]-O-SO2-R'Aryl-ZnX[Aryl]-ZnXPolar7.58No baseNo BaseNo base#N/A#N/A
TETRAHEDRON
_0.53#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XOS(=O)(C(F)(C(F)(C(F)(C(F)(F)F)F)F)F)=O[Zn]ClC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1O=P([H])(OCC)OCC#N/AC1CCOC1
738
7982/7/2022101
Kelly
j.tet.2006.03.123
C-O Activation
x10.1016/j.tet.2006.03.1232006
E-NuOTf
VinylZnX
Aryl(EtO)2P(O)H
#N/A#N/ATHFNEPTHF#N/APhosphine (Monodentate)PhosphineCsp2-Csp2_arWeakOO-SO2-R'ZnCsp2Csp2_arCsp2-OCsp2_ar-ZnVinyl-O[Vinyl]-O-SO2-R'Aryl-ZnX[Aryl]-ZnXPolar7.58No baseNo BaseNo baseEasyOSO2-EWG
TETRAHEDRON
_0.53#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XOS(=O)(=O)C(F)(F)F[Zn]ClC=CC1=CC=CC=C1C=CC1=CC=CC=C1O=P([H])(OCC)OCC#N/AC1CCOC1
739
7992/7/2022223
Kelly
ol403209k
C-O Activation
x10.1021/ol403209k2014
X=OSO2NMe211.5E-NuOSO2NMe2
ArylH
N(H)Aryldppf
#N/A#N/A110K3PO4CPMECPMEMeCNP-PPhosphine (Bidentate)PhosphineCsp2_ar-Nsp3WeakOO-SO2-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-SO2-R'N(H)Aryl-H[N(H)Aryl]-HPolar4.76Ionic-PO4K+MediumOSO2-EDG
ORGANIC LETTERS
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!11.526.021.706749553.2392069642.4729782574.96639928#REF!#REF!OS(=O)(N(C)C)=OHC1=CC=CC=C1NC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1Nc1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1#N/ACOC1CCCC1
740
8012/7/2022223
Kelly
ol403209k
C-O Activation
x10.1021/ol403209k2014
X=OTf11.5E-NuOTf
ArylH
N(H)Aryldppf
#N/A#N/A110K3PO4CPMECPMEMeCNP-PPhosphine (Bidentate)PhosphineCsp2_ar-Nsp3WeakOO-SO2-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-SO2-R'N(H)Aryl-H[N(H)Aryl]-HPolar4.76Ionic-PO4K+EasyOSO2-EWG
ORGANIC LETTERS
_0.532.244780372.9696246982.6072025343.5700586912.37#REF!11.526.021.706749553.2392069642.4729782574.96639928#REF!#REF!OS(=O)(=O)C(F)(F)FHC1=CC=CC=C1NC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1Nc1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1#N/ACOC1CCCC1
741
8022/7/2022223
Kelly
ol403209k
C-O Activation
x10.1021/ol403209k2014
X=OMs11.5E-NuOMs
ArylH
N(H)Aryldppf
#N/A#N/A110K3PO4CPMECPMEMeCNP-PPhosphine (Bidentate)PhosphineCsp2_ar-Nsp3WeakOO-SO2-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-SO2-R'N(H)Aryl-H[N(H)Aryl]-HPolar4.76Ionic-PO4K+EasyOSO2-EDG
ORGANIC LETTERS
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!11.526.021.706749553.2392069642.4729782574.96639928#REF!#REF!OS(=O)(=O)CHC1=CC=CC=C1NC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1Nc1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1#N/ACOC1CCCC1
742
8032/7/2022223
Kelly
ol403209k
C-O Activation
x10.1021/ol403209k2014
X=OSO2NMe211.5E-NuOSO2NMe2
ArylH
N(Alkyl)Aryldppf
#N/A#N/A110K3PO4CPMECPMEMeCNP-PPhosphine (Bidentate)PhosphineCsp2_ar-Nsp3WeakOO-SO2-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-SO2-R'N(Alkyl)Aryl-H[N(Alkyl)Aryl]-HPolar4.76Ionic-PO4K+MediumOSO2-EDG
ORGANIC LETTERS
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!15.1912.031.706749553.2392069642.4729782574.96639928#REF!#REF!OS(=O)(N(C)C)=OHC1=CC=CC=C1N(C)C(C(=O)C)C1=CC=CC=C1CC(=O)CN(C)c1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1#N/ACOC1CCCC1
743
8042/7/202243
Kelly
c7cc01932g
C-O Activation
x10.1039/c7cc01932g2017
X=I0.380.25E-EOTs
AlkylI
Arylbpy
#N/A#N/A30KIDMFDMFMnVB12N-NbpyNitrogenCsp3-Csp2_arWeakOO-SO2-R'XCsp3Csp2_arCsp3-OCsp2_ar-XAlkyl-O[Alkyl]-O-SO2-R'Aryl-I[Aryl]-IPolar36.7#N/ANo Base#N/AEasyOSO2-EDG
CHEMICAL COMMUNICATIONS
_0.36#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOS(=O)(=O)(C1=CC=C(C)C=C1)ICCC1=CC=CC=C1CCC1=CC=CC=C1C1(C2=NC=CC=C2)=CC=CC=N1#N/ACN(C)C=O
744
8052/7/202243
Kelly
c7cc01932g
C-O Activation
x10.1039/c7cc01932g2017
X=Br0.380.25E-EOTs
AlkylBr
Arylbpy
#N/A#N/A30KIDMFDMFMnVB12N-NbpyNitrogenCsp3-Csp2_arWeakOO-SO2-R'XCsp3Csp2_arCsp3-OCsp2_ar-XAlkyl-O[Alkyl]-O-SO2-R'Aryl-Br[Aryl]-BrPolar36.7#N/ANo Base#N/AEasyOSO2-EDG
CHEMICAL COMMUNICATIONS
_0.36#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOS(=O)(=O)(C1=CC=C(C)C=C1)BrCCC1=CC=CC=C1CCC1=CC=CC=C1C1(C2=NC=CC=C2)=CC=CC=N1#N/ACN(C)C=O
745
8062/7/202243
Kelly
c7cc01932g
C-O Activation
x10.1039/c7cc01932g2017
X=Cl0.380.25E-EOTs
AlkylCl
Arylbpy
#N/A#N/A30KIDMFDMFMnVB12N-NbpyNitrogenCsp3-Csp2_arWeakOO-SO2-R'XCsp3Csp2_arCsp3-OCsp2_ar-XAlkyl-O[Alkyl]-O-SO2-R'Aryl-Cl[Aryl]-ClPolar36.7#N/ANo Base#N/AEasyOSO2-EDG
CHEMICAL COMMUNICATIONS
_0.36#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOS(=O)(=O)(C1=CC=C(C)C=C1)ClCCC1=CC=CC=C1CCC1=CC=CC=C1C1(C2=NC=CC=C2)=CC=CC=N1#N/ACN(C)C=O
746
8072/7/202238
Kelly
acs.orglett.9b01164
C-O Activation
x10.1021/acs.orglett.9b011642019
E-EOTf
VinylF
Carbonylttbtpy
#N/A#N/A70DMAtolueneDMAMnN-N-NterpyNitrogenCsp2-Csp2WeakOO-SO2-R'XCsp2Csp2Csp2-OCsp2-XVinyl-O[Vinyl]-O-SO2-R'Carbonyl-F[Carbonyl]-FPolar37.8No baseNo BaseNo baseEasyOSO2-EWG
ORGANIC LETTERS
_0.53#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOS(=O)(=O)C(F)(F)FFC=CCC(=O)CC=CC(=O)CCCC(C)(C1=CN=C(C2=NC(C3=NC=C(C(C)(C)C)C=C3)=CC(C(C)(C)C)=C2)C=C1)C#N/ACN(C)C(C)=O
747
8082/7/202230
Kelly
anie.202002392
C-O Activation
x10.1002/anie.2020023922020
X is OCONEt2E-NuOCONEt2
HetH
NHSO2RPhPAd-Dalphos
#N/A#N/AP-PPhosphine (Bidentate)PhosphineCsp2_ar-Nsp3MediumOO-CO-R'HCsp2_arNsp3Csp2_ar-ONsp3-HHet-O[Het]-O-CO-R'NHSO2R-H[NHSO2R]-H#N/A#N/ANo baseNo BaseNo baseMediumOCO-EDG
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.3121.41#N/A#N/A#N/A#N/A#N/A#REF!#N/A#N/A1.706749553.2392069642.4729782574.96639928#REF!#REF!#N/AOC(N(CC)CC)=OHC1=NC=CC=C1NS(=O)=OC1=CC=NC=C1O=S(=O)NC[C@@]12C[C@](O3)(C)O[C@@](CC3(C)P1C4=CC=CC=C4P(C5=CC=CC=C5)C6=CC=CC=C6)(O2)C#N/A#N/A
748
8092/7/2022161
Long
ja5026485
C-O Activation
xx10.1021/ja50264852014
E-NuOMe
ArylH
VinylPCy3
#N/A#N/ArtPhMePhMePPhosphine (Monodentate)PhosphineCsp2_ar-Csp2StrongOO-Csp3HCsp2_arCsp2Csp2_ar-OCsp2-HAryl-O[Aryl]-O-Csp3Vinyl-H[Vinyl]-H#N/A#N/ANo baseNo BaseNo baseHardO-EDG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!6.0701.706749553.2392069642.4729782574.96639928#REF!#REF!115.6OCHC1=CC=CC=C1C=CC1=CC=CC=C1C=CC1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/A#N/A
749
8102/7/2022189
Kelly
ol901217m
C-O Activation
x10.1021/ol901217m2009
15E-NuOMe
ArylMgX
ArylPCy3
#N/A#N/A100toluenenBu2O
toluene/nBu2O
PPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
StrongOO-Csp3MgCsp2_arCsp2_arCsp2_ar-OCsp2_ar-MgAryl-O[Aryl]-O-Csp3Aryl-MgX[Aryl]-MgX#N/A#N/ANo baseNo BaseNo baseHardO-EDG
ORGANIC LETTERS
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2OC[Mg]ClC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/ACc1ccccc1
750
8112/8/202223
Gerry
ejic.201900692
C-O Activation
x10.1002/ejic.2019006922019
0.50.75E-NuOMe
ArylMgX
ArylC1-CDC
#N/A#N/A60m-xylenem-xylene#N/AN-NNitrogen
Csp2_ar-Csp2_ar
StrongOO-Csp3MgCsp2_arCsp2_arCsp2_ar-OCsp2_ar-MgAryl-O[Aryl]-O-Csp3Aryl-MgX[Aryl]-MgXNon-Polar2.36No baseNo BaseNo baseHardO-EDG
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2OC[Mg]ClC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1CC(N1C2=CC=CC=C2N(C1CC3N(C4=C(N3C)C=CC=C4)C)C(C)C)C#N/ACc1cccc(c1)C
751
8122/8/202223
Gerry
ejic.201900692
C-O Activation
x10.1002/ejic.2019006922019
0.50.75E-NuOMe
ArylMgX
ArylC1-CDC
#N/A#N/A60m-xylenem-xylene#N/AN-NNitrogen
Csp2_ar-Csp2_ar
StrongOO-Csp3MgCsp2_arCsp2_arCsp2_ar-OCsp2_ar-MgAryl-O[Aryl]-O-Csp3Aryl-MgX[Aryl]-MgXNon-Polar2.36No baseNo BaseNo baseHardO-EDG
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2OC[Mg]ClC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1CC(N1C2=CC=CC=C2N(C1CC3N(C4=C(N3C)C=CC=C4)C)C(C)C)C#N/ACc1cccc(c1)C
752
8132/8/202223
Gerry
ejic.201900692
C-O Activation
x10.1002/ejic.2019006922019
0.50.75E-NuOMe
ArylMgX
ArylC1-CDC
#N/A#N/A60m-xylenem-xylene#N/AN-NNitrogen
Csp2_ar-Csp2_ar
StrongOO-Csp3MgCsp2_arCsp2_arCsp2_ar-OCsp2_ar-MgAryl-O[Aryl]-O-Csp3Aryl-MgX[Aryl]-MgXNon-Polar2.36No baseNo BaseNo baseHardO-EDG
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2OC[Mg]ClC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1CC(N1C2=CC=CC=C2N(C1CC3N(C4=C(N3C)C=CC=C4)C)C(C)C)C#N/ACc1cccc(c1)C
753
8142/10/2022100
Long
chem.201003403
C-O Activation
x10.1002/chem.2010034032011
E-NuOH
ArylB(OH)2
Aryldppp
#N/A#N/A100Et3NK3PO4dioxaneP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
StrongOOHBCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-OHAryl-B(OH)2[Aryl]-B(OH)2#N/A#N/AIonic-PO4K+HardOH
CHEMISTRY-A EUROPEAN JOURNAL
_-0.8110.942.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(c1ccccc1)(c2ccccc2)CCCP(c3ccccc3)c4ccccc4#N/AC1COCCO1
754
8152/10/2022211
Long
0022-328x(85)80354-5
C-O Activation
x10.1016/0022-328x(85)80354-51985
E-NuOCO2Me
AlkylH
AlkylPPh3
#N/A#N/A65THFPPhosphine (Monodentate)PhosphineCsp3-Csp3MediumOO-CO-R'HCsp3Csp3Csp3-OCsp3-HAlkyl-O[Alkyl]-O-CO-R'Alkyl-H[Alkyl]-H#N/A#N/ANo baseNo BaseNo base#N/A#N/A
JOURNAL OF ORGANOMETALLIC CHEMISTRY
_0.318.58#N/A#N/A#N/A#N/A#N/A#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5OC(=O)OCHCCCCCCCCP(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3#N/AC1CCOC1
755
8162/10/202260
Long
c0cc02173c
C-O Activation
x10.1039/c0cc02173c2011
E-NuOTs
Aryl(trialkyl)silanes
ArylPPh3
#N/A#N/A80Cs2CO3acetoneDMFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'SiCsp2_arCsp2_arCsp2_ar-OCsp2_ar-SiAryl-O[Aryl]-O-SO2-R'Aryl-(trialkyl)silanes[Aryl]-(trialkyl)silanes#N/A#N/AIonic-CO3Cs+EasyOSO2-EDG
CHEMICAL COMMUNICATIONS
_0.361.72.530430542.115215273.4538974810.33#REF!0#REF!#REF!OS(=O)(=O)(C1=CC=C(C)C=C1)[Si](C)(C)C1C(C(C)(C)O)CCCC1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3#N/ACC(=O)C
756
8172/14/2022210
Kelly
c0cc01716g
C-O Activation
x10.1039/c0cc01716g2010
NA
11E-EOAc
VinylOAc
Vinylttbtpy
#N/A#N/A40-80DMFDMFMnN-N-NterpyNitrogenCsp2-Csp2MediumOO-CO-R'OCsp2Csp2Csp2-OCsp2-OVinyl-O[Vinyl]-O-CO-R'Vinyl-OAc[Vinyl]-OAcPolar36.7No baseNo BaseNo baseMediumOCO-EDG
CHEMICAL COMMUNICATIONS
_0.318.64#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOC(C)=OOC(C)=OC=CC=CC=CC=CCC(C)(C1=CN=C(C2=NC(C3=NC=C(C(C)(C)C)C=C3)=CC(C(C)(C)C)=C2)C=C1)C#N/ACN(C)C=O
757
8182/14/2022210
Kelly
c0cc01716g
C-O Activation
x10.1039/c0cc01716g2010
NA
11E-EOMs
AlkylOMs
Alkylttbtpy
#N/A#N/A40-80DMFDMFMnN-N-NterpyNitrogenCsp3-Csp3WeakOO-SO2-R'OCsp3Csp3Csp3-OCsp3-OAlkyl-O[Alkyl]-O-SO2-R'Alkyl-OMs[Alkyl]-OMsPolar36.7No baseNo BaseNo baseEasyOSO2-EDG
CHEMICAL COMMUNICATIONS
_0.36#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOS(=O)(=O)COS(=O)(=O)CCCCCCCCCCC(C)(C1=CN=C(C2=NC(C3=NC=C(C(C)(C)C)C=C3)=CC(C(C)(C)C)=C2)C=C1)C#N/ACN(C)C=O
758
8192/14/202265
Kelly
cl.1986.407
C-O Activation
x10.1246/cl.1986.4071986
NA11E-EOTf
ArylOTf
ArylPPh3
#N/A#N/A60DMFDMFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'OCsp2_arCsp2_arCsp2_ar-OCsp2_ar-OAryl-O[Aryl]-O-SO2-R'Aryl-OTf[Aryl]-OTfPolar36.7No baseNo BaseNo baseEasyOSO2-EWG
CHEMISTRY LETTERS
_0.53#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOS(=O)(=O)C(F)(F)FOS(=O)(=O)C(F)(F)FC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3#N/ACN(C)C=O
759
8202/14/202280
Gerry
chem.201502329
C-O Activation
x10.1002/chem.2015023292015
11.5E-NuOH
AllylH
N(Alkyl)Alkyldppf
#N/A#N/A60MeCNP-PPhosphine (Bidentate)PhosphineCsp3-Nsp3StrongOOHHCsp3Nsp3Csp3-ONsp3-HAllyl-O[Allyl]-OHN(Alkyl)Alkyl-H[N(Alkyl)Alkyl]-H#N/A#N/ANo baseNo BaseNo baseHardOH
CHEMISTRY-A EUROPEAN JOURNAL
_-0.813.21#N/A#N/A#N/A#N/A#N/A#REF!9.6512.031.706749553.2392069642.4729782574.96639928#REF!#REF!OHCC=CN(C)CC=CCC(C)Nc1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1#N/ACC#N
760
8212/14/202280
Gerry
chem.201502329
C-O Activation
x10.1002/chem.2015023292015
11.5E-NuOH
AllylH
N(Alkyl)Aryldppf
#N/A#N/A60MeCNP-PPhosphine (Bidentate)PhosphineCsp3-Nsp3StrongOOHHCsp3Nsp3Csp3-ONsp3-HAllyl-O[Allyl]-OHN(Alkyl)Aryl-H[N(Alkyl)Aryl]-H#N/A#N/ANo baseNo BaseNo baseHardOH
CHEMISTRY-A EUROPEAN JOURNAL
_-0.813.21#N/A#N/A#N/A#N/A#N/A#REF!15.1912.031.706749553.2392069642.4729782574.96639928#REF!#REF!OHCC=CN(C)C(C(=O)C)C=CCCC(=O)CN(C)c1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1#N/ACC#N
761
8232/14/202268
Gerry
c6cc09685a
Deleted
x10.1039/c6cc09685a2017
13E-NuOTs
VinylH
Alkyldtbbpy
#N/A#N/A25Cs2CO3DMFN-NbpyNitrogenCsp2-Csp3WeakOO-SO2-R'HCsp2Csp3Csp2-OCsp3-HVinyl-O[Vinyl]-O-SO2-R'Alkyl-H[Alkyl]-H#N/A#N/AIonic-CO3Cs+EasyOSO2-EDG
CHEM COMMUN
_0.361.72.530430542.115215273.4538974810.33#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5OS(=O)(=O)(C1=CC=C(C)C=C1)HC=CCCC=CCCCC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/ACN(C)C=O
762
6361/5/202234
Kelly
acscatal.7b02014
C-O Activation
x10.1021/acscatal.7b020142017
11.5E-NuOTf
ArylH
N(H)AlkylCyPAd-DalPhos
#N/A#N/A110NaOtButoluenetolueneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Nsp3WeakOO-SO2-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-SO2-R'N(H)Alkyl-H[N(H)Alkyl]-HNon-Polar2.38Ionic-OtBuNa+EasyOSO2-EWG
ACS CATALYSIS
_0.532.8589353663.2821934583.0705644124.0077900319#REF!5.6643.091.706749553.2392069642.4729782574.96639928#REF!#REF!OS(=O)(=O)C(F)(F)FHC1=CC=CC=C1NCC1=CC=CC=C1CNC[C@@]12C[C@](O3)(C)O[C@@](CC3(C)P1C4=CC=CC=C4P(C5CCCCC5)C6CCCCC6)(O2)C#N/ACc1ccccc1
763
8262/15/202244
Kelly
adsc.201100241
C-O Activation
x10.1002/adsc.2011002412011
1.21E-NuOH
ArylH
Benzyldppm
#N/A#N/A115KOHtoluenetoluene#N/APhosphine (Bidentate)Phosphine
Csp2_ar-Csp3-ring(s)
StrongOOHHCsp2_arCsp3-ring(s)Csp2_ar-OCsp3-ring(s)-HAryl-O[Aryl]-OHBenzyl-H[Benzyl]-HNon-Polar2.38Ionic-ORK+HardOH
ADVANCED SYNTHESIS & CATALYSIS
_-0.8110.94015.74#REF!12.1701.706749553.2392069642.4729782574.96639928#REF!#REF!21.3OHC1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1C(P(c1ccccc1)c2ccccc2)P(c3ccccc3)c4ccccc4#N/ACc1ccccc1
764
8272/15/2022120
Gerry
b803072c
C-O Activation
x10.1039/b803072c2008
11.2E-NuOTs
ArylZnX
BenzylPPh3
#N/A#N/A60THF/NMPPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp3-ring(s)
WeakOO-SO2-R'ZnCsp2_arCsp3-ring(s)Csp2_ar-OCsp3-ring(s)-ZnAryl-O[Aryl]-O-SO2-R'Benzyl-ZnX[Benzyl]-ZnX#N/A#N/ANo baseNo BaseNo baseEasyOSO2-EDG
CHEMICAL COMMUNICATIONS
_0.36#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XOS(=O)(=O)(C1=CC=C(C)C=C1)[Zn]ClC1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3#N/A#N/A
765
8282/15/202219
Gerry
s-0036-1590863
C-O Activation
x10.1055/s-0036-15908632017
11.5E-NuOCONEt2
ArylAl(iBu)2
ArylPCy3
#N/A#N/A25toluenePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
MediumOO-CO-R'AlCsp2_arCsp2_arCsp2_ar-OCsp2_ar-AlAryl-O[Aryl]-O-CO-R'Aryl-Al(iBu)2[Aryl]-Al(iBu)2#N/A#N/ANo baseNo BaseNo baseMediumOCO-EDGSYNLETT_0.3121.41#N/A#N/A#N/A#N/A#N/A#REF!27.6402.4811865675.826321844.1537542046.96337555#REF!#REF!128OC(N(CC)CC)=O[Al](CC(C)C)CC(C)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/ACc1ccccc1
766
8292/15/202294
Gerry
chem.201103050
C-O Activation
x10.1002/chem.2011030502012
No ligand11.5E-NuOTs
ArylMgX
Aryl#N/A#N/A#N/A60THF#N/A#N/A#N/A
Csp2_ar-Csp2_ar
WeakOO-SO2-R'MgCsp2_arCsp2_arCsp2_ar-OCsp2_ar-MgAryl-O[Aryl]-O-SO2-R'Aryl-MgX[Aryl]-MgX#N/A#N/ANo baseNo BaseNo baseEasyOSO2-EDG
CHEMISTRY-A EUROPEAN JOURNAL
_0.36#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2OS(=O)(=O)(C1=CC=C(C)C=C1)[Mg]ClC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1#N/A#N/AC1CCOC1
767
8302/16/2022337
Gerry
ja2082087
C-H Activation
x10.1021/ja20820872011
12E-NuH
AlkylCl
Aryl(R)-BINAP
#N/A#N/A60NaOtButolueneP-PPhosphine (Bidentate)PhosphineCsp3-Csp2_arNu-HHXCsp3Csp2_arCsp3-HCsp2_ar-XAlkyl-H[Alkyl]-Aryl-Cl[Aryl]-Cl#N/A#N/AIonic-OtBuNa+
J AM CHEM SOC
_2.8589353663.2821934583.0705644124.0077900319#REF!0#REF!#REF!XHClCCC1=CC=CC=C1CCC1=CC=CC=C1c1ccc(cc1)P(c2ccccc2)c3ccc4ccccc4c3-c5c(ccc6ccccc56)P(c7ccccc7)c8ccccc8#N/ACc1ccccc1
768
8322/16/20229
Gerry
anie.202110391
C-O Activation
x10.1002/anie.2021103912022
NA
12E-EOAc
AlkylI
Aryl4,4',4''-Trimethoxy-2,2':6',2''-terpyridine
#N/A#N/A25THF#N/AterpyNitrogenCsp3-Csp2_arMediumOO-CO-R'XCsp3Csp2_arCsp3-OCsp2_ar-XAlkyl-O[Alkyl]-O-CO-R'Aryl-I[Aryl]-I#N/A#N/ANo baseNo BaseNo baseMediumOCO-EDG
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.317.81#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOC(C)=OICCC1=CC=CC=C1CCC1=CC=CC=C1COC1=CC(=NC=C1)C2=CC(=CC(=N2)C3=NC=CC(=C3)OC)OC#N/AC1CCOC1
769
8332/17/202236
Long
anie.202012048
C-N Activation
x10.1002/anie.2020120482021
NA
E-NuN(Bn)Boc
CarbonylBpin
ArylBenz-ICy.HCl
#N/A#N/A120K3PO4tolueneNHCBImN-R2CarbeneCsp2-Csp2_arNN(Bn)BocBCsp2Csp2_arCsp2-NCsp2_ar-BCarbonyl-N[Carbonyl]-N(Bn)BocAryl-Bpin[Aryl]-Bpin#N/A#N/AIonic-PO4K+#N/A#N/A
ANGEW CHEM INT EDIT
_2.244780372.9696246982.6072025343.5700586912.37#REF!24.0118.463.1465845953.9827799333.5646822646.55194167#REF!#REF!131.5N(C(=O)OC(C)(C)(C))C(C1=CC=CC=C1)[B](OC1(C)(C))OC1(C)(C)CC(=O)CC1=CC=CC=C1C(=O)CCC1=CC=CC=C1C12=CC=CC=C1N(C=[N+]2C3CCCCC3)C4CCCCC4.[Cl-]#N/ACc1ccccc1
770
8342/17/2022#N/A#N/A
s0040403999004396
#N/A#N/A#N/Ax#N/A#N/A#N/A#N/A#N/A
NAE-NuOTf
VinylMgX
Alkyldppp
#N/A#N/ArttolueneP-PPhosphine (Bidentate)PhosphineCsp2-Csp3WeakOO-SO2-R'MgCsp2Csp3Csp2-OCsp3-MgVinyl-O[Vinyl]-O-SO2-R'Alkyl-MgX[Alkyl]-MgX#N/A#N/ANo baseNo BaseNo baseEasyOSO2-EWG#N/A#N/A0.53#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OS(=O)(=O)C(F)(F)F[Mg]ClC=CCCC=CCCP(c1ccccc1)(c2ccccc2)CCCP(c3ccccc3)c4ccccc4#N/ACc1ccccc1
771
8352/17/2022#N/A#N/As0040403999004396#N/A#N/A#N/Ax#N/A#N/A#N/A#N/A#N/A
NA
E-NuOTf
VinylMgX
Benzyldppp
#N/A#N/A55tolueneP-PPhosphine (Bidentate)Phosphine
Csp2-Csp3-ring(s)
WeakOO-SO2-R'MgCsp2Csp3-ring(s)Csp2-OCsp3-ring(s)-MgVinyl-O[Vinyl]-O-SO2-R'Benzyl-MgX[Benzyl]-MgX#N/A#N/ANo baseNo BaseNo baseEasyOSO2-EWG#N/A#N/A0.53#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!29OS(=O)(=O)C(F)(F)F[Mg]ClC=CCC1=CC=CC=C1C=CCC1=CC=CC=C1P(c1ccccc1)(c2ccccc2)CCCP(c3ccccc3)c4ccccc4#N/ACc1ccccc1
772
8362/17/2022#N/A#N/As0040403999004396#N/A#N/A#N/Ax#N/A#N/A#N/A#N/A#N/A
NAE-NuOTf
CarbonylMgX
Alkyldppp
#N/A#N/ArttolueneP-PPhosphine (Bidentate)PhosphineCsp2-Csp3WeakOO-SO2-R'MgCsp2Csp3Csp2-OCsp3-MgCarbonyl-O[Carbonyl]-O-SO2-R'Alkyl-MgX[Alkyl]-MgX#N/A#N/ANo baseNo BaseNo baseEasyOSO2-EWG#N/A#N/A0.53#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OS(=O)(=O)C(F)(F)F[Mg]ClCC(=O)CCCC(=O)CCCCP(c1ccccc1)(c2ccccc2)CCCP(c3ccccc3)c4ccccc4#N/ACc1ccccc1
773
8372/17/2022130
Long
c39830000112
C-O Activation
x10.1039/c398300001121983
E-NuOPh
AlkylMgX
Aryldmpe
#N/A#N/AP-PPhosphine (Bidentate)PhosphineCsp3-Csp2_arStrongOO-Csp2MgCsp3Csp2_arCsp3-OCsp2_ar-MgAlkyl-O[Alkyl]-O-Csp2Aryl-MgX[Aryl]-MgX#N/A#N/ANo baseNo BaseNo baseHardO-EDG
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS
_-0.3212.86#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2OC1=CC=CC=C1[Mg]ClCCC1=CC=CC=C1CCC1=CC=CC=C1CP(C)CCP(C)C#N/A#N/A
774
8382/17/2022130
Long
c39830000112
C-O Activation
x10.1039/c398300001121983
E-NuOPh
AlkylMgX
Alkyldmpe
#N/A#N/AP-PPhosphine (Bidentate)PhosphineCsp3-Csp3StrongOO-Csp2MgCsp3Csp3Csp3-OCsp3-MgAlkyl-O[Alkyl]-O-Csp2Alkyl-MgX[Alkyl]-MgX#N/A#N/ANo baseNo BaseNo baseHardO-EDG
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS
_-0.3212.86#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OC1=CC=CC=C1[Mg]ClCCCCCCCCCP(C)CCP(C)C#N/A#N/A
775
8392/17/2022169
Long
s0040-4020(01)87621-3
C-O Activation
x10.1016/s0040-4020(01)87621-31986
E-NuOPh
AlkylMgX
Benzyl(R)-PROPHOS
#N/A#N/A#N/APhosphine (Bidentate)Phosphine
Csp3-Csp3-ring(s)
StrongOO-Csp2MgCsp3Csp3-ring(s)Csp3-OCsp3-ring(s)-MgAlkyl-O[Alkyl]-O-Csp2Benzyl-MgX[Benzyl]-MgX#N/A#N/ANo baseNo BaseNo baseHardO-EDG
TETRAHEDRON
_-0.3212.86#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!29OC1=CC=CC=C1[Mg]ClCCCC1=CC=CC=C1CCCC1=CC=CC=C1C[C@@H](P(c1ccccc1)c2ccccc2)CP(c3ccccc3)c4ccccc4#N/A#N/A
776
8402/17/2022169
Long
s0040-4020(01)87621-3
C-O Activation
x10.1016/s0040-4020(01)87621-31986
E-NuOPh
AlkylMgX
Benzyl(S,S)-Chiraphos
#N/A#N/A#N/APhosphine (Bidentate)Phosphine
Csp3-Csp3-ring(s)
StrongOO-Csp2MgCsp3Csp3-ring(s)Csp3-OCsp3-ring(s)-MgAlkyl-O[Alkyl]-O-Csp2Benzyl-MgX[Benzyl]-MgX#N/A#N/ANo baseNo BaseNo baseHardO-EDG
TETRAHEDRON
_-0.3212.86#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!29OC1=CC=CC=C1[Mg]ClCCCC1=CC=CC=C1CCCC1=CC=CC=C1
C[C@@H]([C@H](C)P(c1ccccc1)c2ccccc2)P(c3ccccc3)c4ccccc4
#N/A#N/A
777
8412/17/202221
c7cc06717h
C-O Activation
x10.1039/c7cc06717h2017
NAE-Nu2-methyl-4,6-bis(p-tolyloxy)-1,3,5-triazine
ArylH
Vinyldppf
#N/A#N/AK3PO4toluenedioxanP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp2StrongOO-Csp2HCsp2_arCsp2Csp2_ar-OCsp2-HAryl-O[Aryl]-O-Csp2Vinyl-H[Vinyl]-H#N/A#N/AIonic-PO4K+#N/A#N/A
CHEMICAL COMMUNICATIONS
_-0.3242.192.244780372.9696246982.6072025343.5700586912.37#REF!6.0701.706749553.2392069642.4729782574.96639928#REF!#REF!115.6OC1=NC(OC2=CC=C(C)C=C2)=NC(OC3=CC=C(C)C=C3)=N1HC1=CC=CC=C1C=CC1=CC=CC=C1C=Cc1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1#N/ACc1ccccc1
778
8422/17/2022102
Long
ol502682q
C-O Activation
x10.1021/ol502682q2014
E-EOTs
AlkylCl
Carbonyl5'-5 dmbpy
#N/A#N/AMgCl2THFCH3TBAI#N/AbpyNitrogenCsp3-Csp2WeakOO-SO2-R'XCsp3Csp2Csp3-OCsp2-XAlkyl-O[Alkyl]-O-SO2-R'Carbonyl-Cl[Carbonyl]-Cl#N/A#N/A#N/ANo Base#N/AEasyOSO2-EDG
ORGANIC LETTERS
_0.36#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOS(=O)(=O)(C1=CC=C(C)C=C1)ClCCCC(=O)CCCC(=O)CCCC1=CC=C(C2=NC=C(C)C=C2)N=C1#N/AC1CCOC1
779
8432/17/20222078-Febja5029793
C-O Activation
x10.1021/ja50297932014
E-NuOTs
ArylH
Carbonyldppf
#N/A#N/A60DMAMnNaIP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp2WeakOO-SO2-R'HCsp2_arCsp2Csp2_ar-OCsp2-HAryl-O[Aryl]-O-SO2-R'Carbonyl-H[Carbonyl]-H#N/A#N/ANo baseNo BaseNo baseEasyOSO2-EDG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.36#N/A#N/A#N/A#N/A#N/A#REF!4.517.071.706749553.2392069642.4729782574.96639928#REF!#REF!199.9OS(=O)(=O)(C1=CC=C(C)C=C1)HC1=CC=CC=C1CC(=O)CC1=CC=CC=C1C(=O)CCc1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1#N/ACN(C)C(C)=O
780
8442/17/202217
Long
s41929-020-00560-3
C-O Activation
x10.1038/s41929-020-00560-32021
E-NuOPiv
ArylZnX
ArylPCy3
#N/A#N/ADMATHFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
MediumOO-CO-R'ZnCsp2_arCsp2_arCsp2_ar-OCsp2_ar-ZnAryl-O[Aryl]-O-CO-R'Aryl-ZnX[Aryl]-ZnX#N/A#N/ANo baseNo BaseNo baseMediumOCO-EDG
NATURE CATALYSIS
_0.3320.28#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XOC(=O)C(C)(C)C[Zn]ClC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/ACN(C)C(C)=O
781
8452/17/202289
Kelly
s-0036-1588845
C-N Activation
10.1055/s-0036-15888452017
NAE-Nupyrrolidine-2,5-dione
CarbonylZnX
ArylPPh3
#N/A#N/AEt2OPPhosphine (Monodentate)PhosphineCsp2-Csp2_arNZnCsp2Csp2_arCsp2-NCsp2_ar-ZnCarbonyl-N[Carbonyl]-Aryl-ZnX[Aryl]-ZnX#N/A#N/ANo baseNo BaseNo base#N/A#N/A
SYNTHESIS-STUTTGART
_#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XN1C(=O)CCC1(=O)[Zn]ClCC(=O)CC1=CC=CC=C1C(=O)CCC1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3#N/ACCOCC
782
8462/22/20221
Gerry
d1cc00634g
C-O Activation
xx10.1039/d1cc00634g2021
13E-NuOTf
ArylH
Vinyldcype
#N/A#N/A100DMAP-PPhosphine (Bidentate)PhosphineCsp2_ar-Csp2WeakOO-SO2-R'HCsp2_arCsp2Csp2_ar-OCsp2-HAryl-O[Aryl]-O-SO2-R'Vinyl-H[Vinyl]-H#N/A#N/ANo baseNo BaseNo baseEasyOSO2-EWG
CHEMICAL COMMUNICATIONS
_0.53#N/A#N/A#N/A#N/A#N/A#REF!6.0701.706749553.2392069642.4729782574.96639928#REF!#REF!115.6OS(=O)(=O)C(F)(F)FHC1=CC=CC=C1C=CC1=CC=CC=C1C=CP(C1CCCCC1)(C2CCCCC2)CCP(C3CCCCC3)C4CCCCC4#N/ACN(C)C(C)=O
783
8472/22/20221
Gerry
d1cc00634g
C-O Activation
xx10.1039/d1cc00634g2021
13E-NuOPiv
ArylH
Vinyl(R,R)-Ph-BPE
#N/A#N/A100toluene#N/APhosphine (Bidentate)PhosphineCsp2_ar-Csp2MediumOO-CO-R'HCsp2_arCsp2Csp2_ar-OCsp2-HAryl-O[Aryl]-O-CO-R'Vinyl-H[Vinyl]-H#N/A#N/ANo baseNo BaseNo baseMediumOCO-EDG
CHEMICAL COMMUNICATIONS
_0.3320.28#N/A#N/A#N/A#N/A#N/A#REF!6.0701.706749553.2392069642.4729782574.96639928#REF!#REF!115.6OC(=O)C(C)(C)CHC1=CC=CC=C1C=CC1=CC=CC=C1C=C[C@H]1(C2=CC=CC=C2)CC[C@H](C3=CC=CC=C3)P1CCP4[C@@H](C5=CC=CC=C5)CC[C@@H]4C6=CC=CC=C6#N/ACc1ccccc1
784
8482/22/20222
Gerry
d1cc02837e
C-O Activation
x10.1039/d1cc02837e2021
NA
12E-EOTs
AlkylBr
Alkyl2-(4,5-dihydro-1H-imidazol-2-yl)pyridine
#N/A#N/A60TBAIK2CO3NMP#N/Apy-imNitrogenCsp3-Csp3WeakOO-SO2-R'XCsp3Csp3Csp3-OCsp3-XAlkyl-O[Alkyl]-O-SO2-R'Alkyl-Br[Alkyl]-Br#N/A#N/AIonic-CO3K+EasyOSO2-EDG
CHEMICAL COMMUNICATIONS
_0.361.72.530430542.115215273.4538974810.33#REF!0#REF!#REF!XOS(=O)(=O)(C1=CC=C(C)C=C1)BrCCCCCCCCC1CN=C(N1)C2=CC=CC=N2#N/ACN1CCCC1=O
785
8502/22/20223
Gerry
anie.202014340
C-O Activation
x10.1002/anie.2020143402021
12E-NuOTf
ArylH
N(H)AlkylPAd2-DalPhos
#N/A#N/A100DBUtolueneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Nsp3WeakOO-SO2-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-SO2-R'N(H)Alkyl-H[N(H)Alkyl]-H#N/A#N/ANitrogenNitrogen(neutral)EasyOSO2-EWG
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.531.7105540393.2426955962.4766248184.97338019#REF!5.6643.091.706749553.2392069642.4729782574.96639928#REF!#REF!OS(=O)(=O)C(F)(F)FHC1=CC=CC=C1NCC1=CC=CC=C1CNC[C@@]1(C[C@](O[C@@](C)(C2)O1)(O3)C)P(C32C)C4=CC=CC=C4P([C@]56C)C7(CC(O[C@@](C6)(C)O7)(O5)C)C#N/ACc1ccccc1
786
8512/22/20224
Gerry
anie.201805611
C-O Activation
x10.1002/anie.2018056112018
12E-NuOH
AllylH
N(Alkyl)Alkyldppf
#N/A#N/A80Bu4NOAcDMAP-PPhosphine (Bidentate)PhosphineCsp3-Nsp3StrongOOHHCsp3Nsp3Csp3-ONsp3-HAllyl-O[Allyl]-OHN(Alkyl)Alkyl-H[N(Alkyl)Alkyl]-H#N/A#N/ANitrogenNitrogen(charged)HardOH
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.813.212.9420199955.1753858444.058702925.80535687#REF!9.6512.031.706749553.2392069642.4729782574.96639928#REF!#REF!OHCC=CN(C)CC=CCC(C)Nc1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1#N/ACN(C)C(C)=O
787
8522/22/20224
Gerry
anie.201805611
C-O Activation
x10.1002/anie.2018056112018
12E-NuOH
AllylH
Hetdppf
#N/A#N/A80Bu4NOAcDMAP-PPhosphine (Bidentate)PhosphineCsp3-Csp2_arStrongOOHHCsp3Csp2_arCsp3-OCsp2_ar-HAllyl-O[Allyl]-OHHet-H[Het]-H#N/A#N/ANitrogenNitrogen(charged)HardOH
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_-0.813.212.9420199955.1753858444.058702925.80535687#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8OHCC=CC1=NC=CC=C1C=CCC1=CC=NC=C1c1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1#N/ACN(C)C(C)=O
788
8562/23/20229
Gerry
acs.orglett.9b04497
C-N Activation
x10.1021/acs.orglett.9b044972020
11.2E-Epyrrolidine-2,5-dione
Carbonyl2,4,6-Tris(4-Methoxyphenyl)Pyridinium+BF4-
Alkylphen
#N/A#N/A60MgCl2NMPN-NbpyNitrogenCsp2-Csp3NNCsp2Csp3Csp2-NCsp3-NCarbonyl-N[Carbonyl]-Alkyl-2,4,6-Tris(4-Methoxyphenyl)Pyridinium+BF4-[Alkyl]-2,4,6-Tris(4-Methoxyphenyl)Pyridinium+BF4-#N/A#N/A#N/ANo Base#N/A#N/A#N/AORG LETT_#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XN1C(=O)CCC1(=O)[N+]1=C(C2=CC=C(OC)C=C2)C=C(C3=CC=C(OC)C=C3)C=C1C4=CC=C(OC)C=C4.F[B-](F)(F)FCC(=O)CCCC(=O)CCCCC1(C(N=CC=C2)=C2C=C3)=C3C=CC=N1#N/ACN1CCCC1=O
789
8572/23/202210
Gerry
s-0037-1610084
C-N Activation
x10.1055/s-0037-16100842018
12E-NuTriphenylpyridinium+BF4-
BenzylB(OH)2
Vinylphen
#N/A#N/A60K3PO4EtOHdioxaneN-NbpyNitrogen
Csp3-ring(s)-Csp2
NPyridiniumBCsp3-ring(s)Csp2Csp3-ring(s)-NCsp2-BBenzyl-N[Benzyl]-PyridiniumVinyl-B(OH)2[Vinyl]-B(OH)2#N/A#N/AIonic-PO4K+#N/A#N/A
SYNTHESIS-STUTTGART
_#N/A2.244780372.9696246982.6072025343.5700586912.37#REF!9.2440.461.923.2525052362.5862526186.55955503#REF!#REF!120.7[N+]1=C(C=C(C=C1C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.F[B-](F)(F)FB(O)OCC1=CC=CC=C1C=CCC1=CC=CC=C1C=CC1(C(N=CC=C2)=C2C=C3)=C3C=CC=N1#N/AOCC
790
8582/23/20225
Gerry
acs.orglett.6b00819
C-O Activation
x10.1021/acs.orglett.6b008192016
1.51E-NuOCONMe2
ArylH
Aryldcype
#N/A#N/A120PhMeP-PPhosphine (Bidentate)Phosphine
Csp2_ar-Csp2_ar
MediumOO-CO-R'HCsp2_arCsp2_arCsp2_ar-OCsp2_ar-HAryl-O[Aryl]-O-CO-R'Aryl-H[Aryl]-H#N/A#N/ANo baseNo BaseNo baseMediumOCO-EDG
ORGANIC LETTERS
_0.3117.73#N/A#N/A#N/A#N/A#N/A#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5OC(=O)N(C)CHC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(C1CCCCC1)(C2CCCCC2)CCP(C3CCCCC3)C4CCCCC4#N/A#N/A
791
8592/23/202219
Gerry
acscatal.7b00442
C-N Activation
xx10.1021/acscatal.7b004422017
No ligand11E-Nu8-aminoquinoline
CarbonylOH
Alkyl#N/A#N/A#N/A80-100#N/A#N/A#N/ACsp2-Csp3NOCsp2Csp3Csp2-NCsp3-OCarbonyl-N[Carbonyl]-Alkyl-OH[Alkyl]-OH#N/A#N/ANo baseNo BaseNo base#N/A#N/AACS Catal._#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XNC1=CC=CC2=C1N=CC=C2OCC(=O)CCCC(=O)CCCC#N/A#N/A#N/A
792
8612/28/2022252
Gerry
jacs.1c08399
C-O Activation
x10.1021/jacs.1c083992021
11.2E-NuOTs
VinylBpin
ArylP(4-FC6H4)3
#N/A#N/A70K3PO4THF#N/APhosphine (Monodentate)PhosphineCsp2-Csp2_arWeakOO-SO2-R'BCsp2Csp2_arCsp2-OCsp2_ar-BVinyl-O[Vinyl]-O-SO2-R'Aryl-Bpin[Aryl]-Bpin#N/A#N/AIonic-PO4K+EasyOSO2-EDG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!24.0118.463.1465845953.9827799333.5646822646.55194167#REF!#REF!131.5OS(=O)(=O)(C1=CC=C(C)C=C1)[B](OC1(C)(C))OC1(C)(C)C=CC1=CC=CC=C1C=CC1=CC=CC=C1P(C1=CC=C(F)C=C1)(C2=CC=C(F)C=C2)C3=CC=C(F)C=C3#N/AC1CCOC1
793
8622/28/2022252
Gerry
jacs.1c08399
C-O Activation
x10.1021/jacs.1c083992021
11.2E-NuOTs
VinylBpin
ArylPCy3
#N/A#N/A70K3PO4tAmOHPPhosphine (Monodentate)PhosphineCsp2-Csp2_arWeakOO-SO2-R'BCsp2Csp2_arCsp2-OCsp2_ar-BVinyl-O[Vinyl]-O-SO2-R'Aryl-Bpin[Aryl]-Bpin#N/A#N/AIonic-PO4K+EasyOSO2-EDG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!24.0118.463.1465845953.9827799333.5646822646.55194167#REF!#REF!131.5OS(=O)(=O)(C1=CC=C(C)C=C1)[B](OC1(C)(C))OC1(C)(C)C=CC1=CC=CC=C1C=CC1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/ACCC(C)(C)O
794
8632/28/2022253
Gerry
c9cc08079a
C-O Activation
x10.1039/c9cc08079a2020
12E-NuO(Ring-Opening)
AlkylB(OH)2
Aryldtbbpy
#N/A#N/A70EtOHN-NbpyNitrogenCsp3-Csp2_arWeakO
O(Ring-Opening)
BCsp3Csp2_arCsp3-OCsp2_ar-BAlkyl-O[Alkyl]-O(Ring-Opening)Aryl-B(OH)2[Aryl]-B(OH)2#N/A#N/ANo baseNo BaseNo base#N/A#N/A
CHEMICAL COMMUNICATIONS
_1#N/A#N/A#N/A#N/A#N/A#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OCB(O)OCCC1=CC=CC=C1CCC1=CC=CC=C1CC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/AOCC
795
8642/28/2022403
Gerry
jo070313d
C-H Activation
x10.1021/jo070313d2007
1.21E-NuH
AlkylX
AryliPr/PPh3
#N/A#N/A100NaOtButoluene#N/ATwo ligand (Carbene and monophosphine)MixedCsp3-Csp2_arNu-HHXCsp3Csp2_arCsp3-HCsp2_ar-XAlkyl-H[Alkyl]-Aryl-X[Aryl]-X#N/A#N/AIonic-OtBuNa+
J ORG CHEM
_2.8589353663.2821934583.0705644124.0077900319#REF!0#REF!#REF!XHClCCC1=CC=CC=C1CCC1=CC=CC=C1#N/ACc1ccccc1
796
8652/28/2022404
Gerry
jacs.5b02945
C-H Activation
x10.1021/jacs.5b029452015
11E-NuH
AlkylBr
VinylIPr·HCl
#N/A#N/A6LiILiHMDSTHFNHC#N/A#N/ACsp3-Csp2Nu-HHXCsp3Csp2Csp3-HCsp2-XAlkyl-H[Alkyl]-Vinyl-Br[Vinyl]-Br#N/A#N/AIonicNitrogen(neutral)Li+
CHEM COMMUN
_1.7105540393.2426955962.4766248184.9733801926#REF!0#REF!#REF!XHBrCCC=CCCC=C#N/A#N/AC1CCOC1
797
8662/28/2022256
Gerry
c8qo00764k
C-O Activation
xx10.1039/c8qo00764k2018
31E-NuOH
AlkylH
BenzylTMEDA
#N/A#N/A130KOtButoluene#N/AN-NNitrogen
Csp3-Csp3-ring(s)
StrongOOHHCsp3Csp3-ring(s)Csp3-OCsp3-ring(s)-HAlkyl-O[Alkyl]-OHBenzyl-H[Benzyl]-H#N/A#N/AIonic-OtBuK+HardOH
ORGANIC CHEMISTRY FRONTIERS
_-0.813.212.8589353663.2821934583.0705644124.0077900319#REF!12.1701.706749553.2392069642.4729782574.96639928#REF!#REF!21.3OHCCCC1=CC=CC=C1CCCC1=CC=CC=C1CN(C)CCN(C)C#N/ACc1ccccc1
798
8673/9/2022408
Gerry
c4cc00959b
C-H Activation
x10.1039/c4cc00959b2014
1.21E-NuH
AlkylX
ArylIPr
#N/A#N/A110NaOtButolueneNHCCarbeneCarbeneCsp3-Csp2_arNu-HHXCsp3Csp2_arCsp3-HCsp2_ar-XAlkyl-H[Alkyl]-Aryl-X[Aryl]-X#N/A#N/AIonic-OtBuNa+
Chem. Commun.
_2.8589353663.2821934583.0705644124.0077900319#REF!0#REF!#REF!XHClCCC1=CC=CC=C1CCC1=CC=CC=C1CC(C)C(C=CC=C1C(C)C)=C1N2C=CN(C3=C(C(C)C)C=CC=C3C(C)C)C2#N/ACc1ccccc1
799
8683/9/2022257
Gerry
nchem.2741
C-O Activation
x10.1038/nchem.27412017
10.6E-NuOMe
ArylB(OH)2
ArylTriceraPhos
#N/A#N/A70toluene#N/APhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
StrongOO-Csp3BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-Csp3Aryl-B(OH)2[Aryl]-B(OH)2#N/A#N/ANo baseNo BaseNo baseHardO-EDG
NATURE CHEMISTRY
_-0.2812.86#N/A#N/A#N/A#N/A#N/A#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OCB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1#N/ACc1ccccc1
800
8693/9/2022258
Gerry
anie.202200352
C-O Activation
x10.1002/anie.2022003522022
11.1E-NuOTs
ArylH
N(Alkyl)CarbonylPAd2-DalPhos
#N/A#N/A110NaTFADBUtolueneP-PPhosphine (Bidentate)PhosphineCsp2_ar-Nsp3WeakOO-SO2-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-SO2-R'N(Alkyl)Carbonyl-H[N(Alkyl)Carbonyl]-H#N/A#N/ANitrogenNitrogen(neutral)EasyOSO2-EDG
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
_0.361.7105540393.2426955962.4766248184.97338019#REF!9.3129.11.706749553.2392069642.4729782574.96639928#REF!#REF!OS(=O)(=O)(C1=CC=C(C)C=C1)HC1=CC=CC=C1N(C)(C(=O)C)C1=CC=CC=C1CC(=O)N(C)C[C@@]1(C[C@](O[C@@](C)(C2)O1)(O3)C)P(C32C)C4=CC=CC=C4P([C@]56C)C7(CC(O[C@@](C6)(C)O7)(O5)C)C#N/ACc1ccccc1
801
8703/9/2022259
Gerry
jacs.1c11044
C-O Activation
x10.1021/jacs.1c110442021
10.5E-NuOCO2Me
AlkylH
OR(R)-Cl-MeO-biphep
#N/A#N/A#N/APhosphine (Bidentate)PhosphineCsp3-Osp2MediumOO-CO-R'HCsp3Osp2Csp3-OOsp2-HAlkyl-O[Alkyl]-O-CO-R'OR-H[OR]-H#N/A#N/ANo baseNo BaseNo base#N/A#N/A
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.318.58#N/A#N/A#N/A#N/A#N/A#REF!3.2120.231.706749553.2392069642.4729782574.96639928#REF!#REF!OC(=O)OCHCCOCCO#N/A#N/A
802
8252/15/202248
Kelly
chem.201605095
C-O Activation
x10.1002/chem.2016050952016
d, X=OTfE-NuOTf
ArylH
N(H)AlkylPAd-DalPhos
#N/A#N/A90NaOtButoluenetoluene#N/APhosphine (Bidentate)PhosphineCsp2_ar-Nsp3WeakOO-SO2-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-SO2-R'N(H)Alkyl-H[N(H)Alkyl]-HNon-Polar2.38Ionic-OtBuNa+EasyOSO2-EWG
CHEMISTRY-A EUROPEAN JOURNAL
_0.532.8589353663.2821934583.0705644124.0077900319#REF!5.6643.091.706749553.2392069642.4729782574.96639928#REF!#REF!OS(=O)(=O)C(F)(F)FHC1=CC=CC=C1NCC1=CC=CC=C1CNC[C@@]12C[C@@]3(C)OC(C)(P1C4=CC=CC=C4P(C5=C(C)C=CC=C5)C6=C(C)C=CC=C6)C[C@](O2)(C)O3#N/ACc1ccccc1
803
8723/10/2022261
Gerry
ncomms11073
C-O Activation
x10.1038/ncomms110732016
13E-NuOTf
ArylH
NH2PAd-DalPhos
#N/A#N/A25LiOtbuNaOtButoluenedioxane#N/APhosphine (Bidentate)PhosphineCsp2_ar-Nsp3WeakOO-SO2-R'HCsp2_arNsp3Csp2_ar-ONsp3-HAryl-O[Aryl]-O-SO2-R'NH2-H[NH2]-H#N/A#N/AIonic-OtBuNa+EasyOSO2-EWG
NATURE COMMUNICATIONS
_0.532.8589353663.2821934583.0705644124.0077900319#REF!2.26#N/A1.706749553.2392069642.4729782574.96639928#REF!#REF!#N/AOS(=O)(=O)C(F)(F)FHC1=CC=CC=C1NC1=CC=CC=C1NC[C@@]12C[C@@]3(C)OC(C)(P1C4=CC=CC=C4P(C5=C(C)C=CC=C5)C6=C(C)C=CC=C6)C[C@](O2)(C)O3#N/ACc1ccccc1
804
8743/10/2022260
Gerry
science.abj4213
C-O Activation
x10.1126/science.abj42132021
10.6E-NuOMe
BenzylB(OH)2
ArylTriceraPhos
#N/A#N/A60toluene#N/APhosphine (Monodentate)Phosphine
Csp3-ring(s)-Csp2_ar
StrongOO-Csp3BCsp3-ring(s)Csp2_arCsp3-ring(s)-OCsp2_ar-BBenzyl-O[Benzyl]-O-Csp3Aryl-B(OH)2[Aryl]-B(OH)2#N/A#N/ANo baseNo BaseNo baseHardO-EDGSCIENCE_-0.28#N/A#N/A#N/A#N/A#N/A#N/A#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OCB(O)OCC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1#N/ACc1ccccc1
805
8753/10/2022262
Gerry
c5cc03113c
C-O Activation
x10.1039/c5cc03113c2015
NA
1.51E-EOH
CarbonylBr
Alkylbpy
#N/A#N/A25MgCl2DMFMeCNN-NbpyNitrogenCsp2-Csp3StrongOOHXCsp2Csp3Csp2-OCsp3-XCarbonyl-O[Carbonyl]-OHAlkyl-Br[Alkyl]-Br#N/A#N/A#N/ANo Base#N/AHardOH
CHEMICAL COMMUNICATIONS
_-0.814.79#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOBrCC(=O)CCCC(=O)CCCCC1(C2=NC=CC=C2)=CC=CC=N1#N/ACN(C)C=O
806
8763/10/2022263
Gerry
acscatal.9b00521
C-O Activation
x10.1021/acscatal.9b005212019
NA
12E-EOH
CarbonylBr
AlkylMe2bpy
#N/A#N/A30DMA#N/AbpyNitrogenCsp2-Csp3StrongOOHXCsp2Csp3Csp2-OCsp3-XCarbonyl-O[Carbonyl]-OHAlkyl-Br[Alkyl]-Br#N/A#N/ANo baseNo BaseNo baseHardOH
ACS CATALYSIS
_-0.814.79#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOBrCC(=O)CCCC(=O)CCCCCc1ccnc(c2nccc(C)c2)c1#N/ACN(C)C(C)=O
807
8773/10/2022264
Gerry
jacs.0c13093
C-O Activation
xx10.1021/jacs.0c13093x2021
12E-EOH
AlkylBr
Aryldtbbpy
#N/A#N/A25LiBrNMPN-NbpyNitrogenCsp3-Csp2_arStrongOOHXCsp3Csp2_arCsp3-OCsp2_ar-XAlkyl-O[Alkyl]-OHAryl-Br[Aryl]-Br#N/A#N/A#N/ANo Base#N/AHardOH
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_-0.813.21#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOBrCCC1=CC=CC=C1CCC1=CC=CC=C1CC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/ACN1CCCC1=O
808
8783/10/2022418
Gerry
acs.organomet.9b00668
C-H Activation
x10.1021/acs.organomet.9b006682019
No ligand11Nu-NuH
HetH
Het#N/A#N/A#N/Atoluene#N/A#N/A#N/A
Csp2_ar-Csp2_ar
Nu-HHHCsp2_arCsp2_arCsp2_ar-HCsp2_ar-HHet-H[Het]-Het-H[Het]-H#N/A#N/ANo baseNo BaseNo base_#N/A#N/A#N/A#N/A#N/A#REF!9.412.891.706749553.2392069642.4729782574.96639928#REF!#REF!149.8HHC1=NC=CC=C1C1=NC=CC=C1C1=CC=NC=C1C1=CC=NC=C1#N/A#N/ACc1ccccc1
809
8793/10/2022419
Gerry
nature22813
C-H Activation
xx10.1038/nature22813x2017
21E-NuH
AlkylBr
Alkyl4,4'-Dimethoxy-2,2'-bipyridine
#N/A#N/A50K2CO3MeCNH2ON-NbpyNitrogenCsp3-Csp3Nu-HHXCsp3Csp3Csp3-HCsp3-XAlkyl-H[Alkyl]-Alkyl-Br[Alkyl]-Br#N/A#N/AIonic-CO3K+_1.72.530430542.115215273.4538974810.33#REF!0#REF!#REF!XHBrCCCCCCCCCOC1=CC=NC(C2=NC=CC(OC)=C2)=C1#N/ACC#N
810
8803/10/2022420
Gerry
chem.201406457
C-H Activation
x10.1002/chem.2014064572015
21E-NuH
AlkylCl
Aryl1,3-Bis(2,6-dibenzhydryl-4-methylphenyl)-1H-imidazole-3-ium
#N/A#N/A80NaOtButoluene#N/ACarbeneCarbeneCsp3-Csp2_arNu-HHXCsp3Csp2_arCsp3-HCsp2_ar-XAlkyl-H[Alkyl]-Aryl-Cl[Aryl]-Cl#N/A#N/AIonic-OtBuNa+_2.8589353663.2821934583.0705644124.0077900319#REF!0#REF!#REF!XHClCCC1=CC=CC=C1CCC1=CC=CC=C1CC1=CC(=C(C(=C1)C(C2=CC=CC=C2)C3=CC=CC=C3)N4C=C[N+](=C4)C5=C(C=C(C=C5C(C6=CC=CC=C6)C7=CC=CC=C7)C)C(C8=CC=CC=C8)C9=CC=CC=C9)C(C1=CC=CC=C1)C1=CC=CC=C1#N/ACc1ccccc1
811
8813/10/2022265
Gerry
ja00502a074
C-O Activation
xx10.1021/ja00502a0741979
E-NuOMe
VinylH
ArylPPh3
#N/A#N/AbenzenePPhosphine (Monodentate)PhosphineCsp2-Csp2_arStrongOO-Csp3HCsp2Csp2_arCsp2-OCsp2_ar-HVinyl-O[Vinyl]-O-Csp3Aryl-H[Aryl]-H#N/A#N/ANo baseNo BaseNo baseHardO-EDG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_-0.286.71#N/A#N/A#N/A#N/A#N/A#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5OCHC=CC1=CC=CC=C1C=CC1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3#N/Ac1ccccc1
812
8823/10/2022266
Gerry
ol702499h
C-O Activation
x10.1021/ol702499h2007
11.2E-NuOTf
ArylMgX
AlkylDPEphos
#N/A#N/A25THFNMPP-O-PP-O-PMixedCsp2_ar-Csp3WeakOO-SO2-R'MgCsp2_arCsp3Csp2_ar-OCsp3-MgAryl-O[Aryl]-O-SO2-R'Alkyl-MgX[Alkyl]-MgX#N/A#N/ANo baseNo BaseNo baseEasyOSO2-EWG
ORGANIC LETTERS
_0.53#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OS(=O)(=O)C(F)(F)F[Mg]ClC1=CC=CC=C1CCC1=CC=CC=C1CCO(c1ccccc1P(c2ccccc2)c3ccccc3)c4ccccc4P(c5ccccc5)c6ccccc6#N/AC1CCOC1
813
8833/10/2022423
Long
anie.201108350
C-H Activation
x10.1002/anie.2011083502012
E-NuH
VinylMgX
Alkyldppp
#N/A#N/A60-100K3PO4toluene#REF!Phosphine (Bidentate)PhosphineCsp2-Csp3Nu-HHMgCsp2Csp3Csp2-HCsp3-MgVinyl-H[Vinyl]-Alkyl-MgX[Alkyl]-MgX#N/A#N/AIonic-PO4K+_2.244780372.9696246982.6072025343.5700586912.37#REF!0#REF!#REF!12.2H[Mg]ClC=CCCC=CCCP(c1ccccc1)(c2ccccc2)CCCP(c3ccccc3)c4ccccc4#N/ACc1ccccc1
814
8853/10/2022267
Long
om010949+
C-O Activation
x10.1021/om010949+2002
E-EONa
AlkylCl
ArylIMes.HCl
#N/A#N/A65THFNHCCarbeneCarbeneCsp3-Csp2_arStrongOO-MetalXCsp3Csp2_arCsp3-OCsp2_ar-XAlkyl-O[Alkyl]-O-MetalAryl-Cl[Aryl]-Cl#N/A#N/ANo baseNo BaseNo base#N/A#N/A
ORGANOMETALLICS
_-0.32#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XO[Na]ClCCC1=CC=CC=C1CCC1=CC=CC=C1CC1=CC(=C(C(=C1)C)N2C=C[N+](=C2)C3=C(C=C(C=C3C)C)C)C.[Cl-]#N/AC1CCOC1
815
8863/10/2022426
Long
anie.201307069
C-H Activation
x10.1002/anie.2013070692013
E-NuH
AlkyneBr
Alkyl2,6-bis((S)-4-isopropyl-4,5-dihydrooxazol-2-yl)pyridine
#N/A#N/A#N/ApyboxNitrogenCsp1-Csp3Nu-HHXCsp1Csp3Csp1-HCsp3-XAlkyne-H[Alkyne]-Alkyl-Br[Alkyl]-Br#N/A#N/ANo baseNo BaseNo base_#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XHBrC#CCCC#CCCCC(C)[C@H]1COC(C2=CC=CC(C3=N[C@H](CO3)C(C)C)=N2)=N1#N/A#N/A
816
8873/10/2022426
Long
anie.201307069
C-H Activation
x10.1002/anie.2013070692013
E-NuH
AlkyneBr
Aryl2,6-bis((S)-4-isopropyl-4,5-dihydrooxazol-2-yl)pyridine
#N/A#N/A#N/ApyboxNitrogenCsp1-Csp2_arNu-HHXCsp1Csp2_arCsp1-HCsp2_ar-XAlkyne-H[Alkyne]-Aryl-Br[Aryl]-Br#N/A#N/ANo baseNo BaseNo base_#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XHBrC#CC1=CC=CC=C1C#CC1=CC=CC=C1CC(C)[C@H]1COC(C2=CC=CC(C3=N[C@H](CO3)C(C)C)=N2)=N1#N/A#N/A
817
8883/10/2022426
Long
anie.201307069
C-H Activation
x10.1002/anie.2013070692013
E-NuH
AlkyneBr
Benzyl2,6-bis((S)-4-isopropyl-4,5-dihydrooxazol-2-yl)pyridine
#N/A#N/A#N/ApyboxNitrogen
Csp1-Csp3-ring(s)
Nu-HHXCsp1Csp3-ring(s)Csp1-HCsp3-ring(s)-XAlkyne-H[Alkyne]-Benzyl-Br[Benzyl]-Br#N/A#N/ANo baseNo BaseNo base_#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XHBrC#CCC1=CC=CC=C1C#CCC1=CC=CC=C1CC(C)[C@H]1COC(C2=CC=CC(C3=N[C@H](CO3)C(C)C)=N2)=N1#N/A#N/A
818
8893/10/2022426
Long
anie.201307069
C-H Activation
x10.1002/anie.2013070692013
E-NuH
AlkyneBr
Csp3-Si2,6-bis((S)-4-isopropyl-4,5-dihydrooxazol-2-yl)pyridine
#N/A#N/A#N/ApyboxNitrogenCsp1-Csp3Nu-HHXCsp1Csp3Csp1-HCsp3-XAlkyne-H[Alkyne]-Csp3-Si-Br[Csp3-Si]-Br#N/A#N/ANo baseNo BaseNo base_#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XHBrC#CC[Si](C)(C)CC#CC[Si](C)(C)CCC(C)[C@H]1COC(C2=CC=CC(C3=N[C@H](CO3)C(C)C)=N2)=N1#N/A#N/A
819
8903/10/2022268
Long
jo982312e
C-O Activation
x10.1021/jo982312e1999
E-EO(Ring-Opening)
AlkylI
Aryldppe
#N/A#N/A70ZnP-PPhosphine (Bidentate)PhosphineCsp3-Csp2_arWeakO
O(Ring-Opening)
XCsp3Csp2_arCsp3-OCsp2_ar-XAlkyl-O[Alkyl]-O(Ring-Opening)Aryl-I[Aryl]-I#N/A#N/ANo baseNo BaseNo base#N/A#N/A
JOURNAL OF ORGANIC CHEMISTRY
_1#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOCICCC1=CC=CC=C1CCC1=CC=CC=C1c1ccc(cc1)P(CCP(c2ccccc2)c3ccccc3)c4ccccc4#N/A#N/A
820
8923/11/2022427
Long
s0040-4039(97)10240-4
C-H Activation
x10.1016/s0040-4039(97)10240-41997
E-NuH
VinylI
ArylPCy2Ph
#N/A#N/A150K2CO3NMP#N/APhosphine (Monodentate)PhosphineCsp2-Csp2_arNu-HHXCsp2Csp2_arCsp2-HCsp2_ar-XVinyl-H[Vinyl]-Aryl-I[Aryl]-I#N/A#N/AIonic-CO3K+_1.72.530430542.115215273.4538974810.33#REF!0#REF!#REF!XHIC=CC1=CC=CC=C1C=CC1=CC=CC=C1C4(CCCCC4)P(C5=CC=CC=C5)C6CCCCC6#N/ACN1CCCC1=O
821
8923/11/2022269
Long
acs.joc.8b02609
C-O Activation
xx10.1021/acs.joc.8b026092019
E-NuOH
BenzylH
Alkylphen
#N/A#N/A140t-BuOKtolueneN-NbpyNitrogen
Csp3-ring(s)-Csp3
StrongOOHHCsp3-ring(s)Csp3Csp3-ring(s)-OCsp3-HBenzyl-O[Benzyl]-OHAlkyl-H[Alkyl]-H#N/A#N/AIonic-OtBuHardOH
JOURNAL OF ORGANIC CHEMISTRY
_-0.81#N/A2.8589353663.2821934583.0705644124.0077900310.33#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5OHCC1=CC=CC=C1CCCC1=CC=CC=C1CCC1(C(N=CC=C2)=C2C=C3)=C3C=CC=N1#N/ACc1ccccc1
822
8933/11/2022254
Long
s-2004-832818
C-O Activation
x10.1055/s-2004-8328182004
NAE-EOMs
VinylI
ArylPPh3
#N/A#N/A90tolueneZnPPhosphine (Monodentate)PhosphineCsp2-Csp2_arWeakOO-SO2-R'XCsp2Csp2_arCsp2-OCsp2_ar-XVinyl-O[Vinyl]-O-SO2-R'Aryl-I[Aryl]-I#N/A#N/ANo baseNo BaseNo baseEasyOSO2-EDGSYNLETT_0.36#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOS(=O)(=O)CIC=CC1=CC=CC=C1C=CC1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3#N/ACc1ccccc1
823
8943/11/2022255
Long
jacs.1c08502
C-O Activation
x10.1021/jacs.1c085022021
E-NuOMs
ArylB(OH)2
ArylPCy3
#N/A#N/A23K3PO4THFPPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(OH)2[Aryl]-B(OH)2#N/A#N/AIonic-PO4K+EasyOSO2-EDG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OS(=O)(=O)CB(O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/AC1CCOC1
824
8953/11/2022255
Long
jacs.1c08502
C-O Activation
x10.1021/jacs.1c085022021
E-NuOMs
ArylB(nep)
ArylPCy3
#N/A#N/A100K3PO4dioxanePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'BCsp2_arCsp2_arCsp2_ar-OCsp2_ar-BAryl-O[Aryl]-O-SO2-R'Aryl-B(nep)[Aryl]-B(nep)#N/A#N/AIonic-PO4K+EasyOSO2-EDG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.362.244780372.9696246982.6072025343.5700586912.37#REF!22.1718.462.3360584073.6882909043.0121746566.54875338#REF!#REF!131.5OS(=O)(=O)CB1OCC(C)(CO1)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/AC1COCCO1
825
8963/11/20226
Long
b002547j
C-O Activation
x10.1039/b002547j2000
E-NuOAc
AlkylMgX
Arylcyclopentane;2-cyclopentyl-4-propan-2-yl-4,5-dihydro-1,3-oxazole;iron
#N/A#N/ArtTHF#N/AoxNitrogenCsp3-Csp2_arMediumOO-CO-R'MgCsp3Csp2_arCsp3-OCsp2_ar-MgAlkyl-O[Alkyl]-O-CO-R'Aryl-MgX[Aryl]-MgX#N/A#N/ANo baseNo BaseNo baseMediumOCO-EDG
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
_0.317.81#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2OC(C)=O[Mg]ClCCC1=CC=CC=C1CCC1=CC=CC=C1CC(C1COC(C23C4C5C6C2[Fe]5463789%10C%11C7C8C9C%11%10)=N1)C#N/AC1CCOC1
826
8973/11/20226
Long
b002547j
C-O Activation
x10.1039/b002547j2000
E-NuOCO2Me
AlkylMgX
Arylcyclopentane;2-cyclopentyl-4-propan-2-yl-4,5-dihydro-1,3-oxazole;iron
#N/A#N/ArtTHF#N/AoxNitrogenCsp3-Csp2_arMediumOO-CO-R'MgCsp3Csp2_arCsp3-OCsp2_ar-MgAlkyl-O[Alkyl]-O-CO-R'Aryl-MgX[Aryl]-MgX#N/A#N/ANo baseNo BaseNo base#N/A#N/A
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
_0.318.58#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2OC(=O)OC[Mg]ClCCC1=CC=CC=C1CCC1=CC=CC=C1CC(C1COC(C23C4C5C6C2[Fe]5463789%10C%11C7C8C9C%11%10)=N1)C#N/AC1CCOC1
827
8983/11/20226
Long
b002547j
C-O Activation
x10.1039/b002547j2000
E-NuOCO2Me
AlkylMgX
Arylcyclopentane;2-cyclopentyl-4-propan-2-yl-4,5-dihydro-1,3-oxazole;iron
#N/A#N/ArtTHF#N/AoxNitrogenCsp3-Csp2_arMediumOO-CO-R'MgCsp3Csp2_arCsp3-OCsp2_ar-MgAlkyl-O[Alkyl]-O-CO-R'Aryl-MgX[Aryl]-MgX#N/A#N/ANo baseNo BaseNo base#N/A#N/A
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
_0.318.58#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2OC(=O)OC[Mg]ClCCC1=CC=CC=C1CCC1=CC=CC=C1CC(C1COC(C23C4C5C6C2[Fe]5463789%10C%11C7C8C9C%11%10)=N1)C#N/AC1CCOC1
828
8993/11/20226
Long
b002547j
C-O Activation
x10.1039/b002547j2000
E-NuOMe
AlkylMgX
Arylcyclopentane;2-cyclopentyl-4-propan-2-yl-4,5-dihydro-1,3-oxazole;iron
#N/A#N/ArtTHF#N/AoxNitrogenCsp3-Csp2_arStrongOO-Csp3MgCsp3Csp2_arCsp3-OCsp2_ar-MgAlkyl-O[Alkyl]-O-Csp3Aryl-MgX[Aryl]-MgX#N/A#N/ANo baseNo BaseNo baseHardO-EDG
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
_-0.285.11#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2OC[Mg]ClCCC1=CC=CC=C1CCC1=CC=CC=C1CC(C1COC(C23C4C5C6C2[Fe]5463789%10C%11C7C8C9C%11%10)=N1)C#N/AC1CCOC1
829
9003/11/20226
Long
b002547j
C-O Activation
x10.1039/b002547j2000
E-NuOMe
AlkylMgX
Arylcyclopentane;2-cyclopentyl-4-propan-2-yl-4,5-dihydro-1,3-oxazole;iron
#N/A#N/ArtTHF#N/AoxNitrogenCsp3-Csp2_arStrongOO-Csp3MgCsp3Csp2_arCsp3-OCsp2_ar-MgAlkyl-O[Alkyl]-O-Csp3Aryl-MgX[Aryl]-MgX#N/A#N/ANo baseNo BaseNo baseHardO-EDG
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
_-0.285.11#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2OC[Mg]ClCCC1=CC=CC=C1CCC1=CC=CC=C1CC(C1COC(C23C4C5C6C2[Fe]5463789%10C%11C7C8C9C%11%10)=N1)C#N/AC1CCOC1
830
9013/11/20226
Long
b002547j
C-O Activation
x10.1039/b002547j2000
E-NuOPh
AlkylMgX
Arylcyclopentane;2-cyclopentyl-4-propan-2-yl-4,5-dihydro-1,3-oxazole;iron
#N/A#N/ArtTHF#N/AoxNitrogenCsp3-Csp2_arStrongOO-Csp2MgCsp3Csp2_arCsp3-OCsp2_ar-MgAlkyl-O[Alkyl]-O-Csp2Aryl-MgX[Aryl]-MgX#N/A#N/ANo baseNo BaseNo baseHardO-EDG
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
_-0.3212.86#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2OC1=CC=CC=C1[Mg]ClCCC1=CC=CC=C1CCC1=CC=CC=C1CC(C1COC(C23C4C5C6C2[Fe]5463789%10C%11C7C8C9C%11%10)=N1)C#N/AC1CCOC1
831
9023/11/20227
Long
ja00132a039
C-O Activation
x10.1021/ja00132a0391995
E-NuOMe
AlkylMgX
ArylPPh3
#N/A#N/A22PPhosphine (Monodentate)PhosphineCsp3-Csp2_arStrongOO-Csp3MgCsp3Csp2_arCsp3-OCsp2_ar-MgAlkyl-O[Alkyl]-O-Csp3Aryl-MgX[Aryl]-MgX#N/A#N/ANo baseNo BaseNo baseHardO-EDG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_-0.285.11#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2OC[Mg]ClCCC1=CC=CC=C1CCC1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3#N/A#N/A
832
9033/11/20227
Long
ja00132a039
C-O Activation
x10.1021/ja00132a0391995
E-NuOMe
AlkylMgX
AlkylPPh3
#N/A#N/A22PPhosphine (Monodentate)PhosphineCsp3-Csp3StrongOO-Csp3MgCsp3Csp3Csp3-OCsp3-MgAlkyl-O[Alkyl]-O-Csp3Alkyl-MgX[Alkyl]-MgX#N/A#N/ANo baseNo BaseNo baseHardO-EDG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_-0.285.11#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OC[Mg]ClCCCCCCCCP(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3#N/A#N/A
833
9043/11/202217
Long
ja209235d
C-H Activation
x10.1021/ja209235d2011
E-NuCl
BenzylH
VinylPhPCy2#N/A#N/A#N/ArtEt3NtolueneP#N/A#N/A
Csp3-ring(s)-Csp2
XHCsp3-ring(s)Csp2Csp3-ring(s)-XCsp2-HBenzyl-X[Benzyl]-Vinyl-H[Vinyl]-H#N/A#N/ANitrogenNitrogen(neutral)Nitrogen(neutral)
J AM CHEM SOC
_#N/A1.7105540393.2426955962.4766248184.9733801910.8#REF!6.0701.706749553.2392069642.4729782574.96639928#REF!#REF!115.6ClHCC1=CC=CC=C1C=CCC1=CC=CC=C1C=C#N/A#N/ACc1ccccc1
834
9053/11/202218
Long
anie.200907040
C-H Activation
10.1002/anie.2009070402010
E-NuH
HetCl
AlkylN1-(2-(dimethylamino)phenyl)-N2,N2-dimethylbenzene-1,2-diamine
#N/A#N/A140LiOtBu#N/AN-N-NNitrogenCsp2_ar-Csp3Nu-HHXCsp2_arCsp3Csp2_ar-HCsp3-XHet-H[Het]-Alkyl-Cl[Alkyl]-Cl#N/A#N/AIonic-OtBuLi+
ANGEW CHEM INT EDIT
_2.8589353663.2821934583.0705644124.0077900319#REF!0#REF!#REF!XHClC1=NC=CC=C1CCC1=CC=NC=C1CCCN(C1=CC=CC=C1NC2=C(C=CC=C2)N(C)C)C#N/A#N/A
835
3/14/2022431
Gerry
acs.orglett.7b00660
C-N activation
x10.1021/acs.orglett.7b006602017
NMe2
CarbonylH
N(H)Arylquin
#N/A#N/A150DMF#N/AMixed (N and O)MixedCsp2-Nsp3NNMe2HCsp2Nsp3Csp2-NNsp3-HCarbonyl-N[Carbonyl]-NMe2N(H)Aryl-H[N(H)Aryl]-H#N/A#N/ANo baseNo BaseNo baseMediumNMe2_#N/A#N/A#N/A#N/A#N/A#REF!11.526.021.706749553.2392069642.4729782574.96639928#REF!#REF!N(C)CHCC(=O)CNC1=CC=CC=C1C(=O)CCC1=CC=CC=C1NOC1=C(N=CC=C2)C2=CC=C1#N/ACN(C)C=O
836
3/14/2022431
Gerry
acs.orglett.7b00660
C-N activation
x10.1021/acs.orglett.7b006602017
NMe2
CarbonylH
N(H)Arylquin
#N/A#N/A150DMA#N/AMixed (N and O)MixedCsp2-Nsp3NNMe2HCsp2Nsp3Csp2-NNsp3-HCarbonyl-N[Carbonyl]-NMe2N(H)Aryl-H[N(H)Aryl]-H#N/A#N/ANo baseNo BaseNo baseMediumNMe2_#N/A#N/A#N/A#N/A#N/A#REF!11.526.021.706749553.2392069642.4729782574.96639928#REF!#REF!N(C)CHCC(=O)CNC1=CC=CC=C1C(=O)CCC1=CC=CC=C1NOC1=C(N=CC=C2)C2=CC=C1#N/ACN(C)C(C)=O
837
3/14/2022271
Gerry
acs.orglett.8b03367
C-O Activation
x10.1021/acs.orglett.8b033672018
11.2E-EOH
BenzylI
ArylMe4phen
#N/A#N/A70THFN-NbpyNitrogen
Csp3-ring(s)-Csp2_ar
StrongOOHXCsp3-ring(s)Csp2_arCsp3-ring(s)-OCsp2_ar-XBenzyl-O[Benzyl]-OHAryl-I[Aryl]-I#N/A#N/ANo baseNo BaseNo baseHardOH
ORGANIC LETTERS
_-0.81#N/A#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOICC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1CC1=C(C)C=NC2=C1C=CC3=C2N=CC(C)=C3C#N/AC1CCOC1
838
3/14/2022271
Gerry
acs.orglett.8b03367
C-O Activation
x10.1021/acs.orglett.8b033672018
11.2E-EOH
BenzylX
Aryl4,7-Dimethoxy-1,10-phenanthroline
#N/A#N/A70THF#N/AbpyNitrogen
Csp3-ring(s)-Csp2_ar
StrongOOHXCsp3-ring(s)Csp2_arCsp3-ring(s)-OCsp2_ar-XBenzyl-O[Benzyl]-OHAryl-X[Aryl]-X#N/A#N/ANo baseNo BaseNo baseHardOH
ORGANIC LETTERS
_-0.81#N/A#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOClCC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1COC1=CC=NC2=C(N=CC=C3OC)C3=CC=C21#N/AC1CCOC1
839
3/14/2022434
Gerry
c6qo00149a
C-H Activation
x10.1039/c6qo00149a2016
11.5H
ArylBpin
ArylP(o-anisyl)3
#N/A#N/A140Ag3PO4Na2CO3toluenePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
Nu-HHBCsp2_arCsp2_arCsp2_ar-HCsp2_ar-BAryl-H[Aryl]-Aryl-Bpin[Aryl]-Bpin#N/A#N/AIonic-CO3Na+_1.72.530430542.115215273.4538974810.33#REF!24.0118.463.1465845953.9827799333.5646822646.55194167#REF!#REF!131.5H[B](OC1(C)(C))OC1(C)(C)C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1COc1ccccc1P(c2ccccc2OC)c3ccccc3OC#N/ACc1ccccc1
840
3/14/2022434
Gerry
c6qo00149a
C-H Activation
x10.1039/c6qo00149a2016
11.5H
ArylBpin
ArylP(o-anisyl)3
#N/A#N/A140Ag3PO4Na2CO3toluenePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
Nu-HHBCsp2_arCsp2_arCsp2_ar-HCsp2_ar-BAryl-H[Aryl]-Aryl-Bpin[Aryl]-Bpin#N/A#N/AIonic-CO3Na+_1.72.530430542.115215273.4538974810.33#REF!24.0118.463.1465845953.9827799333.5646822646.55194167#REF!#REF!131.5H[B](OC1(C)(C))OC1(C)(C)C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1COc1ccccc1P(c2ccccc2OC)c3ccccc3OC#N/ACc1ccccc1
841
3/14/2022437
Gerry
jo901065y
C-H Activation
x10.1021/jo901065y2009
51H
CarbonylBr
Aryltris(2,4-ditert-butylphenyl) phosphite
#N/A#N/A110KOMediglyme#N/APhosphine (Monodentate)PhosphineCsp2-Csp2_arNu-HHXCsp2Csp2_arCsp2-HCsp2_ar-XCarbonyl-H[Carbonyl]-Aryl-Br[Aryl]-Br#N/A#N/AIonic-OR_0#REF!0#REF!#REF!XHBrCC(=O)CC1=CC=CC=C1C(=O)CCC1=CC=CC=C1CC(C(C=C(C(C)(C)C)C=C1)=C1OP(OC2=C(C(C)(C)C)C=C(C(C)(C)C)C=C2)OC3=C(C(C)(C)C)C=C(C(C)(C)C)C=C3)(C)C#N/ACOCCOCCOC
842
3/14/2022272
Gerry
ol702122d
C-O Activation
x10.1021/ol702122d2007
11.2E-NuOAc
AlkylH
ORP(OEt)3
#N/A#N/A50NaHTHFDMF#N/APhosphine (Monodentate)PhosphineCsp3-Osp2MediumOO-CO-R'HCsp3Osp2Csp3-OOsp2-HAlkyl-O[Alkyl]-O-CO-R'OR-H[OR]-H#N/A#N/AIonic-HNa+MediumOCO-EDG
ORGANIC LETTERS
_0.317.81035#REF!3.2120.231.706749553.2392069642.4729782574.96639928#REF!#REF!OC(C)=OHCCOCCOCCOP(OCC)OCC#N/AC1CCOC1
843
3/14/2022272
Gerry
ol702122d
C-O Activation
x10.1021/ol702122d2007
11.2E-NuOAc
AlkylH
thionitrosylP(OEt)3
#N/A#N/A120NaHDMF#N/APhosphine (Monodentate)PhosphineCsp3-Nsp2MediumOO-CO-R'HCsp3Nsp2Csp3-ONsp2-HAlkyl-O[Alkyl]-O-CO-R'thionitrosyl-H[thionitrosyl]-H#N/A#N/AIonic-HNa+MediumOCO-EDG
ORGANIC LETTERS
_0.317.81035#REF!11.5#N/A1.706749553.2392069642.4729782574.96639928#REF!#REF!#N/AOC(C)=OHCCN=SCCS=NCCOP(OCC)OCC#N/ACN(C)C=O
844
3/14/2022273
Gerry
c39950001863
C-O Activation
x10.1039/c399500018631995
E-NuOAc
AllylH
N(Alkyl)Alkyldppb
#N/A#N/A80THF#N/APhosphine (Bidentate)PhosphineCsp3-Nsp3MediumOO-CO-R'HCsp3Nsp3Csp3-ONsp3-HAllyl-O[Allyl]-O-CO-R'N(Alkyl)Alkyl-H[N(Alkyl)Alkyl]-H#N/A#N/ANo baseNo BaseNo baseMediumOCO-EDG
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS
_0.317.81#N/A#N/A#N/A#N/A#N/A#REF!9.6512.031.706749553.2392069642.4729782574.96639928#REF!#REF!OC(C)=OHCC=CN(C)CC=CCC(C)NP(C1=CC=CC=C1)(C2=CC=CC=C2)CCCCP(C3=CC=CC=C3)C4=CC=CC=C4#N/AC1CCOC1
845
3/14/2022274
Gerry
0040-4039(96)01302-0
C-O Activation
x10.1016/0040-4039(96)01302-01996
E-NuOAc
AllylH
Alkyldppb
#N/A#N/A80THF#N/APhosphine (Bidentate)PhosphineCsp3-Csp3MediumOO-CO-R'HCsp3Csp3Csp3-OCsp3-HAllyl-O[Allyl]-O-CO-R'Alkyl-H[Alkyl]-H#N/A#N/ANo baseNo BaseNo baseMediumOCO-EDG
TETRAHEDRON LETTERS
_0.317.81#N/A#N/A#N/A#N/A#N/A#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5OC(C)=OHCC=CCCC=CCCCP(C1=CC=CC=C1)(C2=CC=CC=C2)CCCCP(C3=CC=CC=C3)C4=CC=CC=C4#N/AC1CCOC1
846
3/15/2022275
Gerry
jacs.0c06904
C-O Activation
x10.1021/jacs.0c069042020
13E-NuOC(S)N(Ph)Bz
AlkylZnX
Arylbathocuproine
#N/A#N/A23MgCl2dioxaneTHF#N/AbpyNitrogenCsp3-Csp2_arMediumOO-CS-R'ZnCsp3Csp2_arCsp3-OCsp2_ar-ZnAlkyl-O[Alkyl]-O-CS-R'Aryl-ZnX[Aryl]-ZnX#N/A#N/A#N/ANo Base#N/A#N/A#N/A
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
_0.3131.53#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XOC(N(C(C1=CC=CC=C1)=O)C2=CC=CC=C2)=S[Zn]ClCCC1=CC=CC=C1CCC1=CC=CC=C1CC1=CC(C2=CC=CC=C2)=C3C=CC4=C(C5=CC=CC=C5)C=C(C)N=C4C3=N1#N/AC1COCCO1
847
3/15/2022276
Gerry
c7sc05216b
C-O Activation
x10.1039/c7sc05216b2018
11E-NuOH
AllylH
Alkyl(R)-P-Phos
#N/A#N/A10Et2O#N/APhosphine (Bidentate)PhosphineCsp3-Csp3StrongOOHHCsp3Csp3Csp3-OCsp3-HAllyl-O[Allyl]-OHAlkyl-H[Alkyl]-H#N/A#N/ANo baseNo BaseNo baseHardOH
CHEMICAL SCIENCE
_-0.813.21#N/A#N/A#N/A#N/A#N/A#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5OHCC=CCCC=CCCCCOC1=CC(P(C2=CC=CC=C2)C3=CC=CC=C3)=[C@@]([C@@]4=C(OC)N=C(OC)C=C4P(C5=CC=CC=C5)C6=CC=CC=C6)C(OC)=N1#N/ACCOCC
848
3/15/2022445
Gerry
ncomms9404
C-H Activation
x10.1038/ncomms94042015
No ligandH
AlkylH
Benzyl#N/A#N/A#N/A140DTBP#N/A#N/A#N/A
Csp3-Csp3-ring(s)
Nu-HHHCsp3Csp3-ring(s)Csp3-HCsp3-ring(s)-HAlkyl-H[Alkyl]-Benzyl-H[Benzyl]-H#N/A#N/ANo baseNo BaseNo base_#N/A#N/A#N/A#N/A#N/A#REF!12.1701.706749553.2392069642.4729782574.96639928#REF!#REF!21.3HHCCCC1=CC=CC=C1CCCC1=CC=CC=C1#N/A#N/AO(OC(C)(C)C)C(C)(C)C
849
3/15/2022445
Gerry
ncomms9404
C-H Activation
x10.1038/ncomms94042015
No ligandH
AlkylH
Benzyl#N/A#N/A#N/A140DTBP#N/A#N/A#N/A
Csp3-Csp3-ring(s)
Nu-HHHCsp3Csp3-ring(s)Csp3-HCsp3-ring(s)-HAlkyl-H[Alkyl]-Benzyl-H[Benzyl]-H#N/A#N/ANo baseNo BaseNo base_#N/A#N/A#N/A#N/A#N/A#REF!12.1701.706749553.2392069642.4729782574.96639928#REF!#REF!21.3HHCCCC1=CC=CC=C1CCCC1=CC=CC=C1#N/A#N/AO(OC(C)(C)C)C(C)(C)C
850
3/15/2022445
Gerry
ncomms9404
C-H Activation
x10.1038/ncomms94042015
No ligandH
AlkylH
Benzyl#N/A#N/A#N/A140DTBP#N/A#N/A#N/A
Csp3-Csp3-ring(s)
Nu-HHHCsp3Csp3-ring(s)Csp3-HCsp3-ring(s)-HAlkyl-H[Alkyl]-Benzyl-H[Benzyl]-H#N/A#N/ANo baseNo BaseNo base_#N/A#N/A#N/A#N/A#N/A#REF!12.1701.706749553.2392069642.4729782574.96639928#REF!#REF!21.3HHCCCC1=CC=CC=C1CCCC1=CC=CC=C1#N/A#N/AO(OC(C)(C)C)C(C)(C)C
851
3/17/2022446
Shihong
adsc.201100487
C-H Activation
x10.1002/adsc.2011004872011
H
HetCl
Alkyldiglyme#N/A#N/A#N/A140t-BuOLiCuI, NaIdioxane#N/A#N/A#N/ACsp2_ar-Csp3Nu-HHXCsp2_arCsp3Csp2_ar-HCsp3-XHet-H[Het]-Alkyl-Cl[Alkyl]-Cl#N/A#N/AIonic-OtBu_2.8589353663.2821934583.0705644124.00779003#REF!0#REF!#REF!XHClC1=NC=CC=C1CCC1=CC=NC=C1CC#N/ACC(C)([O-])C.[Li+]C1COCCO1
852
3/17/2022448
Shihong
acscatal.9b02230
C-H Activation
x10.1021/acscatal.9b022302019
71H
VinylBr
ArylPPh3
#N/A#N/A70pyridineNaIDMFpyridine
6 mA, (+)Fe/(-)Ni
PPhosphine (Monodentate)PhosphineCsp2-Csp2_arNu-HHXCsp2Csp2_arCsp2-HCsp2_ar-XVinyl-H[Vinyl]-Aryl-Br[Aryl]-Br#N/A#N/ANitrogenNitrogen(neutral)Nitrogen(neutral)_1.7105540393.2426955962.4766248184.973380195.17#REF!0#REF!#REF!XHBrC=CC1=CC=CC=C1C=CC1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3C1=CN=CC=C1CN(C)C=O
853
3/17/2022449
Shihong
anie.201810757
C-H Activation
x10.1002/anie.2018107572018
11H
VinylBr
AlkylXantphos
#N/A#N/A80Et3NMeCNMnP-O-PP-O-PMixedCsp2-Csp3Nu-HHXCsp2Csp3Csp2-HCsp3-XVinyl-H[Vinyl]-Alkyl-Br[Alkyl]-Br#N/A#N/ANitrogenNitrogen(neutral)Nitrogen(neutral)_1.7105540393.2426955962.4766248184.9733801910.8#REF!0#REF!#REF!XHBrC=CCCC=CCCO6c1c(cccc1P(c2ccccc2)c3ccccc3)C(c7cccc(P(c4ccccc4)c5ccccc5)c67)(C)CCCN(CC)CCCC#N
854
3/17/2022277
Shihong
acs.orglett.9b00174
C-O Activation
x10.1021/acs.orglett.9b001742019
NA
1.51E-EMonomethyl Oxalate
AlkylBr
Aryl2-(4,5-dihydro-1H-imidazol-2-yl)pyridine
#N/A#N/A25pyridineMgCl2DMAZn#N/Apy-imNitrogenCsp3-Csp2_arStrongOO-CO-R'XCsp3Csp2_arCsp3-OCsp2_ar-XAlkyl-O[Alkyl]-O-CO-R'Aryl-Br[Aryl]-Br#N/A#N/ANitrogenNitrogen(neutral)Nitrogen(neutral)#N/A#N/A
ORGANIC LETTERS
_0.1310.571.7105540393.2426955962.4766248184.973380195.17#REF!0#REF!#REF!XOC(=O)C(=O)OCBrCCC1=CC=CC=C1CCC1=CC=CC=C1C1CN=C(N1)C2=CC=CC=N2C1=CN=CC=C1CN(C)C(C)=O
855
3/17/2022278
Shihong
c2cc33232a
C-O Activation
x10.1039/c2cc33232a2012
NA21E-EOCOPh
CarbonylI
Alkylbphen
#N/A#N/A25MgCl2MeCNZnN-NbpyNitrogenCsp2-Csp3StrongOO-CO-R'XCsp2Csp3Csp2-OCsp3-XCarbonyl-O[Carbonyl]-O-CO-R'Alkyl-I[Alkyl]-I#N/A#N/ANo baseNo BaseNo base#N/A#N/A
CHEMICAL COMMUNICATIONS
0.1316.34#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOC(=O)C1=CC=CC=C1ICC(=O)CCCC(=O)CCCCC1(C2=CC=CC=C2)=CC=NC3=C1C=CC4=C3N=CC=C4C5=CC=CC=C5#N/ACC#N
856
3/17/2022278
Shihong
c2cc33232a
C-O Activation
x10.1039/c2cc33232a2012
NA41E-EOH
CarbonylI
Alkylbphen
#N/A#N/A25MgCl2MeCNZnN-NbpyNitrogenCsp2-Csp3StrongOOHXCsp2Csp3Csp2-OCsp3-XCarbonyl-O[Carbonyl]-OHAlkyl-I[Alkyl]-I#N/A#N/ANo baseNo BaseNo baseHardOH
CHEMICAL COMMUNICATIONS
-0.814.79#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOICC(=O)CCCC(=O)CCCCC1(C2=CC=CC=C2)=CC=NC3=C1C=CC4=C3N=CC=C4C5=CC=CC=C5#N/ACC#N
857
3/24/2022279
Shihong
ol3002078
C-O Activation
x10.1021/ol30020782012
110E-NuO(Ring-Opening)
CarbonylH
Alkyl(R)-Ni2-Schiff
Base Catalyst
#N/A#N/A-20CHCl3#N/AMixed (N and O)MixedCsp2-Csp3WeakO
O(Ring-Opening)
HCsp2Csp3Csp2-OCsp3-HCarbonyl-O[Carbonyl]-O(Ring-Opening)Alkyl-H[Alkyl]-H#N/A#N/ANo baseNo BaseNo base#N/A#N/A
ORGANIC LETTERS
1#N/A#N/A#N/A#N/A#N/A#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5OCHCC(=O)CCCC(=O)CCCCC12=C(C3=C(C24[N]5=CC6=CC=CC(O[Ni]78O9)=C6O8[Ni]%105O7C(C9=CC=C%11)=C%11C=[N]4%10)C=CC%12=CC=CC=C%123)C(C=CC=C%13)=C%13C=C1#N/ACC(Cl)(Cl)Cl
858
3/24/2022279
Shihong
ol3002078
C-O Activation
x10.1021/ol30020782012
110E-NuO(Ring-Opening)
CarbonylH
Benzyl(R)-Ni2-Schiff
Base Catalyst
#N/A#N/A0CHCl3#N/AMixed (N and O)Mixed
Csp2-Csp3-ring(s)
WeakO
O(Ring-Opening)
HCsp2Csp3-ring(s)Csp2-OCsp3-ring(s)-HCarbonyl-O[Carbonyl]-O(Ring-Opening)Benzyl-H[Benzyl]-H#N/A#N/ANo baseNo BaseNo base#N/A#N/A
ORGANIC LETTERS
1#N/A#N/A#N/A#N/A#N/A#REF!12.1701.706749553.2392069642.4729782574.96639928#REF!#REF!21.3OCHCC(=O)CCC1=CC=CC=C1C(=O)CCCC1=CC=CC=C1C12=C(C3=C(C24[N]5=CC6=CC=CC(O[Ni]78O9)=C6O8[Ni]%105O7C(C9=CC=C%11)=C%11C=[N]4%10)C=CC%12=CC=CC=C%123)C(C=CC=C%13)=C%13C=C1#N/ACC(Cl)(Cl)Cl
859
3/24/2022459
Shihong
c1dt10858a
C-H Activation
x10.1039/c1dt10858a2011
51H
VinylI
Aryldi-NHC
#N/A#N/A150Na2CO3DMF#N/ACarbene (Bidentate)CarbeneCsp2-Csp2_arNu-HHXCsp2Csp2_arCsp2-HCsp2_ar-XVinyl-H[Vinyl]-Aryl-I[Aryl]-I#N/A#N/AIonic-CO3Na+1.72.530430542.115215273.4538974810.33#REF!0#REF!#REF!XHIC=CC1=CC=CC=C1C=CC1=CC=CC=C1N(C1)(CC2=CC=CC=C2)C=CN1CN3C=CN(CC4=CC=CC=C4)C3[Na+].[Na+].[O-]C([O-])=OCN(C)C=O
860
3/24/2022280
Shihong
jo0158377
C-O Activation
xx10.1021/jo01583772001
11E-NuOAc
AllylH
AlkyneP(OiPr)3
#N/A#N/A80THF#N/APhosphine (Monodentate)PhosphineCsp3-Csp1MediumOO-CO-R'HCsp3Csp1Csp3-OCsp1-HAllyl-O[Allyl]-O-CO-R'Alkyne-H[Alkyne]-H#N/A#N/ANo baseNo BaseNo baseMediumOCO-EDG
JOURNAL OF ORGANIC CHEMISTRY
0.31#N/A#N/A#N/A#N/A#N/A#REF!#N/A#N/A1.706749553.2392069642.4729782574.96639928#REF!#REF!#N/AOC(C)=OHCC=CC#CC=CCC#CCC(C)OP(OC(C)C)OC(C)C#N/AC1CCOC1
861
3/24/2022466
Shihong
s-2005-869854
C-H Activation
x10.1055/s-2005-8698542005
31H
VinylI
ArylIMes.HCl
#N/A#N/A150Na2CO3DMFNHCCarbeneCarbeneCsp2-Csp2_arNu-HHXCsp2Csp2_arCsp2-HCsp2_ar-XVinyl-H[Vinyl]-Aryl-I[Aryl]-I#N/A#N/AIonic-CO3Na+1.72.530430542.115215273.4538974810.33#REF!0#REF!#REF!XHIC=CC1=CC=CC=C1C=CC1=CC=CC=C1CC1=CC(=C(C(=C1)C)N2C=C[N+](=C2)C3=C(C=C(C=C3C)C)C)C.[Cl-][Na+].[Na+].[O-]C([O-])=OCN(C)C=O
862
4/4/2022468
Kelly
anie.201508536
C-N Activation
x10.1002/anie.2015085362015
11.2E-NuN(Me)Ph
CarbonylH
ORSIPr
#N/A#N/A80toluenetolueneNHCCarbeneCarbeneCsp2-Osp2NN(Ph)AlkylHCsp2Osp2Csp2-NOsp2-HCarbonyl-N[Carbonyl]-N(Ph)AlkylOR-H[OR]-HNon-Polar2.38No baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#REF!3.2120.231.706749553.2392069642.4729782574.96639928#REF!#REF!N(C1=CC=CC=C1)HCC(=O)COC(=O)CCOCC(C)c1cccc(C(C)C)c1N2[C]N(CC2)c3c(cccc3C(C)C)C(C)C#N/ACc1ccccc1
863
4/4/2022471
Kelly
anie.202112454
C-N Activation
x10.1002/anie.202112454
Triphenylpyridinium+BF4-
BenzylCONHPI
Alkyl4,4'-(CF3)-bpy
#N/A#N/A60dioxaneMeCN
Dioxane/MeCN
Mn#N/AbpyNitrogen
Csp3-ring(s)-Csp3
NPyridiniumCsp2Csp3-ring(s)Csp3Csp3-ring(s)-NCsp3-Csp2Benzyl-N[Benzyl]-PyridiniumAlkyl-CONHPI[Alkyl]-CONHPI#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!X[N+]1=C(C=C(C=C1C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.F[B-](F)(F)FC(ON1C(C2=CC=CC=C2C1=O)=O)=OCC1=CC=CC=C1CCCC1=CC=CC=C1CCFC(F)(F)C1=CC(C2=NC=CC(C(F)(F)F)=C2)=NC=C1#N/AC1COCCO1
864
4/4/2022473
Kelly
acs.orglett.7b01194
C-H Activation
x10.1021/acs.orglett.7b011942017
10.2H
AlkyneCON(CO)2(CH2)3
Aryldcype
#N/A#N/A150dioxanedioxaneCuIP-PPhosphine (Bidentate)PhosphineCsp1-Csp2_arNu-HHCCsp1Csp2_arCsp1-HCsp2_ar-CAlkyne-H[Alkyne]-Aryl-CON(CO)2(CH2)3[Aryl]-CON(CO)2(CH2)3Polar2.25No baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XHC(N(C(CCC1)=O)C1=O)=OC#CC1=CC=CC=C1C#CC1=CC=CC=C1P(C1CCCCC1)(C2CCCCC2)CCP(C3CCCCC3)C4CCCCC4#N/AC1COCCO1
865
4/15/2022281
Long
c4sc03106g
C-O Activation
x10.1039/c4sc03106g2015
E-EOP(O)(OEt)2
BenzylBr
Aryldtbbpy
#N/A#N/ADMAPhBrN-NbpyNitrogen
Csp3-ring(s)-Csp2_ar
StrongOO-PO(OR')2XCsp3-ring(s)Csp2_arCsp3-ring(s)-OCsp2_ar-XBenzyl-O[Benzyl]-O-PO(OR')2Aryl-Br[Aryl]-Br#N/A#N/ANo baseNo BaseNo baseHardOPO-EDG
CHEMICAL SCIENCE
0.04#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOP(OCC)(OCC)=OBrCC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1CC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/ACN(C)C(C)=O
866
4/15/2022282
Long
jacs.1c05661
C-O Activation
x10.1021/jacs.1c056612021
E-NuOH
BenzylAl(iBu)2
ArylPCyNArCF3
#N/A#N/A75TMPtoluene#N/AMixed (N and P)Mixed
Csp3-ring(s)-Csp2_ar
StrongOOHAlCsp3-ring(s)Csp2_arCsp3-ring(s)-OCsp2_ar-AlBenzyl-O[Benzyl]-OHAryl-Al(iBu)2[Aryl]-Al(iBu)2#N/A#N/ANitrogenNitrogen(neutral)Nitrogen(neutral)HardOH
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
-0.811.7105540393.2426955962.4766248184.9733801910.92#REF!27.6402.4811865675.826321844.1537542046.96337555#REF!#REF!128O[Al](CC(C)C)CC(C)CCC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1CC1(C)CCCC(C)(C)N1Cc1ccccc1
867
4/15/2022282
Long
jacs.1c05661
C-O Activation
x10.1021/jacs.1c056612021
E-NuOH
AlkylAl(iBu)2
ArylPCyNArCF3
#N/A#N/A75TMPtoluene#N/AMixed (N and P)MixedCsp3-Csp2_arStrongOOHAlCsp3Csp2_arCsp3-OCsp2_ar-AlAlkyl-O[Alkyl]-OHAryl-Al(iBu)2[Aryl]-Al(iBu)2#N/A#N/ANitrogenNitrogen(neutral)Nitrogen(neutral)HardOH
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
-0.811.7105540393.2426955962.4766248184.9733801910.92#REF!27.6402.4811865675.826321844.1537542046.96337555#REF!#REF!128O[Al](CC(C)C)CC(C)CCCC1=CC=CC=C1CCC1=CC=CC=C1CC1(C)CCCC(C)(C)N1Cc1ccccc1
868
4/15/2022478
Long
jacs.1c10932
C-N Activation
x10.1021/jacs.1c109322021
E-ETriphenylpyridinium+BF4-
BenzylI
Aryldtbbpy
#N/A#N/ATMEDMAcN-NbpyNitrogen
Csp3-ring(s)-Csp2_ar
NPyridiniumXCsp3-ring(s)Csp2_arCsp3-ring(s)-NCsp2_ar-XBenzyl-N[Benzyl]-PyridiniumAryl-I[Aryl]-I#N/A#N/ANitrogenNitrogen(neutral)#N/A#N/A#N/A1.7105540393.2426955962.4766248184.97338019#REF!0#REF!#REF!X[N+]1=C(C=C(C=C1C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.F[B-](F)(F)FICC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1CC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/ACN(C)C(C)=O
869
4/15/2022480
Long
jacs.8b13251
C-H Activation
x10.1021/jacs.8b132512019
E-NuH
VinylVinyl
AlkylPCy3
#N/A#N/AtoluenePPhosphine (Monodentate)PhosphineCsp2-Csp3Nu-HHCsp2Csp3Csp2-HCsp3-Vinyl-H[Vinyl]-Alkyl-Vinyl[Alkyl]-Vinyl#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!HC=CC=CCCC=CCCC1CCC(CC1)P(C2CCCCC2)C3CCCCC3#N/ACc1ccccc1
870
4/15/2022283
Long
s41467-018-07198-7
C-O Activation
x10.1038/s41467-018-07198-72018
E-EOTf
ArylOTf
ArylPMe3
#N/A#N/A110K3PO4dioxanePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'OCsp2_arCsp2_arCsp2_ar-OCsp2_ar-OAryl-O[Aryl]-O-SO2-R'Aryl-OTf[Aryl]-OTf#N/A#N/AIonic-PO4K+EasyOSO2-EWG
NATURE COMMUNICATIONS
0.532.244780372.9696246982.6072025343.5700586912.37#REF!0#REF!#REF!XOS(=O)(=O)C(F)(F)FOS(=O)(=O)C(F)(F)FC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1CP(C)C[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1COCCO1
871
4/15/2022283
Long
s41467-018-07198-7
C-O Activation
x10.1038/s41467-018-07198-72018
E-EOMs
ArylOMs
ArylPMe3
#N/A#N/A110K3PO4dioxanePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'OCsp2_arCsp2_arCsp2_ar-OCsp2_ar-OAryl-O[Aryl]-O-SO2-R'Aryl-OMs[Aryl]-OMs#N/A#N/AIonic-PO4K+EasyOSO2-EDG
NATURE COMMUNICATIONS
0.362.244780372.9696246982.6072025343.5700586912.37#REF!0#REF!#REF!OS(=O)(=O)COS(=O)(=O)CC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1CP(C)C[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1COCCO1
872
4/15/2022283
Long
s41467-018-07198-7
C-O Activation
x10.1038/s41467-018-07198-72018
E-EOTs
ArylOTs
ArylPMe3
#N/A#N/A110K3PO4dioxanePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
WeakOO-SO2-R'OCsp2_arCsp2_arCsp2_ar-OCsp2_ar-OAryl-O[Aryl]-O-SO2-R'Aryl-OTs[Aryl]-OTs#N/A#N/AIonic-PO4K+EasyOSO2-EDG
NATURE COMMUNICATIONS
0.362.244780372.9696246982.6072025343.5700586912.37#REF!0#REF!#REF!OS(=O)(=O)(C1=CC=C(C)C=C1)OS(=O)(=O)(C1=CC=C(C)C=C1)C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1CP(C)C[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1COCCO1
873
5/11/2022484
Gideon
jacs.7b09482
C-N Activation
10.1021/jacs.7b094822017
E-Nupiperidine-2,6-dione
CarbonylB(OH)2
ArylPCy3
#N/A#N/A150Na2CO3dioxanePPhosphine (Monodentate)PhosphineCsp2-Csp2_arE-HNGlutarimideBCsp2Csp2_arCsp2-NCsp2_ar-BCarbonyl-N[Carbonyl]-GlutarimideAryl-B(OH)2[Aryl]-B(OH)2#N/A#N/AIonic-CO3Na+#N/A#N/A1.72.530430542.115215273.4538974810.33#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6N1C(CCCC1=O)=OB(O)OCC(=O)CC1=CC=CC=C1C(=O)CCC1=CC=CC=C1C1CCC(CC1)P(C2CCCCC2)C3CCCCC3[Na+].[Na+].[O-]C([O-])=OC1COCCO1
874
6/1/2022495
William
jacs.6b08397
C-H Activation
xx10.1021/jacs.6b08397x2016
H
AlkylCl
Aryldtbbpy
#N/A#N/A23K3PO4N-NbpyNitrogenCsp3-Csp2_arNu-HHXCsp3Csp2_arCsp3-HCsp2_ar-XAlkyl-H[Alkyl]-Aryl-Cl[Aryl]-Cl#N/A#N/AIonic-PO4K+2.244780372.9696246982.6072025343.5700586912.37#REF!0#REF!#REF!XHClCCC1=CC=CC=C1CCC1=CC=CC=C1CC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C[O-]P(=O)([O-])[O-].[K+].[K+].[K+]#N/A
875
6/1/2022496
William
acscatal.1c02851
C-H Activation
xx10.1021/acscatal.1c02851x2021
A2H
BenzylBr
VinylIrdtbbpy
#N/A#N/AK2HPO4dioxane
4-MeOC6H4
N-NbpyNitrogen
Csp3-ring(s)-Csp2
Nu-HHXCsp3-ring(s)Csp2Csp3-ring(s)-HCsp2-XBenzyl-H[Benzyl]-Vinyl-Br[Vinyl]-Br#N/A#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XHBrCC1=CC=CC=C1C=CCC1=CC=CC=C1C=CCC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)CC1COCCO1
876
6/1/2022497
William
jacs.7b07078
C-H Activation
xx10.1021/jacs.7b07078x2017
H
CarbonylBr
ArylIrdtbbpy
#N/A#N/AK2CO3dioxaneN-NbpyNitrogenCsp2-Csp2_arNu-HHXCsp2Csp2_arCsp2-HCsp2_ar-XCarbonyl-H[Carbonyl]-Aryl-Br[Aryl]-Br#N/A#N/AIonic-CO3K+1.72.530430542.115215273.4538974810.33#REF!0#REF!#REF!XHBrCC(=O)CC1=CC=CC=C1C(=O)CCC1=CC=CC=C1CC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)CO=C([O-])[O-].[K+].[K+]C1COCCO1
877
6/1/2022498
William
jacs.8b07405
C-H Activation
xx10.1021/jacs.8b07405x2018
H
AlkylBr
Aryl5'-5 dmbpy
#N/A#N/ANa2CO3#N/AbpyNitrogenCsp3-Csp2_arNu-HHXCsp3Csp2_arCsp3-HCsp2_ar-XAlkyl-H[Alkyl]-Aryl-Br[Aryl]-Br#N/A#N/AIonic-CO3Na+1.72.530430542.115215273.4538974810.33#REF!0#REF!#REF!XHBrCCC1=CC=CC=C1CCC1=CC=CC=C1CC1=CC=C(C2=NC=C(C)C=C2)N=C1[Na+].[Na+].[O-]C([O-])=O#N/A
878
6/1/2022499
William
c6sc02815b
C-H Activation
xX10.1039/c6sc02815bx2016
forligand: R=H (BiOx)H
AlkylI
ArylIrBiOx
#N/A#N/AKOHDMF#N/AboxNitrogenCsp3-Csp2_arNu-HHXCsp3Csp2_arCsp3-HCsp2_ar-XAlkyl-H[Alkyl]-Aryl-I[Aryl]-I#N/A#N/AIonic-ORK+015.74#REF!0#REF!#REF!XHICCC1=CC=CC=C1CCC1=CC=CC=C1CC(C1=NCCO1)(C)C2=NCCO2[K+].[OH-]CN(C)C=O
879
6/1/2022500
William
anie.201901327
C-H Activation
xx10.1002/anie.201901327x2019
H
BenzylBr
Aryldtbbpy
#N/A#N/A-35K2HPO4N-NbpyNitrogen
Csp3-ring(s)-Csp2_ar
Nu-HHXCsp3-ring(s)Csp2_arCsp3-ring(s)-HCsp2_ar-XBenzyl-H[Benzyl]-Aryl-Br[Aryl]-Br#N/A#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XHBrCC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1CC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/A
880
6/1/2022501
William
anie.201810526
C-H Activation
xx10.1002/anie.201810526x2019
H
AlkylBr
Alkyldtbbpy
#N/A#N/AK2HPO4N-NbpyNitrogenCsp3-Csp3Nu-HHXCsp3Csp3Csp3-HCsp3-XAlkyl-H[Alkyl]-Alkyl-Br[Alkyl]-Br#N/A#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XHBrCCCCCCCCCC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/A
881
6/1/2022504
William
anie.201800749
C-H Activation
xx10.1002/anie.201800749x2018
H
AlkylBr
ArylMe4phen
#N/A#N/AK3PO4DMSOquinclidineN-NbpyNitrogenCsp3-Csp2_arNu-HHXCsp3Csp2_arCsp3-HCsp2_ar-XAlkyl-H[Alkyl]-Aryl-Br[Aryl]-Br#N/A#N/AIonic-PO4K+2.244780372.9696246982.6072025343.5700586912.37#REF!0#REF!#REF!XHBrCCC1=CC=CC=C1CCC1=CC=CC=C1CC1=C(C)C=NC2=C1C=CC3=C2N=CC(C)=C3C[O-]P(=O)([O-])[O-].[K+].[K+].[K+]CS(=O)C
882
6/1/2022505
William
acscatal.0c01318
C-H Activation
xX10.1021/acscatal.0c01318x2020
H
AlkylBr
AlkylIrbpy
#N/A#N/AK3PO4dioxaneN-NbpyNitrogenCsp3-Csp3Nu-HHXCsp3Csp3Csp3-HCsp3-XAlkyl-H[Alkyl]-Alkyl-Br[Alkyl]-Br#N/A#N/AIonic-PO4K+2.244780372.9696246982.6072025343.5700586912.37#REF!0#REF!#REF!XHBrCCCCCCCCC1(C2=NC=CC=C2)=CC=CC=N1[O-]P(=O)([O-])[O-].[K+].[K+].[K+]C1COCCO1
883
6/1/2022506
William
acs.orglett.7b03826
C-H Activation
xX10.1021/acs.orglett.7b03826x2018
H
AlkylX
AlkylIrdtbbpy
#N/A#N/ADMEN-NbpyNitrogenCsp3-Csp3Nu-HHXCsp3Csp3Csp3-HCsp3-XAlkyl-H[Alkyl]-Alkyl-X[Alkyl]-X#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XHClCCCCCCCCCC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/ACOCCOC
884
6/1/2022507
William
jacs.9b07014
C-H Activation
xX10.1021/jacs.9b07014x2019
H
AlkylBr
AlkylMe2bpy
#N/A#N/AK3PO4MeCN#N/AbpyNitrogenCsp3-Csp3Nu-HHXCsp3Csp3Csp3-HCsp3-XAlkyl-H[Alkyl]-Alkyl-Br[Alkyl]-Br#N/A#N/AIonic-PO4K+2.244780372.9696246982.6072025343.5700586912.37#REF!0#REF!#REF!XHBrCCCCCCCCCc1ccnc(c2nccc(C)c2)c1[O-]P(=O)([O-])[O-].[K+].[K+].[K+]CC#N
885
6/1/2022509
William
acscatal.0c05694
C-H Activation
xX10.1021/acscatal.0c05694x2021
H
AlkylBr
Arylbpy
#N/A#N/AN-NbpyNitrogenCsp3-Csp2_arNu-HHXCsp3Csp2_arCsp3-HCsp2_ar-XAlkyl-H[Alkyl]-Aryl-Br[Aryl]-Br#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XHBrCCC1=CC=CC=C1CCC1=CC=CC=C1C1(C2=NC=CC=C2)=CC=CC=N1#N/A#N/A
886
6/1/2022508
William
acscatal.1c04314
C-H Activation
xX10.1021/acscatal.1c04314x2021
H
AlkylBr
VinylIrdtbbpy
#N/A#N/A15K2CO3EtOAcN-NbpyNitrogenCsp3-Csp2Nu-HHXCsp3Csp2Csp3-HCsp2-XAlkyl-H[Alkyl]-Vinyl-Br[Vinyl]-Br#N/A#N/AIonic-CO3K+1.72.530430542.115215273.4538974810.33#REF!0#REF!#REF!XHBrCCC=CCCC=CCC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)CO=C([O-])[O-].[K+].[K+]#N/A
887
6/1/2022510
William
jacs.6b04789
C-H Activation
xX10.1021/jacs.6b04789x2016
H
AlkylBr
Csp3-(Het)(Ar)Irdtbbpy
#N/A#N/AK2HPO4N-NbpyNitrogen
Csp3-Csp3-ring(s)
Nu-HHXCsp3Csp3-ring(s)Csp3-HCsp3-ring(s)-XAlkyl-H[Alkyl]-Csp3-(Het)(Ar)-Br[Csp3-(Het)(Ar)]-Br#N/A#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XHBrCCC(C1=NC=CC=C1)C2=CC=CC=C2CCC1=CC=CC=C1C(C2=CC=CN=C2)CC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/A
888
6/1/2022511
William
science.abh2623
C-H Activation
xX10.1126/science.abh2623x2021
H
AlkylCH3
AlkylIrttbtpy
#N/A#N/AMeCNN-N-NterpyNitrogenCsp3-Csp3Nu-HHCsp3Csp3Csp3Csp3-HCsp3-Csp3Alkyl-H[Alkyl]-Alkyl-CH3[Alkyl]-CH3#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XHCCCCCCCCCCC(C)(C1=CN=C(C2=NC(C3=NC=C(C(C)(C)C)C=C3)=CC(C(C)(C)C)=C2)C=C1)C#N/ACC#N
889
6/1/2022512
William
s41586-018-0366-x
C-H Activation
xX10.1038/s41586-018-0366-xx2018
H
AlkylBr
Aryldtbbpy
#N/A#N/AK3PO4CH3CNN-NbpyNitrogenCsp3-Csp2_arNu-HHXCsp3Csp2_arCsp3-HCsp2_ar-XAlkyl-H[Alkyl]-Aryl-Br[Aryl]-Br#N/A#N/AIonic-PO4K+2.244780372.9696246982.6072025343.5700586912.37#REF!0#REF!#REF!XHBrCCC1=CC=CC=C1CCC1=CC=CC=C1CC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C[O-]P(=O)([O-])[O-].[K+].[K+].[K+]CH3CN
890
6/1/2022284
Justin
anie.201910168
C-O Activation
xx10.1002/anie.201910168x2019
radical initiation, radical create nu radical.
PC generate catalyst
E-NuOC(O)
CarbonylDHP
Alkyl(S,S)-Ph-box
#N/A#N/A10THF#N/AboxNitrogenCsp2-Csp3OO-Csp2Csp3Csp2Csp3Csp2-OCsp3-Csp3Carbonyl-O[Carbonyl]-O-Csp2Alkyl-DHP[Alkyl]-DHP#N/A#N/ANo baseNo BaseNo base#N/A#N/A
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!OC(=O)CCC1C(CC(=O)OCCC)=C(C)CC(C)=C1(CC(=O)OCCC)CC(=O)CCCC(=O)CCCCCC(C1=N[C@@H](C2=CC=CC=C2)CO1)(C)C3=N[C@@H](C4=CC=CC=C4)CO3#N/AC1CCOC1
891
6/1/2022285
Justin
jacs.0c10471
C-O Activation
xx10.1021/jacs.0c10471x2020
propagation radical
E-NuOH
AlkylH
Alkyl(4R,4'R,5S,5'S)-2,2'-(cyclopentane-1,1-diyl)bis(4,5-diphenyl-4,5-dihydrooxazole)
#N/A#N/ANa2HPO4NH4ClPC#N/ACsp3-Csp3StrongOOHHCsp3Csp3Csp3-OCsp3-HAlkyl-O[Alkyl]-OHAlkyl-H[Alkyl]-H#N/A#N/AHardOH
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
-0.81#N/A#N/A#N/A#N/A#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5OHCCCCCCCC[C@H]1(C2=CC=CC=C2)[C@@H](C3=CC=CC=C3)N=C(C4(CCCC4)C5=N[C@H](C6=CC=CC=C6)[C@H](C7=CC=CC=C7)O5)O1#N/A
892
6/1/2022524
Chun Hey
d0cc01480j
C-H Activation
xx10.1039/d0cc01480jx2020
11H
BenzylCl
Carbonyldtbbpy
#N/A#N/A35K2HPO4N-NbpyNitrogen
Csp3-ring(s)-Csp2
Nu-HHXCsp3-ring(s)Csp2Csp3-ring(s)-HCsp2-XBenzyl-H[Benzyl]-Carbonyl-Cl[Carbonyl]-Cl#N/A#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XHClCC1=CC=CC=C1CC(=O)CCC1=CC=CC=C1C(=O)CCCC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/A
893
6/9/2022513
William
acs.orglett.7b01588
C-O Activation
xx10.1021/acs.orglett.7b01588x2017
radical initiation
E-NuOH
CarbonylBF3K
AlkylIrdtbbpy
#N/A#N/ATHFN-NbpyNitrogenCsp2-Csp3StrongOOHBCsp2Csp3Csp2-OCsp3-BCarbonyl-O[Carbonyl]-OHAlkyl-BF3K[Alkyl]-BF3K#N/A#N/ANo baseNo BaseNo baseHardOH
ORGANIC LETTERS
-0.81#N/A#N/A#N/A#N/A#N/A#REF!XX2.2294683593.2807152032.7550917816.56810798#REF!#REF!XO[B-](F)(F)F.[K+]CC(=O)CCCC(=O)CCCCCC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/AC1CCOC1
894
6/9/2022515
William
d0sc01445a
C-H Activation
xx10.1039/d0sc01445ax2020
H
ArylBr
Csp3-(Het)(Ar)4,4'-Dimethoxy-2,2'-bipyridine
#N/A#N/A40Lutidine
[LutH]ClO4
THFMeCNN-NbpyNitrogen
Csp2_ar-Csp3-ring(s)
Nu-HHXCsp2_arCsp3-ring(s)Csp2_ar-HCsp3-ring(s)-XAryl-H[Aryl]-Csp3-(Het)(Ar)-Br[Csp3-(Het)(Ar)]-Br#N/A#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XHBrC1=CC=CC=C1C(C1=NC=CC=C1)C2=CC=CC=C2C1=CC=CC=C1C1=CC=CC=C1C(C2=CC=CN=C2)COC1=CC=NC(C2=NC=CC(OC)=C2)=C1C1CCOC1
895
6/9/2022516
William
anie.202108987
C-H Activation
xx10.1002/anie.202108987x2021
H
AlkylCl
Carbonyldtbbpy
#N/A#N/ALutidine MeCNN-NbpyNitrogenCsp3-Csp2Nu-HHXCsp3Csp2Csp3-HCsp2-XAlkyl-H[Alkyl]-Carbonyl-Cl[Carbonyl]-Cl#N/A#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XHClCCCC(=O)CCCC(=O)CCCC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)CCC#N
896
6/9/2022517
William
d1cc06247f
C-H Activation
xx10.1039/d1cc06247fx2022
H
AlkylF
Alkyldtbbpy
#N/A#N/AMeCNN-NbpyNitrogenCsp3-Csp3Nu-HHXCsp3Csp3Csp3-HCsp3-XAlkyl-H[Alkyl]-Alkyl-F[Alkyl]-F#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XHFCCCCCCCCCC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/ACC#N
897
6/15/2022286
Justin
s41467-020-17224-2
C-O Activation
xx10.1038/s41467-020-17224-2x2020
PPh3 radical -> make nucleophile radical
E-EOH
CarbonylBr
Aryldtbpy
#N/A#N/A#N/AbpyNitrogenCsp2-Csp2_arStrongOOHXCsp2Csp2_arCsp2-OCsp2_ar-XCarbonyl-O[Carbonyl]-OHAryl-Br[Aryl]-Br#N/A#N/ANo baseNo BaseNo baseHardOH
NATURE COMMUNICATIONS
-0.81#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOBrCC(=O)CC1=CC=CC=C1C(=O)CCC1=CC=CC=C1#N/A#N/A
898
6/15/2022287
Justin
anie.201511438
C-O Activation
xx10.1002/anie.201511438x2016
initiation
1.51E-NuOC(O)
CarbonylH
Alkyldtbbpy
#N/A#N/AN-NbpyNitrogenCsp2-Csp3OO-Csp2HCsp2Csp3Csp2-OCsp3-HCarbonyl-O[Carbonyl]-O-Csp2Alkyl-H[Alkyl]-H#N/A#N/ANo baseNo BaseNo base#N/A#N/A
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
#N/A#N/A#N/A#N/A#N/A#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5OC(=O)CCHCC(=O)CCCC(=O)CCCCCC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/A#N/A
899
6/15/2022292
Justin
s41467-021-27507-x
C-O Activation
xx10.1038/s41467-021-27507-xx2022
PPh3 radical -> make nucleophile radical
E-EOTf
ArylOH
Aryl4,4'-Dimethoxy-2,2'-bipyridine
#N/A#N/ANa2CO3N-NbpyNitrogen
Csp2_ar-Csp2_ar
WeakOO-SO2-R'OCsp2_arCsp2_arCsp2_ar-OCsp2_ar-OAryl-O[Aryl]-O-SO2-R'Aryl-OH[Aryl]-OH#N/A#N/AIonic-CO3Na+EasyOSO2-EWG
NATURE COMMUNICATIONS
0.531.72.530430542.115215273.4538974810.33#REF!0#REF!#REF!OS(=O)(=O)C(F)(F)FOC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1COC1=CC=NC(C2=NC=CC(OC)=C2)=C1[Na+].[Na+].[O-]C([O-])=O#N/A
900
6/15/2022288
Justin
anie.201800701
C-O Activation
xx10.1002/anie.201800701x2018
11.5E-NuOH
AlkylDHP
Alkyldtbbpy
#N/A#N/AacetoneN-NbpyNitrogenCsp3-Csp3StrongOOHCsp3Csp3Csp3Csp3-OCsp3-Csp3Alkyl-O[Alkyl]-OHAlkyl-DHP[Alkyl]-DHP#N/A#N/ANo baseNo BaseNo baseHardOH
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
-0.81#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!OC1C(CC(=O)OCCC)=C(C)CC(C)=C1(CC(=O)OCCC)CCCCCCCCCC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/ACC(=O)C
901
6/15/2022289
William
acscatal.7b00772
C-O Activation
xx10.1021/acscatal.7b00772x2017
propagation radical
E-EOC(S)SMe
BenzylBr
Aryldtbbpy
bpy
df(CF3)ppy
N-NbpyNitrogen
Csp3-ring(s)-Csp2_ar
MediumOO-CS-R'XCsp3-ring(s)Csp2_arCsp3-ring(s)-OCsp2_ar-XBenzyl-O[Benzyl]-O-CS-R'Aryl-Br[Aryl]-Br#N/A#N/ANo baseNo BaseNo base#N/A#N/A
ACS CATALYSIS
#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOC(SC)=SBrCC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1CC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/A#N/A
902
6/15/2022290
William
acs.joc.6b00800
C-O Activation
xx10.1021/acs.joc.6b00800x2016
initiation
E-EOTf
Aryl2,2'-spirobi[benzo[d][1,3,2]dioxasilole]
AlkylRudtbbpy
bpy
#N/ADMFN-NbpyNitrogenCsp2_ar-Csp3WeakOO-SO2-R'SiCsp2_arCsp3Csp2_ar-OCsp3-SiAryl-O[Aryl]-O-SO2-R'Alkyl-2,2'-spirobi[benzo[d][1,3,2]dioxasilole][Alkyl]-2,2'-spirobi[benzo[d][1,3,2]dioxasilole]#N/A#N/ANo baseNo BaseNo baseEasyOSO2-EWG
JOURNAL OF ORGANIC CHEMISTRY
0.53#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOS(=O)(=O)C(F)(F)F[Si-]12(OC3=CC=CC=C3O2)OC4=C(C=CC=C4)O1.[H][N+](CC)(CC)CCC1=CC=CC=C1CCC1=CC=CC=C1CCCC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/ACN(C)C=O
903
6/15/2022294
William
jacs.0c02805
C-O Activation
xx10.1021/jacs.0c02805x2020
initiation radicalE-Edimethoxymethanol
AlkylCl
Csp3-(Het)(Ar)Irdtbpy
#N/A#N/A#N/AbpyNitrogen
Csp3-Csp3-ring(s)
OO-Csp3XCsp3Csp3-ring(s)Csp3-OCsp3-ring(s)-XAlkyl-O[Alkyl]-O-Csp3Csp3-(Het)(Ar)-Cl[Csp3-(Het)(Ar)]-Cl#N/A#N/ANo baseNo BaseNo base#N/A#N/A
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOC(OC)(OC)ClCCC(C1=NC=CC=C1)C2=CC=CC=C2CCC1=CC=CC=C1C(C2=CC=CN=C2)#N/A#N/A
904
6/15/2022532
William
jacs.8b12025
Cheating ?
xx10.1021/jacs.8b12025x2018
Not C-O activation, MeO help to make MeBr
E-EOTs
AlkylBr
AlkylIrdtbbpy
#N/A#N/ANa2CO3MeCNN-NbpyNitrogenCsp3-Csp3WeakOO-SO2-R'XCsp3Csp3Csp3-OCsp3-XAlkyl-O[Alkyl]-O-SO2-R'Alkyl-Br[Alkyl]-Br#N/A#N/AIonic-CO3Na+EasyOSO2-EDG0.361.72.530430542.115215273.4538974810.33#REF!0#REF!#REF!XOS(=O)(=O)(C1=CC=C(C)C=C1)BrCCCCCCCCCC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C[Na+].[Na+].[O-]C([O-])=OCC#N
905
6/15/2022295
William
anie.201700097
C-O Activation
xx10.1002/anie.201700097x2017
E-NuO(Ring-Opening)
ORBF3K
Benzyl(4S,4'S)-2,2'-(propane-2,2-diyl)bis(4-phenyl-4,5-dihydrooxazole)
#N/A#N/Adioxane#N/ANitrogen
Osp2-Csp3-ring(s)
WeakO
O(Ring-Opening)
BOsp2Csp3-ring(s)Osp2-OCsp3-ring(s)-BOR-O[OR]-O(Ring-Opening)Benzyl-BF3K[Benzyl]-BF3K#N/A#N/ANo baseNo BaseNo base#N/A#N/A
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
1#N/A#N/A#N/A#N/A#N/A#REF!XX2.2294683593.2807152032.7550917816.56810798#REF!#REF!XOC[B-](F)(F)F.[K+]OCC1=CC=CC=C1OCC1=CC=CC=C1CC(C1=N[C@@H](C2=CC=CC=C2)CO1)(C3=N[C@@H](C4=CC=CC=C4)CO3)C#N/AC1COCCO1
906
6/15/2022296
William
chem.201604452
C-O Activation
xx10.1002/chem.201604452x2016
initiation radicalE-EOTf
ArylCOOH
N(H)AlkylIrdtbpy
#N/A#N/ACs2CO3MeCN#N/AbpyNitrogenCsp2_ar-Nsp3WeakOO-SO2-R'Csp2Csp2_arNsp3Csp2_ar-ONsp3-Csp2Aryl-O[Aryl]-O-SO2-R'N(H)Alkyl-COOH[N(H)Alkyl]-COOH#N/A#N/AIonic-CO3Cs+EasyOSO2-EWG
CHEMISTRY-A EUROPEAN JOURNAL
0.531.72.530430542.115215273.4538974810.33#REF!0#REF!#REF!XOS(=O)(=O)C(F)(F)FC(=O)OC1=CC=CC=C1NCC1=CC=CC=C1CNC(=O)([O-])[O-].[Cs+].[Cs+]CC#N
907
6/15/2022297
William
anie.201809919
C-O Activation
xx10.1002/anie.201809919x2018
E-NuO(Ring-Opening)
AlkylBF3K
AlkylIrdtbbpy
bpy
2-(2,4-difluorophenyl)-5-(trifluoromethyl)pyridine
Lutidine acetoneMeOHN-NbpyNitrogenCsp3-Csp3WeakO
O(Ring-Opening)
BCsp3Csp3Csp3-OCsp3-BAlkyl-O[Alkyl]-O(Ring-Opening)Alkyl-BF3K[Alkyl]-BF3K#N/A#N/A#N/A#N/A
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
1#N/A#N/A#N/A#N/A#REF!XX2.2294683593.2807152032.7550917816.56810798#REF!#REF!XOC[B-](F)(F)F.[K+]CCCCCCCCCC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)CCC(=O)C
908
6/15/2022299
William
anie.201909543
C-O Activation
xx10.1002/anie.201909543x2020
imanuel check thisE-EOTf
VinylOBoc
AllylRubpy
#N/A#N/ADABCODMSON-NbpyNitrogenCsp2-Csp3WeakOO-SO2-R'OCsp2Csp3Csp2-OCsp3-OVinyl-O[Vinyl]-O-SO2-R'Allyl-OBoc[Allyl]-OBoc#N/A#N/ANitrogenNitrogen(neutral)Nitrogen(neutral)EasyOSO2-EWG
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
0.531.7105540393.2426955962.4766248184.973380198.8#REF!0#REF!#REF!XOS(=O)(=O)C(F)(F)FOC(=O)OC(C)(C)CC=CCC=CC=CC=CCC1(C2=NC=CC=C2)=CC=CC=N1C1CN2CCN1CC2CS(=O)C
909
6/15/2022300
William
acscatal.0c01199
C-O Activation
xx10.1021/acscatal.0c01199x2020
Imanuel check this
E-EO(Ring-Opening)
AlkylX
ArylTidtbbpy
#N/A#N/AEt3NDMFN-NbpyNitrogenCsp3-Csp2_arWeakO
O(Ring-Opening)
XCsp3Csp2_arCsp3-OCsp2_ar-XAlkyl-O[Alkyl]-O(Ring-Opening)Aryl-X[Aryl]-X#N/A#N/ANitrogenNitrogen(neutral)Nitrogen(neutral)#N/A#N/A
ACS CATALYSIS
11.7105540393.2426955962.4766248184.9733801910.8#REF!0#REF!#REF!XOCClCCC1=CC=CC=C1CCC1=CC=CC=C1CC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)CCCN(CC)CCCN(C)C=O
910
6/15/2022301
William
acscatal.9b02458
C-O Activation
xx10.1021/acscatal.9b02458x2019
check this one
E-EO(Ring-Opening)
Alkyldiethyl 2,6-dimethyl-4-(tetrahydro-2H-pyran-4-yl)-1,4-dihydropyridine-3,5-dicarboxylate
Alkyl(1E,2E)-N1,N2-di-p-tolylacenaphthylene-1,2-diimine
#N/A#N/Aacetone#N/ACsp3-Csp3WeakO
O(Ring-Opening)
NCsp3Csp3Csp3-OCsp3-NAlkyl-O[Alkyl]-O(Ring-Opening)Alkyl-diethyl 2,6-dimethyl-4-(tetrahydro-2H-pyran-4-yl)-1,4-dihydropyridine-3,5-dicarboxylate[Alkyl]-diethyl 2,6-dimethyl-4-(tetrahydro-2H-pyran-4-yl)-1,4-dihydropyridine-3,5-dicarboxylate#N/A#N/ANo baseNo BaseNo base#N/A#N/A
ACS CATALYSIS
1#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOCN1C(C)=C(C(=O)OCC)C(C2CCOCC2)C(C(=O)OCC)=C1(C)CCCCCCCCCC(C=C1)=CC=C1/N=C2C3=C(C(C\2=N/C4=CC=C(C)C=C4)=CC=C5)C5=CC=C3#N/ACC(=O)C
911
6/16/2022304
William
acscatal.2c00512
C-O Activation
xx10.1021/acscatal.2c00512x2022
generating Ni(0)
E-EO(Ring-Opening)
AlkylOAc
Allylbpy
#N/A#N/AEt3NN-NbpyNitrogenCsp3-Csp3WeakO
O(Ring-Opening)
OCsp3Csp3Csp3-OCsp3-OAlkyl-O[Alkyl]-O(Ring-Opening)Allyl-OAc[Allyl]-OAc#N/A#N/ANitrogenNitrogen(neutral)Nitrogen(neutral)#N/A#N/A
ACS CATALYSIS
11.7105540393.2426955962.4766248184.9733801910.8#REF!0#REF!#REF!XOCOC(C)=OCCCC=CCCC=CCC1(C2=NC=CC=C2)=CC=CC=N1CCN(CC)CC#N/A
912
6/21/2022303
William
anie.202114731
C-O Activation
xx10.1002/anie.202114731x2022
Initiation radical, radical as Nu
E-EOPy
CarbonylCONHPI
Alkyldimethyl [2,2'-bipyridine]-4,4'-dicarboxylate
#N/A#N/ADMAc#N/ACsp2-Csp3StrongOO-Csp2Csp2Csp2Csp3Csp2-OCsp3-Csp2Carbonyl-O[Carbonyl]-O-Csp2Alkyl-CONHPI[Alkyl]-CONHPI#N/A#N/ANo baseNo BaseNo baseMediumO-EDG
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
-0.32#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOC1=NC=CC=C1C(ON1C(C2=CC=CC=C2C1=O)=O)=OCC(=O)CCCC(=O)CCCCO=C(OC)C1=CC(C2=NC=CC(C(OC)=O)=C2)=NC=C1#N/ACN(C)C(C)=O
913
6/21/2022302
William
jacs.1c12203
C-O Activation
xx10.1021/jacs.1c12203x2022
Initiation radical, radical as Nu
E-E(dimethoxymethyl)benzene
AlkylCl
AlkylIrdtbbpy
#N/A#N/AK3PO4MeCNN-NbpyNitrogenCsp3-Csp3OO-Csp3XCsp3Csp3Csp3-OCsp3-XAlkyl-O[Alkyl]-O-Csp3Alkyl-Cl[Alkyl]-Cl#N/A#N/AIonic-PO4K+#N/A#N/A
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
2.244780372.9696246982.6072025343.5700586912.37#REF!0#REF!#REF!XOC(OC)CC1=CC=CC=C1ClCCCCCCCCCC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C[O-]P(=O)([O-])[O-].[K+].[K+].[K+]CC#N
914
6/21/2022519
Justin
jacs.1c08157
C-H Activation
xx10.1021/jacs.1c08157x2021
H
ArylBr
Aryldtbpy
#N/A#N/ANa2CO3dioxane#N/AbpyNitrogen
Csp2_ar-Csp2_ar
Nu-HHXCsp2_arCsp2_arCsp2_ar-HCsp2_ar-XAryl-H[Aryl]-Aryl-Br[Aryl]-Br#N/A#N/AIonic-CO3Na+1.72.530430542.115215273.4538974810.33#REF!0#REF!#REF!XHBrC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1[Na+].[Na+].[O-]C([O-])=OC1COCCO1
915
6/21/2022522
Justin
acs.orglett.9b01097
C-N Activation
xx10.1021/acs.orglett.9b01097x2019
Br
ArylTriphenylpyridinium+BF4-
Alkyl1,2,3,5-Tetrakis(carbazol-9-yl)-4,6-dicyanobenzene, 2,4,5,6-Tetrakis(9H-carbazol-9-yl) isophthalonitrile
#N/A#N/ATHFTEA#N/ANitrogenCsp2_ar-Csp3XNCsp2_arCsp3Csp2_ar-XCsp3-NAryl-X[Aryl]-Alkyl-Triphenylpyridinium+BF4-[Alkyl]-Triphenylpyridinium+BF4-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XBr[N+]1=C(C=C(C=C1C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.F[B-](F)(F)FC1=CC=CC=C1CCC1=CC=CC=C1CC#N/AC1CCOC1
916
6/21/2022293
Long
s41467-021-23887-2
C-O Activation
xx10.1038/s41467-021-23887-2x2021
propagation radical
E-NuOH
CarbonylH
ArylIr(4S,4'S)-2,2'-(cyclopentane-1,1-diyl)bis(4-phenyl-4,5-dihydrooxazole)
df(CF3)ppy
bpy
Na2HPO4NH4ClPC#N/ANirogenCsp2-Csp2_arStrongOOHHCsp2Csp2_arCsp2-OCsp2_ar-HCarbonyl-O[Carbonyl]-OHAryl-H[Aryl]-H#N/A#N/ANo baseNo BaseNo baseHardOH
NATURE COMMUNICATIONS
-0.81#N/A#N/A#N/A#N/A#N/A#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5OHCC(=O)CC1=CC=CC=C1C(=O)CCC1=CC=CC=C1C1(C2(CCCC2)C3=N[C@@H](C4=CC=CC=C4)CO3)=N[C@@H](C5=CC=CC=C5)CO1#N/A#N/A
917
6/21/2022526
Justin
anie.201805118
C-H Activation
xx10.1002/anie.201805118x2018
Br
ArylH
Alkyldtbpy
#N/A#N/A2,6-LutidineDCE#N/AbpyNitrogenCsp2_ar-Csp3XHCsp2_arCsp3Csp2_ar-XCsp3-HAryl-X[Aryl]-Alkyl-H[Alkyl]-H#N/A#N/A#N/A#N/A#N/A#N/A#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5BrHC1=CC=CC=C1CCC1=CC=CC=C1CCClCCCl
918
6/21/2022527
Justin
anie.202201662
C-H Activation
xx10.1002/anie.202201662x2022
Br
AlkylH
NR2dtbbpy
DTBP
#N/ApyridineCH3CNN-NbpyNitrogen#N/AXHCsp3#N/ACsp3-X#N/AAlkyl-X[Alkyl]-NR2-H[NR2]-H#N/A#N/ANitrogenNitrogen(neutral)Nitrogen(neutral)1.7105540393.2426955962.4766248184.973380195.17#N/A1.706749553.2392069642.4729782574.96639928#REF!#N/ABrHCC#N/ACC#N/ACC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)CC1=CN=CC=C1CH3CN
919
6/21/2022533
Justin
C9CC04726C
C-H Activation
xx10.1039/c9cc04726cx2019
Br
ArylH
Carbonyldmbpy
#N/A#N/ANa2CO3acetone#N/AbpyNitrogenCsp2_ar-Csp2XHCsp2_arCsp2Csp2_ar-XCsp2-HAryl-X[Aryl]-Carbonyl-H[Carbonyl]-H#N/A#N/AIonic-CO3Na+1.72.530430542.115215273.4538974810.33#REF!4.517.071.706749553.2392069642.4729782574.96639928#REF!#REF!199.9BrHC1=CC=CC=C1CC(=O)CC1=CC=CC=C1C(=O)CC[Na+].[Na+].[O-]C([O-])=OCC(=O)C
920
6/21/2022542
Justin
acs.orglett.7b01552
C-H Activation
xx10.1021/acs.orglett.7b01552x
H
NR2Cl
Carbonyldtbbpy
#N/A#N/AK3PO4N-NbpyNitrogen#N/ANu-HHX#N/ACsp2#N/ACsp2-XNR2-H[NR2]-Carbonyl-Cl[Carbonyl]-Cl#N/A#N/AIonic-PO4K+2.244780372.9696246982.6072025343.5700586912.37#REF!0#N/A#REF!XHCl#N/ACC(=O)C#N/AC(=O)CCCC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C[O-]P(=O)([O-])[O-].[K+].[K+].[K+]#N/A
921
6/21/2022544
Justin
jacs.0c01724
C-N Activation
xx10.1021/jacs.0c01724x
N(Ring-Opening)
AlkylI
Aryldtbbpy
#N/A#N/AEt3NTHFN-NbpyNitrogenCsp3-Csp2_arN
N(Ring-Opening)
XCsp3Csp2_arCsp3-NCsp2_ar-XAlkyl-N[Alkyl]-N(Ring-Opening)Aryl-I[Aryl]-I#N/A#N/ANitrogenNitrogen(neutral)Nitrogen(neutral)#N/A#N/A1.7105540393.2426955962.4766248184.9733801910.8#REF!0#REF!#REF!XNCICCC1=CC=CC=C1CCC1=CC=CC=C1CC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)CCCN(CC)CCC1CCOC1
922
6/21/2022546
Justin
anie.202004441
C-N Activation
xx10.1002/anie.202004441x
pyrrolidine-2,5-dione
CarbonylH
Alkyldtbbpy
#N/A#N/AK2CO3N-NbpyNitrogenCsp2-Csp3NHCsp2Csp3Csp2-NCsp3-HCarbonyl-N[Carbonyl]-Alkyl-H[Alkyl]-H#N/A#N/AIonic-CO3K+#N/A#N/A1.72.530430542.115215273.4538974810.33#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5N1C(=O)CCC1(=O)HCC(=O)CCCC(=O)CCCCCC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)CO=C([O-])[O-].[K+].[K+]#N/A
923
6/21/2022547
Justin
acs.orglett.7b03747
C-N Activation
xx10.1021/acs.orglett.7b03747x
N(Ring-Opening)
AlkylBF3K
Aryl1-((3aR,6R)-8,8-dimethyl-2,2-dioxidotetrahydro-3H-3a,6-methanobenzo[c]isothiazol-1(4H)-yl)-6-((3aS,6S)-8,8-dimethyl-2,2-dioxidotetrahydro-3H-3a,6-methanobenzo[c]isothiazol-1(4H)-yl)hexane-2,5-dione
#N/A#N/Adioxane#N/ANitrogenCsp3-Csp2_arN
N(Ring-Opening)
BCsp3Csp2_arCsp3-NCsp2_ar-BAlkyl-N[Alkyl]-N(Ring-Opening)Aryl-BF3K[Aryl]-BF3K#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#REF!11.8902.2294683593.2807152032.7550917816.56810798#REF!#REF!150.1NC[B-](F)(F)F.[K+]CCC1=CC=CC=C1CCC1=CC=CC=C1#N/AC1COCCO1
924
6/21/2022550
Justin
acscatal.1c01416
C-N Activation
xx10.1021/acscatal.1c01416x
Triphenylpyridinium+BF4-
AlkylBr
Aryl4,4'-Dimethoxy-2,2'-bipyridine
#N/A#N/ADMAN-NbpyNitrogenCsp3-Csp2_arNPyridiniumXCsp3Csp2_arCsp3-NCsp2_ar-XAlkyl-N[Alkyl]-PyridiniumAryl-Br[Aryl]-Br#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!X[N+]1=C(C=C(C=C1C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.F[B-](F)(F)FBrCCC1=CC=CC=C1CCC1=CC=CC=C1COC1=CC=NC(C2=NC=CC(OC)=C2)=C1#N/ACN(C)C(C)=O
925
6/22/2022293
Long
s41467-021-23887-2
C-O Activation
xx10.1038/s41467-021-23887-2x2021
E-NuOH
CarbonylH
BenzylIr(4S,4'S)-2,2'-(cyclopentane-1,1-diyl)bis(4-phenyl-4,5-dihydrooxazole)
bpy
df(CF3)ppy
iPr2ONa2HPO4#N/ANirogen
Csp2-Csp3-ring(s)
StrongOOHHCsp2Csp3-ring(s)Csp2-OCsp3-ring(s)-HCarbonyl-O[Carbonyl]-OHBenzyl-H[Benzyl]-H#N/A#N/ANo baseNo BaseNo baseHardOH
NATURE COMMUNICATIONS
-0.81#N/A#N/A#N/A#N/A#N/A#REF!12.1701.706749553.2392069642.4729782574.96639928#REF!#REF!21.3OHCC(=O)CCC1=CC=CC=C1C(=O)CCCC1=CC=CC=C1C1(C2(CCCC2)C3=N[C@@H](C4=CC=CC=C4)CO3)=N[C@@H](C5=CC=CC=C5)CO1#N/AO(C(C)C)C(C)C
926
6/29/2022557
William
acs.orglett.9b02643
C-N Activation
x10.1021/acs.orglett.9b026432019
Ni=NiCl2DME ligand=4,4'-dmbpy
Triphenylpyridinium+BF4-
AlkylB(OH)2
Aryl4,4'-dimethyl-2,2'-bipyridine
#N/A#N/AK2CO3MeCN#N/ACsp3-Csp2_arNPyridiniumBCsp3Csp2_arCsp3-NCsp2_ar-BAlkyl-N[Alkyl]-PyridiniumAryl-B(OH)2[Aryl]-B(OH)2#N/A#N/AIonic-CO3K+#N/A#N/A1.72.530430542.115215273.4538974810.33#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6[N+]1=C(C=C(C=C1C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.F[B-](F)(F)FB(O)OCCC1=CC=CC=C1CCC1=CC=CC=C1O=C([O-])[O-].[K+].[K+]CC#N
927
6/29/2022558
William
c5gc01931a
C-H activation
xx10.1039/c5gc01931ax2016
H
AlkylCOOH
CarbonylIrdtbbpy
#N/A#N/ACs2CO3LiFDMFN-NbpyNitrogenCsp3-Csp2Nu-HHCsp2Csp3Csp2Csp3-HCsp2-Csp2Alkyl-H[Alkyl]-Carbonyl-COOH[Carbonyl]-COOH#N/A#N/AIonic-CO3Cs+1.72.530430542.115215273.4538974810.33#REF!0#REF!#REF!XHC(=O)OCCCC(=O)CCCC(=O)CCCC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)CC(=O)([O-])[O-].[Cs+].[Cs+]CN(C)C=O
928
6/29/2022559
William
jacs.9b13920
C-H activation
x10.1021/jacs.9b13920x2020
H
AlkylH
CarbonylIrdtbbpy
#N/A#N/AEtOAcN-NbpyNitrogenCsp3-Csp2Nu-HHHCsp3Csp2Csp3-HCsp2-HAlkyl-H[Alkyl]-Carbonyl-H[Carbonyl]-H#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#REF!4.517.071.706749553.2392069642.4729782574.96639928#REF!#REF!199.9HHCCCC(=O)CCCC(=O)CCCC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/AO=C(OCC)C
929
6/29/2022560
William
anie.201901801
C-H activation
x10.1002/anie.201901801x2019
H
CarbonylH
Alkyl#N/A#N/A#N/A0AgCltolueneHFIP#N/A#N/A#N/ACsp2-Csp3Nu-HHHCsp2Csp3Csp2-HCsp3-HCarbonyl-H[Carbonyl]-Alkyl-H[Alkyl]-H#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5HHCC(=O)CCCC(=O)CCCC#N/A#N/ACc1ccccc1
930
6/29/2022555
Justin
c9cc07840a
C-H activation
xx10.1039/c9cc07840ax2019
H
Aryl1,3-dioxoisoindolin-2-yl acetate
Alkyldtbpy
#N/A#N/ACH3CN#N/AbpyNitrogenCsp2_ar-Csp3Nu-HHCCsp2_arCsp3Csp2_ar-HCsp3-CAryl-H[Aryl]-Alkyl-1,3-dioxoisoindolin-2-yl acetate[Alkyl]-1,3-dioxoisoindolin-2-yl acetate#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XHC1=CC=CC=C1CCC1=CC=CC=C1CC#N/ACH3CN
931
6/29/2022556
Justin
jacs.9b04175
C-H activation
x10.1021/jacs.9b041752019
H
AlkylBr
Carbonyl#N/A#N/A#N/ANaOMeEt2OEt2Zn#N/A#N/A#N/ACsp3-Csp2Nu-HHXCsp3Csp2Csp3-HCsp2-XAlkyl-H[Alkyl]-Carbonyl-Br[Carbonyl]-Br#N/A#N/AIonic-ORNa+015.1#REF!0#REF!#REF!XHBrCCCC(=O)CCCC(=O)CC#N/A[Na]OCCCOCC
932
6/29/2022305
Justin
ja408561b
C-O Activation
x10.1021/ja408561b2013
E-NuOH
AlkylZnX
Aryl(4S,4'S,5S,5'S)-4,4'-bis(methoxymethyl)-5,5'-diphenyl-4,4',5,5'-tetrahydro-2,2'-bioxazole
#N/A#N/ACH2Cl2THF#N/ANitrogenCsp3-Csp2_arStrongOOHZnCsp3Csp2_arCsp3-OCsp2_ar-ZnAlkyl-O[Alkyl]-OHAryl-ZnX[Aryl]-ZnX#N/A#N/ANo baseNo BaseNo baseHardOH
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
-0.81#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XO[Zn]ClCCC1=CC=CC=C1CCC1=CC=CC=C1#N/AClCCl
933
7/6/2022307
Justin
acscatal.7b02817
C-O Activation
x10.1021/acscatal.7b028172017
E-NuOH
BenzylH
N(H)Arylphen
#N/A#N/At-BuOKtolueneN-NbpyNitrogen
Csp3-ring(s)-Nsp3
StrongOOHHCsp3-ring(s)Nsp3Csp3-ring(s)-ONsp3-HBenzyl-O[Benzyl]-OHN(H)Aryl-H[N(H)Aryl]-H#N/A#N/AIonic-OtBuHardOH
ACS CATALYSIS
-0.812.8589353663.2821934583.0705644124.0077900319#REF!11.526.021.706749553.2392069642.4729782574.96639928#REF!#REF!OHCC1=CC=CC=C1NC1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1NC1(C(N=CC=C2)=C2C=C3)=C3C=CC=N1[O-]C(C)(C)C.[K+]Cc1ccccc1
934
7/6/2022564
Justin
anie.201410322
C-H activation
x10.1002/anie.201410322
H
CarbonylH
Alkyl#N/A#N/A#N/Adioxane#N/A#N/A#N/ACsp2-Csp3Nu-HHHCsp2Csp3Csp2-HCsp3-HCarbonyl-H[Carbonyl]-Alkyl-H[Alkyl]-H#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5HHCC(=O)CCCC(=O)CCCC#N/A#N/AC1COCCO1
935
7/6/2022565
Justin
jo0261707
C-H activation
x10.1021/jo0261707
H
Alkyne(Z)-methyl(styryl)selane
Aryldppe
#N/A#N/AP-PPhosphine (Bidentate)PhosphineCsp1-Csp2_arNu-HHCsp1Csp2_arCsp1-HCsp2_ar-Alkyne-H[Alkyne]-Aryl-(Z)-methyl(styryl)selane[Aryl]-(Z)-methyl(styryl)selane#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XHC#CC1=CC=CC=C1C#CC1=CC=CC=C1c1ccc(cc1)P(CCP(c2ccccc2)c3ccccc3)c4ccccc4#N/A#N/A
936
7/6/2022566
Justin
S0040-4039(03)01174-2
C-H Activation
x10.1016/s0040-4039(03)01174-2
H
ArylI
ArylPPh3
#N/A#N/AK2CO3dioxanePPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
Nu-HHXCsp2_arCsp2_arCsp2_ar-HCsp2_ar-XAryl-H[Aryl]-Aryl-I[Aryl]-I#N/A#N/AIonic-CO3K+1.72.530430542.115215273.4538974810.33#REF!0#REF!#REF!XHIC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3O=C([O-])[O-].[K+].[K+]C1COCCO1
937
7/6/2022567
William
ja4076716
C-N Activation
x10.1021/ja4076716
N(Ring-Opening)
AlkylBr
Alkyldimethyl fumarate
#N/A#N/A23LiClTHF?Csp3-Csp3N
N(Ring-Opening)
XCsp3Csp3Csp3-NCsp3-XAlkyl-N[Alkyl]-N(Ring-Opening)Alkyl-Br[Alkyl]-Br#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XNCBrCCCCCCCCO=C(/C=C/C(OC)=O)OC#N/AC1CCOC1
938
7/6/2022308
William
a908076g
C-O Activation
x10.1039/a908076g2000
R=i-pr base=KOH
E-NuOAc
AlkylB(OH)2
Aryl(diphenylphosphino)ferrocenyl((S)-5-isopropyl-4,5-dihydrooxazole)
#N/A#N/AKOHTHF#N/ACsp3-Csp2_arMediumOO-CO-R'BCsp3Csp2_arCsp3-OCsp2_ar-BAlkyl-O[Alkyl]-O-CO-R'Aryl-B(OH)2[Aryl]-B(OH)2#N/A#N/AIonic-ORK+MediumOCO-EDG
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
0.31015.74#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6OC(C)=OB(O)OCCC1=CC=CC=C1CCC1=CC=CC=C1CC([C@@H](CO1)N=C1C23C4(P(C5=CC=CC=C5)C6=CC=CC=C6)C7C8C2[Fe]8479%10%11%123C%13C9C%10C%11C%13%12)C[K+].[OH-]C1CCOC1
939
7/6/2022309
William
jo026449n
C-O Activation
x10.1021/jo026449n2003
E-NuOSO2Ph
AlkylMgX
Aryldppf
#N/A#N/ATHFP-PPhosphine (Bidentate)PhosphineCsp3-Csp2_arWeakOO-SO2-R'MgCsp3Csp2_arCsp3-OCsp2_ar-MgAlkyl-O[Alkyl]-O-SO2-R'Aryl-MgX[Aryl]-MgX#N/A#N/ANo baseNo BaseNo baseEasyOSO2-EDG
JOURNAL OF ORGANIC CHEMISTRY
0.7#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2OS(=O)(=O)(C1=CC=CC=C1)[Mg]ClCCC1=CC=CC=C1CCC1=CC=CC=C1c1(P(C23C4C5C6C2[Fe]5643789%10C%11C7C8(P(c%12ccccc%12)c%13ccccc%13)C9C%11%10)c%14ccccc%14)ccccc1#N/AC1CCOC1
940
7/6/2022310
William
jacs.2c02062
C-O Activation
x10.1021/jacs.2c02062x2022
E-EOH
AlkylCOOH
AlkylIr5,6-di-tert-butyl-3-phenylbenzo[d]oxazol-3-ium
#N/A#N/ADMSOMTBE#N/ACsp3-Csp3StrongOOHCsp2Csp3Csp3Csp3-OCsp3-Csp2Alkyl-O[Alkyl]-OHAlkyl-COOH[Alkyl]-COOH#N/A#N/ANo baseNo BaseNo baseHardOH
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
-0.81#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOC(=O)OCCCCCCCCCC(C1=C(C(C)(C)C)C=C(OC=[N+]2C3=CC=CC=C3)C2=C1)(C)C.F[B-](F)(F)F#N/ACS(=O)C
941
7/6/2022#N/A
William
C9CC03344K #N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
E-NuOAc
AllylH
CarbonylRuphen
#N/A#N/AMeCNN-NbpyNitrogenCsp3-Csp2MediumOO-CO-R'HCsp3Csp2Csp3-OCsp2-HAllyl-O[Allyl]-O-CO-R'Carbonyl-H[Carbonyl]-H#N/A#N/ANo baseNo BaseNo baseMediumOCO-EDG#N/A#N/A0.31#N/A#N/A#N/A#N/A#N/A#REF!4.517.071.706749553.2392069642.4729782574.96639928#REF!#REF!199.9OC(C)=OHCC=CCC(=O)CC=CCC(=O)CCC1(C(N=CC=C2)=C2C=C3)=C3C=CC=N1#N/ACC#N
942
7/6/2022#N/A
William
ange.201700097
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
E-NuO(Ring-Opening)
AlkylBF3K
Benzyl(4S,4'S)-2,2'-(propane-2,2-diyl)bis(4-phenyl-4,5-dihydrooxazole)
#N/A#N/Adioxane#N/ANitrogen
Csp3-Csp3-ring(s)
WeakO
O(Ring-Opening)
BCsp3Csp3-ring(s)Csp3-OCsp3-ring(s)-BAlkyl-O[Alkyl]-O(Ring-Opening)Benzyl-BF3K[Benzyl]-BF3K#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A1#N/A#N/A#N/A#N/A#N/A#REF!XX2.2294683593.2807152032.7550917816.56810798#REF!#REF!XOC[B-](F)(F)F.[K+]CCCC1=CC=CC=C1CCCC1=CC=CC=C1CC(C1=N[C@@H](C2=CC=CC=C2)CO1)(C3=N[C@@H](C4=CC=CC=C4)CO3)C#N/AC1COCCO1
943
7/6/2022313
William
acscatal.8b02954
C-O Activation
x10.1021/acscatal.8b02954x2018
E-EX
BenzylN2ArylRu#N/A#N/A#N/A27DMF#N/A#N/A#N/A
Csp3-ring(s)-Csp2_ar
XNCsp3-ring(s)Csp2_arCsp3-ring(s)-XCsp2_ar-NBenzyl-X[Benzyl]-Aryl-N2[Aryl]-N2#N/A#N/ANo baseNo BaseNo base
ACS CATALYSIS
#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XClNNCC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1#N/A#N/ACN(C)C=O
944
7/6/2022314
William
jacs.1c08105
C-O Activation
x10.1021/jacs.1c08105x2021
E-EO(Ring-Opening)
AlkylX
Alkyl(4S,4'S)-1,1'-bis(3-(tert-butyl)phenyl)-4,4'-diisopropyl-4,4',5,5'-tetrahydro-1H,1'H-2,2'-biimidazole
#N/A#N/AEt3NMgCl2THF#N/ACsp3-Csp3WeakO
O(Ring-Opening)
XCsp3Csp3Csp3-OCsp3-XAlkyl-O[Alkyl]-O(Ring-Opening)Alkyl-X[Alkyl]-X#N/A#N/ANitrogenNitrogen(neutral)Nitrogen(neutral)#N/A#N/A
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
11.7105540393.2426955962.4766248184.9733801910.8#REF!0#REF!#REF!XOCClCCCCCCCCCC(C1=CC(N2C[C@H](C(C)C)N=C2C3=N[C@@H](C(C)C)CN3C4=CC(C(C)(C)C)=CC=C4)=CC=C1)(C)CCCN(CC)CCC1CCOC1
945
7/6/2022315
anie.202114981
C-O Activation
x10.1002/anie.202114981x2022
E-NuOAc
AllylH
Carbonyl
(3aR,3a'R,8aS,8a'S)-2,2'-(pentane-3,3-diyl)bis(3a,8a-dihydro-8H-indeno[1,2-d]oxazole)
#N/A#N/ATHF#N/AboxNitrogenCsp3-Csp2MediumOO-CO-R'HCsp3Csp2Csp3-OCsp2-HAllyl-O[Allyl]-O-CO-R'Carbonyl-H[Carbonyl]-H#N/A#N/ANo baseNo BaseNo baseMediumOCO-EDG
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
0.31#N/A#N/A#N/A#N/A#N/A#REF!4.517.071.706749553.2392069642.4729782574.96639928#REF!#REF!199.9OC(C)=OHCC=CCC(=O)CC=CCC(=O)CCCCC(C1=N[C@H](C2=C(C=CC=C2)C3)[C@H]3O1)(CC)C4=N[C@@H]5C6=C(C=CC=C6)C[C@@H]5O4#N/AC1CCOC1
946
7/28/2022578
William
ja9093956
C-X Activation
10.1021/ja9093956
X
ArylX
Alkylpyridine
#N/A#N/A#N/ApyNitrogenCsp2_ar-Csp3XXCsp2_arCsp3Csp2_ar-XCsp3-XAryl-X[Aryl]-Alkyl-X[Alkyl]-X#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XClClC1=CC=CC=C1CCC1=CC=CC=C1CCC1=CC=NC=C1#N/A#N/A
947
7/28/2022579
William
ja301769r
C-X Activation
10.1021/ja301769r
Br
ArylBr
Alkylpyridine
#N/A#N/A60#N/ApyNitrogenCsp2_ar-Csp3XXCsp2_arCsp3Csp2_ar-XCsp3-XAryl-X[Aryl]-Alkyl-Br[Alkyl]-Br#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XBrBrC1=CC=CC=C1CCC1=CC=CC=C1CCC1=CC=NC=C1#N/A#N/A
948
7/28/2022598
William
science.1255525
Decarbonyl
x10.1126/science.1255525x
COOH
AlkylBr
Aryldtbbpy
#N/A#N/A23Cs2CO3DMFN-NbpyNitrogenCsp3-Csp2_arCsp2XCsp3Csp2_arCsp3-Csp2Csp2_ar-XAlkyl-Csp2[Alkyl]-Aryl-Br[Aryl]-Br#N/A#N/AIonic-CO3Cs+#N/A#N/A1.72.530430542.115215273.4538974810.33#REF!0#REF!#REF!XC(=O)OBrCCC1=CC=CC=C1CCC1=CC=CC=C1CC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)CC(=O)([O-])[O-].[Cs+].[Cs+]CN(C)C=O
949
7/28/2022599
William
jo00430a041
C-X Activation
10.1021/jo00430a041
Br
ArylZnX
ArylPPh3
#N/A#N/APPhosphine (Monodentate)Phosphine
Csp2_ar-Csp2_ar
XZnCsp2_arCsp2_arCsp2_ar-XCsp2_ar-ZnAryl-X[Aryl]-Aryl-ZnX[Aryl]-ZnX#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#REF!XX0#REF!#REF!XBr[Zn]ClC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3#N/A#N/A
950
7/28/2022600
William
science.1253647
C-X Activation
x10.1126/science.1253647x
Br
AlkylBF3K
Aryldtbbpy
#N/A#N/AN-NbpyNitrogenCsp3-Csp2_arXBCsp3Csp2_arCsp3-XCsp2_ar-BAlkyl-X[Alkyl]-Aryl-BF3K[Aryl]-BF3K#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#REF!11.8902.2294683593.2807152032.7550917816.56810798#REF!#REF!150.1Br[B-](F)(F)F.[K+]CCC1=CC=CC=C1CCC1=CC=CC=C1CC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/A#N/A
951
7/28/2022601
William
0040-4020(82)80117-8
C-X Activation
10.1016/0040-4020(82)80117-8
X
AlkylMgX
Alkyldppp
#N/A#N/AP-PPhosphine (Bidentate)PhosphineCsp3-Csp3XMgCsp3Csp3Csp3-XCsp3-MgAlkyl-X[Alkyl]-Alkyl-MgX[Alkyl]-MgX#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2Cl[Mg]ClCCCCCCCCP(c1ccccc1)(c2ccccc2)CCCP(c3ccccc3)c4ccccc4#N/A#N/A
952
7/28/2022602
William
bcsj.49.1958
C-X Activation
10.1246/bcsj.49.1958
Cl
AlkylMgX
Aryl#N/A#N/A#N/A#N/A#N/A#N/ACsp3-Csp2_arXMgCsp3Csp2_arCsp3-XCsp2_ar-MgAlkyl-X[Alkyl]-Aryl-MgX[Aryl]-MgX#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2Cl[Mg]ClCCC1=CC=CC=C1CCC1=CC=CC=C1#N/A#N/A#N/A
953
7/28/2022603
William
pac198052030669
C-X Activation
10.1351/pac198052030669
L=dpppCl
AlkylMgX
Aryldppp
#N/A#N/AP-PPhosphine (Bidentate)PhosphineCsp3-Csp2_arXMgCsp3Csp2_arCsp3-XCsp2_ar-MgAlkyl-X[Alkyl]-Aryl-MgX[Aryl]-MgX#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2Cl[Mg]ClCCC1=CC=CC=C1CCC1=CC=CC=C1P(c1ccccc1)(c2ccccc2)CCCP(c3ccccc3)c4ccccc4#N/A#N/A
954
7/28/2022317
William
acs.accounts.5b00051
C-O Activation
10.1021/acs.accounts.5b00051
2015
E-NuOMe
AlkylMgX
AlkylPPh3
#N/A#N/APPhosphine (Monodentate)PhosphineCsp3-Csp3StrongOO-Csp3MgCsp3Csp3Csp3-OCsp3-MgAlkyl-O[Alkyl]-O-Csp3Alkyl-MgX[Alkyl]-MgX#N/A#N/ANo baseNo BaseNo baseHardO-EDG
ACCOUNTS OF CHEMICAL RESEARCH
-0.28#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!12.2OC[Mg]ClCCCCCCCCP(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3#N/A#N/A
955
7/28/2022580
William
ja027433h
C-X Activation
10.1021/ja027433h
Br
NR2H
Benzyl#N/A#N/A#N/A110K3PO4toluene#N/A#N/A#N/A#N/AXH#N/ACsp3-ring(s)#N/ACsp3-ring(s)-HNR2-X[NR2]-Benzyl-H[Benzyl]-H#N/A#N/AIonic-PO4K+2.244780372.9696246982.6072025343.5700586912.37#REF!12.1701.706749553.2392069642.4729782574.96639928#N/A#REF!21.3BrH#N/ACC1=CC=CC=C1#N/ACC1=CC=CC=C1#N/A[O-]P(=O)([O-])[O-].[K+].[K+].[K+]#N/A
956
7/28/2022581
William
ja301553c
C-X Activation
x10.1021/ja301553cx
X
ArylB(OH)2
Alkyl#N/A#N/A#N/A60K2CO3DMF#N/A#N/A#N/ACsp2_ar-Csp3XBCsp2_arCsp3Csp2_ar-XCsp3-BAryl-X[Aryl]-Alkyl-B(OH)2[Alkyl]-B(OH)2#N/A#N/AIonic-CO3K+1.72.530430542.115215273.4538974810.33#REF!1.923.2525052362.5862526186.55955503#REF!#REF!XClB(O)OC1=CC=CC=C1CCC1=CC=CC=C1CC#N/AO=C([O-])[O-].[K+].[K+]#N/A
957
7/28/2022629
chem.202103643
C-H Activation
10.1002/chem.202103643
H
VinylAl(iBu)2
Arylbpy
#N/A#N/ADMAMnN-NbpyNitrogenCsp2-Csp2_arNu-HHAlCsp2Csp2_arCsp2-HCsp2_ar-AlVinyl-H[Vinyl]-Aryl-Al(iBu)2[Aryl]-Al(iBu)2Polar37.8No baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#REF!27.6402.4811865675.826321844.1537542046.96337555#REF!#REF!128H[Al](CC(C)C)CC(C)CC=CC1=CC=CC=C1C=CC1=CC=CC=C1C1(C2=NC=CC=C2)=CC=CC=N1#N/A#N/A
958
7/28/2022628
anie.201912753
C-X Activation
x10.1002/anie.201912753x
X
ArylX
AlkylNeocuproine
#N/A#N/ADMADMA#N/AbpyNitrogenCsp2_ar-Csp3XXCsp2_arCsp3Csp2_ar-XCsp3-XAryl-X[Aryl]-Alkyl-X[Alkyl]-XPolar37.8No baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XClClC1=CC=CC=C1CCC1=CC=CC=C1CCCC1=NC2=C(C=C1)C=CC3=C2N=C(C)C=C3#N/ACN(C)C(C)=O
959
7/28/2022627
jacs.9b01886
C-X Activation
x10.1021/jacs.9b01886x
X
ArylH
NR2dtbbpy
#N/A#N/ADMAN-NbpyNitrogen#N/AXHCsp2_ar#N/ACsp2_ar-X#N/AAryl-X[Aryl]-NR2-H[NR2]-H#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A1.706749553.2392069642.4729782574.96639928#REF!#N/AClHC1=CC=CC=C1#N/AC1=CC=CC=C1#N/ACC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/ACN(C)C(C)=O
960
7/28/2022616
anie.201707906
C-X Activation
x10.1002/anie.201707906x
X
ArylH
Alkyldtbbpy
#N/A#N/ADMAN-NbpyNitrogenCsp2_ar-Csp3XHCsp2_arCsp3Csp2_ar-XCsp3-HAryl-X[Aryl]-Alkyl-H[Alkyl]-H#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5ClHC1=CC=CC=C1CCC1=CC=CC=C1CCCC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/ACN(C)C(C)=O
961
7/28/2022624
ja909689t
C-X Activation
10.1021/ja909689t
X
AllylMgX
Aryl#N/A#N/A#N/A#N/A#N/A#N/ACsp3-Csp2_arXMgCsp3Csp2_arCsp3-XCsp2_ar-MgAllyl-X[Allyl]-Aryl-MgX[Aryl]-MgX#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!93.2Cl[Mg]ClCC=CC1=CC=CC=C1C=CCC1=CC=CC=C1#N/A#N/A#N/A
962
7/28/2022619
anie.202014244
C-X Activation
x10.1002/anie.202014244x
X
ArylBF3K
Benzyldtbbpy
#N/A#N/ALIClO4DMFN-NbpyNitrogen
Csp2_ar-Csp3-ring(s)
XBCsp2_arCsp3-ring(s)Csp2_ar-XCsp3-ring(s)-BAryl-X[Aryl]-Benzyl-BF3K[Benzyl]-BF3K#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#REF!XX2.2294683593.2807152032.7550917816.56810798#REF!#REF!XCl[B-](F)(F)F.[K+]C1=CC=CC=C1CC1=CC=CC=C1C1=CC=CC=C1CC1=CC=CC=C1CC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/ACN(C)C=O
963
7/28/2022619
anie.202014244
C-X Activation
x10.1002/anie.202014244x
X
AlkylBF3K
Benzyldtbpy
#N/A#N/ALIClO4DMF#N/AbpyNitrogen
Csp3-Csp3-ring(s)
XBCsp3Csp3-ring(s)Csp3-XCsp3-ring(s)-BAlkyl-X[Alkyl]-Benzyl-BF3K[Benzyl]-BF3K#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#REF!XX2.2294683593.2807152032.7550917816.56810798#REF!#REF!XCl[B-](F)(F)F.[K+]CCCC1=CC=CC=C1CCCC1=CC=CC=C1#N/ACN(C)C=O
964
7/28/2022618
jacs.0c01475
C-X Activation
x10.1021/jacs.0c01475x
X
ArylX
Alkyldtbbpy
#N/A#N/ADMAN-NbpyNitrogenCsp2_ar-Csp3XXCsp2_arCsp3Csp2_ar-XCsp3-XAryl-X[Aryl]-Alkyl-X[Alkyl]-X#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XClClC1=CC=CC=C1CCC1=CC=CC=C1CCCC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/ACN(C)C(C)=O
965
7/28/2022612
j.cclet.2022.01.077
C-X Activation
10.1016/j.cclet.2022.01.077
X
ArylX
Alkyldicyclohexyl(2',4',6'-triisopropyl-[1,1'-biphenyl]-2-yl)phosphane
#N/A#N/ADMA#N/APhosphineCsp2_ar-Csp3XXCsp2_arCsp3Csp2_ar-XCsp3-XAryl-X[Aryl]-Alkyl-X[Alkyl]-X#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XClClC1=CC=CC=C1CCC1=CC=CC=C1CC#N/ACN(C)C(C)=O
966
7/28/2022611
ja511913h
C-X Activation
x10.1021/ja511913hx
X
VinylCOOH
Alkyldtbbpy
#N/A#N/ADMSON-NbpyNitrogenCsp2-Csp3XCsp2Csp2Csp3Csp2-XCsp3-Csp2Vinyl-X[Vinyl]-Alkyl-COOH[Alkyl]-COOH#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XClC(=O)OC=CCCC=CCCCC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C#N/ACS(=O)C
967
7/28/2022607
nature14875
C-X Activation
x10.1038/nature14875x
X
ArylH
Csp3-(Aryl)(OR)dtbbpy
#N/A#N/AK2CO3N-NbpyNitrogen
Csp2_ar-Csp3-ring(s)
XHCsp2_arCsp3-ring(s)Csp2_ar-XCsp3-ring(s)-HAryl-X[Aryl]-Csp3-(Aryl)(OR)-H[Csp3-(Aryl)(OR)]-H#N/A#N/AIonic-CO3K+1.72.530430542.115215273.4538974810.33#REF!#N/A#N/A1.706749553.2392069642.4729782574.96639928#REF!#REF!#N/AClHC1=CC=CC=C1C(O)C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C(O)CC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)CO=C([O-])[O-].[K+].[K+]#N/A
968
7/28/2022606
acscatal.5b02204
C-X Activation
x10.1021/acscatal.5b02204x
x
ArylCOOH
Alkylbpy
#N/A#N/AN-NbpyNitrogenCsp2_ar-Csp3XCsp2Csp2_arCsp3Csp2_ar-XCsp3-Csp2Aryl-X[Aryl]-Alkyl-COOH[Alkyl]-COOH#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XClC(=O)OC1=CC=CC=C1CCC1=CC=CC=C1CCC1(C2=NC=CC=C2)=CC=CC=N1#N/A#N/A
969
7/28/2022609
jacs.5b13211
C-X Activation
x10.1021/jacs.5b13211x
x
ArylCOOH
Aryl(E)-2-(4-(4-(tert-butyl)phenyl)-4,5-dihydrooxazol-2-yl)-2-(4-(4-(tert-butyl)phenyl)oxazolidin-2-ylidene)acetonitrile
#N/A#N/A#N/ANitrogen
Csp2_ar-Csp2_ar
XCsp2Csp2_arCsp2_arCsp2_ar-XCsp2_ar-Csp2Aryl-X[Aryl]-Aryl-COOH[Aryl]-COOH#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XClC(=O)OC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1CC(C)(C)C(C=C1)=CC=C1C(N/2)COC2=C(C3=NC(C4=CC=C(C(C)(C)C)C=C4)CO3)/C#N#N/A#N/A
970
582
William
jo049658b
C-X Activation
10.1021/jo049658b
X
NR2H
Aryl#N/A#N/A#N/A110K3PO4NaItoluene#N/A#N/A#N/A#N/AXH#N/ACsp2_ar#N/ACsp2_ar-HNR2-X[NR2]-Aryl-H[Aryl]-H#N/A#N/AIonic-PO4K+2.244780372.9696246982.6072025343.5700586912.37#REF!10.401.706749553.2392069642.4729782574.96639928#N/A#REF!128.5ClH#N/AC1=CC=CC=C1#N/AC1=CC=CC=C1#N/A[O-]P(=O)([O-])[O-].[K+].[K+].[K+]Cc1ccccc1
971
583
William
ol0171867
C-X Activation
10.1021/ol0171867
X
N(H)ArylH
Aryl#N/A#N/A#N/A80K3PO4#N/A#N/A#N/ANsp3-Csp2_arXHNsp3Csp2_arNsp3-XCsp2_ar-HN(H)Aryl-X[N(H)Aryl]-Aryl-H[Aryl]-H#N/A#N/AIonic-PO4K+2.244780372.9696246982.6072025343.5700586912.37#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5ClHNC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1NC1=CC=CC=C1#N/A[O-]P(=O)([O-])[O-].[K+].[K+].[K+]#N/A
972
584
William
ol0257732
C-X Activation
10.1021/ol0257732
X
AlkylH
ArylPPh3
#N/A#N/A60PPhosphine (Monodentate)PhosphineCsp3-Csp2_arXHCsp3Csp2_arCsp3-XCsp2_ar-HAlkyl-X[Alkyl]-Aryl-H[Aryl]-H#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5ClHCCC1=CC=CC=C1CCC1=CC=CC=C1P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3#N/A#N/A
973
585
William
ol035355c
C-X Activation
10.1021/ol035355c
Br
N(Alkyl)CarbonylH
AlkylN1,N2-dimethylethane-1,2-diamine
#N/A#N/A110K2CO3toluene#N/ANsp3-Csp3XHNsp3Csp3Nsp3-XCsp3-HN(Alkyl)Carbonyl-X[N(Alkyl)Carbonyl]-Alkyl-H[Alkyl]-H#N/A#N/AIonic-CO3K+1.72.530430542.115215273.4538974810.33#REF!4.4401.706749553.2392069642.4729782574.96639928#REF!#REF!6.5BrHN(C)(C(=O)C)CCCC(=O)N(C)CCCNCCNCO=C([O-])[O-].[K+].[K+]Cc1ccccc1
974
586
William
S0040-4039(99)00291-9
C-X Activation
10.1016/S0040-4039(99)00291-9
X
NR2H
Aryl#N/A#N/A#N/A110-125Cs2CO3#N/A#N/A#N/A#N/AXH#N/ACsp2_ar#N/ACsp2_ar-HNR2-X[NR2]-Aryl-H[Aryl]-H#N/A#N/AIonic-CO3Cs+1.72.530430542.115215273.4538974810.33#REF!10.401.706749553.2392069642.4729782574.96639928#N/A#REF!128.5ClH#N/AC1=CC=CC=C1#N/AC1=CC=CC=C1#N/AC(=O)([O-])[O-].[Cs+].[Cs+]#N/A
975
587
William
ol025548k
C-X Activation
10.1021/ol025548k
X
ORH
Aryl#N/A#N/A#N/A110Cs2CO3toluene#N/A#N/A#N/AOsp2-Csp2_arXHOsp2Csp2_arOsp2-XCsp2_ar-HOR-X[OR]-Aryl-H[Aryl]-H#N/A#N/AIonic-CO3Cs+1.72.530430542.115215273.4538974810.33#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5ClHOC1=CC=CC=C1OC1=CC=CC=C1#N/AC(=O)([O-])[O-].[Cs+].[Cs+]Cc1ccccc1
976
588
William
anie.200603173
C-X Activation
10.1002/anie.200603173
X
N(H)ArylH
Aryl#N/A#N/A#N/A90Cs2CO3DMF#N/A#N/A#N/ANsp3-Csp2_arXHNsp3Csp2_arNsp3-XCsp2_ar-HN(H)Aryl-X[N(H)Aryl]-Aryl-H[Aryl]-H#N/A#N/AIonic-CO3Cs+1.72.530430542.115215273.4538974810.33#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5ClHNC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1NC1=CC=CC=C1#N/AC(=O)([O-])[O-].[Cs+].[Cs+]CN(C)C=O
977
589
William
ol005832g
C-X Activation
10.1021/ol005832g
H
AlkylB(OH)2
Aryl#N/A#N/A#N/ADMFpyridine#N/A#N/A#N/ACsp3-Csp2_arNu-HHBCsp3Csp2_arCsp3-HCsp2_ar-BAlkyl-H[Alkyl]-Aryl-B(OH)2[Aryl]-B(OH)2#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6HB(O)OCCC1=CC=CC=C1CCC1=CC=CC=C1#N/A#N/ACN(C)C=O
978
590
William
ol000033j C
C-X Activation
10.1021/ol000033j C
https://sci-hub.wf/10.1021/ol000033j C
H
N(H)ArylB(OH)2
ArylTMEDA
#N/A#N/ACH2Cl2#N/AN-NNitrogenNsp3-Csp2_arNu-HHBNsp3Csp2_arNsp3-HCsp2_ar-BN(H)Aryl-H[N(H)Aryl]-Aryl-B(OH)2[Aryl]-B(OH)2#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#REF!13.5340.461.923.2525052362.5862526186.55955503#REF!#REF!107.6HB(O)ONC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1NC1=CC=CC=C1CN(C)CCN(C)C#N/AClCCl
979
591
William
jo048599z
C-X Activation
10.1021/jo048599z
X
AlkyneH
Aryl#N/A#N/A#N/AH2O#N/A#N/A#N/ACsp1-Csp2_arXHCsp1Csp2_arCsp1-XCsp2_ar-HAlkyne-X[Alkyne]-Aryl-H[Aryl]-H#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#REF!10.401.706749553.2392069642.4729782574.96639928#REF!#REF!128.5ClHC#CC1=CC=CC=C1C#CC1=CC=CC=C1#N/A#N/AO
980
593
William
ol0168216
C-X Activation
10.1021/ol0168216
X
NR2H
Aryl#N/A#N/A#N/A80Cs2CO3DMF#N/A#N/A#N/A#N/AXH#N/ACsp2_ar#N/ACsp2_ar-HNR2-X[NR2]-Aryl-H[Aryl]-H#N/A#N/AIonic-CO3Cs+1.72.530430542.115215273.4538974810.33#REF!10.401.706749553.2392069642.4729782574.96639928#N/A#REF!128.5ClH#N/AC1=CC=CC=C1#N/AC1=CC=CC=C1#N/AC(=O)([O-])[O-].[Cs+].[Cs+]CN(C)C=O
981
318
a-1467-2494
C-O Activation
10.1055/a-1467-24942021
E-NuOMe
ArylMgX
Csp3-SiIcy
#N/A#N/AtolueneNHCCarbeneCarbeneCsp2_ar-Csp3StrongOO-Csp3MgCsp2_arCsp3Csp2_ar-OCsp3-MgAryl-O[Aryl]-O-Csp3Csp3-Si-MgX[Csp3-Si]-MgX#N/A#N/ANo baseNo BaseNo baseHardO-EDG
SYNTHESIS
-0.28#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOC[Mg]ClC1=CC=CC=C1C[Si](C)(C)CC1=CC=CC=C1C[Si](C)(C)CN1(C2CCCCC2)C=CN(C3CCCCC3)[C]1#N/ACc1ccccc1
982
318
a-1467-2494
C-O Activation
10.1055/a-1467-24942021
E-NuOMe
ArylMgX
Csp3-SiIMes
#N/A#N/Atoluene#N/ACarbeneCarbeneCsp2_ar-Csp3StrongOO-Csp3MgCsp2_arCsp3Csp2_ar-OCsp3-MgAryl-O[Aryl]-O-Csp3Csp3-Si-MgX[Csp3-Si]-MgX#N/A#N/ANo baseNo BaseNo baseHardO-EDG
SYNTHESIS
-0.28#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOC[Mg]ClC1=CC=CC=C1C[Si](C)(C)CC1=CC=CC=C1C[Si](C)(C)CCC1=CC(=C(C(=C1)C)N2C=C[N+](=C2)C3=C(C=C(C=C3C)C)C)C.[Cl-]#N/ACc1ccccc1
983
319
science.abo0039
C-O Activation
x10.1126/science.abo0039x2022
E-EOTf
ArylBr
Alkylbpp
#N/A#N/ADMFN-N-NterpyNitrogenCsp2_ar-Csp3WeakOO-SO2-R'XCsp2_arCsp3Csp2_ar-OCsp3-XAryl-O[Aryl]-O-SO2-R'Alkyl-Br[Alkyl]-Br#N/A#N/ANo baseNo BaseNo baseEasyOSO2-EWGSCIENCE0.53#N/A#N/A#N/A#N/A#N/A#REF!0#REF!#REF!XOS(=O)(=O)C(F)(F)FBrC1=CC=CC=C1CCC1=CC=CC=C1CCC1(N2C=CC=N2)=NC(N3C=CC=N3)=CC=C1#N/ACN(C)C=O
984
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
985
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
986
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
987
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
988
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
989
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
990
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
991
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
992
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
993
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
994
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
995
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
996
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
997
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
998
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
999
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1000
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1001
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1002
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1003
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1004
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1005
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1006
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1007
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1008
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1009
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1010
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1011
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1012
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1013
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1014
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1015
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1016
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1017
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1018
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1019
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1020
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1021
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1022
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1023
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1024
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1025
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1026
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1027
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1028
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1029
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1030
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1031
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1032
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1033
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1034
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1035
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1036
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1037
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1038
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1039
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1040
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1041
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1042
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1043
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1044
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1045
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1046
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1047
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1048
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1049
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1050
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1051
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1052
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1053
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1054
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1055
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1056
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1057
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1058
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1059
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1060
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1061
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1062
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1063
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1064
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1065
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1066
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1067
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1068
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1069
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1070
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1071
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1072
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1073
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1074
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1075
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1076
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1077
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1078
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1079
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1080
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1081
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1082
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1083
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1084
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1085
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1086
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1087
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1088
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1089
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1090
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1091
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1092
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1093
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1094
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1095
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1096
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1097
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1098
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1099
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1100
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1101
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1102
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1103
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1104
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1105
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1106
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1107
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1108
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1109
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1110
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1111
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1112
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1113
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1114
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1115
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1116
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1117
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1118
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1119
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1120
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1121
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1122
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1123
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1124
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1125
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1126
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1127
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1128
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1129
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1130
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1131
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1132
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1133
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1134
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1135
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1136
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1137
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1138
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1139
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1140
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1141
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1142
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1143
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1144
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1145
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1146
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1147
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1148
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1149
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1150
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1151
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1152
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1153
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1154
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1155
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1156
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1157
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1158
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1159
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1160
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1161
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1162
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1163
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1164
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1165
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1166
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1167
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1168
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1169
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1170
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1171
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1172
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1173
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1174
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1175
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1176
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1177
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1178
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1179
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1180
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1181
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1182
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1183
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1184
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1185
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1186
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1187
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1188
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1189
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1190
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1191
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1192
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1193
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1194
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1195
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1196
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1197
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1198
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1199
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1200
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1201
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1202
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1203
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1204
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1205
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1206
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1207
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1208
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1209
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1210
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1211
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1212
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1213
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1214
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1215
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1216
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1217
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1218
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1219
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1220
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1221
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1222
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1223
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1224
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1225
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1226
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1227
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1228
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1229
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1230
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1231
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1232
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1233
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1234
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1235
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1236
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1237
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1238
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1239
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1240
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1241
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1242
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1243
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1244
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1245
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1246
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1247
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1248
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1249
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1250
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1251
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1252
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1253
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1254
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1255
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1256
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1257
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1258
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1259
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1260
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1261
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1262
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1263
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1264
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1265
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1266
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1267
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1268
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1269
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1270
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1271
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1272
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1273
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1274
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1275
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1276
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1277
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1278
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1279
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1280
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1281
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1282
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1283
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1284
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1285
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1286
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1287
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1288
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1289
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1290
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1291
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1292
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1293
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1294
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1295
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1296
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1297
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1298
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1299
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1300
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1301
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1302
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1303
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1304
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1305
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1306
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1307
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1308
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1309
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1310
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1311
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1312
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1313
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1314
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1315
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1316
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1317
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1318
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1319
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1320
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1321
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1322
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1323
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1324
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1325
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1326
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1327
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1328
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1329
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1330
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1331
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1332
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1333
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1334
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1335
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1336
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1337
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1338
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1339
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1340
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1341
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1342
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1343
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1344
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1345
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1346
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1347
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1348
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1349
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1350
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1351
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1352
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1353
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1354
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1355
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1356
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1357
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1358
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1359
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1360
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1361
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1362
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1363
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1364
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1365
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1366
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1367
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1368
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1369
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1370
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1371
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1372
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1373
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1374
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1375
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1376
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1377
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1378
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1379
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1380
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1381
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1382
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1383
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1384
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1385
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1386
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1387
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1388
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1389
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1390
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1391
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1392
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1393
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1394
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1395
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1396
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1397
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1398
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1399
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1400
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1401
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1402
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1403
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1404
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1405
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1406
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1407
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1408
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1409
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1410
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1411
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1412
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1413
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1414
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1415
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1416
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1417
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1418
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1419
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1420
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1421
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1422
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1423
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1424
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1425
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1426
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1427
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1428
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1429
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1430
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1431
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1432
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1433
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1434
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1435
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1436
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1437
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1438
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1439
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1440
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1441
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1442
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1443
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1444
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1445
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1446
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1447
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1448
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1449
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1450
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1451
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1452
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1453
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1454
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1455
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1456
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1457
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1458
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1459
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1460
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1461
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1462
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1463
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1464
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1465
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1466
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1467
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1468
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1469
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1470
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1471
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1472
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1473
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1474
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1475
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1476
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1477
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1478
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1479
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1480
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1481
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1482
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1483
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1484
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1485
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1486
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1487
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1488
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1489
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1490
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1491
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1492
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1493
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1494
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1495
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1496
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1497
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1498
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1499
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1500
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1501
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1502
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1503
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1504
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1505
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1506
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1507
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1508
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1509
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1510
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1511
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1512
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1513
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1514
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1515
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1516
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1517
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1518
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1519
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1520
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1521
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1522
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1523
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1524
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1525
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1526
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1527
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1528
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1529
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1530
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1531
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1532
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1533
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1534
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1535
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1536
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1537
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1538
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1539
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1540
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1541
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1542
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1543
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1544
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1545
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1546
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1547
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1548
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1549
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1550
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1551
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1552
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1553
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1554
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1555
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1556
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1557
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1558
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1559
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1560
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1561
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1562
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1563
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1564
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1565
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1566
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1567
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1568
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1569
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1570
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1571
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1572
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1573
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1574
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1575
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1576
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1577
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1578
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1579
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1580
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1581
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1582
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1583
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1584
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1585
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1586
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1587
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1588
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1589
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1590
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1591
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1592
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1593
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1594
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1595
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1596
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1597
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1598
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1599
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1600
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1601
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1602
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1603
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1604
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1605
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1606
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1607
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1608
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1609
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1610
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1611
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1612
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1613
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1614
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1615
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1616
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1617
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1618
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1619
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1620
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1621
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1622
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1623
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1624
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1625
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1626
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1627
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1628
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1629
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1630
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1631
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1632
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1633
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1634
#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A-[]-#N/A#N/ANo baseNo BaseNo base#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A#N/A
1635
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1636
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1637
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1638
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1639
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1640
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1641
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1642
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1643
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